To reduce variation of a measurement result by aligning a
mass resolution of a plurality of devices.SOLUTION: In an embodiment of a TOFMS according to the present invention, the TOFMS includes a measurement part (1) containing: each flight
magnetic field formation part that forms a
magnetic field for flying an
ion into a
flight space (153, 154, and 155); and each
ion acceleration part (151 and 152) that accelerates the
ion as a measurement object and feeds it into the
flight space. The TOFMS comprises: a control part (3) that repeatedly executes a measurement to a predetermined sample while changing a
voltage applied to an
electrode contained in the measurement part, and operates the measurement part so as to calculates a
mass resolution on the basis of the measurement result in each measurement; an approximate calculation part (3) that calculates an approximate for approximating a relation of them on the basis of data of a plurality of pairs of an application
voltage to the
electrode and a resolution corresponded to them, obtained under a control by the control part; and a
voltage determination part (3) that calculates a voltage value corresponded to a target value of the
mass resolution by using the approximate, and determines the voltage value as an application voltage to the
electrode in the device.SELECTED DRAWING: Figure 1