The PFAS capturing
system 10 comprises a structuring reactor 20 including a reaction tank 21 and a pressurized floating separation apparatus 30 including a circulation device 40, wherein into a
contaminated water with a PFAS-containing aqueous mixture stored in the reaction tank 21 of the structuring reactor 20, structural agents 1 and 2 are fed from the feeding section 22, the structural agent 1 is including a water-soluble cationic polymeric flocculant (A) capable of forming a high
order structure containing high molecular weight carbon chains as a main structural agent, the structural agent 2 is including a water-soluble cationic
polymer flocculant (B) as a main structural agent with a smaller cationic value than the water-soluble cationic
polymer flocculant (A) which contains a positive charge and has a higher cationic value than the water-soluble cationic polymeric flocculant (A), which including at least one of an inorganic agent containing polyiron,
ferric chloride,
ferrous sulfate,
ferric sulfate,
polyaluminum chloride,
sulfate band, and
zinc chloride. By feeding the structural agent 1, a structure 1 is formed in
contaminated water, and PFAS with anionic properties are adsorbed on the structure 1, and further, on the PFAS adsorbed on the structure 1, made of iron cation,
aluminum cation etc., with hydrophobic carbon chains is formed by the structural agent 2, PFAS is held stably in a sandwich-like state between the structure 1 and the structure 2 so that it can be separated from the water. The PFAS is then formed in a pressure floating separation tank 32 of the pressurized floating separation apparatus 30, where a jet of pressurized ultrafine bubble containing water is formed in the
contaminated water, and the contaminated water is circulated in the tank 32, and the structure 1 and the captured PFAS are made to float by the ultrafine bubbles and taken out as flotation scum, and the rest is made into PFAS reduced water, thus enabling the separation and capture of 30% or more of PFAS that are difficult to capture in the contaminated water.