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132results about How to "In situ repair" patented technology

Multivariate controllable synthesis method of BiOCl photocatalyst

The invention discloses a multivariate controllable synthesis method of a BiOCl photocatalyst, and belongs to the technical field of photocatalytic water treatment of environmental chemical engineering. The multivariate controllable synthesis method is characterized by comprising the following steps: adding BiCl3 with proper concentration to diethylene glycol or a mixed solvent of diethylene glycol and water; adding a urea precipitation agent, directly transferring sol or transferring sol subjected to ultrasonic pretreatment into a Teflon high-pressure reaction kettle to carry out solvothermal reaction at certain temperature to generate sediments after evenly mixing; and baking the sediments at 80 DEG C after washing with water and ethanol, so as to obtain BiOCl photocatalyst powder with different morphologies. The synthesis method disclosed by the invention has the characteristics that the preparation cycle of BiOCl is short, use of a surfactant is avoided, grains with controllable crystal faces (110 and 102) and controllable morphologies (two-dimensional flakes, three-dimensional flowers or spheres) can be conveniently achieved by controlling and ultrasonic pretreatment on the solvent. The catalyst is applied to photocatalytic degradation of carbamazepine medicine wastewater, displays the photocatalytic activity superior to that of TiO2(P25) under ultraviolet light and simulated sunlight, and has a practical application prospect.
Owner:TAIYUAN UNIV OF TECH

Method for increasing speed of oxidative degradation of organic pollutant in soil

The invention relates to the technical field of pollution repairing and treatment of organic pollutants in soil, and especially discloses a chemically repairing method used in soil polluted by nitrobenzene, nitrochlorobenzene and the like. By means of the method in which the nitrobenzene, the nitrochlorobenzene and the like are firstly reduced into phenylamine which is easy to oxidatively degrade with zero-valent iron and finally the degraded product is oxidized to generate carbon dioxide and water, the soil, which is polluted by the organic pollutants including the nitrobenzene and the like, is completely repaired and removal efficiency of the organic pollutants is increased. The method can achieve a removal rate of the nitrochlorobenzene being 88.3-95.8%, wherein the nitrochlorobenzene is a difficultly-degraded organic substance. The method can overcome problems of low removal efficiency, high medicine cost and troublesome follow-up treatment during removal of the nitrobenzene-series organic pollutants in the soil with Fenton reagents, potassium persulfate, sodium permanganate and the like which are common in the prior art. By means of an indirectly oxidative degradation in which reduction is carried out firstly and oxidization is carried out after that, usage amount of an oxidizing agent can be reduced and the removal rate of the nitrobenzene-series organic pollutants can be increased. Meanwhile, the method is simple in operation and can avoid secondary pollution to environment by the oxidizing agent. The method can effectively achieve in-situ repairing of polluted soil and is especially suitable for complete repair of the soil severely polluted by the organic pollutants in local factory removal.
Owner:江苏迈克环境工程有限公司

Preparation method of floating embedding bacterium agents for in-situ remediation of oil polluted water

The invention relates to a preparation method of floating embedding bacterium agents for in-situ remediation of oil polluted water, specifically relating to a technology for fixing oil degradation bacteria by using expanded graphite, sodium alginate and calcium chloride, absorbing and degrading to purify the petroleum polluted water. The preparation method of the floating embedding bacterium agents comprises the following steps: adding petroleum degrading bacteria liquid into sodium alginate sol containing the expanded graphite, mixing uniformly, dropping into calcium chloride solution and cross-linking overnight at 4 degrees centigrade to obtain the floating embedding bacterium agents fixing hydrocarbon degradation bacteria. The floating embedding bacterium agents prepared by the preparation method has the advantages of high mechanical strength, good floatability and mass transfer performance and high degradation efficiency; the floating embedding bacterium agents can be directly put onto the surface of the petroleum polluted water; the embedding bacterium agents can float on an oil-water interface for long term so as to ensure effective contact between the bacterium agent and the petroleum; the embedding technology increases the concentration of microorganisms, prevents the bacteria influencing by the water using environment, effectively improves the degradation efficiency, recovers and recycles conveniently and has no secondary pollution risk.
Owner:TONGJI UNIV

Drill pipe device for mixed injection of various medicaments

The invention discloses a drill pipe device for mixed injection of various medicaments. The drill pipe device comprises an outer pipe, an inner pipe and a drill bit. Both the outer pipe and the inner pipe are of hollow structure and sleeved together, and a gap between the outer pipe and the inner pipe forms a first cavity. The upper portion of the outer pipe is provided with a first medicament connecting hole which is communicated with the first cavity. The inner wall of the bottom of the outer pipe is provided with a step, and the first cavity is closed by the step and the outer wall of the inner pipe together. The upper portion of the inner pipe is provided with a second medicament connecting hole which is communicated with a cavity of the inner pipe. The drill bit is connected with the outer pipe, and a second cavity is formed inside the drill bit and is communicated with the cavity of the inner pipe. Jet holes communicated with the outside are respectively formed in the side walls of the first cavity and the second cavity. The drill pipe device for injection in situ of soil and underground water realizes underground mixing of various medicaments, reduces interaction consumption before the medicaments contact with pollutants, and improves effect of in-situ repair.
Owner:NANJING YIDESI ENVIRONMENTAL SCI & TECH CO LTD

Method for preparing solid repair agent by using protein peptide and repairing soil by using soil repair agent

The invention provides a method for preparing a solid repair agent by using protein peptide and repairing soil by using the soil repair agent. The method comprises the steps of: preparing the protein peptide prepared by using a method in the patent ZL200610019063.7 or the protein peptide prepared by using protein-containing waste according to the following formula in site, wherein the formula comprises 1) 5-10 percent of protein peptide, 2-6 percent of molasses and the balance of water; 2) 5-10 percent of protein peptide, 0.5-1.0 percent of laccase crude product, 1-2 percent of laccase strain and the balance of water; and 3), 5-10 percent of protein peptide and the balance of water. The formula 1 is suitable for the soil in which plants are planted and which is seriously polluted by heavy metal ions; the formula 2 is suitable for the soil in which plants are planted and which is seriously polluted by heavy metal ions and is polluted by polycyclic aromatic hydrocarbon; and the formula 3 is suitable for directly acting on conventional polluted soil with light pollution. The protein peptide soil repair agent can be used as a nutrient in which a microorganism or indigenous microorganism for promoting the enrichment of the plants to the heavy metal ions, so that the polluted soil is repaired. The soil repair agent has low price, high efficiency and good effect.
Owner:HUBEI UNIV

Method of using native function microflora to in-situ purify ground water polluted by uranium

The invention relates to a method of using native function microflora to in-situ purify ground water polluted by uranium. The method translates transferable hexavalent uranium into nontransferable uranous uranium in the ground water through nitrate reducing bacteria flora, ferric iron reducing bacteria flora and sulfate reducing bacteria flora which are formed under the anaerobic condition by microorganism, and therefore the purpose of purifying the ground water polluted by the uranium is achieved. The specific implementation method comprises: (1) adjusting a potential of hydrogen (Ph) value of the ground water polluted by the uranium; (2) activating the microorganism in sediments; (3) regulating and controlling variation of the microflora, accelerating evolution of the nitrate reducing bacteria flora, the ferric iron reducing bacteria flora and the sulfate reducing bacteria flora by means of adding a carbon source, regulating oxidation reduction potential of the water polluted by the uranium and the like; (4) continuously regulating and controlling the microbial flora until uranium concentration in the ground water polluted by the uranium is reduced below the national emission standard and the purpose of purifying the groundwater polluted by the uranium is achieved. The method of using the native function microflora to in-situ purify the ground water polluted by the uranium solves in-situ purifying problem of the ground water polluted by the uranium, and has the advantages of being high in purifying efficient, short in period, simple in equipment, short in process procedure, low in purifying cost, strong in operability, free of secondary pollution, good in purifying effect and the like.
Owner:NANHUA UNIV

Heavy metal contaminated soil remediation device

The invention discloses a heavy metal contaminated soil remediation device which comprises a storage barrel, a conveyor belt, a treatment seat, a connecting plate and a bucket, wherein two pairs of first traveling wheels are symmetrically arranged on two sides of the bottom end of an outer side wall of the treatment seat; and the connecting plate is welded on one side of the bottom end of the outer side wall of the treatment seat. A pulley matched with a guide seat is arranged on a connecting rod at one end of the screening bucket, and a movable sleeve is arranged on the outer side of a guiderod in a sleeving manner on the outer side wall of the screening bucket. On one hand, by utilizing guide of a bevel end of the guide seat, the screening bucket is matched with a reset spring at the other end of the screening bucket in a process of driving the screening bucket to rotate by a motor, so that the screening bucket can sway from side to side in the rotating and screening process, and the screening efficiency and the screening effect are improved; on the other hand, a second magnetic block having the same magnetism as a first magnetic block is arranged on the top of the movable sleeve, so that the movable sleeve enabling the screening bucket to rotate to a position just under the first magnetic block has a vibratory cleaning effect on the screening bucket, and blockage of sieve pores is avoided.
Owner:ANHUI LANDING ENVIRONMENTAL PROTECTION ENERGY TECH

Multifunctional bio-organic fertilizer and preparation method thereof

The invention discloses a multifunctional bio-organic fertilizer and a preparation method thereof, and relates to the technical field of agricultural fertilizers. The multifunctional bio-organic fertilizer is prepared from the following raw materials in parts by weight: 40-60 parts of forestry and agricultural residues, 10-16 parts of active humic acid, 5-15 parts of degreased tea-seed pancake, 0.5-1.5 parts of expanded vermiculite, 0.2-0.8 part of abscisic acid, 0.2-0.8 part of zymophyte, 0.2-0.8 part of beneficial bacterium, 0.2-0.8 part of degrading bacteria, 5-9 parts of urea, 8-12 parts of calcium magnesium phosphate fertilizer, 4-8 parts of potassium sulfate, and 0.5-1.5 parts of medium and trace element. The multifunctional bio-organic fertilizer has the characteristics that the nutritional elements for plant growing are contained; the organic substances are rich; in addition, the contaminated oil can be remediated; the soil structure can be activated; the multifunctional bio-organic fertilizer is applicable to the planting of crops such as rice of southern China, vegetables, watermelon, tobacco, fresh ginger, rape and tea, fruits such as naval orange, grapefruit and pear, garden nursery stock and flowers.
Owner:HUNAN ZHONGKE AGRI

Combined contaminated soil restoration system and using method thereof

The invention relates to a combined contaminated soil restoration system and a using method thereof. According to the technical scheme, an anode infiltration mode reaction wall and an anode groove (21) are sequentially arranged on the left side of to-be-restored combined contaminated soil (19) from inside to outside, and a cathode infiltration mode reaction wall and a cathode groove (17) are sequentially arranged on the right side of the to-be-restored combined contaminated soil (19) from inside to outside. The anode infiltration mode reaction wall is composed of a first inorganic permeable membrane (4), a second inorganic permeable membrane (5) and geotechnical cloth (6); and the cathode infiltration mode reaction wall is composed of a third inorganic permeable membrane (11), a fourth inorganic permeable membrane (12) and geotechnical cloth (10). An anode laccase/ABTS mediator system (20) is added into the anode infiltration mode reaction wall, and a cathode laccase/ABTS mediator system (18) is added into the cathode infiltration mode reaction wall; and the voltage of a constant-voltage DC source (7) is 0.5 V/cm<2> to 1.5 V/cm<2>. The combined contaminated soil restoration system is environment-friendly, simple in structure, convenient to operate, small in original soil disturbance, and capable of achieving heavy metal and PAHs degradation and migration at the same time.
Owner:WUHAN UNIV OF SCI & TECH

Force-responding polymer foam composite

The invention discloses a force-responding polymer foam composite material, which is characterized by comprising polymer foam particles with skins and a force-responding polymer, wherein a polymer chain of the force-responding polymer contains at least one force-sensitive group, and/or at least one force-responding component is blended in the polymer; under the action of mechanical force, a force-sensitive group and/or a force response component in the force response polymer are/is subjected to chemical and/or physical change to realize force response, wherein the polymer foam particle with the skin is prepared from an expandable polymer (composition) or an expandable polymer precursor (composition) through direct foaming and/or 3D printing, and has a skin structure; the coated polymer foam particles are compounded with the force-responding polymer and other optional components to form the composite material. The composite material has the characteristics of low density, lightness, heat insulation, sound insulation, buffering, shock absorption and force response, and can be widely applied to manufacturing of packaging materials, building materials, impact-resistant protective materials, shock absorption materials, buffering materials, sound attenuation materials, heat preservation materials, shape memory materials, electronic and electrical appliance materials, medical suppliesand the like.
Owner:厦门天策材料科技有限公司

Built-in biochemical-ecological system based on in-river rainwater runoff purification river bank

The invention discloses a built-in biochemical-ecological system based on an in-river rainwater runoff purification river bank. The built-in biochemical-ecological system is formed by five parts of a rainwater desanding well, a rainwater runoff rubble filter dam, an anaerobic organism filter dam, a bidirectional flow wetland purification system and a rubble slope protection in-river water quality repairing system. The built-in biochemical-ecological system disclosed by the invention has the advantages of no energy consumption, ecologicalization, landscaping, and efficient rainwater runoff purification, can guarantee the in-river water quality, and is a necessary means for realizing long effectiveness of river governance; meanwhile, the built-in biochemical-ecological system has a function of repairing a water body, realize rainwater containment, and is an effective measure for building a sponge type city at present; the built-in biochemical-ecological system is positioned at the inner part and the upper part of the river bank, so that the land resource needs not to be additionally occupied, and flood discharging is not affected as the hydraulic radius of a river way is not reduced; meanwhile, a landscape effect of the river way can be increased, so that many purposes can be achieved at one stroke.
Owner:HARBIN INST OF TECH

Method of constructing ecological revetment for intensively intercepting and clearing non-point pollution based on organisms

The invention relates to a method of constructing an ecological revetment for intensively intercepting and clearing non-point pollution based on organisms, which comprises the steps of investigating hydrologic conditions of a river, determining non-point pollution load and hydraulic retention time of a riparian zone in a unit length, analyzing characteristics of the non-point pollution along the river, screening a high-efficiency bacterium which can efficiently remove the non-point pollution or constructing gene engineering bacteria capable of removing nondegradable organic pollutants, constructing hollow hexahedral ecological revetment members, and growing plants in the members, thereby constructing the ecological revetment. Compared with the prior art, with the adoption of the method, the non-point pollution, particularly the nondegradable organic pollutants, can be removed effectively, the river pollution load can be decreased, potential ecological risks of the non-point pollution to a river ecosystem are reduced, and local raw materials are utilized to improve the environmental compatibility of the members, so that good habitat conditions are provided for the growth of microbial communities and vegetations at the riparian zone, and the mechanical stability of the riparian zone is improved.
Owner:TONGJI UNIV

Multifunctional nitrogen and phosphorus removing agent as well as preparation method and application thereof

The invention discloses a multifunctional nitrogen and phosphorus removing agent as well as a preparation method and an application thereof. The preparation method of the multifunctional nitrogen and phosphorus removing agent comprises steps as follows: nano Fe3O4 is prepared from ferric chloride and ferrous sulfate with a coprecipitation method, an inorganic polymeric flocculant is deposited on the surface of nano Fe3O4 with a deposition process or an organic polymeric flocculant is deposited on the surface of nano Fe3O4 with an in-situ polymerization method, a nano Fe3O4/polymeric flocculant composite material is obtained and supported with microbial strains, and the multifunctional nitrogen and phosphorus removing agent is obtained. The agent has quite strong capacity of molecular bonding capture, flocculating settling, biodegradation and adsorption, can synergistically remove nitrogen and phosphorus compounds, organic matter and heavy metal such as Pb(II), Cd(II), Mn(II), Cr(III) and the like in a water body, is low in sludge yield, can rapidly realize solid-liquid separation under the action of external magnetic field force without secondary pollution, is environment-friendly and has good application prospect.
Owner:AEROSPACE KAITIAN ENVIRONMENTAL TECH CO LTD

Surface water protection and remediation floating bioreactor and using method thereof

The invention relates to a water protection and remediation technique, in particular to a surface water protection and remediation floating bioreactor. In a vertical tubular barrel (2), a porous material serves as a carrier for a biomembrane (4); the center of the upper part of the barrel (2) is communicated with a vertically upward water outlet pipe (1), a water inlet (6) is formed at the bottomof the barrel (2), and the water inlet (6) is connected with a submersible pump (5); and a plurality of buoys (3) are arranged on the outside of the barrel (2). The using method of the bioreactor comprises: allowing solution containing microbes to be absorbed on the surface of the porous material to form the biomembrane (4); continuously delivering water to the reactor by the submersible pump (5)and allowing the water to flow by the surface of the biomembrane (4) to purify the water; and the outlet end of the water outlet pipe (1) is designed to be in a spring or waterfall mode. In the invention, the water purification and remediation speed is high, and the water purification and remediation quality is high; the bioreactor can float on water surface and can move and float in a larger water area to perform water remediation, the pertinence of the bioreactor is high, the effect is desirable, the overall remediation speed is high, and the bioreactor can be designed with a landscape enjoying and water purification combined structure.
Owner:SHANGHAI NORMAL UNIVERSITY

Method for repairing PAHs-polluted soil by enhancing electrodynamics through surface active agent

InactiveCN106111688AEnhanced Solubility and Migration EfficiencyImprove degradation rateContaminated soil reclamationPhysicsSurface-active agents
The invention relates to a method for repairing PAHs-polluted soil by enhancing the electrodynamics through a surface active agent. The method is characterized by comprising the steps that a work shed is built above the PAHs-polluted soil (11) to be repaired, and the PAHs-polluted soil (11) to be repaired is loosened mechanically; a surface active agent solution is sprayed to the surface of the loosened soil with the spraying amount being 10-100 L/m<2>; an anode chamber (13) and a cathode chamber (9) are symmetrically arranged on the two sides of the PAHs-polluted soil (11) to be repaired, an anode buffer solution flows circularly between the anode chamber (13) and an anode buffer pool (2), and a cathode buffer solution flows circularly between the cathode chamber (9) and a cathode buffer pool (5); the voltage gradient of a constant-voltage direct-current power source (3) is 0.1-1 V/cm; and on the 1st-3rd day of the circulation flowing process, 10-100 L of a laccase solution is sprayed to the surface of each square meter of the PAHs-polluted soil (11) to be repaired at a time. The method has the characteristics of being simple in repairing system, capable of achieving in-situ repairing, environmentally friendly and safe, and migration and degradation of pollutants in the PAHs-polluted soil can be achieved simultaneously.
Owner:WUHAN UNIV OF SCI & TECH
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