311 results about "Diammonium phosphate" patented technology

A forest fire retardant composition contains a retardant compound that includes a phosphate salt. The phosphate salt may include diammonium phosphate, diammonium orthophosphate, monoammonium phosphate, monoammonium orthophosphate, monosodium phosphate, disodium phosphate, disodium phosphate hydrate, sodium ammonium phosphate, sodium ammonium phosphate hydrate, sodium tripolyphosphate, trisodium phosphate, or dipotassium phosphate, and combinations thereof. The forest fire retardant composition may include an ammonium source. The composition may be in the form of a dry concentrate, a liquid concentrate, or a final diluted product. The final diluted product is effective in suppressing, retarding, and controlling forest fires while exhibiting corrosion resistance and low toxicity.

A forest fire retardant composition contains a retardant compound that includes a phosphate salt. The phosphate salt may include diammonium phosphate, diammonium orthophosphate, monoammonium phosphate, monoammonium orthophosphate, monosodium phosphate, disodium phosphate, disodium phosphate hydrate, sodium ammonium phosphate, sodium ammonium phosphate hydrate, sodium tripolyphosphate, trisodium phosphate, or dipotassium phosphate, and combinations thereof. The forest fire retardant composition may include an ammonium source. The composition may be in the form of a dry concentrate, a liquid concentrate, or a final diluted product. The final diluted product is effective in suppressing, retarding, and controlling forest fires while exhibiting corrosion resistance and low toxicity.

The invention discloses low-alkali solid waste cementing material-based plant-growing concrete and a preparation method thereof. The vegetation concrete comprises a base layer framework and a surface layer material laid on the framework. Wherein the base layer framework is prepared from the following raw material components in parts by weight: 160 to 200 parts of low-alkali solid waste cement, 15 to 25 parts of phosphogypsum, 1380 to 2100 parts of mineralized concrete recycled aggregate, 62 to 102 parts of mineral admixture and 60 to 90 parts of mixing water. The surface layer material comprises the following raw material components: 1-5% of sodium alginate, 1-10% of calcium superphosphate, 1-10% of urea and the balance of soil. The mineralized concrete recycled aggregate is prepared by the following steps: soaking the concrete recycled aggregate in a diammonium hydrogen phosphate solution, and separating out the aggregate after soaking is completed, thereby obtaining the mineralized concrete recycled aggregate. According to the plant-growing concrete, alkalinity in concrete pores can be remarkably reduced, and the plant-growing concrete has stable later strength and good plant germination rate.

The invention provides a fermentation medium for efficiently producing lipopeptide by bacillus subtilis as well as application and a method of the fermentation medium. Each liter of the fermentation medium comprises 20-60g of a carbon source; 5-10 g of a nitrogen source; 1-5g of corn steep liquor dry powder; 1 to 5g of monopotassium phosphate; 1 to 5g of disodium hydrogen phosphate; 0.1 to 0.5 g of magnesium sulfate; 5 to 10 mg of calcium chloride; 5 to 10 mg of manganese sulfate; 5 to 10 mg of ferrous sulfate; and vegetable oil with a volume fraction of 1-5%. The carbon source is selected from at least one of glucose, maltodextrin and brown sugar; the nitrogen source is selected from at least one of diammonium hydrogen phosphate, sodium nitrate and urea; the vegetable oil is selected from at least one of soybean oil and corn oil. Bacillus subtilis with the volume fraction of 1-5% is inoculated into a fermentation culture medium for fermentation and fed-batch culture, and the yield of lipopeptide reaches 48.58 g / L. The method improves the lipopeptide production capability of the bacillus subtilis while eliminating foam, and is suitable for large-scale production and application.

The invention provides a method for recycling a waste lithium iron phosphate battery positive electrode material based on organic solvent soaking. The method comprises the following steps: mixing waste lithium iron phosphate positive electrode material powder and a crown ether chelating type co-dissolving agent to obtain a leaching solution; hydrogen peroxide is added into the leachate, the pH is adjusted, a diammonium hydrogen phosphate solution is added, and iron phosphate and filtrate containing lithium ions are obtained; adding sodium carbonate into the filtrate containing lithium ions, and adjusting the pH value to obtain lithium carbonate; mixing the iron phosphate with a phosphoric acid solution to obtain purified iron phosphate; and mixing the purified iron phosphate, lithium carbonate and acetylene black to obtain the regenerated lithium iron phosphate positive electrode material. According to the method for recycling the positive electrode material of the waste lithium iron phosphate battery based on soaking of the organic solvent, the leaching rate of the lithium element is effectively increased, the selectivity to other metal ions is low, and the regenerated positive electrode material of the lithium iron phosphate battery has relatively high discharge capacity and good cycling stability.

The invention relates to the technical field of fertilizers, and discloses a slow-release coated fertilizer and a preparation method thereof. Comprising the following raw materials in parts by weight: 57 to 77.6 parts of urea, 14.25 to 24.25 parts of diammonium phosphate, 0 to 5 parts of calcium superphosphate, 4.75 to 14.55 parts of potassium chloride, 0.03 to 0.2 part of chitosan, 0.0075 to 0.05 part of nano silicon dioxide, 0.001 to 0.015 part of glutaraldehyde, 2.96 to 4.94 parts of deionized water, 0.01 to 0.1 part of bacillus subtilis, 0.05 to 0.2 part of mesoporous silicon dioxide loaded nano selenium and 0.5 to 1 part of potassium fulvate. Chitosan, nano silicon dioxide and glutaraldehyde are matched with one another, and chitosan has pH responsiveness, so that the problems that a coating layer of a traditional slow-release fertilizer is prone to being affected by the environment and broken in advance, nutrients are rapidly released, and the slow-release effect is reduced are solved.

The invention discloses a decay-promoting and carbon-retaining agent and a preparation method, application and a verification method thereof. The decay-promoting and carbon-retaining agent comprises a complex microbial inoculant and a nutrient preparation, the complex microbial inoculant comprises the following substances in parts by weight: 2 parts of aspergillus oryzae, 4 parts of saccharomyces cerevisiae, 3 parts of bacillus subtilis, 2 parts of lactic acid bacteria, 4 parts of Koxime saccharomycetes, 3 parts of acetobacter aceti, 4 parts of aspergillus candidus, 1 part of deuteromycetes and 1 part of arthrobacter; the nutrient preparation comprises the following substances in parts by weight: 5 parts of urea, 2 parts of diammonium phosphate and 1.3 parts of potassium sulfate. According to the method, the method for verifying the effect of mixed application of the straw and the decay-promoting and carbon-retaining agent to the soil is constructed, and the 13C isotope tracing technology is combined to verify the SOC immobilization effect of the decay-promoting and carbon-retaining agent on the soil with different textures, so that the situation that the decay-promoting and carbon-retaining agent with different components can achieve more effective SOC immobilization on the soil with the different textures is obtained, and straw resources are fully utilized.

The present invention discloses a livestock and poultry manure biochar-based fertilizer, comprising the following raw materials in parts by weight: 10-42% of dilute protein solution and collagenase-modified livestock and poultry manure biochar, 20-40% of urea, 7-25% of diammonium phosphate, 7-24% of potassium chloride or potassium sulfate, 0.5-1% of modified starch, and 6-23% of bentonite. The livestock and poultry manure is selected from one of chicken manure, cow manure, and pig manure. After the biochar is modified with collagenase, the surface of the biochar has more phenolic hydroxyl groups, carboxyl groups, aldehyde groups, and hydroxyl functional groups, which are effective for NH4 + , PO4 3‑ , K + , has a stronger adsorption effect, collagenase modification makes the protein distribution more uniform, and the generated groups form a stable chemical bond with the biochar surface: it improves the dispersibility of the modified biochar in aqueous solution and reduces agglomeration; it has better chemical stability in acidic and alkaline environments.

The invention relates to the field of photovoltaic cells, and particularly discloses low-temperature cured copper paste and a preparation method and application thereof. The copper paste is prepared from the following raw material components in parts by weight: 85 to 95 parts of copper powder, 2 to 8 parts of a carrier, 2 to 5 parts of a solvent, 0.1 to 3 parts of a curing agent, 0.01 to 0.05 part of an accelerant, 0.5 to 1.5 parts of zinc borate, 0.1 to 0.5 part of nickel nitrate, 0.05 to 0.15 part of ethylenediamine, 0.05 to 0.15 part of diammonium hydrogen phosphate and 0.1 to 0.3 part of citric acid, wherein the purity of the copper powder is 99%-99.9%. The preparation method of the low-temperature cured copper paste comprises the following steps: respectively adding the curing agent, the accelerant, the solvent, the zinc borate, the nickel nitrate, the ethylenediamine, the diammonium hydrogen phosphate, the citric acid and other raw materials into the carrier, uniformly stirring and mixing, then adding the copper powder, mixing and stirring, grinding, and stirring to obtain the low-temperature cured copper paste.

The invention provides a method for preparing a biological organic fertilizer through plant straw fermentation, and belongs to the technical field of organic fertilizers. The method comprises the steps of plant straw pretreatment, fermentation solid preparation, bacteriostatic active ingredient preparation, functional additive preparation and fermentation. The fermentation comprises the following steps: stacking pretreated plant straws, fermentation solids and a functional additive for fermentation, carrying out first turning when the temperature in a pile reaches 52-56 DEG C, turning once every 18-21 hours, stopping turning after turning twice, standing until the temperature in the pile is reduced to 30-34 DEG C, adding fulvic acid, diammonium phosphate, ammonium chloride, calcium superphosphate and magnesium sulfate, uniformly mixing, and fermenting again, turning the pile once every 15-17h, and after turning the pile twice in total, finishing fermentation, and granulating and drying to obtain the biological organic fertilizer. The biological organic fertilizer prepared by the method disclosed by the invention is low in harmful pathogen content, short in fermentation period, stable in effect and excellent in application effect.

The preparation method comprises the following steps: shredding a light fibrous plant raw material which is difficult to process to 1-5mm, adding a certain amount of lignin, fully mixing with diammonium hydrogen phosphate or ammonium dihydrogen phosphate, carrying out hot press molding at 130-190 DEG C by using a pelletizer to prepare heavy particles with the particle size of 8-10mm, and carrying out high-temperature sintering to obtain the columnar activated carbon for desulfurization and denitrification of the fibrous plant raw material, thereby obtaining the columnar activated carbon for desulfurization and denitrification of the fibrous plant raw material and the columnar activated carbon for desulfurization and denitrification of the fibrous plant raw material. Heating the heavy particles to 400-700 DEG C in a rotary furnace, carbonizing for 1-3 hours, introducing a mixed gas of water vapor and air, and carrying out segmented activation at 850-950 DEG C-1000 DEG C to prepare high-quality activated carbon with the iodine value of more than or equal to 950 mg / g; crushing activated carbon to 140-325 meshes, mixing the crushed activated carbon with the composite glue solution, adding a proper amount of water for kneading, and forming the mixture into 2-8mm columnar particles by a hydraulic granulator or a screw extrusion granulator; through drying at the temperature of 100-300 DEG C and heat treatment at the temperature of 700-900 DEG C in a nitrogen, water vapor or anaerobic atmosphere, a basic group generated by the binder in the heat treatment has a very strong chemical adsorption effect on acid gas, later-stage modification is not needed, and excellent desulfurization and denitrification performance is achieved.

The invention discloses a decommissioned lithium iron phosphate positive electrode material green restoration upgrading regeneration technology, which comprises the following steps: completely dissolving a lithium salt and tea polyphenol in a solvent to obtain a reduction restoration agent solution; mixing the retired lithium iron phosphate positive electrode material with the direct reduction repairing agent solution to obtain a mixed suspension; putting the turbid liquid into a reaction kettle, heating in a drying oven, keeping the temperature for a period of time, cooling, collecting and washing to obtain a precipitate; and mixing the precipitate with an aluminum nitrate solution and a diammonium hydrogen phosphate solution, evaporating to dryness, adding a trace amount of lithium salt, and annealing in a nitrogen atmosphere to obtain the upgraded and regenerated aluminum phosphate / lithium phosphate coated lithium iron phosphate positive electrode material. According to the upgrading, repairing and regenerating technology, rich natural green reducing and repairing agent-tea polyphenol is used, and the technology is environmentally friendly and can be recycled and reused; meanwhile, the aluminum phosphate / lithium phosphate coating layer is low in price, the electrochemical performance of the lithium iron phosphate waste powder is obviously repaired and improved, and the method is suitable for industrial popularization and application.

The invention belongs to the technical field of inorganic material preparation, and particularly relates to a method for preparing battery-grade lithium dihydrogen phosphate by using a waste lithium molecular sieve, which comprises the following steps: grinding the waste lithium molecular sieve, sieving with a 100-mesh sieve, mixing with a diammonium hydrogen phosphate solution, adding oxalic acid solid, adjusting the pH value of slurry to 5-6, stirring, and filtering to obtain filter residue and filtrate; performing the operations on the filter residue, filtering, and mixing with the first filtrate to obtain a solution 1; adding EDTA (Ethylene Diamine Tetraacetic Acid) into the solution 1, stirring, adding lithium hydroxide monohydrate, adjusting the pH value to 12.5-13, heating until boiling, and filtering while hot to obtain a lithium phosphate wet material; then adding pure water to obtain slurry, adding the slurry into phosphoric acid and hydrogen peroxide, and dissolving and clarifying to obtain a lithium dihydrogen phosphate clean solution; and then evaporating, stopping heating when the temperature of the solution reaches 125-130 DEG C, cooling, and then centrifuging and drying to obtain the battery-grade lithium dihydrogen phosphate. According to the invention, zero discharge of waste liquid is realized, and the lithium yield is high.

The invention discloses a formula and a preparation process of a synthetic biotechnology-based endowed netting loss-control pesticide fertilizer, and relates to the technical field of fertilizers, the loss-control pesticide fertilizer is prepared from the following components by weight: 60-80 parts of a compound fertilizer, 10-20 parts of diammonium phosphate, 2-10 parts of trace elements, 2-8 parts of modified attapulgite, 1-4 parts of an insecticide, 0.5-3 parts of polyglutamic acid, and 1-5 parts of polyvinyl alcohol; according to the invention, a high-efficiency netting loss control system is formed through the energization of polyglutamic acid and the synergistic effect of multiple components, so that not only are the problems of easy nutrient loss and poor pesticide stability in the traditional pesticide fertilizer solved, but also the synergistic slow release of nutrients and pesticide is realized, the utilization rate of the fertilizer is remarkably increased, the control period of the pesticide is remarkably prolonged, and the application value is good.

The present invention belongs to the technical field of phosphate fertilizer production, and specifically relates to a zinc-containing diammonium phosphate, a preparation method thereof, and a fertilizer containing zinc-containing diammonium phosphate. Zinc-containing diammonium phosphate is prepared by coating elemental sulfur on the outer layer of solid zinc fertilizer to obtain a sulfur-containing zinc mixed slurry, which is then sprayed onto the diammonium phosphate for granulation to obtain the zinc-containing diammonium phosphate. The amount of solid zinc fertilizer added accounts for 30 to 100% of the total mass of elemental sulfur; and the amount of sulfur-containing zinc mixed slurry added is 1 to 10% based on the total weight of the zinc-containing diammonium phosphate. This preparation method avoids direct contact and antagonistic reactions between phosphate and zinc ions, prevents degradation of phosphorus and zinc nutrients, and maintains a good ratio of water-soluble zinc content and water-soluble phosphorus content.

The present invention provides a composite insecticide containing plant extracts and its preparation process, belonging to the technical field of pesticide preparation; the preparation process includes the following steps: preparing a composite carrier powder; preparing a modified composite carrier powder; preparing a Corydalis extract; preparing a composite insecticide. By first dispersing nano-calcium carbonate powder in deionized water, then adding a mixed solution of calcium nitrate solution and diammonium hydrogen phosphate solution, and carrying out a hydrothermal reaction to prepare a composite carrier powder of nano-calcium carbonate and hydroxyapatite, after loading the Corydalis extract and veratridine with this composite carrier powder, the prepared composite insecticide can have a slow-release effect, extend the insecticidal action time, reduce the number of pesticide applications, and reduce environmental pollution. In addition, after modifying the composite carrier powder, its loading rate for the Corydalis extract and veratridine can be improved, thereby enhancing the insecticidal effect of the composite insecticide.

The invention discloses a method for preparing low-ash-content activated carbon from coconut shells, and belongs to the technical field of activated carbon. Comprising the following steps: crushing, ball-milling and sieving coconut shells to obtain a material A; soaking the material A in a hydrochloric acid solution, heating, stirring, washing and drying in vacuum to obtain a material B; mixing the material B with deionized water, and adding sodium hydroxide, ammonium carbonate and diammonium hydrogen phosphate to obtain a material C; performing oxidation treatment on the material C to obtain a material D; the material D is taken for carbonization treatment and activation treatment, coconut shell activated carbon with low ash content is obtained, the ash content is reduced, and high-quality activated carbon is obtained.

The invention discloses heat-resistant ammonium polyphosphate with ultrahigh polymerization degree and a synthesis method thereof. The method comprises the following steps: (1) preparing ammonium polyphosphate: S1, mixing phosphorus pentoxide and diammonium hydrogen phosphate, stirring to react, and introducing ammonia gas to react; s2, mixing phosphoric acid with melamine for reaction, supplementing phosphoric acid, and stirring for reaction; s3, when the temperature in the first-step reaction is 280-300 DEG C, stopping introducing the ammonia gas, adding a product obtained in the step S2, supplementing diammonium hydrogen phosphate, and introducing the ammonia gas to continue the reaction; (2) end sealing; (3) pre-curing; and (4) mixing and dissolving epoxy resin and a curing agent, and then coating the surface of the pre-cured ammonium polyphosphate with the mixture. The initial polymerization degree of the ammonium polyphosphate can be improved, the initial molecular weight of the ammonium polyphosphate is higher, the application capacity of the ammonium polyphosphate in a humid and hot environment can be improved after modification treatment, especially when the ammonium polyphosphate is soaked in hot water at the temperature of 80 DEG C for 4 h, the product does not separate out or migrate, and the stability of the flame-retardant effect of the product is guaranteed.

The utility model discloses a diammonium phosphate granulating and drying system which comprises a grid plate, a grid plate is horizontally fixed at the lower part of the granulator, and a plurality of strip-shaped holes which are parallel to one another are formed in the grid plate; a plurality of sliding grooves are formed in the inner wall of the tail of the drying machine in the axial direction, a crushing base plate is inserted into each sliding groove in a sliding mode, the crushing base plates are fixedly connected with the drying machine through penetrating screws, and a plurality of crushing teeth are vertically fixed to the crushing base plates. The device has the advantages that caked materials granulated by the granulator are intercepted on the grid plate, and part of the caked materials are pushed out from the discharge door by the material pushing plate, so that the caked materials are cleaned; after the materials are dried by the drying machine, the materials are thrown up by the material raising plate and fall on the crushing teeth on the crushing base plate under the action of gravity, so that the primary crushing effect on the dried caked materials is achieved, the caked materials generated in the granulation process can be effectively crushed, and the normal production efficiency and the production quality are prevented from being influenced by material blockage.

The invention belongs to the technical field of agriculture, and particularly relates to a fertilization method for improving the quality and yield of oat seeds, diammonium hydrogen phosphate and biochar are used as base fertilizers, the application amount of the diammonium hydrogen phosphate is 10-12 kg / mu, the application amount of the biochar is 10-15 kg / mu, bacterial fertilizer dressing is carried out in the seedling emergence period of crops, and chemical fertilizer dressing is not carried out in the later period; the bacterial fertilizer is an arbuscular mycorrhizal fungus inoculant and a trichoderma inoculant. The use amount of the chemical fertilizer is reduced, and the negative effect of excessive use of the chemical fertilizer on crop growth is reduced; the soil environment is improved by additionally applying biochar, and the nutrient utilization efficiency is improved; by utilizing a hypha network formed by arbuscular mycorrhizal fungi and root systems, the absorption area of the oat root systems is increased, and the nutrient utilization efficiency of plants is improved; the application of the trichoderma can promote the development of lateral roots of plants and accelerate the growth speed of the plants in the seedling stage; the fertilization method can improve the quality and yield of the oat seeds, is simple and easy to implement, is suitable for large-scale popularization and application, and has a wide market prospect.

The invention provides a water-soluble fertilizer containing rare earth and a preparation method thereof. The water-soluble fertilizer is prepared from the following raw materials in parts by weight: 30 to 40 parts of nitrogen phosphorus and potassium components, 10 to 15 parts of calcium magnesium components, 3 to 5 parts of mineral element components, 0.5 to 1.0 part of nickel cobalt selenium components, 10 to 15 parts of humic acid, 5 to 10 parts of sodium alginate, 5 to 10 parts of fish protein, 3 to 5 parts of pyroligneous liquor, 2 to 4 parts of chelating agents and 0.5 to 1.0 part of rare earth. Wherein the nitrogen-phosphorus-potassium component is prepared by mixing urea, monoammonium phosphate, diammonium phosphate and potassium nitrate according to the mass ratio of (2-3): (1-2): (1-2): (2-3), the anti-caking agent is prepared from starch phosphate, microcrystalline cellulose and nano clay according to the mass ratio of (2.0-4.0): (1.5-3.5): (1.0-2.0), and the chelating agent is prepared from ethylenediamine tetraacetic acid, erythritol, glycine, salicylic acid or derivatives thereof according to the mass ratio of (4-6): (2-3): (1-2): (0.1-0.6). The complex multi-element ligand system is formed by combined use of ethylenediamine tetraacetic acid, erythritol, glycine, salicylic acid or derivatives thereof. Through the synergistic effect of a multi-element ligand system, rare earth ions are more effectively stabilized, and more stable chelated rare earth is formed, so that the solubility of the chelated rare earth in water is improved.

The invention relates to the technical field of surface strengthening treatment and coating preparation, in particular to a micro-arc oxidation electrolyte, a preparation method of the micro-arc oxidation electrolyte and a preparation method of an oxide ceramic coating on the surface of a magnesium-copper dissimilar metal material component. The invention provides a micro-arc oxidation electrolyte. The micro-arc oxidation electrolyte comprises a main film-forming agent, an arcing aid, a pH regulator, a corrosion inhibitor and water, the main film-forming agent comprises ammonium fluozirconate and / or potassium fluozirconate; the arcing aid comprises one or more of disodium hydrogen phosphate, sodium dihydrogen phosphate, ammonium dihydrogen phosphate and diammonium hydrogen phosphate; the corrosion inhibitor comprises one or more of hexamethylenetetramine, ammonium bifluoride and triethanolamine. The micro-arc oxidation electrolyte breaks through the problem that valve metal and non-valve metal cannot be subjected to arc discharge at the same time for micro-arc oxidation treatment in the micro-arc oxidation process.

The invention belongs to the technical field of saline-alkali soil improvement and crop planting, and particularly relates to a method for saline-alkali soil improvement and oat planting, which comprises the following steps: sowing mixed bean green manure crops in April every year, and scattering diammonium phosphate into ploughed soil before sowing; the mixed bean green manure is common vetch and S001 wild soybean; turning, pressing and returning to the field in a green manure full-bloom stage; the oats are planted every 15 days, and before the oats are planted, charcoal is scattered into the ploughed soil; the method comprises the following steps: selecting a saline-alkaline tolerant feeding oat variety, and cradling in a heading period. By sowing the mixed bean green manure, the soil composition of the saline-alkali soil can be effectively improved, the pH value of the soil and the total amount of water-soluble salt are reduced, and the content of total nitrogen, available phosphorus, quick-acting potassium and organic matter is remarkably increased, so that the method is suitable for oat planting; by sowing mixed bean green manure, turning, pressing and returning the mixed bean green manure to the field and applying biochar base fertilizer, the plant height and the yield of the oats are remarkably increased; the method is simple, effective, low in cost and suitable for large-scale popularization and application.

The invention discloses an extraction method of microalgae, and belongs to the technical field of microorganisms, and the extraction method comprises the three steps of microalgae culture, enzymolysis reaction and compounding aftertreatment. When a microalgae extract is applied to a microalgae fertilizer, the yield and quality of crops can be effectively improved; and the schizochytrium limacinum culture medium is treated by using p-hydroxybenzoic acid and diammonium phosphate, so that the cell membrane permeability of the schizochytrium limacinum is changed, other nutrient substances can enter the schizochytrium limacinum conveniently, and meanwhile, cell wall breaking of the schizochytrium limacinum is facilitated. Under a proper ratio of an enzymolysis mixture, pyrolytic biochar, bentonite and biomass tar, the prepared microalgae-biochar simultaneously has abundant pore structures, a large amount of microalgae loads and strong combination structural performance, the activity performance of the microalgae-biochar can be effectively maintained, and the application range of the microalgae-biochar is widened. The method has a wide market prospect when being used for preparing a microalgae fertilizer.

The invention relates to the field of wastewater treatment, and discloses a hydroxyapatite modified biochar material as well as a preparation method and application thereof in treatment of fluorine-containing wastewater. The preparation method comprises the following steps: preparing a hydroxyapatite-biochar composite material by using an in-situ precipitation method, and modifying by using metal aluminum ions, specifically, uniformly mixing peanut shell powder and anhydrous calcium chloride, dispersing, dropwise adding diammonium hydrogen phosphate for reacting, adjusting pH by using NaOH, stirring at constant temperature for reacting, washing with water and absolute ethyl alcohol to be neutral, and drying to obtain an HAP / C composite material; the HAP / C composite material is placed in a tubular furnace for pyrolysis, and an HAP / BC composite material is obtained; and adding an A1Cl3. 6H2O solution into the HAP / BC composite material, uniformly stirring, standing, carrying out suction filtration and washing until the HAP / BC composite material is neutral, and finally drying the HAP / BC composite material in a constant-temperature drying box to obtain the Al-HAP / BC composite material with low cost, large adsorption capacity and strong stable regeneration performance, and the obtained Al-HAP / BC composite material is applied to fluorine ion-containing wastewater, has a remarkable fluorine removal effect and has a good application prospect.

The invention discloses a method for mineralizing concrete recycled aggregate through exopolysaccharide compound microorganisms, and belongs to the technical field of microorganisms and concrete materials. The composite dispersion liquid composed of diammonium hydrogen phosphate, chitin and cellulose is used, the aggregate is soaked from low concentration to high concentration, effective modification of the surface of the aggregate can be achieved, and then the aggregate is treated with a composite microbial agent composed of bacillus subtilis and sporosarcina mectacitae, so that the surface of the aggregate is improved, and the surface of the aggregate is improved. Wherein the mineralization activity is effectively improved after the two selected microbial strains with high high-temperature resistance and alkali resistance are mixed in equal proportion, high-activity urease can be produced in a high-temperature and high-alkali environment, pores and microcracks of the recycled aggregate are effectively filled by formed calcium carbonate, effective regeneration of the waste concrete aggregate is realized, the treatment is convenient, and the efficiency is high. The biological polysaccharide compound microorganism method adopted by the invention has the characteristics of high efficiency, maintenance condition simplification, economy, environmental protection and the like, and formed minerals are stable in property and strong in durability.

The invention provides a deodorant for air disinfection and deodorization and a preparation process thereof, and belongs to the technical field of air purification. Comprising the following components: a composite deodorizing material, a composite essential oil microcapsule, a surfactant, benzalkonium bromide and water. The preparation method comprises the following steps: mixing and dissolving calcium nitrate tetrahydrate and diammonium hydrogen phosphate, adding hexadecyl trimethyl ammonium bromide and ammonia water to prepare a mesoporous nano-hydroxyapatite precursor suspension, adding a zinc nitrate solution, and carrying out hydrothermal reaction and calcination to prepare a composite carrier material; when the composite essential oil is loaded into the composite carrier material by using a vacuum impregnation method, the composite essential oil can have a slow release effect, the long-acting deodorization effect of the deodorant is improved, and more adsorption sites can be provided for the composite essential oil, so that the loading rate of the composite carrier material to the composite essential oil can be remarkably improved, and the deodorization effect of the deodorant is improved. The deodorization effect of the deodorant is further improved.

The invention relates to the technical field of agricultural fertilizers, in particular to a slow / controlled-release fertilizer for saline-alkali soil and a preparation method of the slow / controlled-release fertilizer. The slow / controlled-release fertilizer sequentially comprises a core layer, an inner coating, a shell layer and an outer coating from inside to outside, the core layer comprises a functional aid, diammonium hydrogen phosphate, urea, isobutylidene diurea, potassium nitrate and biochar; a shell layer contains bagasse, a compound strain and fulvic acid; the coating material is an adhesive containing montmorillonite powder; the functional additive is loaded with an organic acid and polymethacrylamide network through modified diatomite, so that the synergistic effect of sodium ion adsorption, acid-base regulation and nutrient slow release is realized; through the multi-layer structure design and the component synergistic effect, it is guaranteed that the slow and controlled release fertilizer can improve the saline-alkali soil structure in a long-acting mode, accurately regulate nutrient release and improve the stress resistance of crops, and the slow and controlled release fertilizer is suitable for efficient utilization of saline-alkali soil.

The invention relates to the technical field of antibacterial materials, in particular to a rare earth antibacterial ultraviolet-proof composite material and a preparation method thereof.The preparation method comprises the following steps that lanthanum oxide is added into a 1-2 mol / L dilute nitric acid solution, heating and stirring are conducted at the temperature of 60-80 DEG C till the lanthanum oxide is completely dissolved, a lanthanum ion solution is obtained, calcium nitrate tetrahydrate and the lanthanum ion solution are added into deionized water, a solution A is prepared, and the solution B is prepared; the preparation method comprises the following steps: adding diammonium hydrogen phosphate and a polymer carrier into deionized water to prepare a solution B, slowly dropwise adding the solution B into the solution A under magnetic stirring to obtain a turbid liquid, adjusting the pH value, stirring for 6-8 hours in an oil bath, standing and aging for 24-36 hours at room temperature, filtering to obtain a precipitate, washing and drying to obtain the rare earth antibacterial ultraviolet-proof composite material. The rare earth antibacterial and ultraviolet-proof composite material prepared by the invention has good antibacterial and ultraviolet shielding properties.

The invention relates to the technical field of cultivation and planting of medicinal plants, in particular to a method for planting folium isatidis in severe saline-alkali soil. The method comprises the following steps: (1) soil preparation; (2) applying a base fertilizer: spreading 10-20 kg / mu of humic acid, 1-5 kg / mu of charcoal, 2000-4000 kg / mu of a microbial organic fertilizer, 100-150 kg / mu of waste mushroom sticks and 10-15 kg / mu of diammonium phosphate on the surface of the soil, and deeply plowing for 25-30 cm for two times; (3) ridging and sowing; (4) field management; (5) pest control; (6) harvesting. Through reasonable base fertilizer application and topdressing, the survival rate and yield of folium isatidis in the severe saline-alkali soil are increased, especially the content of effective components such as indirubin is increased, and high economic benefits are obtained while the severe saline-alkali soil is utilized.