25 results about "Melamine phosphate" patented technology

The invention discloses a preparation method and application of fine-grained melamine phosphate.The preparation method comprises the steps that after melamine, water and a composite surfactant are ultrasonically mixed to be uniform, the ultrasonic power is improved, phosphoric acid is dropwise added, then the ultrasonic power is reduced, a temperature rise reaction is conducted to obtain reaction liquid, and then the fine-grained melamine phosphate is obtained after cooling, filtering, washing and drying are conducted; wherein the composite surfactant is composed of a gemini surfactant and a polymer surfactant according to a mass ratio of (1-20): (5-40). According to the preparation method disclosed by the invention, the composite surfactant and the multi-stage ultrasonic treatment are utilized to cooperate with the mixed materials and react, so that the fine-grained melamine phosphate with the particle size of 1-4.5 microns is prepared, and the preparation method has the advantages of high reaction efficiency, simplicity in operation and the like.

The invention provides a polyethylene composition as well as a preparation method and application thereof, and the polyethylene composition comprises the following components in parts by weight: 54-71 parts of low-density polyethylene, 9-16 parts of linear low-density polyethylene, 15-35 parts of a composite flame retardant, 0.1-1 part of an antioxidant and 0.1-1 part of an anti-dripping aid, wherein the composite flame retardant comprises a phosphoric acid flame retardant, an inorganic zinc salt flame retardant, melamine polyphosphate and melamine cyanurate; the polyethylene composition provided by the invention has high flame retardancy, high toughness and high flow processability under the conditions of no halogen-containing flame retardancy, safety and environmental protection.

The invention relates to a high-voltage-resistant anti-breakdown automobile wire sheath and a preparation method thereof, and relates to the technical field of automobile wire harnesses, and the high-voltage-resistant anti-breakdown automobile wire sheath comprises a modified styrene-ethylene-butylene-styrene block copolymer, polypropylene, functionalized magnesium hydroxide, melamine polyphosphate, white oil and a functional auxiliary agent. An N-vinylcarbazole group grafted on a styrene-ethylene-butylene-styrene block copolymer molecular chain is used as an electron donor, an anthraquinone derivative chemically bonded on the surface of a magnesium hydroxide particle is used as an electron acceptor, and the N-vinylcarbazole group and the anthraquinone derivative form a large number of charge transfer complexes at an interface through pi-pi interaction. According to the charge transfer complexes, a high-density deep energy level trap is introduced into an energy band structure of the material, so that the charge behavior of the material in a high electric field is changed, and high-performance high-voltage-resistant and anti-breakdown effects are realized.

The invention discloses a weather-resistant flame-retardant single-component perfluoropolyether waterproof coating and a gradient catalytic preparation method thereof, and the coating is mainly prepared from the following components in parts by weight: 20-30 parts of perfluoropolyether diol with the molecular weight of 4000, 5-10 parts of perfluoropolyether diol with the molecular weight of 2000, 5-7 parts of isophorone diisocyanate and 25-35 parts of piperazine pyrophosphate. The coating comprises the following components in parts by weight: 20-30 parts of epoxy resin, 3-6 parts of melamine phosphate, 0.3-1.0 part of secondary amino silane, 0.1-0.2 part of an organic bismuth catalyst and 0.03-0.08 part of dimorpholine diethyl ether. The weather-resistant flame-retardant single-component perfluoropolyether waterproof coating disclosed by the invention has the advantages of excellent storage stability, outstanding mechanical properties, excellent weather resistance, up-to-standard flame retardance, high curing efficiency and good self-cleaning performance, and is particularly suitable for exposed waterproof projects of high-standard buildings.

The present application relates to the technical field of carbon material preparation, in particular to a coal-tar pitch-based heteroatom-doped porous carbon, a preparation method and application thereof, a three-dimensional network boron-nitrogen-phosphorus-doped porous carbon is prepared by taking coal-tar pitch as a precursor, boric acid as a boron source, melamine phosphate as a phosphorus-nitrogen source and potassium bicarbonate as an activating agent. By changing the types of raw materials, the pore structure and morphology of the porous carbon material can be regulated, and a unique three-dimensional porous network structure is constructed. The specific surface area of the obtained porous carbon material is between 522 and 1245 m 2 / g, the addition of boric acid and melamine phosphate realizes the doping of boron, nitrogen and phosphorus elements. The obtained porous carbon material has good rate performance and cycle performance as a zinc ion hybrid capacitor electrode material.

The invention relates to the technical field of cables, and provides a high-temperature-resistant flame-retardant cable which sequentially comprises a conductor, an insulating layer and a sheath layer from inside to outside, and the sheath layer is prepared from the following raw materials in parts by weight: 70 parts of a composite polyethylene material, 6-12 parts of polypropylene, 5-10 parts of an ethylene-vinyl acetate copolymer, 10-20 parts of mullite powder, 1-2 parts of an antioxidant, 1-3 parts of a plasticizer and 8-12 parts of a flame retardant; the preparation method of the composite polyethylene material comprises the following steps: A1, uniformly mixing dolomite powder, melamine phosphate and erythritol, and carrying out ball milling to obtain a blend; a2, the blend and polyethylene are blended and extruded, and the composite polyethylene material is obtained. According to the technical scheme, the problem that the flame retardant property of the cable sheath layer is poor in the prior art is solved.

A thermoplastic composition including: a polyester including a poly(alkylene arylate); optionally, a polyetherimide; a flame retardant composition comprising a dialkyl phosphinic acid salt, and optionally; optionally an auxiliary flame retardant comprising melamine polyphosphate, melamine cyanurate, melamine pyrophosphate, melamine phosphate, or a combination thereof; a mineral flame retardant synergist comprising a modified fibrillated magnesium silicate, a modified fibrillated aluminum silicate, or a combination thereof; optionally, glass fibers; and optionally, an additive composition; wherein the sum of the wt% of the polyester, the flame retardant composition, the mineral flame retardant synergist, the optional polyetherimide, the optional glass fibers, and the optional additive composition total 100 wt%, and wherein the thermoplastic composition comprises 1500 ppm or less of intentionally added fluorine, and a sample of the thermoplastic composition exhibits a UL 94 flame test rating of V-0 at a thickness of 1.5 mm.

This invention discloses a method for preparing piperazine pyrophosphate using wet-process phosphoric acid, relating to the field of flame retardant technology. Unconcentrated wet-process phosphoric acid is reacted with melamine to obtain a first slurry containing melamine phosphate salt. The first slurry is separated, impurities removed, and then reacted with piperazine to obtain a second slurry containing piperazine diphosphate. After solid-liquid separation of the second slurry, the filtrate is crystallized, and the crystals are dehydrated under a nitrogen atmosphere to obtain the piperazine pyrophosphate. Using unconcentrated wet-process phosphoric acid as a raw material to synthesize piperazine pyrophosphate is inexpensive, stable, and easier to operate than traditional phosphoric acid methods. In the reaction process, the wet-process phosphoric acid is first reacted with melamine to generate melamine phosphate salt as an intermediate, thereby effectively reducing impurity ions present in the wet-process phosphoric acid and improving the purity of the product. After reacting with piperazine, the filtrate is crystallized and dehydrated at high temperature to obtain piperazine pyrophosphate, without affecting its performance as a flame retardant material.

The present invention discloses a thermoplastic polyolefin elastomer composition and an artificial leather thereof. The thermoplastic polyolefin elastomer composition comprises a polymer composition, and the polymer composition comprises a polyolefin resin or a mixture of a polyolefin resin and a rubber elastomer. The thermoplastic polyolefin elastomer composition comprises a halogen-free flame retardant, and the halogen-free flame retardant comprises aluminum diethylphosphinate, piperazine pyrophosphate, and melamine polyphosphate. According to the present invention, flame retardancy of the thermoplastic polyolefin elastomer composition and the artificial leather prepared therefrom is improved by compound use of the three, that is, the aluminum diethylphosphinate, the piperazine pyrophosphate, and the melamine polyphosphate, thereby meeting requirements for safety and environmental protection.

The application provides a kind of supramolecular self-assembly uranium adsorbent and its preparation method and application, the preparation raw material of the uranium adsorbent includes melamine, cyanuric acid and melamine phosphate, by selecting the three substances of melamine, cyanuric acid and melamine phosphate to carry out supramolecular self-assembly, the obtained uranium adsorbent can have high adsorption capacity, high adsorption rate and higher selectivity, and the preparation raw material is low in price and simple in preparation process, suitable for application in seawater uranium extraction.

This invention discloses a flame-retardant non-isocyanate polyurethane (NIPU) foam, its preparation method, and its applications, belonging to the field of polymer foam material technology. This invention uses melamine phosphate as a reactive monomer, with its primary amine groups participating in the construction of the polymer network. Phosphorus-nitrogen flame-retardant units are introduced into the polyurethane backbone through covalent bonds, solving the migration problem of traditional additive flame retardants. This invention utilizes the cascade exothermic effect of the ammonolysis reaction and the epoxy ring-opening reaction to trigger the hydrolysis of cyclic carbonates to generate carbon dioxide gas, achieving a room-temperature self-foaming process without external heating, thus reducing energy consumption. The resulting NIPU foam exhibits excellent flame-retardant properties (limiting oxygen index >27%, vertical burning rating reaching V-0), high char residue, low heat release, and low smoke release characteristics, providing a new technical approach for the preparation of green, safe, and high-performance polyurethane foam materials.

The application relates to a preparation method of nitrogen-phosphorus co-doped carbon encapsulated MoO3-Mo2C heterostructure material for water treatment, in particular to the following steps: mixing alpha-MoO3 powder and H2O2, hydrothermally synthesizing alpha-MoO3 nanosheets; dispersing the alpha-MoO3 nanosheets in water, mixing and dispersing glucose and melamine phosphate in water, mixing the two aqueous solutions, putting foamed NiFe into the mixed solution, heating and evaporating water under oil bath conditions to form a slurry material, then putting the slurry material into a tube furnace, and roasting under Ar atmosphere to obtain nitrogen-phosphorus co-doped carbon encapsulated MoO3-Mo2C heterostructure material; and the application of the prepared nitrogen-phosphorus co-doped carbon encapsulated MoO3-Mo2C heterostructure material in a water treatment reaction.

The application provides a battery fireproof partition plate and a preparation method thereof, a battery module and a new energy vehicle. The battery fireproof partition plate comprises a high-temperature heat-resistant insulating sheet, and the high-temperature heat-resistant insulating sheet is arranged on the outer side of a modified polyurethane fireproof core plate. The modified polyurethane fireproof core plate comprises component A and component B. Component A comprises 30-50 parts of medium-functionality polyether polyol, 1-5 parts of a catalyst, 1-10 parts of an organic phosphate, 10-25 parts of melamine phosphate, 1-10 parts of a low-functionality chain extender, 1-10 parts of pentaerythritol, 1-10 parts of aluminum hydroxide, 1-10 parts of hollow glass microbeads and 1-5 parts of a smoke suppressant. Component B comprises 20-40 parts of an isocyanate mixture. The battery fireproof partition plate not only has a good mechanical protection effect, but also improves the fireproof and heat insulation performance of the battery fireproof partition plate, that is, the fireproof and heat insulation time of the battery fireproof partition plate is 300 s at a temperature above 1300 DEG C, thereby effectively preventing the flame energy from spreading to the surrounding.

The invention provides a method for preparing melamine polyphosphate at low temperature, and relates to the field of melamine polyphosphate. The method for preparing melamine polyphosphate at low temperature comprises the following steps: dispersing polyphosphoric acid, reacting at low temperature and post-treating. The method for preparing melamine polyphosphate at low temperature can solve the problems of high intermediate dehydration temperature, complex process, high production cost and energy consumption, poor product chromaticity and stability, difficult solvent recovery and prominent safety and environmental protection risks in the existing production process; the melamine polyphosphate with good chromaticity and stability can be prepared in one step on the premise that high-temperature dehydration and solvent recovery are not needed, the process is simple and controllable, the production cost is low and the equipment requirement is low.

The application provides a deep anti-seepage reinforcing material and a preparation method and application thereof, and belongs to the technical field of composite materials. Modified nano silicon dioxide prepared by hydrolysis modification of polymethyl hydrogen siloxane is mixed with a premixing material, the premixing material is obtained by pre-polymerization reaction of hyperbranched flame-retardant polyester generated by polyphosphoric melamine / tripolymer graphite composite reaction, polyether polyol and isocyanate, and then pouring, curing and obtaining the deep anti-seepage reinforcing material. The application prepares a polyurethane-based deep anti-seepage reinforcing material, which has strong cementation performance, good toughness, good durability, excellent mechanical properties, good flame retardance and good heat conduction performance.

The invention discloses flame-retardant plastic and a preparation method thereof, and belongs to the field of engineering plastics, the flame-retardant plastic comprises ABS, a compatilizer, a flexibilizer, a flame retardant, modified polybutylene terephthalate and an antioxidant, and the flame retardant comprises a covalent flame retardant composed of plasma fluorinated phosphazene boron nitride and a graphene nanosheet-melamine phosphate hybrid. The flame-retardant plastic prepared by the invention has excellent flame retardance and impact resistance.

The invention belongs to the technical field of solid waste recycling and wastewater treatment, and particularly relates to a method for combined treatment of organic amine flue gas desulfurization residues and chromium-containing wastewater. According to the method, organic amine flue gas desulfurization residues are used as a reducing agent, phosphoric acid is used for controlling the pH value of wastewater, hexavalent chromium is reduced into trivalent chromium under the acidic condition, meanwhile, desulfurization ash is converted into a melamine phosphate flame-retardant material, and trivalent chromium is separated from water in a precipitation form under the neutral condition; and roasting the precipitate to obtain chromium sesquioxide powder with relatively high purity, and separating and recovering excessive phosphate radicals from the wastewater in the form of calcium phosphate. While the flue gas desulfurization slag and the chromium-containing wastewater are treated, melamine phosphate, chromium trioxide and calcium phosphate byproducts can be recovered, the treatment cost of the wastewater and solid wastes is reduced, and cyclic utilization of resources is realized.

The invention relates to the technical field of cables, and provides a high-flame-retardant power cable which sequentially comprises a cable core, a crosslinked polyethylene insulating layer and a sheath layer from inside to outside. The cable core comprises a conductor and a wrapping tape arranged outside the conductor; the conductor is formed by twisting tin-plated aluminum wires; the sheath layer comprises the following components in parts by weight: 58-64 parts of polyethylene, 36-42 parts of polyvinyl chloride, 12-18 parts of a flame retardant, 4-6 parts of a compatibilizer, 0.5-2 parts of an antioxidant, 5-10 parts of a reinforcing agent and 2-4 parts of a heat stabilizer; the flame retardant is prepared from the following components in parts by weight: 1 to 10 parts of melamine phosphate modified molybdenum trioxide and 1 to 10 parts of guanidyl flame retardant. According to the technical scheme, the problem of insufficient flame retardant property of the power cable in the prior art is solved.

The invention provides a flame-retardant antibacterial skin-friendly functional lyocell fiber and a preparation method thereof, and belongs to the field of fiber materials.The flame-retardant antibacterial skin-friendly functional lyocell fiber is prepared by preparing microencapsulated melamine phosphate powder and an amino acid cross-linked phytic acid solution, infiltrating the microencapsulated melamine phosphate powder into the amino acid cross-linked phytic acid solution, curing, washing and drying, and the flame-retardant antibacterial skin-friendly functional lyocell fiber is obtained. Modified flame retardant powder is obtained; dissolving pulp in an NMMO aqueous solution, adding a stabilizer, a cross-linking agent and the modified flame retardant powder, and mixing and reacting to obtain a spinning solution; and performing ultrasonic treatment and oil bath on the spinning solution, and spinning to obtain the flame-retardant antibacterial skin-friendly functional lyocell fiber. The phytic acid and the microencapsulated melamine phosphate are utilized to modify the lyocell fibers through crosslinking and curing, efficient, durable, flame-retardant and antibacterial effects are achieved, the preparation process is simple, and the lyocell fibers can be widely applied to the fields of close-fitting household textile articles, medical textile articles and the like.

The invention discloses a tannic acid-based flame retardant, a preparation method thereof and application of the tannic acid-based flame retardant in semi-rigid polyurethane foam, and belongs to the technical field of flame-retardant materials. According to the flame retardant, tannic acid, melamine polyphosphate and zinc ions are compounded to form a novel synergistic flame-retardant system. The preparation method comprises the following steps: dispersing MPP and paraformaldehyde in water, adding tannic acid for reaction, introducing zinc chloride for coordination crosslinking, and finally washing and drying to obtain the product. According to the flame retardant, a polyphenol structure of tannic acid is used for enhancing compatibility and dispersity with a polyurethane matrix, under the synergistic effect of the tannic acid, phosphorus-nitrogen flame-retardant components and metal ions, formation of a compact carbon layer is effectively promoted, and the flame-retardant efficiency is remarkably improved. When being applied to semi-rigid polyurethane foam, the composite material can greatly improve the limit oxygen index of the material, the limit oxygen index reaches up to 29.4% and passes the UL-94 V-0 grade, and meanwhile, the excellent mechanical property is kept.

The invention relates to the technical field of polypropylene resin compositions, in particular to a flame-retardant polypropylene resin composition as well as a preparation method and application thereof. The polypropylene resin composition with flame retardance is prepared from the following components in parts by mass: 20 to 40 parts of polypropylene resin, 45 to 65 parts of shell powder, 0.5 to 5.0 parts of compatilizer, 10 to 25 parts of flame retardant mixture and 0.1 to 2 parts of auxiliary agent, and the flame retardant mixture is prepared from ammonium polyphosphate, melamine polyphosphate, pentaerythritol and zinc borate. The polypropylene resin is used as a polymer matrix and filled with high-content shell powder, so that the composition has flame retardance and good product quality, and the raw material cost can be reduced. By utilizing the ceramization effect of zinc borate, the structure can be prevented from collapsing during fire, and flame spreading can be effectively blocked. According to the present invention, by using melamine polyphosphate having excellent heat resistance, it is possible to suppress the generation of gas due to early decomposition of a flame retardant, thereby manufacturing a plate having a beautiful surface.

The objective is to provide a highly dispersed flame-retardant masterbatch and a method for manufacturing the same. [Solution] The present invention belongs to the field of polymer materials and relates to a highly dispersed flame retardant masterbatch and a method for producing the same. The highly dispersed flame retardant masterbatch comprises, by weight, 8 to 30 parts by weight of a polymer, 30 to 95 parts by weight of a composite flame retardant containing antimony trioxide, borate, and an organophosphorus-nitrogen complex, 6 to 20 parts by weight of a plasticizer, and 0.1 to 15 parts by weight of an auxiliary agent, wherein the organophosphorus-nitrogen complex is one or more of a mixture of DOPO and MCA, polyphosphate melamine, and ammonium polyphosphate. The present invention significantly improves the flame retardant performance of the material by optimizing the recipe of the flame retardant.

The application relates to a preparation method of a nitrogen-phosphorus co-doped carbon encapsulated WO3-WP2 heterostructure material for water treatment, in particular to the following steps: dispersing WO3 powder in water, mixing and dispersing glucose and phosphoric acid melamine in water, mixing the two aqueous solutions, putting foamed NiFe into the mixed solution, evaporating water under oil bath heating to form a slurry material, then putting the slurry material into a tube furnace, and roasting under an Ar atmosphere to obtain the nitrogen-phosphorus co-doped carbon encapsulated WO3-WP2 heterostructure material; and the application of the prepared nitrogen-phosphorus co-doped carbon encapsulated WO3-WP2 heterostructure material in a water treatment reaction.

The invention discloses a light-weight thermoplastic composite material and application of the light-weight thermoplastic composite material in a storage battery plastic shell, and belongs to the technical field of thermoplastic composite materials. Then transferring the mixture into a high-speed mixer, adding ABS particles, polycarbonate particles, polypropylene particles, maleic anhydride grafted ABS, a flame-retardant filler and assistants (an antioxidant, an anti-aging agent and a lubricant), mechanically mixing, carrying out melt extrusion, and finally pelletizing to obtain the lightweight thermoplastic composite material. According to the lightweight thermoplastic composite material disclosed by the invention, halogen-free raw materials are selected, and the flame-retardant filler takes biomass composite powder as a carrier to load melamine phosphate, so that halogen pollution can be avoided, and a more environment-friendly and sustainable flame-retardant solution is provided for a storage battery plastic shell.

The application discloses high-flame-retardant pouring sealant and a preparation method thereof, and belongs to the field of flame-retardant materials. The pouring sealant comprises component A and component B. The component A comprises the following raw materials: base glue, inorganic filler, titanium white, flame retardant and deep curing agent. The component B comprises the following raw materials: diluent, waterproof agent, crosslinking agent, coupling agent and catalyst. The inorganic filler comprises at least one of aluminum hydroxide or magnesium hydroxide, and the flame retardant comprises at least one of UN-333, melamine phosphate, melamine cyanurate or melamine polyphosphate. The high-flame-retardant pouring sealant can improve the flame retardance of the product by adding a small amount of flame retardant, and can also add a proper amount of magnesium hydroxide filler to enhance the flame retardance, and the flame retardance grade is UL94 V0. The pouring sealant can realize deep curing quickly, has the synchronous curing effect of the colloid surface and the inside, and simultaneously has excellent tensile strength, elongation at break, low glue viscosity, good fluidity and excellent aging resistance.