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34results about How to "Good thermal oxidation resistance" patented technology

Polyphenylacetylene silicon oxide borane and preparation method thereof

ActiveCN102234375ADoes not affect crosslink densitySolve molding difficultiesBoron carbideSilicon oxide
The invention discloses polyphenylacetylene silicon oxide borane and a preparation method thereof. The structure of the prepared polyphenylacetylene silicon oxide borane is shown as a formula I, wherein R1 and R2 refer to CH3, C6H5, and n is 1-100. The preparation method comprises the following steps of: performing hydrogen chloride removal reaction on trichlorosilane and alkyl boric acid to obtain polychlorosilicon oxide borane; and reacting the polychlorosilicon oxide borane with phenylacetylenelithium to obtain the polyphenylacetylene silicon oxide borane. In the polymer, a repeat unit contains polyphenylacetylene, so the magnitude of the polymerization degree cannot influence the crosslinking density of the polymer. The molecular weight of the polymer can be controlled by proportioning raw materials. In high temperature environment, the surface of a material is vitrified, and a ceramic layer such as a silicon carbide layer or a boron carbide layer is formed, so that the inner material is isolated from heat and oxygen; therefore, the thermal oxidation performance of the structural material is improved. The polyphenylacetylene silicon oxide borane is applied to preparing ceramic precursors, high-performance composite material matrixes, ablation resistant materials, high temperature resistant coatings and the like. The formula I is shown in the specifications.
Owner:EAST CHINA UNIV OF SCI & TECH +1

Environment-friendly type fireproof decorative board

The invention discloses an environment-friendly type fireproof decorative board and belongs to the field of decoration. The decorative board comprises a board body, wherein a side wall of the board body is covered with an environment-friendly type fireproof coating; the environment-friendly type fireproof coating is prepared from the following components in parts by weight: 30 to 50 parts of acrylate emulsion adhesive, 1 to 5 parts of aluminum hydroxide, 2 to 6 parts of ammonium polyphosphate, 1 to 4 parts of mica powder and 2 to 6 parts of sodium hexametaphosphate. The environment-friendly type fireproof decorative board disclosed by the invention has the following beneficial effects that the ammonium polyphosphate has relatively good flame-retarding and smoke-suppression effects; the aluminum hydroxide has three functions of flame retarding, smoke suppression and filling; the ammonium polyphosphate has a strong dehydration effect and the aluminum hydroxide can be dehydrated, crystallized and heated, so that the flame-retarding effect of a flame retarding system is increased, and furthermore, a synergetic effect is generated. The sodium hexametaphosphate has a dispersion effect and each component can be uniformly dispersed in an acrylate emulsion adhesive system, so that the flame-retarding effect of the raw materials of the environment-friendly type fireproof coating is improved; meanwhile, the synergetic effect between the aluminum hydroxide and the ammonium polyphosphate is further improved.
Owner:温州北宸建设有限公司

Single-component water-based silicon-fluorine modified acrylate emulsion wood lacquer and preparation method thereof

The invention discloses a single-component water-based silicon-fluorine modified acrylate emulsion wood lacquer and a preparation method thereof. The preparation method comprises the following steps: S1, weighing a certain amount of water, an emulsifier, butyl acrylate, methyl methacrylate, acrylonitrile, styrene, acrylic acid and hydroxyethyl methylacrylate; S2, mixing the raw materials to obtain a pre-emulsion A; S3, mixing a part of the pre-emulsion A, vinyl triisopropoxy silane and a silicon-fluorine modified resin to obtain an organic silicon-fluorine pre-emulsion B; S4, mixing water, part of the pre-emulsion A, ammonium persulfate and sodium bicarbonate to obtain a solution, heating the solution to 80-85 DEG C, and stirring until the solution presents blue light; S5, adding an ammonium persulfate aqueous solution and the pre-emulsion A, adding the organic silicon-fluorine pre-emulsion B after the pre-emulsion A is added, then heating to 85-90 DEG C, keeping the temperature for 2-3 hours, then cooling to 65-70 DEG C, adding tert-butyl hydroperoxide and sodium erythorbate, and keeping the temperature for 0.5-1 hour; and S6, cooling to room temperature, adding a preservative and a defoaming agent, and then adjusting the pH value to 7-8 to obtain a finished product.
Owner:LIAONING FIXED STAR FINE CHEM +1

Preparation method of epoxy resin-based heat-conducting, heat-resisting and electric-conducting adhesive film

The invention discloses a preparation method of an epoxy resin-based heat-conducting, heat-resisting and electric-conducting adhesive film, and relates to the field of epoxy resin-based heat-conducting, heat-resisting and electric-conducting adhesive films. Epoxy resin and an electric-conducting accelerant are uniformly mixed and fully ground, silver powder is added, then a diluent, a coupling agent and an anti-aging agent are added and uniformly mixed, a curing agent is added and uniformly mixed, and the epoxy resin-based heat-conducting, heat-resisting and electric-conducting adhesive film is obtained. The epoxy resin-based heat-conducting, heat-resisting and electric-conducting adhesive film solves the problems that the design requirement cannot be met when an electric-conducting silver adhesive material is used for packaging, and cracking deformation is caused by thermo-oxidative aging of an epoxy resin-based material; through the synergistic effect of the epoxy resin, the electric conduction accelerant, the silver powder and the anti-aging agent, the epoxy resin-based heat-conducting, heat-resisting and electric-conducting adhesive film has good manufacturability during application, packaging of thinner and smaller chips is achieved, meanwhile, piperazine and piperidine are integrated in the same molecule through a chemical synthesis method, and therefore the heat-conducting, heat-resisting and electric-conducting adhesive film is obtained. And the anti-aging agent has a more efficient anti-aging effect.
Owner:常州宏巨电子科技有限公司
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