The application discloses a preparation method and application of
fluorine-containing cross-linkable
polyimide-based carbon
molecular sieve membrane and belongs to the technical field of
gas separation membranes. 4,4'-(hexafluoroisopropyl) diphthalic anhydride is used as a dianhydride
monomer, 3,5'-diaminobenzoic acid and 4,4'-diamino
diphenyl ether are used as common
diamine monomers to copolymerize a
polyamide acid solution; the
polyamide acid solution is prepared into a
casting solution, and after standing and defoaming, a
polyamide acid membrane is prepared by using a
coating method, and the polyamide acid membrane is imidized to prepare a
polyimide membrane; the
polyimide membrane is used as a
polymer precursor membrane of the carbon
molecular sieve membrane, is placed in a programmed temperature
carbonization furnace with a protective
atmosphere and is high-temperature baked to obtain the
fluorine-containing cross-linkable polyimide-based carbon
molecular sieve membrane. The carbon molecular
sieve membrane is not only easy to prepare but also excellent in anti-aging capacity; the carbon molecular
sieve membrane is used for CO2 / N2 and CO2 / CH4 separation, and has a high CO2
permeation coefficient and CO2 / N2 and CO2 / CH4 separation factors.