This invention provides a
ceramic proton exchange membrane for microbial
fuel cells and its preparation method, comprising the following steps: mixing clay, an inorganic modifier, and an organic modifier to obtain a
solid powder; the inorganic modifier is
alumina and
silicon dioxide, and the organic modifier is selected from one or more of
wheat flour,
biochar powder,
straw powder, and bamboo powder; the
solid powder is ball-milled, granulated, pressed into sheets, and calcined to obtain the
ceramic proton exchange membrane. This invention addresses the problems of poor
mass transfer performance and low power generation performance of traditional pure clay
ceramic membranes. Using clay as the matrix material, and through specific inorganic and organic modifiers, the pore structure of the material is adjusted. A novel ceramic
proton exchange membrane is then prepared through ball milling,
granulation, pressing, and
calcination. This membrane has low manufacturing cost, good
proton transport efficiency, and extremely low
internal resistance. When applied to microbial
fuel cells, it can achieve higher output
voltage and more stable power generation performance.