The invention relates to an environment-friendly-type polluted oil processing agent, which is prepared by a surfactant, a flocculating agent and a solvent through uniformly mixing in a mechanical blending mode, the surfactant is a cationic surfactant and/or an anionic surfactant and/or a non-ionic surface active agent and/or an ampholytic surfactant, the flocculating agent is one of polyferric sulfate, polymeric aluminum ferric sulfate, polymeric aluminium and aluminum sulfate, and the solvent is a mixture of one or more of methyl alcohol, ethyl alcohol, ethylene glycol, propylene glycol, propanetriol or ethylene glycol butyl ether. According to the invention, a plurality of surfactants are employed for compounding, so that electrostatic neutralization effect can be generated on the surface of oil droplets, the stability of an emulsion is worse, so that the purposes of demulsification and oil-water separation can be reached, the flocculating agent has the effect for removing small impurity and mud, as well as demulsificating, so that oil removal efficiency can be increased. According to the invention, dewatering efficiency of the polluted oil processing agent is high, the crude oil can be effectively separated from the polluted oil, the pollution of the polluted oil to the environment can be reduced, and the administration cost is saved.