The invention relates to a method for preparing no-binding agent ZSM-11
zeolite, which mainly aims at overcoming the defects of difficult
recovery, easy deactivation and easy aggregation existing in the practical application of the
zeolite powder and the problems of small
effective surface area and limited
diffusion due to the addition of the binding agent in the forming process. In the invention, at least one of diatomaceous earth, carbon white, silicasol or water glass is taken as a
silicon source, at least one of aluminum
oxide, aluminum salt or
aluminate is taken as an aluminum source, and proper quantity of necessary
crystal seed guiding agents are added and subjected to pugging,
extrusion and forming so as to obtain a precursor mixture with the
mass ratio of XNa2O:YAl2O3:100SiO2, wherein x is between 0.5 and 14, and y is between 0 and 6, and the precursor mixture is subjected to hydrothermal
crystallization treatment in the water solution containing tetrabutyl
ammonium positive ions and converted to the no-binding agent ZSM-11
zeolite. The technical proposal of the invention better resolves the problems, and can be applied to the industrial preparation of the ZSM-11 zeolite
molecular sieve catalyst.