Transition metal sulfide/graphene composite material, and preparation method and application thereof

Abstract

The invention discloses a transition metal sulfide / graphene composite material which is composed of a nano transition metal sulfide and graphene, wherein the transition metal sulfide is Ni2S3, NiS, FeS, FeS2, CoS, CoS2, CuS2, CuS, MnS or MnS2. Under the dispersion and loading actions of the graphene, the transition metal sulfide can be uniformly distributed and have small particle size, the stability and loop stability of the transition metal sulfide in the charging and discharging process can be effectively enhanced, and the composite material can be used as a lithium ion battery negative pole material. The invention also discloses a one-step low-temperature preparation method of the composite material, which has the advantages of simple technique, low cost, short cycle, low energy consumption and the like and is suitable for large-scale industrial production.

Description

technical field

[0001] The invention relates to the field of composite materials for lithium ion batteries, in particular to a transition metal sulfide / graphene composite material and a preparation method and application thereof. Background technique

[0002] Lithium-ion batteries have the advantages of high working voltage, high energy density, and good safety performance. Therefore, they are widely used in portable electronic products such as digital cameras, mobile phones, and notebook computers. They also have application prospects for electric bicycles and electric vehicles. At present, commercial lithium-ion batteries generally use carbon-based negative electrode materials, such as graphite. Although this material has high stability, its theoretical capacity is only 372mAh·g -1 .

[0003] Compared with carbon materials, some transition metal sulfides have higher theoretical capacity, such as NiS with a theoretical capacity of up to 589mAh g -1 . This type of transit...

Images