866 results about "Biomass feedstock" patented technology

The invention discloses a biomass asphalt composite derivative hard carbon material and a preparation method and application thereof, and the preparation method comprises the following steps: step (1), placing biomass raw material powder in an acid pickling solvent for acid pickling, washing to be neutral after acid pickling, and drying to obtain a biomass precursor; (2) mixing the biomass precursor with asphalt to obtain a precursor mixture; and (3) carrying out low-temperature pre-oxidation on the precursor mixture, and then carrying out high-temperature carbonization, so as to obtain the biomass asphalt composite derivative hard carbon material after the high-temperature carbonization is finished. The prepared biomass asphalt composite derivative hard carbon material is used for preparing a sodium ion battery negative electrode. The technical problems that an existing biomass hard carbon material is low in capacity and tap density, difficult in impurity removal and the like can be solved, the biomass hard carbon material can be used for a sodium-ion battery negative electrode, and the sodium storage performance of a sodium-ion battery is improved.

The invention relates to the technical field of mesoporous carbon material preparation, in particular to a high-temperature mesoporous carbon preparation method which comprises the following steps: S1, mixing a metal halide and an inorganic hydrogen bond donor, and heating and stirring until a solution is clear to obtain an inorganic eutectic solvent; s2, mixing the inorganic eutectic solvent and a biomass raw material for reaction; s3, filtering and washing the material obtained in the step S2; and S4, carbonizing the material obtained in the step S3 in a high-temperature inert atmosphere to obtain the high-temperature mesoporous carbon. According to the method, the wood fiber biomass such as the lowest-value straw, the lowest-value bamboo and the lowest-value wood dust is directly used as raw materials, component separation does not need to be conducted on the wood fiber biomass, and high-value utilization of a large amount of low-value wood fiber biomass can be achieved. The method is relatively simple in process, relatively mild in condition and relatively high in product yield, and an activating agent does not need to be used. The biomass mesoporous carbon prepared by the method also has a high specific surface area in a huge mesoporous volume state, and the specific capacitance in an alkaline electrolyte exceeds 260F / g.

The invention relates to the technical field of soil function improvement, in particular to a rice field soil recarburization and capacity expansion method based on a charcoal-based organic fertilizer. The method comprises the following steps: crushing a biomass raw material, pyrolyzing and cooling to obtain biochar; immersing the biochar in a functional bacteria solution containing actinomycetes and bacillus for activating treatment to obtain modified biochar; mixing the modified biochar and decomposed straw, composting and fermenting to obtain organic fertilizers with different particle sizes; the large-particle-size organic fertilizer is applied to deep soil, the soil is covered with soil after straw is laid on the soil, and the small-particle-size organic fertilizer is applied to surface soil. Through layered application, the large-particle-size biochar repairs the deep soil structure and expands the carbon storage capacity, and meanwhile, the carbon stability is improved through carbon-nitrogen synergistic metabolism driven by functional bacteria, so that the carbon immobilization efficiency is improved, meanwhile, soil recarburization and expansion are achieved, the contradiction between carbon sequestration and structure degradation and nutrient imbalance in a traditional recarburization and expansion technology is solved, and the soil recarburization and expansion efficiency is improved. Synergic improvement of a carbon sink function and agricultural productivity is promoted.

The invention discloses a biomass-based sodium ion battery hard carbon material and a preparation method and application thereof, and the preparation method comprises the following steps: uniformly mixing a biomass raw material, an oxidation pore-forming reagent and water to obtain a precursor dispersion liquid, standing and drying the precursor dispersion liquid to obtain a hard carbon precursor, pre-carbonizing the hard carbon precursor at 650-900 DEG C for 1-5 h, and cooling to room temperature to obtain the biomass-based sodium ion battery hard carbon material. And carrying out acid pickling to remove impurities so as to obtain an oxidation pore-forming activated material, carrying out deep carbonization on the oxidation pore-forming activated material at 1150-1450 DEG C for 1-8 hours, and cooling to room temperature, so as to obtain the biomass-based sodium ion battery hard carbon material. The biomass-based sodium-ion battery hard carbon material obtained by the invention has the advantages of high first-circle charge specific capacity, high first-circle discharge specific capacity, high slope capacity, high first-circle coulombic efficiency and high cycle stability.

The invention relates to the technical field of chemical automation control, and discloses an intelligent closed-loop control system for producing p-dichlorobenzene by a biomass method, which comprises a signal acquisition module, a residence time reconstruction module, a thermal coupling analysis module, a parameter self-adaptive scheduling module and an execution control module. The rheological characteristics of raw materials are monitored by collecting the current of a stirring motor, the liquid level is dynamically increased through a retention time reconstruction module to prolong the retention time of the materials, and a liquid level periodic migration strategy is introduced to prevent scaling of a gas-liquid interface; the thermal coupling analysis module and the parameter self-adaptive scheduling module are used for calculating thermal retardation post factors, temperature control parameters are corrected in real time, the upper limit of cooling output is limited, inner wall supercooling crystallization is prevented, and the problems that the conversion rate is reduced, the heat transfer efficiency is reduced and equipment is hung on the wall due to viscosity fluctuation of biomass raw materials are effectively solved. And the self-adaptive stable control of the reaction process is realized.

The invention provides a biochar composite porous material for heavy metal contaminated soil remediation and a preparation method and application of the biochar composite porous material. The preparation method comprises the steps that biomass raw materials are subjected to high-temperature pyrolysis carbonization and then smashed, ground and sieved, and biochar powder is obtained; dispersing in a phosphoric acid solution to obtain a biochar solution, and filtering, washing and drying after a hydrothermal activation reaction to obtain activated biochar; dispersing in a chitosan solution, carrying out ultrasonic oscillation, filtering, washing and drying to obtain modified charcoal; mixing sodium bentonite, attapulgite and deionized water, uniformly mixing the modified charcoal, the functional slurry and a sodium carboxymethyl cellulose solution to obtain composite slurry, performing compression molding to obtain a green body, and then drying and calcining the green body. The biochar composite porous material prepared by the invention can simultaneously play multiple roles of physical adsorption, chemical chelation, ion exchange and the like in a heavy metal contaminated soil treatment process, so that efficient fixation of various heavy metal ions is realized.

The invention provides phosphorus-doped hydrothermal synchronously-activated hierarchical pore green biochar, a preparation method thereof and application of the phosphorus-doped hydrothermal synchronously-activated hierarchical pore green biochar in formaldehyde adsorption, and belongs to the technical field of biomass resource high-value utilization and air pollution control. The preparation method comprises the following steps: mixing a biomass raw material with a phosphoric acid catalyst, carrying out hydrothermal carbonization reaction, carrying out solid-liquid separation on a reaction product after the reaction is finished, collecting a solid-phase material, drying, mixing with potassium hydroxide, activating, washing and drying the obtained product, and thus obtaining the phosphorus-doped hydrothermal synchronously-activated hierarchical porous green charcoal. Phosphoric acid is introduced in the hydrothermal stage to serve as a structure-directing agent and a doping source, uniform doping of phosphorus and coordinated regulation and control of a pore structure are achieved, a hierarchical pore channel system is formed in the subsequent activation process, and the physical adsorption and chemical fixation capacity of the biochar to formaldehyde molecules is greatly improved.

The invention relates to the technical field of soil remediation, in particular to a charcoal-fungus symbiont for a freeze-thaw environment and a preparation method and application of the charcoal-fungus symbiont. The preparation method of the charcoal-fungus symbiont comprises the following steps: crushing a biomass raw material, and carrying out pyrolysis to prepare basic charcoal; placing the basic biochar in an iron oxide solution, and carrying out an iron oxide loading reaction to obtain iron oxide biochar; the preparation method comprises the following steps: dipping iron oxide biochar in a chitosan solution for coating modification, then continuously adding a cross-linking agent for cross-linking solidification, and freeze-drying to obtain chitosan-iron oxide composite modified biochar; and immersing the chitosan-iron oxide composite modified biochar into a bacterial suspension of functional microorganisms, oscillating and adsorbing, and freeze-drying to obtain the carbon-bacteria symbiont. The invention aims to improve the heavy metal pollution phenomenon of soil and the soybean root rot disaster in the freezing and thawing cycle environment at the same time.

The invention relates to the field of biomass energy and chemical industry, in particular to an efficient methanol preparation method based on biomass graded catalytic conversion and cycle coupling. The method comprises the following steps: in a graded catalytic oxidation reaction system, mixing a biomass raw material with a composite vanadium-based catalyst, water, oxygen and circulating methanol for reaction to generate a gas-liquid mixture containing methyl formate; recycling methyl formate by using a gradient variable-pressure rectification separation system; carrying out an interface hydrogenation reaction under the action of a copper-zinc-LTA hierarchical pore catalyst to generate methanol; finally, part of methanol is purified and recycled through membrane separation. The method realizes efficient conversion from biomass to methanol, has the advantages of mild reaction conditions, low energy consumption, high yield and good catalyst stability, and opens up a new path for industrialization of preparation of methanol from biomass.

The invention relates to the technical field of aquaculture, in particular to an aquaculture water environment repairing agent and a preparation method thereof, and the repairing agent is composed of a modified biochar composite material, chlorella microspheres, a cross-linking agent and a microbial compound inoculant. The modified biochar composite material is prepared through the steps of mixing attapulgite and biomass raw materials, performing acid activation, performing pyrolysis and the like, and tannic acid is used for further modification so as to enhance the adsorption capacity; the chlorella microspheres are prepared from sodium alginate and a CaCl2 solution, and have good suspension property and stability; the microbial complex microbial inoculant contains various beneficial bacteria, and can decompose organic matters and reduce the content of ammonia nitrogen and nitrite; the components of the repairing agent are combined through the cross-linking agent to form particles, so that the repairing agent is convenient to put and recycle. The repairing agent disclosed by the invention has efficient pollutant removal capacity, and can be used for remarkably improving the water quality of aquatic water, improving the transparency of the water, increasing dissolved oxygen and promoting the health and stability of an aquatic ecosystem.

Through sourcing net-primary productivity additive algae-based biomass feedstock, the exclusive use of renewable energy in processing, and the appropriate formulation and processing, a novel algae-derived bio-based plastic is both carbon-negative and provides some performance advantages over existing algae-based film plastics especially with regard to optical clarity. A system may be provided that produces a carbon-negative bioplastic. The production of the bioplastic in a process chamber may be controlled by an electronic controller. The electronic controller may be controlled by a host system, such a server. The electronic controller may be configured to direct production of the bioplastic in the process chamber using hydrocolloid, which is derived from algae.

The invention discloses a method for preparing biomass-based hard carbon through in-situ continuous catalytic carbonization and application, and belongs to the technical field of biomass-based carbon material preparation and energy storage. The method comprises the following steps: mixing a biomass raw material with a zinc salt aqueous solution; performing low-temperature pyrolysis and carbonization on the mixed material in an inert atmosphere; performing high-temperature carbonization on the low-temperature pyrolysis carbonization intermediate in an inert atmosphere; and after high-temperature carbonization is finished, naturally cooling to room temperature, washing and drying to obtain the hard carbon material. By utilizing the differentiated existence forms of the zinc salt at different temperatures and the characteristics of in-situ continuous catalysis and high-temperature volatilization, special rapid heating equipment is not needed, and the catalyst does not need to be washed off after low-temperature pyrolysis carbonization, so that the cooperative regulation and control of the interlayer spacing and the closed-pore structure of the biomass-based hard carbon microcrystalline are realized; the biomass-based hard carbon with wide microcrystalline interlayer spacing and rich closed pore structures is obtained. The obtained hard carbon has large reversible specific capacitance, high platform capacity and high rate performance when being applied to a sodium / lithium ion battery negative electrode material.

The utility model discloses a catalytic hydrogenation reactor for treating a biomass raw material with a high acid value and a high iodine value, and belongs to the technical field of oil product hydrogenation. The catalytic hydrogenation reactor comprises a reactor pressure-bearing container, an inner cylinder, an ash discharge port, a feeding assembly, a reaction assembly and a discharging assembly, the inner cylinder is arranged in the reactor pressure-bearing container, the feeding assembly and the reaction assembly are arranged in the inner cylinder, the reaction assembly comprises a ceramic tube bundle internal part, the discharging assembly is arranged above the inner cylinder, and the discharging assembly is arranged above the inner cylinder. The ash discharge port is formed in the center of the bottom of the reactor pressure-bearing container. By arranging the ceramic tube bundle internal part in the catalytic hydrogenation reactor, on one hand, the ceramic tube bundle internal part serves as a reaction assembly and has certain acid corrosion resistance, and on the other hand, the ceramic tube bundle internal part serves as a solid catalyst carrier, selective hydrogenation of high-acid-value and high-iodine-value biomass raw materials is achieved, the iodine value is effectively reduced, and coking of the high-iodine-value biomass raw materials in the reaction process is avoided; in addition, the acid value is maintained as far as possible while the iodine value is reduced, and the solid catalyst and the catalytic hydrogenation reactor are not corroded, so that the stability of the solid catalyst and the yield of the product are improved.

The invention provides a polygeneration system and method for coupling wind-solar hydrogen production with CO2 capture and utilization, and relates to the technical field of green energy. The system comprises a renewable energy source driving subsystem used for providing green electric energy and preparing green hydrogen as an energy carrier and a synthetic raw material to be supplied to a multi-path utilization subsystem; the carbon source conversion and capture subsystem is used for receiving the biomass raw material, generating gasified synthesis gas and biomass charcoal through gasification reaction, and capturing and recycling CO2 in flue gas discharged by the system; the multi-path utilization subsystem is used for receiving H2, the gasified synthesis gas and CO2 and blending reaction components to realize synthesis of green methanol, conventional methanol and green ammonia; closed-loop circulation of carbon resources is formed among the subsystems through continuous conversion, capture and feedback paths of H2, CO2 and biomass charcoal. According to the scheme, efficient synergistic conversion of hydrogen and carbon resources and full-amount utilization of carbon elements can be achieved in regions with limited carbon sources.

This invention belongs to the field of high-value utilization technology of biomass resources, and discloses a method for catalyzing the depolymerization of lignin into phenolic compounds using a RuNiZn / Nb2O5 catalyst. The method includes: uniformly mixing the RuNiZn / Nb2O5 catalyst, lignin-containing biomass feedstock, and water; stirring under hydrogen atmosphere to carry out the depolymerization reaction; after the reaction, cooling to room temperature and performing solid-liquid separation; evaporating the solvent to obtain the hydrogenated depolymerization product containing monophenols. In this invention, the RuNiZn / Nb2O5 catalyst employs a technique of replacing precious metals with various non-precious metals, which improves the catalyst's reactivity and reduces the amount of precious metals used. This increases the yield of lignin depolymerization products, provides milder depolymerization reaction conditions, and ultimately significantly reduces the catalyst preparation cost and the energy cost of the lignin depolymerization process.

The invention relates to the technical field of steel sintering processes, in particular to a biomass gasification coupling system for a steel sintering process, which comprises a biomass gasification system, a circular cooler waste heat utilization system and a waste heat power generation system, the biomass gasification system comprises a biomass drying system, a raw material conveying belt system, a biomass gasification furnace, a biomass gas heat insulation combustion chamber, a sintered coke powder preparation system and a biomass gas purification system, and the biomass drying system is used for drying biomass raw materials; and the dried biomass raw materials are conveyed to the biomass gasification furnace through the raw material conveying belt system. According to the coupling system for biomass gasification for the steel sintering process and the control method, biomass serves as zero-carbon energy, and biomass charcoal obtained after biomass gasification can replace part of solid fuel to achieve the carbon reduction effect. Meanwhile, the biomass gasified gas can replace a part of coal gas, and the carbon reduction effect can also be achieved.

The present invention provides a biomass gasification control system and a biomass gasification control method, and belongs to the field of biosynthesis, the biomass gasification control system comprises: a first-stage fluidized bed pyrolysis reactor for performing a preliminary pyrolysis reaction on a biomass raw material to obtain a pyrolysis reactant; the second-stage fluidized bed gasification reactor is used for carrying out gasification reaction on the pyrolysis reactant by utilizing various gasification agents to obtain target synthesis gas, including H2 and CO; wherein the multiple gasifying agents comprise oxygen, water vapor and carbon dioxide; the sensor monitoring module is used for monitoring real-time state data in the first-stage fluidized bed pyrolysis reactor and the second-stage fluidized bed gasification reactor; the central control module is used for sending out an adjusting instruction according to the real-time state data, and the adjusting instruction is used for adjusting and controlling the flow of the multiple gasifying agents, the rotating speed of the fan and the reaction temperature, so that the molar ratio of H2 to CO in the generated target synthesis gas is within a first threshold value range.

The invention discloses a biomass fuel rod and a production method and application thereof, and belongs to the technical field of biomass fuels, the biomass fuel rod comprises the following components by mass: 60-80 parts of a biomass raw material, 10-20 parts of a binder, 1-5 parts of a combustion improver, 3-8 parts of a sulfur and chlorine fixing agent, 1-3 parts of a denitration agent, and 2-5 parts of an ash content regulator. The production method specifically comprises the following steps: (1) pretreatment: crushing a biomass raw material until the particle size is less than or equal to 2mm, and carrying out pretreatment by adopting baking semi-carbonization; (2) mixing: sequentially adding a binder, a combustion improver, a sulfur-fixing and chlorine-fixing agent, a denitration agent and an ash content regulator which are ground until the particle size is less than or equal to 2mm, and stirring and mixing for 5-10 minutes; (3) forming: carrying out extrusion forming by adopting a twin-screw extruder under the pressure of 15-25MPa and the temperature of 80-100 DEG C to obtain a fuel rod with the density of 1.2-1.4 g / cm < 3 >; the production method is simple and easy to implement, the combustion performance of the produced fuel rod is good, and the combustion efficiency and the environmental protection property are improved.

The invention belongs to the technical field of battery materials, and mainly relates to a pre-oxidized asphalt synergistically coated double-layer hard carbon negative electrode material, a preparation method thereof and a sodium ion battery. The method comprises the following steps: crushing and sieving a biomass raw material, and then carrying out pre-carbonization treatment to obtain a pre-carbonized precursor; carrying out ball milling and sieving on the pre-carbonized precursor, carrying out acid pickling, and drying to obtain a purified precursor; stirring and mixing the purified precursor and asphalt, and performing heating pre-oxidation synergistic coating treatment by adopting an oxygen concentration gradient control method to obtain a pre-oxidized asphalt synergistic coating material; and performing high-temperature carbonization treatment on the pre-oxidized asphalt synergetic coating material to obtain the pre-oxidized asphalt synergetic coating double-layer hard carbon negative electrode material. The pre-oxidized asphalt synergistically coated double-layer hard carbon negative electrode material has a low specific surface area and a stable coating layer structure, and can be used as a sodium ion battery negative electrode material to effectively improve the conductivity of a sodium ion battery, improve the first coulombic efficiency and rate capability and prolong the cycle life of the battery.

The invention belongs to the field of simulation optimization control, and particularly relates to a biomass gas blending combustion parameter optimization simulation control system based on combustion product prediction, and the system comprises an acquisition module which carries out data preprocessing based on multi-source pilot frequency sampling and through frequency division domain adaptive filtering and variable step size gradient descent optimization; the prediction module is used for predicting combustion product characteristic indexes through a mechanism and data driven double-layer fusion model; the control mapping module is used for obtaining a boiler control response parameter set by adopting deep reinforcement learning strategy network analysis under multi-target constraint; and the simulation adjustment module is used for loading control parameters in the digital twin platform, judging deviation based on a dynamic self-adaptive threshold value and triggering closed-loop feedback adjustment. According to the method, the problems of inaccurate pollutant prediction and control lag caused by fluctuation of biomass raw materials are solved, and feed-forward accurate control and closed-loop adaptive optimization are realized.

The present invention discloses a biomass-based ionic liquid-modified carbon quantum dots, a preparation method thereof, and a composite lubricant. The preparation method of the biomass-based ionic liquid-modified carbon quantum dots uses biomass raw materials, choline chloride, and amino acids to prepare carbon quantum dots and choline amino acid ionic liquid. The choline amino acid ionic liquid is used to modify the carbon quantum dots to produce a biomass composite lubricant. This uses renewable biomass resources instead of traditional petrochemical resources, is environmentally friendly, can be decomposed by nature, achieves clean production, and eliminates environmental pollution. The CQDs / ILs composite lubricant can function as "nanoballs," thereby improving its load-bearing capacity and reducing wear. In addition to having good lubricating properties, the choline amino acid ionic liquid also has good solubility. Modifying the carbon quantum dots with the choline amino acid ionic liquid not only improves the dispersibility of the carbon quantum dots but also further enhances their tribological properties.

The invention provides a synthesis gas preparation method based on a double-circulation gasifier. The synthesis gas preparation method based on the double-circulation gasification furnace comprises the following steps: S1, feeding a biomass raw material and a gasification agent into the double-circulation gasification furnace for gasification; s2, performing primary separation on the synthesis gas generated by gasification, returning a solid material generated by the primary separation to the double-circulation gasification furnace, and performing secondary separation on the synthesis gas after the primary separation; and S3, returning the solid material generated by the second-stage separation to the double-circulation gasification furnace. According to the preparation method of the synthesis gas, the carbon conversion rate and the gasification efficiency can be effectively improved, the total concentration of carbon monoxide and hydrogen in the synthesis gas is greater than 65%, and the quality of the biomass gasification synthesis gas is greatly improved.

The invention discloses an intelligent biomass raw material feeding system which comprises a front-end recognition device, an unmanned forklift and a control device, and the front-end recognition device is arranged in a biomass bin, comprises a millimeter-wave radar and an industrial camera and is used for recognizing material piles, the forklift, trucks, personnel and the like; the unmanned forklift is used for carrying out corresponding tasks according to instructions of the control device; the control device comprises a processing module, a communication module and a storage module, and the processing module carries out processing according to data of the front-end recognition device and the unmanned forklift, generates forklift path planning and multi-forklift cooperative control instructions, controls the unmanned forklift to complete corresponding tasks and carries out intelligent management on unloading and stacking. The problems that in the prior art, biomass raw material feeding is low in efficiency, inaccurate in recognition, high in cost and the like can be solved, and unmanned, intelligent and efficient biomass raw material feeding operation can be achieved easily.

The invention discloses an element-doped biomass hard carbon negative electrode material and a preparation method thereof. The preparation method of the biomass hard carbon negative electrode material comprises the following steps: carrying out pretreatment, pre-oxidation treatment, stepped acid washing, alkali washing, pre-carbonization treatment, element doping, vapor phase diffusion deposition coating and high-temperature carbonization on a biomass raw material to prepare the element-doped biomass hard carbon negative electrode material. According to the invention, the biomass raw material is subjected to pre-oxidation and element co-doping, and the surface of the biomass raw material is modified through gas phase diffusion deposition coating, so that the biomass hard carbon negative electrode material has relatively high specific capacity and first coulombic efficiency, and can show good rate capability and cycling stability.

The present application belongs to the technical field of biomass energy power generation, and particularly relates to a decoupling type biomass gasification power generation system and a multi-parameter collaborative control method, which comprises the following steps: 1) biomass raw materials are fed into a vertical multi-stage decoupling gasification furnace for gasification, a gasification agent and water vapor are introduced into the decoupling gasification furnace, the amount of the gasification agent and water vapor introduced is adjusted, and the temperature in the reduction zone is controlled at 700-900 DEG C; 2) the gasification products of the decoupling gasification furnace are cooled by a heat exchanger, then filtered by a filter I for the first time, water is removed by a steam-water condenser separator, pressurized by a Roots blower, filtered by a filter II for the second time, and then fed into an internal combustion engine for power generation; and 3) the gas discharged from the internal combustion engine is pressurized by an exhaust gas turbocharger, then compressed by a compressed air generator, and then fed into the decoupling gasification furnace as a gasification agent. The present application has the advantages that the present application can realize in-situ high-temperature catalytic cracking of tar, efficient utilization of waste heat, and stable operation of the system, thereby improving the power generation efficiency and reducing the equipment cost.

The invention discloses a method for preparing phenol by utilizing a biomass raw material, which comprises the following steps: 1) crushing biomass, adding the crushed biomass into a caustic alkali solution to carry out hemicellulose removal treatment, and carrying out solid-liquid separation to take a solid substance, so as to obtain hemicellulose-removed biomass; 2) adding the hemicellulose-removed biomass into an ethylene glycol-ferric chloride eutectic solvent for lignin extraction, then adding an acetone-water mixed solution, then carrying out solid-liquid separation, taking a liquid substance, adding water to precipitate the lignin, then carrying out solid-liquid separation, and taking a solid substance to obtain the lignin; and 3) pyrolyzing the lignin in a protective atmosphere to obtain lignin oil containing phenol. The method for preparing phenol from biomass raw materials has the advantages of simple operation, high phenol yield, high product purity, low energy consumption, safety, environmental protection and the like, and is suitable for large-scale industrial application.

The invention discloses a metal sulfide loaded biochar demercuration adsorbent as well as a preparation method and application thereof. The preparation method comprises the following steps: carrying out mechanochemical grinding on a biomass raw material and metal sulfate through a high-energy ball mill to obtain a uniform precursor; and then performing one-step pyrolysis in an inert atmosphere, synchronously carbonizing the biomass and reducing the metal sulfate into metal sulfide, and finally preparing the metal sulfide nanoparticle and charcoal matrix strong coupling composite material. The method is simple in process, green and efficient, and avoids the defects of a traditional liquid phase method. The prepared adsorbent is high in active component dispersity, is firmly combined with a carrier, shows high adsorption capacity, high removal efficiency and good anti-interference stability for elemental mercury in flue gas, and has a wide application prospect in the field of mercury pollution control of coal-fired flue gas.

The invention discloses a hydrogen-coupled green methanol production system and method, and a green methanol product is obtained through the procedures of gasification, purification, methanol synthesis, methanol rectification and the like. The hydrogen-coupled green methanol production system comprises a gas making unit, a purification unit, a methanol synthesis unit and a methanol rectification unit, the gas making unit is a biomass gasification unit, the biomass gasification unit comprises a normal-pressure circulating fluidized bed, the normal-pressure circulating fluidized bed gasifies a biomass raw material to generate crude synthesis gas, the purification unit is used for purifying the crude synthesis gas, and the methanol rectification unit is used for rectifying the crude synthesis gas. The hydrogen compression unit is connected in front of the methanol synthesis unit, the hydrogen compression unit is used for providing hydrogen, the methanol synthesis unit is used for synthesizing synthesis gas and hydrogen into crude methanol, and the methanol rectification unit is used for rectifying the crude methanol into refined methanol. The method can promote the resource utilization of biomass materials, achieves the purposes of energy conservation, emission reduction and environmental protection, meets the current requirements of environmental protection, energy conservation and low-carbon economy, and is beneficial to green and sustainable development.

A method for lignocellulose hydrolysis is provided. The method includes: crushing an agroforestry biomass feedstock, extracting with a toluene-ethanol solution, and drying to obtain a de-extracted feedstock; weighing a metal salt and glycerol for mixing to obtain a type IV deep eutectic solvent; weighing the de-extracted feedstock and adding into the type IV deep eutectic solvent, and reacting for 2 h-4 h at a temperature of 80° C.-120° C. and a stirring speed of 300 rpm-500 rpm to obtain a pretreatment mixture; performing a solid-liquid separation to the pretreatment mixture to obtain a filter residue and a filtrate, and then drying the filter residue after washing to obtain a lignocellulose residue after pretreatment; and performing enzymatic hydrolysis reaction to the lignocellulose residue to obtain fermentable sugar.

The invention relates to the technical field of preparation of activated carbon materials, in particular to a coupling activation preparation method and application of a biomass-derived porous carbon material. According to the coupling activation preparation method of the biomass-derived porous carbon material, the biomass-derived porous carbon material is prepared from a biomass raw material through the steps of fermentation, acid leaching reinforcement, hydrothermal carbonization, activation and acid pickling impurity removal. The biomass-derived porous activated carbon material prepared by the above steps is detected by a scanning electron microscope, and the biomass-derived porous activated carbon material is in a porous layer shape and has rich micropore and mesoporous structures; through electrochemical test experiment detection, the biomass derived porous activated carbon material has excellent capacitive performance, and when the current density is 0.5 A / g, the specific capacity value range is 200-400 F / g; the material also has good stability, the biomass derived porous activated carbon material is assembled into a symmetric supercapacitor, and after 10000 circles of stability tests, the retention rate of the specific capacitance of the symmetric supercapacitor can be maintained at about 96.4%.