887 results about "Coal gasification" patented technology

The invention provides a method for preparing aerogel by using high-carbon components in coal gas fine slag, which is characterized in that the high-carbon components with ash content lower than 30% in the coal gas fine slag are separated into light carbon and heavy carbon through an isodensity gradient centrifugation or ultrasonic separation technology. The light carbon is subjected to acid leaching impurity removal to obtain a carbon precursor, and then carbon aerogel is synthesized through a chemical activation method; the preparation method comprises the following steps: carrying out oxidation stripping on heavy carbon by using strong acid to obtain graphene oxide, then carrying out alkali activation for reduction, and finally carrying out acid pickling to obtain the graphene aerogel. The composition structural characteristics of the coal gasification fine slag residual carbon are fully utilized, and the preparation of the high-performance aerogel is realized through refined separation and treatment. According to the method, the resource utilization rate of the coal gasification fine slag can be increased, and a new path is provided for preparation of a high-added-value carbon material.

The invention discloses a coal gasification slag-based backfill material for replacing flow-state solidified soil, a preparation method and an application, utilizes a synergistic gelling effect among three raw materials, breaks through a material strength forming mechanism of traditional flow-state solidified soil, solves the problems of multiple components and high cost of a flow-state solidified soil material in the prior art, and has the advantages of low raw material cost, low raw material cost, low raw material cost, low raw material cost and the like. And the product popularization is facilitated. The specific scheme is as follows: the coal gasification slag-based backfill material for replacing the fluidized stabilized soil comprises coal gasification slag, carbide slag and titanium gypsum, the ratio of the coal gasification slag to the carbide slag to the titanium gypsum is 6-8: 1.5-3.5: 0.5-1.5, and an alkaline activator is also added; the coal gasification slag is a slag block with a set particle size formed after slag at the bottom of a gasification furnace is cooled, the carbide slag is waste slag which takes calcium oxide as a main component after acetylene gas is obtained by hydrolyzing calcium carbide, and under the action of an exciting agent, the coal gasification slag and the carbide slag are fully activated to release polyhedrons; part of the polyhedrons form a gelling product so as to improve the early strength of the coal gasification slag-based backfill material.

The invention relates to the technical field of adsorbent preparation, in particular to an ammonia modified porous carbon adsorbent and a preparation method thereof. The preparation method of the ammonia modified porous carbon adsorbent comprises the following steps: carrying out hydrothermal acid leaching on gasified fine residues and an acid solution to obtain acid leaching residues; stirring the acid leaching residues in an alkali solution, washing and drying to obtain a porous carbon material; and dipping the porous carbon material in a tetraethylenepentamine solution, and then drying to obtain the ammonia modified porous carbon adsorbent. The ammonia modified porous carbon adsorbent is successfully constructed by taking a porous carbon material derived from coal gasification fine slag as a substrate and further adopting a surface ammonia functionalization modification strategy. The preparation method is simple, the raw materials are easy to obtain, and the prepared ammonia modified porous carbon adsorbent has a good adsorption effect on methylene blue and hexavalent chromium. According to the method, high-added-value resource utilization of the coal gasification solid waste is achieved, and a solution is provided for treatment of the dye wastewater and the heavy metal wastewater.

The invention discloses a carbon / nano zero-valent iron composite material based on coal gasification slag and a preparation method of the carbon / nano zero-valent iron composite material. The method comprises the following steps: performing component separation on the coal gasification slag to obtain an iron-rich residual carbon component, mixing and grinding the iron-rich residual carbon component and sodium hydroxide according to a specific mass ratio, performing high-temperature calcination treatment in a nitrogen protective atmosphere, and performing hydrothermal activation reaction, solid-liquid separation, washing and drying to obtain the carbon / nano zero-valent iron composite material. The material shows excellent hexavalent chromium removal performance, can realize efficient removal of Cr (VI) in water within 5 minutes (the removal rate reaches 78.9%), and has remarkable structural stability. Synergistic activation of the endogenous iron-carbon components in the industrial solid waste is creatively achieved, a green and environment-friendly novel functional material solution is provided for heavy metal pollution treatment, and the method has important environmental benefits and industrial application value.

The invention discloses a method for preparing silicon carbide materials by using coal gasification slag, belonging to the field of solid waste recycling. The solution of the invention includes first pre-treating the coal gasification slag, then performing acid leaching, water washing, suction filtration and drying on the pre-treated coal gasification slag, and then performing Joule heating treatment. After calcination, silicon carbide is obtained; in the Joule heating treatment, the discharge voltage is set to 120V-150V, and the number of discharges is 1-5 times. By performing Joule heating treatment on the coal gasification slag, the reaction time of each Joule heating reaction is extremely short, greatly reducing the energy consumption, and sharply shortening the reaction time, solving the technical problem of high energy consumption caused by the long reaction time in the traditional carbothermal reduction for preparing silicon carbide materials in the prior art.

The invention discloses multi-scale toughened full-solid-waste ultrahigh-ductility concrete, which is prepared from the following raw materials in parts by weight: 500 to 650 parts of full-solid-waste cementing materials, 110 to 150 parts of calcined coal gasification slag, 190 to 250 parts of calcined fly ash, 20 to 40 parts of silica fume, 10 to 30 parts of metakaolin, 780 to 930 parts of washed sand, 10 to 25 parts of fly ash fibers, 0.6 to 0.9 part of hydroxypropyl methyl cellulose, 20 to 30 parts of polycarboxylic acid water reducing agents and 300 to 400 parts of water. The calcined coal gasification slag is subjected to gradient heating to 800-960 DEG C, heat preservation is conducted for 30-60 min, then the calcined coal gasification slag is cooled to the room temperature at the cooling rate of 10-15 DEG C / min, and the calcined coal gasification slag is obtained after powder grinding. According to the multi-scale toughened full-solid-waste ultrahigh-ductility concrete provided by the invention, the toughness and the mechanical property of the concrete can be enhanced, the performance of the concrete in an extreme environment is improved, meanwhile, the solid waste utilization rate is increased, and the production cost of the concrete is reduced.

The invention relates to the technical field of coal chemical industry, in particular to a coal gasification black water circulation and black water waste heat recycling system and method. The coal gasification black water circulation and black water waste heat recycling system comprises a synthesis gas washing tower, a high-pressure flash tank, a low-pressure flash tank, a black water heat exchanger, a vacuum flash tank, a settling tank, a grey water tank, a low-pressure flash steam stripping tower and a high-pressure flash steam stripping tower. The coal gasification black water treated by the coal gasification black water circulating and black water waste heat recycling system can be reused as circulating water of a synthesis gas washing tower, so that the cyclic utilization of water resources is realized, the use of fresh water and the discharge of waste water are reduced, and the production cost and the environmental pressure are reduced. Meanwhile, the problem that a black water pipeline is scaled and blocked due to high temperature is solved, waste heat of the black water can be fully replaced for effective utilization, carbon is reduced, energy is saved, the purpose of cooling the black water is achieved, the cooling cost of a vacuum flash evaporation system is saved, and continuous and reliable economic benefits are created for enterprises.

The invention provides a cocatalyst for promoting Fe < 3 + > reduction in the electro-Fenton application process and a preparation method thereof, and relates to the field of wastewater treatment.The preparation method comprises the steps that sodium molybdate, thiourea and coal gasification fine slag are evenly dispersed in deionized water, the mass ratio of sodium molybdate to thiourea is (0.30-2.5): (1.5-3.5), and a mixed system is obtained; the mixed system is subjected to heat preservation treatment at the temperature of 120-180 DEG C, sodium molybdate is subjected to a reduction reaction with thiourea after being subjected to thermal decomposition, nano lamellar cluster-shaped molybdenum sulfide is obtained, and reaction liquid is obtained; sediments in a reaction solution are subjected to microwave drying and freeze drying to obtain the cocatalyst for promoting Fe < 3 + > reduction in the electro-Fenton application process, Fe < 3 + > reduction can be promoted through valence change of molybdenum ions dissolved out of a solution and the unsaturated property of sulfur, and therefore Fenton reaction is enhanced to generate strong oxidizing free radicals to treat organic wastewater.

The invention relates to the technical field of coalification black water treatment, and particularly discloses a coal gasification black water flash steam waste heat steam turbine gradient utilization system which comprises a black water flash steam turbine module and a steam exhaust condensation module. The black water flash steam turbine module comprises a high-pressure flash evaporator, a low-pressure flash evaporator, a vacuum flash evaporator, a supplementary condensing steam turbine, a generator and a settling tank, and a water outlet of the vacuum flash evaporator is connected with the settling tank; the steam exhaust condensation module comprises an evaporative condenser and a condensate pump. Through the design of the scale scraping and water uniformizing piece, part of cooling water falling around the heat exchange coil from top to bottom falls on the water uniformizing plate to drive the water uniformizing plate to rotate, when the water uniformizing plate rotates, water on the water uniformizing plate is thrown out under the action of centrifugal force, cooling water without heat exchange can be uniformized to other heat exchange pipes for heat exchange, and the heat exchange efficiency is improved. Therefore, the cooling water flows more uniformly among the heat exchange coils, the utilization rate of the cooling water is improved, and the heat exchange efficiency is improved.

The application discloses a coal gasification slag heavy metal oxidation leaching separation processing system and method in the technical field of mine solid waste treatment, which comprises a multi-radical pre-oxidation device, a primary slag slurry separation and recovery device, a three-stage leaching device and a secondary slag slurry separation and recovery device. The multi-radical pre-oxidation device adds an oxidizing agent solution to the coal gasification slag in three stages and simultaneously performs ozone oxidation and mixing and stirring to obtain coal gasification slag slurry. The primary slag slurry separation and recovery device separates the coal gasification slag slurry, recovers excess oxidizing agent solution and screens out the coal gasification slag. The three-stage leaching device adds mixed organic acid solution to the screened coal gasification slag in three stages, performs mixing and stirring, gradually transfers the heavy metals in the coal gasification slag from the solid phase to the liquid phase, and obtains tail slurry. The application has the advantages of simple operation, low cost, good separation effect and the purpose of effectively controlling the risk of coal gasification slag heavy metal leakage.

The invention relates to the field of coal gasification chilled water, in particular to a coal gasification chilled water filtering system which comprises at least two filter bodies connected into a coal gasification chilled water system and arranged in parallel, and each filter body comprises a shell, a V-shaped sieve plate, a sieve plate flushing assembly and a shell flushing assembly. According to the coal gasification chilled water filtering system, on-line automatic dual cleaning of the filter body can be achieved, under the condition that normal operation of the filtering system is not affected, high-pressure grey water of a coal gasification grey water system is used for cleaning the sieve plate from the upper portion through the top flushing spray head, the inner wall of the shell is flushed through the combination of the side flushing pipe, and the filtering effect is good. The flushing effect of the filter body is improved, the service life of the filter body is prolonged, recycling of the filter body is achieved, the problems that at present, ash blocks the filter, chilled water supply is insufficient, and a gasification furnace cannot operate for a long period are solved, the working intensity of workers is reduced, and the production investment cost is saved.

The purpose of this invention is to provide a method for preparing cemented backfill materials based on response surface methodology using composite activating coal gasification slag. This method belongs to the field of mining engineering technology. Based on sorting and removing impurities from the coal gasification slag and drying it, the invention obtains ultrafine powder of the coal gasification slag for preparing the backfill material through ball milling. Then, coal gangue is crushed and screened using a crusher to obtain coarse, medium, and fine aggregates for the backfill material. Finally, cement, ultrafine coal gasification slag powder, coal gangue aggregate, activator, and water are mixed evenly to prepare the cemented backfill material. This invention not only solves the problem of low activity of coal gasification slag volcanic ash but also effectively controls the shortage of cemented backfill materials and high backfilling costs during cemented backfill mining, ensuring sustainable development. Furthermore, it effectively utilizes the widely accumulated coal gasification slag, reducing pollution and large-scale land occupation of the surrounding environment.

The invention belongs to the technical field of entrained-flow bed coal gasification processes, and particularly relates to an entrained-flow bed coal gasification grey water quality optimization method which comprises the following steps: (1) performing multi-stage flash evaporation on black water to be treated to obtain multi-stage concentrated black water; (2) adding a flocculating agent into the multi-stage concentrated black water to settle, and enabling the obtained supernatant liquid as overflow grey water to enter a filtration-adsorption system; (3) preparing a filter aid mixed solution in advance; before the filter is put into use, the filter aid mixed solution is introduced into the filter for precoating, and after precoating and filtering, the filter aid forms a filter aid filtering base layer on filter cloth of the filter; after the pre-coating process of the filter aid is finished, the overflow grey water is introduced into a filter for filtration-adsorption treatment; and (4) adding a dispersing agent into the obtained ash water filtrate to prepare recycled ash water, and feeding the recycled ash water into a washing tower and a gasification furnace for cyclic utilization. The method can effectively improve the water quality of the recycled grey water under the condition of reducing the dosage of the flocculating agent and the dispersing agent, and prolongs the operation period of a water system.

The invention discloses a grouting material for sealing CO2 in coal-based solid waste composite grouting and a preparation method, and belongs to the field of filling mining. The grouting material comprises the following components in parts by weight: 20-40 parts of coal gasification slag powder, 10-20 parts of coal gangue powder, 1-5 parts of an alkali activator, 0.1-1.0 part of a CO2 reinforced introduction agent and 15-50 parts of water. The preparation method comprises the following steps: firstly, mixing the coal gasification slag powder and the coal gangue powder in a mixer for 2-10 minutes to obtain mixed powder; secondly, sequentially adding water, an alkali activator and a CO2 reinforced introduction agent, and mixing and stirring for 3-5 minutes to obtain a mixed solution; and then, pouring the mixed solution into the mixed powder, and mixing and stirring for 5-10 minutes to obtain the grouting material. The method for sealing and storing CO2 comprises the following steps: pouring the grouting material into a mineralization reaction kettle, and stirring for 10-60 minutes in a CO2 atmosphere with the temperature of 35-60 DEG C and the pressure of 0.1-0.5 MPa to form the grouting and sealing and storing CO2 material. The prepared grouting material has the advantages of being low in cost, large in CO2 storage amount and the like.

The invention provides a coal gasification slag denitration catalyst and a preparation method thereof, and belongs to the technical field of coal gasification slag denitration catalyst preparation. The preparation method of the coal gasification slag denitration catalyst comprises the following steps: mixing coal gasification slag and an acetic acid solution to obtain a mixed system, standing and aging the mixed system, and heating and drying to obtain a coal gasification slag acetic acid modified product; grinding and sieving the coal gasification slag acetic acid modified product to obtain coal gasification slag acetic acid modified powder; and calcining the coal gasification slag acetic acid modified powder to prepare the acetic acid modified coal gasification slag denitration catalyst. The preparation method disclosed by the invention is simple and feasible in process, low in cost and suitable for industrial large-scale batch production, and high-value recycling of solid waste coal gasification slag can be realized. After acetic acid modification treatment provided by the invention, the denitration activity of the coal gasification slag denitration catalyst is remarkably improved.

The invention discloses a rock permeability testing system in a high-temperature and high-pressure environment and a using method thereof, and belongs to the technical field of geothermal development or coal in-situ gasification mining. The test system is composed of a stress loading system, a test kettle assembly and a magnetic particle imaging system. When in use, the stress loading system and the test kettle assembly provide conditions such as high temperature, high pressure, seepage fluid and the like for a test piece; and detecting the spatial distribution state of the nano magnetic induction particles added in the seepage fluid through a magnetic particle imaging system to observe the pore and crack distribution characteristics in the test piece or detecting the nano magnetic induction particles added in the pollutant solution to observe the pollutant migration condition. The test system is scientific in design, simple in structure and easy to operate and maintain, can monitor pore fracture distribution and pollutant migration conditions in the test piece in real time under high-temperature and high-pressure conditions, provides accurate dynamic observation data, and provides important technical support for reservoir assessment and optimization in a complex environment.

The invention discloses a coal gasification slag-steel slag-based high-carbon-storage type filling material and a preparation method thereof, and belongs to the field of coal-based solid waste resource utilization and carbon emission reduction. The filling material comprises the following components in parts by weight: 100 parts of a cementing material, 10-20 parts of aggregate and 10-20 parts of water. 38 to 52 parts of aggregate; 24 to 40 parts of water; the cementing material comprises the following raw materials: 65-85 parts of coal gasification slag; 15 to 35 parts of steel slag; and 3.0 to 10.5 parts of a composite exciting agent. According to the method, the coal gasification slag can be consumed on a large scale, CO2 is fixed and stored through the carbonization reaction, and stable storage of CO2 is achieved through engineering application of a filling material; the problems of industrial solid waste treatment, carbon emission control, natural resource consumption, environmental pollution and the like are effectively solved, and good environmental protection benefits and practical values are achieved; the invention provides a new technical path for realizing solid waste resource utilization and carbon neutralization targets.

The invention relates to the technical field of coal gas water treatment, and discloses a purification treatment system for coal gas water after coal gasification, which comprises a pretreatment tank, a biochemical treatment tank is arranged on one side of the pretreatment tank, a deep treatment tank is arranged on one side of the biochemical treatment tank, a pipe frame is arranged in the biochemical treatment tank, and the pipe frame is arranged in the deep treatment tank. Membrane filaments are arranged in the pipe frame. In the coal gas water treatment process, when the membrane wires are broken, two-stage plugging of the pipeline can be achieved, so that the coal gas water which is sucked into the membrane wires due to the fact that the membrane wires are broken and not filtered cannot enter the transverse pipe, the coal gas water cannot enter the pipe frame to pollute the pipe frame and the transverse pipe, the plugging effect is good through two-stage plugging of the pipeline, and the sealing effect is good. The anti-pollution effect on the pipe frame and the transverse pipe is improved, it can be guaranteed that no impurity is accumulated at the end of the circular ring before plugging is conducted, and a pipeline can be better plugged in cooperation with a plugging ball without impurity accumulation.

The invention relates to the technical field of adsorbent preparation and hexavalent chromium Cr (VI) adsorption, in particular to application of an ammonia modified porous carbon adsorbent in Cr (VI) adsorption. According to the method, an ammonia modified porous carbon adsorbent is added into a water sample containing Cr (VI) for adsorption, so that Cr (VI) in the water sample is removed; the preparation method of the ammonia modified porous carbon adsorbent comprises the following steps: carrying out hydrothermal acid leaching on gasified fine residues and an acid solution to obtain acid leaching residues; stirring the acid leaching residues in an alkali solution, washing and drying to obtain a porous carbon material; and dipping the porous carbon material in a tetraethylenepentamine solution, and then drying to obtain the ammonia modified porous carbon adsorbent. The ammonia modified porous carbon adsorbent is successfully constructed by taking a porous carbon material derived from coal gasification fine slag as a substrate and further adopting a surface ammonia functionalization modification strategy. The ammonia modified porous carbon adsorbent has a good adsorption effect on Cr (VI).

The invention discloses a dehydration, crushing and curing integrated treatment method for sand washing mud. Comprising the following steps: mixing a conditioner with sand washing mud, dehydrating and crushing, mixing and stirring with a curing material, extruding, vibrating and molding, and curing to obtain the sand washing mud-based cured body. According to the invention, polyacrylamide, polyaluminum chloride and fly ash / coal gasification slag are used as conditioners, colloidal particles are flocculated and precipitated under the effects of electrical neutralization, adsorption bridging and net capturing of the conditioners, and fly ash / coal gasification slag plays a role in a skeleton, so that a drainage channel can be provided inside the sand washing mud, the problem of crushing of a filter cake is solved, and the service life of the filter cake is prolonged. The method realizes the spanning of high pollution and low efficiency of sand washing mud treatment to recycling and high performance, has triple values of process innovation, environmental protection standard reaching and economic feasibility, and provides an efficient solution for recycling of building wastes. Meanwhile, the invention is suitable for multi-scene building application of roadbed materials, baking-free bricks, artificial aggregates and the like.

The invention relates to the technical field of comprehensive utilization of coal gasification ash, and discloses a coal gasification ash solid waste quality-divided gradient comprehensive utilization method which comprises the following steps: dividing ash into coarse slag and fine slag; performing physical separation on the fine slag to obtain a fine slag filter cake with the carbon content of 5-70%, first low-carbon ash slag with the carbon content of less than or equal to 5% and carbon-rich ash slag with the carbon content of more than or equal to 70%; forming the fine slag filter cake into second low-carbon ash slag by utilizing a fine slag decarburization technology; adding a binder into the carbon-rich ash residue, and gasifying for utilization to obtain third low-carbon ash residue and coal gas; preparing polyaluminum chloride and the like from the high-aluminum ash with Al2O3 greater than or equal to 20% in the low-carbon ash; preparing a water glass agent from the high-silicon ash slag with SiO2 greater than or equal to 40%; preparing a coal-based solid waste cementing material or a coal-based solid waste filling material from the low-silicon aluminum ash residue containing less than 40% of SiO2 and less than 20% of Al2O3 and coal gangue or fly ash; the ash utilization method is simple, the comprehensive utilization rate is high, the coal gasification ash can be treated on a large scale, the ecological environment is protected, and the value of the coal gasification ash can be fully utilized.

A fly ash prevention device for treating high-concentration water relates to the technical field of petrochemical engineering and comprises a flash evaporation concentration tower, a flash steam outlet is formed in the top of the flash evaporation concentration tower, and a black water outlet is formed in the bottom of the flash evaporation concentration tower; the tower wall of the flash concentration tower is connected with a black water connecting pipe, and black water tangentially enters the tower through the black water connecting pipe; a black water concentration chamber is arranged at the bottom in the flash evaporation concentration tower, the bottom of the black water concentration chamber is communicated with a black water outlet, an ascending pipe is arranged above the black water concentration chamber, a steam ascending cap is arranged on the ascending pipe, a fly ash prevention filler washing assembly is arranged above the steam ascending cap, and a gas distributor is arranged above the fly ash prevention filler washing assembly; a high-efficiency demister is arranged at the top in the flash evaporation concentration tower and is arranged on the flash steam outlet; according to the technical scheme, coal gasification and heavy oil gasification water systems are optimized, black water is concentrated, the washing environment is improved, and fly ash is prevented from being carried into a rear system.

The invention provides a crushing and screening device which comprises a vibration base, a body part, a screening part, a weight sensor and a control system, and the vibration base comprises a power output part; the body part is arranged on the vibration base and provided with a screening cavity, a material inlet communicating with the top of the screening cavity and a plurality of material outlets. The multiple screening parts are distributed in the screening cavity at intervals in the height direction of the body part, screening holes are formed in each screening part, and the hole diameters of the screening holes in the multiple screening parts are gradually reduced from top to bottom. A weight sensor is arranged at the bottom of each screening part and used for detecting the weight of materials on the corresponding screening part. The control system controls the vibration frequency of the vibration base according to data detected by the weight sensor. The coal gasification coarse slag can be screened only through one crushing and screening device, multiple devices of different specifications are not needed, the screening efficiency is improved, and the production cost is reduced.

The invention relates to the technical field of adsorbent preparation and methylene blue adsorption, in particular to application of an ammonia modified porous carbon adsorbent in methylene blue adsorption. An ammonia modified porous carbon adsorbent is added into a water sample containing methylene blue for adsorption, so that the methylene blue in the water sample is removed; the preparation method of the ammonia modified porous carbon adsorbent comprises the following steps: carrying out hydrothermal acid leaching on gasified fine residues and an acid solution to obtain acid leaching residues; stirring the acid leaching residues in an alkali solution, washing and drying to obtain a porous carbon material; and dipping the porous carbon material in a tetraethylenepentamine solution, and then drying to obtain the ammonia modified porous carbon adsorbent. The ammonia modified porous carbon adsorbent is successfully constructed by taking a porous carbon material derived from coal gasification fine slag as a substrate and further adopting a surface ammonia functionalization modification strategy. The ammonia modified porous carbon adsorbent has a good adsorption effect on methylene blue.

The invention discloses a method for preparing a porous carbon material by recycling coal gasification slag and semi-coke wastewater, which comprises the following steps: by taking coal gasification fine slag as a carrier and semi-coke wastewater as a phenol source, carrying out flotation-acid leaching modification on the fine slag to purify a carbon-rich component and optimize the surface adsorption activity of the carbon-rich component; then fully adsorbing phenolic substances in the wastewater by utilizing the modified slag body; introducing a composite aldehyde cross-linking agent, and initiating an in-situ phenolic aldehyde polymerization reaction to generate a composite precursor; the precursor is subjected to high-temperature carbonization and alkali activation pore forming, and finally the porous carbon material with the characteristics of high specific surface area, rich graded pores and low ash content is prepared. According to the process, full-amount collaborative recycling of the two wastes is achieved, and the process is green and free of secondary pollution. The obtained material is high in carbon content and rich in defect structure and surface functional groups, shows excellent adsorption capacity and catalytic carrier performance, can be widely applied to the fields of deep purification of water pollutants, adsorption of volatile organic compounds, energy catalysis and the like, and has remarkable environmental protection benefits and resource economic values.

The utility model relates to a raw gas source upgrading system for an internal heating type vertical furnace. The raw gas source upgrading system comprises a dry distillation furnace, a carbon dioxide removal device and a pure oxygen preparation device, the device further comprises a first multi-stage mixer, a second multi-stage mixer, a gas sampling analysis tube and a gas component detector. Pure oxygen is adopted as a combustion improver, so that the content of nitrogen in the raw gas is greatly reduced, and the application scene of coal gasification production and deep processing of the internal heating type vertical furnace is expanded; the components of combustion-supporting gas, combustible gas and inert gas in mixed gas in a lattice wall of the dry distillation furnace are controlled by adopting double-circulation control of carbon dioxide and recirculated gas, the combustion intensity and the uniformity degree are strictly controlled under the condition that dry distillation heat supply is met, and scabbing and burning loss of a dry distillation furnace body are avoided.

The invention provides a coal-based solid waste foamed cement material for filling a coal mine tunnel and a preparation method of the coal-based solid waste foamed cement material. The coal-based solid waste foamed cement material comprises 10-30 parts of coal gasification coarse slag micro powder, 0-30 parts of first-grade fly ash, 70-90 parts of cement, 0.3-0.8 part of a foam stabilizer and 0.1-0.5 part of an additive, the coal-based solid waste foamed cement material is further doped with foam, the mixing amount of the foam is 2-5 times of the volume of the cement slurry, the coal gasification coarse slag micro powder is coal water slurry furnace gasification coarse slag, and the coal gasification coarse slag micro powder is prepared from, by mass, 40% of silicon dioxide, 19% of aluminum oxide, 15% of ferric oxide, 16% of calcium oxide, 3% of sulfur trioxide, 3% of sodium oxide, 1% of magnesium oxide and 0.5% of titanium oxide. And 0.5% of potassium oxide. According to the invention, a physical foaming method is utilized, coal-based solid waste is used as a raw material to replace part of cement, and the foamed cement material with light weight and high strength is prepared, so that the foamed cement material meets the use requirements of underground roadway filling.

In view to the technical problems of low recovery rate of metal elements in metallurgical slag and the problem of inefficient recovery of residual heat of metallurgical slag generated by traditional technology, the present application provides a technology and method for preparing microporous-rich metallurgical slag particles based on carbon etching and efficiently recovering residual heat of metallurgical slag in coal gasification, mainly including four parts of granulation system, etching powder adhesion system, etching gasification system and screening separation system which are sequentially connected, and mainly through four steps of molten metallurgical slag granulation, etching powder adhesion, etching gasification reaction, screening and separation, the efficient recovery and utilization of residual heat of metallurgical slag and the high value conversion of metallurgical slag particle products are realized. The utilization value of metallurgical slag particles is increased by 10-15 times through the system.

The invention provides anti-crack foam concrete as well as a preparation method and application thereof, and belongs to the technical field of building materials. The added quick lime can generate a certain micro-expansion effect when encountering water, shrinkage of the material caused by hydration can be compensated to a certain extent, an alkaline environment can be provided for the foaming agent, and smooth foaming is guaranteed; the magnesite tailing powder is added, so that dicalcium silicate, tricalcium silicate and periclase crystal phases with relatively high fire resistance can be obtained when a fire disaster occurs; the phosphogypsum is added as an activator of the coal gasification slag, so that the hydration induction period is shortened, the later strength development is promoted, and the crack resistance of the foam concrete is improved; the modified fibers are added, the fibers form an irregular supporting structure in the multi-bubble slurry to play a role in protecting the foam, meanwhile, the fibers can improve the pore structure and also have an effect of hindering microcrack propagation, and the three fibers have a synergistic effect, so that the crack resistance of the foam concrete is improved.

The application discloses an energy-saving, efficient and adjustable alcohol pre-gas ammonia production process method, and particularly comprises the following steps: S1, a raw material gas is separated from a pressurized coal gasification methanol device as alcohol pre-gas and is sent to a shift device of synthetic ammonia through a sealed pipeline; S2, when entering the shift device, the alcohol pre-gas is mixed with a crude synthetic gas to form a mixed gas, then high-pressure steam is introduced to adjust the water-gas and increase the mixed temperature, carbon monoxide is reacted with water vapor in the shift device, and hydrogen gas is prepared as a shift gas; S3, the shift gas is subjected to low-temperature methanol washing and liquid nitrogen washing, then nitrogen gas produced by air separation is added, a synthetic gas is prepared, and the synthetic gas is sent to an ammonia synthesis device. The energy-saving, efficient and adjustable alcohol pre-gas ammonia production process method is adopted, raw material gas is comprehensively utilized in an energy-saving mode, the methanol and synthetic ammonia production yield is flexibly adjusted, and enterprise benefits are improved.