The invention provides a method for preparing a poly-aluminum and functional
silicon material by activating
coal gasification
slag and waste
hydrochloric acid through
microwave synergistic
mechanical force, and belongs to the technical field of industrial
solid waste recycling. The method comprises the following steps that the
coal gasification
slag is sequentially subjected to
microwave radiation treatment and ball milling, activated
slag and waste
hydrochloric acid are subjected to an acid leaching reaction, and aluminum-iron-containing
leachate and
silicon-rich slag are obtained; extracting the aluminum-iron-containing leaching solution to obtain an iron-rich organic phase and a purified aluminum
chloride solution; performing thermal
polymerization reaction on the purified aluminum
chloride solution to obtain
polyaluminum chloride; the method comprises the following steps: carrying out alkaline leaching reaction on
silicon-rich slag and waste alkali liquor, adding a structure-directing agent into a
sodium silicate solution, and sequentially carrying out aging, solution pH value adjustment and
crystallization precipitation to obtain
mesoporous silica. According to the method, the aluminum-silicon
leaching rate is remarkably increased through
microwave-
mechanical force synergistic activation, synergistic and efficient treatment of the three kinds of waste including the
coal gasification slag, the waste
hydrochloric acid and the waste alkali liquid is achieved, the technological process is closed, the product additional value is high, and the environmental and
economic benefits are remarkable.