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88results about How to "Efficient and clean utilization" patented technology

Multi-layer belt type drying system

The invention discloses a multi-layer belt type drying system. The multi-layer belt type drying system comprises a drying box with an exhaust port in the top and multiple layers of transmission net belts in the drying box, wherein the input end of the lower-layer transmission net belt is connected with the output end of the adjacent upper-layer transmission net belt, and a plurality of circulation fans are arranged under each layer of transmission net belt. A horizontal separation plate dividing the drying box into a drying chamber and a cooling chamber is arranged in the drying box, an air feeding port is formed in the bottom of the cooling chamber, a draught fan used for exhausting the air is arranged inside the cooling chamber, the air feeding port and the draught fan are arranged at two sides of the transmission net belts, a heater is arranged in the drying chamber, an air inlet of the heater is communicated with an air outlet of the draught fan, and a plurality of air outlets corresponding to the transmission net belts in the drying chamber one to one are formed in the heater. The multi-layer belt type drying system is simple in structure and reasonable in arrangement, preheats a heating medium by recycling waste heat of off gas and utilizing dried upgrading materials with high temperature, and lowers the energy consumption in the drying process.
Owner:ZHEJIANG UNIV

Process for producing natural gas by coal coking and pyrolysis coal gas thereof

The invention relates to a process for producing natural gas by coal coking and pyrolysis coal gas thereof, in the process, raw coal gas generated by a coke oven taking H2 as fuel is purified and then completely sent to a mixer for being directly mixed with part of clean gasified coal gas for regulating hydrogen-carbon ratio, and then methanation reaction is performed under the action of a catalyst so as to prepare a product, namely the natural gas; and transformation and decarburization are performed on the other part of the clean gasified coal gas, then carbon dioxide is enriched and caught, and produced hydrogen is sent to the coke oven for burning and supplying heat. In the process, coal gasification and coke dry quenching are simultaneously performed, and a set of air separation device is realized for providing a heat carrier, namely N2, and a gasifying agent, namely O2, for the coke dry quenching and the coal gasification respectively, thereby enabling the air separation processeffect to be higher. Coke making by hydrogen burning, air separation, the coke dry quenching, the coal gasification and methanation of the coal gas of the coke oven are organically integrated, and the clean production in the coking industry and the economic and high-efficient utilization of the pyrolysis coal gas are realized, thereby having great application value in the aspects of energy utilization, CO2 emission reduction and environmental protection.
Owner:TAIYUAN UNIV OF TECH

Combination method using semi-coke tail gas for power generation to cogenerate liquefied natural gas

The invention discloses a combination method using semi-coke tail gas for power generation to cogenerate liquefied natural gas. The semi-coke tail gas is pressurized by an air blower and enters a pretreatment process, and impurities of tar, naphthalene, hydrogen sulfide and the like in the semi-coke tail gas are removed; a small part of preliminary purified gas after compression enters a gas generator unit directly, and the generated power is used for liquefying natural gas in a subsequent work section; and a large part of the preliminary purified gas enters a liquefied natural gas work section and is subjected to tar and naphthalene refined removing, sulfur resistance conversion, deep purification, methanation, liquefied cryogenic separation and the like to manufacture the liquefied natural gas. According to the combination method using semi-coke tail gas for power generation to cogenerate liquefied natural gas, all chemical engineering units operate according to set rated operating conditions and need not purchase electricity externally, problems of self power generation limits and ultra-low on-grid electricity price are solved for enterprises, and the economy of semi-coke enterprises is enhanced. Simultaneously, industrial exhausted semi-coke tail gas is prepared into the clean energy of the liquefied natural gas which is shortage in China, and accordingly, efficient and clean usage of the semi-coke tail gas is achieved.
Owner:SOUTHWEST RES & DESIGN INST OF CHEM IND

Technique for decomposing Baotou rare-earth ores

The invention relates to a technique for decomposing Baotou rare-earth ores. The invention solves the technical problems of environmental pollution and resource loss caused by the rare-earth ore separation technique in the prior art. The technique comprises the following steps: carrying out oxidizing roasting on mixed rare-earth concentrate; leaching the roasted ores with an H2SO4 solution to obtain a leach solution and urdite; extracting and separating Ce (IV), F and Th as well as single RE (III) from the sulfuric acid leach solution; and carrying out alkali conversion on the urdite to obtain a rare-earth alkali cake, carrying out size mixing, filtering, and crystallizing the alkaline solution to recover sodium phosphate, wherein the residual alkali liquor is used for cyclically leaching urdite slag. When being used for treating the mixed rare-earth concentrate, the technique provided by the invention can implement multi-step extraction of bastnaesite and urdite in the mixed ores. Besides, the invention is beneficial to further effectively recovering Th, F and P from baotite, thereby avoiding environmental pollution, enhancing the rare-earth yield, saving the cost and implementing clean production and comprehensive resource utilization in deed.
Owner:CHANGCHUN INST OF APPLIED CHEMISTRY - CHINESE ACAD OF SCI

Biomass gasified gas re-burning mode and system for coal-fired fluidized bed

The invention belongs to the technical field of N2O emission reduction in a coal-fired fluidized bed, and particularly relates to a biomass gasified gas re-burning mode and a biomass gasified gas re-burning system for a coal-fired fluidized bed. The wall of a fluidized bed boiler is provided with a plurality of biomass gasified gas nozzles, biomass gasified gas is introduced into a hearth of the fluidized bed boiler, and the biomass gasified gas is reacted with N2O-containing smoke generated by burning of coal dust in the hearth to realize multi-stage re-burning so as to improve the burning efficiency of the whole fluidized bed and reduce the emission of N2O. Compared with pyrolysis and direct burning, the biomass gas rich in combustible substances such as H2, CH4, CO and the like has low ash content and extremely low sulfur content, has no sulfur removal problem, is ideal re-burning fuel and can effectively reduce the emission of nitrogen oxides by using mixed burning of the biomass gasified gas and the coal dust; and because of low alkali metal and chlorine content in the gasified gas, problems of slag formation and corrosion can be avoided, utilization of the coal dust is not affected and efficient clean utilization of the biomass can be realized.
Owner:NORTH CHINA ELECTRIC POWER UNIV (BAODING)

Series connection and parallel connection switching type heat supplying method of compressing absorbing hybrid heat pump of gas engine

The invention discloses a series connection and parallel connection switching type heat supplying method of a compressing absorbing hybrid heat pump of a gas engine. The method involves a parallel connection mode and a series connection mode; when the environmental temperature is high, a hybrid heat pump heat supplying system enters the parallel connection mode, and user returned water is divided into two parts; one part of the returned water is sequentially heated through a first condenser, a cylinder sleeve heat exchanger and a smoke heat exchanger through connecting pipes; another part of the user returned water sequentially flows through a first valve, a second water pump, an absorber, a second condenser and a fourth valve by the connecting pipes and then is mixed with previous hot water; when the environmental temperature is low, the hybrid heat pump heat supplying system enters the series connection mode, and the user returned water is sequentially heated through the first condenser, the cylinder sleeve heat exchanger and the smoke heat exchanger so as to produce water supplied to a user. With the adoption of the method, the heating capacity of the whole system can be greatly improved, and meanwhile, the smoke exhaust temperature can be reduced.
Owner:TIANJIN CHENGJIAN UNIV

Process for co-producing LNG (Liquefied Natural Gas) by using pyrolysis gas generated in power generation system

The invention discloses a process for further co-producing LNG (Liquefied Natural Gas) by using pyrolysis gas generated after low-rank coal is used for generating power in a power generation system. According to the process, semi-cokes generated by coal in a pyrolyzing furnace and separated hot ash are fed into a power generating boiler system so as to be combusted and utilized, the generated power is used for LNG in the subsequent process, raw gas and fine ash particles generated through pyrolysis enter into a separation system, and products with high additional values can be extracted from the separated tar. The process specifically comprises the following steps of pressurizing the raw gas and then entering into a pretreatment process; removing impurities such as dust, oil tar, naphthalene and H2S in the raw gas; compressing pre-purified gas and then entering into units such as a pyrolysis gas deep purification unit, a methanation unit and cryopenic separation and liquidation units, thereby preparing clean energy liquefied natural gas which is short in China. According to the invention, coal pyrolysis and gasification are organically combined with gas, chemical, electric and heat production processes on the basis that heat supply and power generation are carried out by taking semi-cokes as solid fuels, so that graded transformation and step-by-step extraction of coal as well as economic benefit maximization are realized, the energy utilization efficiency is increased, and the economical efficiencies of thermoelectricity enterprises are increased.
Owner:SOUTHWEST RES & DESIGN INST OF CHEM IND

Coal-based fuel near zero emission power generation system and method

The invention provides a coal-based fuel near zero emission power generation system and a method, and the invention relates to the technical field of coal-based fuel CO2 zero emission power generation. The method comprises the following steps: raw coal is subjected to demineralization pretreatment to be produced into ultra-clean coal; the ultra-clean coal is combusted in a high-pressure combustion chamber under pure oxygen condition; water sprayed into the combustion chamber step by step is directly heated into high temperature and high pressure mixed gas and an advanced turbine is pushed by the mixed gas to do work; exhaust gas is condensed by using a condenser to be produced into high concentration CO2; and zero emission of atmospheric pollutant is finally realized. The invention also provides a system for realizing the above processes. The system mainly consists of a demineralization pretreatment system, an ultra-clean coal pure oxygen combustor, an air separation system, the high-pressure combustion chamber, the advanced turbine, the condenser, a water purification treatment system and a CO2 recovery processing device. According to the invention, problems of conventional power generation methods, such as high pollutant emission and high CO2 capture cost, are solved. Furthermore, efficient and clean usage and zero pollutant emission of combusted coal are realized.
Owner:HARBIN INST OF TECH

Device and method for joint production of iron, sulfur and gas in smelting process of pyrite

The invention relates to a device and method for joint production of iron, sulfur and gas in the smelting process of pyrite, and belongs to the field of metal smelting. The method comprises the following steps of calcining the pyrite at the bottom part of the interior of a calcining-gasifying reaction tower, enabling pulverized coal and fly ash to generate gasifying reaction at the middle upper part, enabling the sulfur-containing flue gas to carry the high-valence oxide of iron produced by calcining at the tower bottom to the middle upper part of the reaction tower, mixing with the gas and coke produced by gasifying, and generating oxidation and reduction reaction; separating the product by an iron-based high-temperature separator and a carbon-based high-temperature separator, and sendingback into an iron oxide reduction tower; performing secondary reduction reaction on the iron oxide in the iron oxide reduction tower, and producing reduction gas, so as to obtain iron slag; purifyingthe crude gas, so as to obtain the purified gas; enabling a sulfur condenser to condense and recycle the sulfur. The method has the advantages that the joint production of iron, sulfur and gas is realized in the smelting process of the pyrite, and the pyrite can be efficiently and cleanly utilized.
Owner:SHANDONG UNIV

Electric power storage system and method employing coal gasification of solid heat carrier

The invention provides an electric power storage system and method employing coal gasification of a solid heat carrier. The system comprises a power supply device, a fluidized bed powdered coal gasifier, a cyclone dust collector, an ash discharge classifier and a fine ash collecting chamber, wherein the power supply device is connected with the fluidized bed powdered coal gasifier; the fluidized bed powdered coal gasifier comprises a gasifier body; a metal heat carrier is contained inside the gasifier body and an electric heating element is arranged outside the gasifier body; a gas outlet of the gasifier body is connected with the cyclone dust collector; a feed opening of the cyclone dust collector is connected to a feeding inlet of the ash discharge classifier; a coarse ash outlet of the ash discharge classifier is connected with a material return opening; and a fine ash outlet of the ash discharge classifier is connected with the fine ash collecting chamber. The method comprises the steps of firstly heating the fluidized bed powdered coal gasifier until the temperature reaches 800-1300 DEG C by adopting the system; carrying out coal gasification reaction by using a preheating gasification agent mixed with pulverized coal and calcium carbonate mixed powder in the coal gasifier; and finally preparing a city gas or a chemical product from the high-temperature coal gas.
Owner:NORTHEASTERN UNIV

Short-process smelting reduction type iron-making system and method

PendingCN109321703AFully pre-restoredImprove reducibilityCombustionThree stage
The invention relates to a short-process smelting reduction type iron-making system and a method, and belongs to the technical field of iron-making. The system comprises a coal powder preparation device, an iron ore powder preparation device, an iron ore powder direct reduction and powder coke preparation device and a gas-solid separation device; the iron ore powder direct reduction and powder coke preparation device is of a U-shaped structure with a communicating bottom, the two sides of the iron ore powder direct reduction and powder coke preparation device serve a low-temperature reductionsection and a high-temperature reduction section correspondingly, the bottom of the iron ore powder direct reduction and powder coke preparation device serves a smelting reduction section, molten ironis obtained at the bottom of the smelting reduction section, the coal powder preparation device and the iron ore powder preparation device are connected with the middle lower portion and the bottom of the low-temperature reduction section correspondingly, the low-temperature reduction section is connected with the gas-solid separation device, and the gas-solid separation device is connected witha top combustion device and the middle of the high-temperature reduction section correspondingly. Through three-stage iron ore powder reduction, the reducibility characteristics of different components of the coal powder are fully utilized, then the multi-stage reduction of the coal powder and the iron ore powder is realized, the comprehensive efficient clean utilization of the coal and the iron ore are finally realized, and the short-process iron-making process is completed on the basis that the separate full utilization of the coal powder is realized.
Owner:TANGSHAN YANSHAN IRON & STEEL CO LTD

Method for preparing oxygen carrier by using vanadium-titanium magnetite, and applications of oxygen carrier

The present invention relates to a method for preparing an oxygen carrier by using vanadium-titanium magnetite, and applications of the oxygen carrier, and belongs to the technical field of efficient comprehensive utilization of mineral resources and energy source chemistry. The method comprises: drying vanadium-titanium magnetite concentrate, crushing, adding a modifier, and calcining in air or an oxygen-rich atmosphere; and adding the treated vanadium-titanium magnetite concentrate to a carrier, an active component and an auxiliary agent, uniformly mixing to obtain a mixture, carrying out conventional molding on the mixture, and baking for 8-12 h at a temperature of 950-1300 DEG C to obtain the oxygen carrier. The oxygen carrier can be used for the methane stepwise conversion way to prepare the synthesis gas and the hydrogen gas. According to the present invention, the oxygen carrier is used for the lattice oxygen transferring in the technology for stepwise preparation of the synthesis gas and the hydrogen gas through the methane conversion, the oxygen carrier preparation method is simple and has characteristics of good reaction circulation property, good CH4 conversion rate, good CO selectivity, and good H2 selectivity.
Owner:KUNMING UNIV OF SCI & TECH

Ferroalumen slag cold-bonded and reduced pellet preparation and recycled lead, zinc and iron synchronous sulfur fixation process method

The invention relates to a ferroalumen slag cold-bonded and reduced pellet preparation and recycled lead, zinc and iron synchronous sulfur fixation process method. Firstly, ferroalumen slags, reducing coal and sulfur fixing agents are mixed and pressed into green ferroalumen slag cold-bonded and reduced pellets; the green ferroalumen slag cold-bonded and reduced pellets are dried, and preparation of ferroalumen slag cold-bonded and reduced pellets is finished; and the ferroalumen slag cold-bonded and reduced pellets are directly reduced and roasted at the temperature of 1100-1250 DEG C, smoke containing lead and zinc and roasted ore containing iron and sulfur are obtained, and ferroalumen slag cold-bonded and reduced pellet recycled lead, zinc and iron synchronous sulfur fixation is finished. The water-containing ferroalumen slags, the reducing coal and the sulfur fixing agents are made into the cold-bonded and reduced pellets, then a lead, zinc and iron chemical compound in the ferroalumen slags is directly reduced and subjected to synchronous sulfur fixation through high-temperature roasting, valuable metals including lead and zinc are recycled from the smoke, iron is recycled from the roasted ore, water difficult to remove in the ferroalumen slags is directly used, sulfur in the ferroalumen slags is fixed, and efficient and clean utilization of the valuable metals in the ferroalumen slags can also be achieved.
Owner:HANZHONG ZINC IND +1

Method and system for low-temperature dry distillation and separation recycling of solid thermal carrier low-rank coal and oil shale

The invention discloses a method and a system for low-temperature dry distillation and separation recycling of solid thermal carrier low-rank coal and oil shale. The method comprises the following steps: by taking the low-rank coal and / or the oil shale as raw materials, drying the raw materials by middle-temperature smoke; carrying out gas-solid separation to obtained dried grains; mixing the dried grains, high-temperature circulating ash dreg and recycled heavy oil and conveying into a dry distillation chamber; raising the temperature to carry out the dry distillation; leading out dry distillation gas and separating to obtain coal gas and tar; discharging a semi-coke and ash dreg mixture generated by the dry distillation out of the dry distillation chamber; enabling separated semi-coke to fall off, and further cooling and discharging; conveying the semi-coke and ash dreg mixture into a circulating fluidized bed to be fluidized and combusted; carrying out gas-solid separation on high-temperature dust-containing smoke obtained by fluidizing and combusting to obtain high-temperature circulating ash dreg; providing heat to the dry distillation by taking the high-temperature circulating ash dreg as the solid thermal carrier; and separating the obtained high-temperature smoke and carrying out secondary gas-solid separation and residual heat recycling, and furthermore, carrying out subsequent smoke treatment. The invention further provides a low-temperature dry distillation and separation recycling system used for the method.
Owner:CHINA UNIV OF PETROLEUM (BEIJING) +1

Thermal power plant peak regulating system based on water-electrolysis hydrogen production

The invention discloses a thermal power plant peak regulating system based on water-electrolysis hydrogen production. The system comprises a coal-fired boiler, a hydrogen production unit arranged in the upstream position of the process of the coal-fired boiler and a flue gas recovery unit arranged in the downstream position of the process of the coal-fired boiler; the hydrogen production unit comprises multiple hydrogen storage tanks; the multiple hydrogen storage tanks are connected in parallel and communicate with water-electrolysis hydrogen production equipment through pipelines to receiveand store hydrogen; the hydrogen production unit communicates with a buffer tank through a pipeline; the buffer tank is located in the downstream position of the process of the hydrogen storage tanks;a valve group is mounted on the hydrogen production unit; and the communication states of the hydrogen storage tanks are switched by the aid of the valve group. According to the system, the multiplehydrogen storage tanks and the buffer tank communicating with the multiple hydrogen storage tanks through series connection are arranged, the multiple hydrogen storage tanks can realize the effect that multiple hydrogen storage tanks are opened while multiple hydrogen storage tanks are standby, and thus later overhauling is facilitated; and stabilized-pressure delivery of hydrogen output by the opened hydrogen storage tanks can be further performed by the buffer tank, so that the safety is improved.
Owner:BEIJING JINMAO GREEN BUILDING TECH CO LTD

Multi-way method for synthesizing ammonia by utilizing low-rank coal

The invention provides a multi-way method for synthesizing ammonia by utilizing low-rank coal. The multi-way method comprises the following steps: drying the low-rank coal to obtain dried low-rank coal and waste gas; removing dust from the waste gas to obtain coal powder; gasifying and reducing the dried low-rank coal to obtain an oil-gas mixture and quality-improved coal, wherein a gasification and reduction technology is a chemical reaction technology for heating the dried low-rank coal under an oxygen-free or micro-aerobic condition; purifying the oil-gas mixture to obtain mixed gas and wastewater; reforming and transforming the mixed gas to prepare synthetic gas; preparing coal water slurry through the wastewater, the coal powder and a coal water slurry additive and then preparing synthetic gas; preparing synthetic gas by utilizing the quality-improved coal; after mixing the three types of synthetic gas, carrying out unconventional conversion and transformation and decarburizationand separating and purifying H2; taking the H2 and N2 as raw materials to synthesize the ammonia. According to the multi-way method, a plurality of ways for synthesizing the ammonia are provided and the cost is low; reutilization of various wastes including the wastewater and the coal powder is realized and resources are saved.
Owner:浙江天禄环境科技有限公司

Method for co-producing ammonium molybdate and sulfuric acid through treating molybdenite by oxygen-pressure water soaking process

The invention provides a method for co-producing ammonium molybdate and sulfuric acid through treating molybdenite by an oxygen-pressure water soaking process. The method comprises the following steps: uniformly mixing molybdenite powder and water according to the solid-to-liquid ratio of (1: 2) to (1: 7), so as to prepare molybdenite slurry; injecting the molybdenite slurry into a pressure reactor, so as to subject the molybdenite slurry to an oxygen-pressure water soaking reaction with oxidizing gas; filtering the obtained slurry, so as to obtain a filter cake and filter liquor; subjecting the filter cake to ammonia leaching, filtering and crystallizing, so as to prepare the ammonium molybdate product; and subjecting the filter liquor to molybdenum removing treatment, thereby obtaining the sulfuric acid product. According to the method provided by the invention, the total recovery rate of molybdenum reaches 95% or more and even reaches up to 98% or more, meanwhile, the sulfuric acid with relatively high concentration can be obtained, and environmental pollution is not caused; and the method is simple, efficient and energy-saving and is an environment-friendly hydrometallurgical clean production process for co-producing ammonium molybdate and sulfuric acid through efficiently utilizing the molybdenite, thereby having a good industrialized application prospect.
Owner:INST OF PROCESS ENG CHINESE ACAD OF SCI

Seaweed pyrolysis oil making system and method thereof

The invention provides a seaweed pyrolysis oil making system and a method thereof. The seaweed pyrolysis oil making system comprises a pyrolysis device, an oil-gas separator, an oil storage device, agas purification device, a gasification device, a cyclone separation device and a hydrothermal device, wherein the upper end of the pyrolysis device is connected with the oil-gas separator; the upperend of the oil-gas separator is connected with the gasification device through the gas purification device, and the lower end of the oil-gas separator is connected with the oil storage device; the lower end of the pyrolysis device is connected with the gasification device; the gasification device is connected with the hydrothermal device through the cyclone separation device; noncondensable gas generated by the pyrolysis of the pyrolysis device can be used as gasification agent used for gasification reaction, semicoke generated by pyrolysis is taken as a gasification raw material, reductive gas generated by gasification participates in hydrothermal reaction to improve the oil production efficiency of a hydrothermal liquidation process. According to the seaweed pyrolysis oil making system,byproducts in a seaweed pyrolysis process can be effectively utilized, in addition, the oil product and the yield of hydrothermal liquefaction bio-oil can be improved, and meanwhile, system energy useefficiency is high.
Owner:JIANGSU UNIV

Method for preparing clean fuel from coal tar, method for preparing clean fuel from coal and prepared clean fuel

The invention discloses a method for preparing clean fuel from coal tar and a method for preparing the clean fuel from coal. The method for preparing the clean fuel from the coal tar comprises following steps: the coal tar is subjected to distillation separation, and a carbolic oil fraction, an intermediate fraction and a heavy fraction are obtained; the carbolic oil fraction and methyl alcohol are subjected to etherification, and a high-octane component is obtained; the heavy fraction is subjected to extraction separation, and deasphalted oil is obtained; the intermediate fraction and the deasphalted oil are subjected to hydrorefining and hydrocracking, a mixture is subjected to fractional distillation, and a gasoline fraction and a diesel fraction are obtained; the high-octane component is added to the gasoline fraction, and blended gasoline is obtained. According to the method for preparing the clean fuel from the coal, the raw material coal is pyrolyzed, and the coal tar, semicoke and pyrolysis gas are obtained. With the adoption of the technical scheme, sufficient deep processing of the coal tar resource and the coal resource are realized, the high-octane component is obtained, and the gasoline fraction meeting the national standard is obtained.
Owner:CHNA ENERGY INVESTMENT CORP LTD +1
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