A catalytic combustion improver of coal for increasing combustion efficiency and decreasing the exhaust of SO2, CO and NOx is composed of the primary raw materials chosen from 17 salts of organic acid, including acetate, oxalate, succinate, etc, the organic compound prepared by reaction between 17 organic acids and ore, metal, metallic oxide, or compound, chloride, etc, and the secondary raw materials chosen from high-caloricity agent, surface coating agent, solvent, assistant, emulsifying disperser, sulfur fixating agent and filler.