The invention relates to a coated priming composition-free nail-shooting ammunition pellet formula and preparation method thereof. The coated priming composition-free nail-shooting ammunition pellet formula comprises, by weight, 89.80 to 99.78% of nitrocellulose, 0.20 to 0.75% of a stabilizing agent, 0.01 to 0.45% of a binder, 0.01 to 3.0% of a coating material, a solvent with an amount<=1.0%, and water with an amount <=5.0%. According to the preparation method, nitrocellulose containing water is taken as a base material; the nitrocellulose containing water, the solvent, the stabilizing agent, and the binder are delivered into a gelling kneading machine for gelling after a certain time of mixing; an obtained mixture is pressed into particles, the particles are dried and are subjected to moulding using a tablet machine so as to obtain pellets; and the pellets are coated with the coating material in a coating kettle, and are subjected to secondary drying. The obtained coated priming composition-free nail-shooting ammunition pellets possess excellent humidity resistance, and problems of the prior art, that drying efficiency is low, energy consumption is high, a large amount of dust is generated, combustion explosion is easily caused, and technology safety is poor, are solved.