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Yellow phosphorus production method and equipment

A production method and production equipment technology, applied in the field of yellow phosphorus production and equipment, can solve the problems of insufficient dust purification treatment, huge construction cost of electrostatic precipitator supporting facilities, high operation and maintenance costs, etc.

Active Publication Date: 2014-01-22
CHENGDU INTERMENT TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Although the production process of the above-mentioned large-scale self-baking electrode phosphorus production furnace can produce less sludge phosphorus and waste water, the construction cost of the electrostatic precipitator supporting facilities is huge, the operation and maintenance costs are high, and the technical requirements for personnel are high, and the furnace gas The dust purification treatment is not sufficient, which cannot ideally solve the problem of PM2.5 emission in the exhaust gas
However, the production process using multi-electrode phosphorus electric furnace will produce a large amount of sludge phosphorus that is difficult to separate, and the dust content in the tail gas is higher

Method used

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  • Yellow phosphorus production method and equipment
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  • Yellow phosphorus production method and equipment

Examples

Experimental program
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Effect test

Embodiment 1

[0070] A multi-electrode phosphorus electric furnace with a transformer capacity of 15000KVA is adopted. Add 50 tons of mixed material to the electric furnace 1 continuously for reaction. At the same time, start the gas supply device 303 and the heater 304. The high-temperature inert preheating gas passes through the second output pipe 306 and enters the filtered furnace gas inlet pipe from the filter 301. device 301, so as to preheat the sintered inorganic porous material filter element (FeAl intermetallic compound porous material filter element) in the filter 301 to 187.5° C., and then close the valve on the second output pipe 306 . Thereafter, the furnace gas discharged from the electric furnace 1 is introduced into the furnace gas dust collection system 3 through the smoke exhaust pipe 2 , and the furnace gas is heated by the heat exchange device 6 during the process. The heated furnace gas discharged from the electric furnace 1 first enters the mechanical dust collector 3...

Embodiment 2

[0072] After the end of embodiment 1, directly adopt its equipment to continue embodiment 2. The second batch of 50 tons of mixed material was continuously fed into the electric furnace 1 for reaction, and at the same time, switched to another refining pot 501 . The furnace gas discharged from the electric furnace 1 is introduced into the furnace gas dust collection system 3 through the smoke exhaust pipe 2 , and the furnace gas is heated by the heat exchange device 6 during the process. The heated furnace gas discharged from the electric furnace 1 first enters the mechanical dust collector 302 through the exhaust pipe 2 for primary dust removal and purification, and then enters the filter 301 for secondary dust removal and purification. The temperature of the furnace gas to be filtered is detected on the inlet pipe of the furnace gas to be filtered by the filter 301 and is kept at about 250° C. The filter 301 starts an online backflush every 600s. During the backflush, the i...

Embodiment 3

[0074] After the end of embodiment 2, directly adopt its equipment to continue embodiment 3. The third batch of 50 tons of mixed material was continuously fed into the electric furnace 1 for reaction, and at the same time, switched to another refining pot 501 . The furnace gas discharged from the electric furnace 1 is introduced into the furnace gas dust collection system 3 through the smoke exhaust pipe 2 , and the furnace gas is heated by the heat exchange device 6 during the process. The heated furnace gas discharged from the electric furnace 1 first enters the mechanical dust collector 302 through the exhaust pipe 2 for primary dust removal and purification, and then enters the filter 301 for secondary dust removal and purification. The temperature of the furnace gas to be filtered is detected on the inlet pipe of the furnace gas to be filtered by the filter 301 and is kept at about 300° C. The filter 301 starts an online backflush every 600s. During the backflush, the in...

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Abstract

The invention discloses a yellow phosphorus production method and equipment which do not produce mud phosphorus and can reduce the dust content in tail gas. The method comprises the technology links as follows: 1, electric furnace smelting; 2, furnace gas purification, furnace gas discharged from an electric furnace is guided into a furnace gas dust collecting system through an exhaust pipeline, the furnace gas dust collecting system comprises at least a filter used for filtering the furnace gas, the filter is provided with a sintering inorganic porous material filter element capable of meeting following work conditions, and the operation performed according to the filter comprises the steps as follows: 1), the operation executed during driving: inert preheating gas is injected into the filter, and the sintering inorganic porous material filter element in the filter is heated to 187.5 DEG C or above; 2), the operation executed during normal operation: to-be-filtered furnace gas with the temperature maintained to be 187.5-280 DEG C is input into the filter, and the dust content in the filtered clean furnace gas is below 10-20 mg / m <3>; and 3), the operation executed during reverse blowing and 4) the operation executed during parking; and 3, phosphorus collecting and refining.

Description

technical field [0001] The application relates to a production method and equipment of yellow phosphorus. Background technique [0002] The electric furnace yellow phosphorus production process for industrial application is divided into the production process using large-scale self-baked electrode phosphorus electric furnace and the production process using multi-electrode phosphorus electric furnace. Although the two processes are different in the type and scale of the electric furnace, the requirements for the treatment of raw materials into the furnace, and the dust removal measures for the furnace gas, the main process is basically the same, that is, the mixture of phosphate rock, silica and coke in proportion. The material is fed into the electric furnace, and the mixture in the electric furnace undergoes a reduction reaction to generate furnace gas. The furnace gas escapes from the reaction melting zone, and after passing through the furnace gas filter layer formed by ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B25/027
Inventor 高麟汪涛樊彬
Owner CHENGDU INTERMENT TECH
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