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806 results about "Non-metallic inclusions" patented technology

Non-metallic inclusions are chemical compounds and nonmetals that are present in steel and other alloys. They are the product of chemical reactions, physical effects, and contamination that occurs during the melting and pouring process. These inclusions are categorized by origin as either endogenous or exogenous. Endogenous inclusions, also known as indigenous, occur within the metal and are the result of chemical reactions. These products precipitate during cooling and are typically very small. Exogenous inclusions are caused by the entrapment of nonmetals. Their size varies greatly and their source can include slag, dross, flux residues, and pieces of the mold.

High-cleanliness pipeline steel smelting process

ActiveCN104630418ASolve the difficulty of cleanliness controlQuality improvementManufacturing convertersSulfurNon-metallic inclusions
The invention discloses a high-cleanliness pipeline steel smelting process. The process route comprises molten iron pouring, molten iron pretreatment, converter smelting, tapping, deoxidizing, alloying, LF refining furnace, treating with calcium, RH vacuum furnace and continuous casting and is characterized by comprising the following specific steps: firstly, converter smelting process; secondly, refining furnace smelting process; and thirdly, continuous casting process. The invention belongs to a steel-making process in the field of metallurgy and relates to a method for smelting and controlling a high-cleanliness pipeline steel. By molten iron desulphurization pretreatment, optimizing a converter tapping and deoxidizing system and a slagging system, LF refining furnace deep deoxygenation and reducing slag manufacturing processes, RH high-vacuum-degree degassing and inclusion removal process, the pouring is protected by the continuous casting in the whole process so that the composition of a casting billet is uniform, the contents of harmful elements such as S, P, O, N and H are low, the non-metallic inclusions are effectively controlled, the casting billet is good in internal quality and the production of high value-added ultra-low sulfur steel is ensured.
Owner:NANJING IRON & STEEL CO LTD

Rapid detection method and rapid detection device of non-metallic inclusions in metal

ActiveCN103123329AQuickly obtain 3D topographyQuick access to ingredientsUsing optical meansMaterial analysis by measuring secondary emissionImaging analysisNon-metallic inclusions
The invention discloses a rapid detection method of non-metallic inclusions in metal. The rapid detection method comprises the following five steps of: heating and smelting a metal test sample, separating the inclusions, detecting the total amounts and the sizes of the inclusions, condensing metal liquid, and detecting the three-dimensional shape and components of the inclusions. The invention further provides a special rapid detection device comprising a heating furnace device, a metal liquid rotation device, a video collection device and an image analysis system. The metal test sample is rapidly smelted and the steel liquid is driven to rotate; centrifugal force and gravity are used for rapidly upwards floating various non-metallic inclusions in the metal liquid and gathering the various non-metallic inclusions at the center of the surface of the metal liquid; high speed photography and video analysis software is used for rapidly obtaining the total amount and the size distribution of the non-metallic inclusions in the metal test sample; the metal liquid is rapidly cooled and condensed and the inclusions are cured on the surface of the metal test sample; and a scanning electron microscope and the energy spectrum analysis are used for obtaining the three-dimensional shapes and the components of the non-metallic inclusions in the metal test sample. According to the rapid detection method and the device disclosed by the invention, the direction is rapid and convenient, the analysis is accurate and visual, and cleaning and no pollution can be realized.
Owner:新兴发展集团有限公司

Electrolytic extraction and detection method of nonmetallic inclusion in steel by utilizing organic solution

ActiveCN102213654AReduce and stabilize liquid junction potentialAvoid destructionElectrolysis componentsPreparing sample for investigationFiltrationSalt bridge
The invention relates to an electrolytic extraction and detection method of nonmetallic inclusion in steel by utilizing an organic solution. The method comprises the following process steps: (1) preparing electrolyte; (2) preparing and electrolyzing a steel sample: soaking the steel sample containing the inclusion into the electrolyte in an electrolytic cell; arranging a salt bath beside the electrolytic cell; erecting a salt bridge between the salt bath and the electrolytic cell; inserting a calomel electrode into the salt bath; inserting a calomel electrode in the salt bath; using the positive electrode of the steel sample, connected with a direct current stabilized power supply, as the anode, using a platinum wire as an electrolysis cathode, charging inert gas, particularly referring to argon; and (3) separating: pouring the electrolyte left after the electrolysis of the steel sample in the step (2) into a funnel which is filled with filter paper; arranging a vacuum filtration device which is loaded with a polytetrafluoroethylene membrane at the position tightly attached to the liquid down port of the funnel; separating the inclusion from the steel sample under the state that the vacuum filtration device is vacuumized; and transferring the polytetrafluoroethylene membrane which is distributed with the inclusion to a scanning electron microscope for detection. In the method provided by the invention, the inclusion can be extracted out of the steel without being damaged; and the three-dimensional shape of the inclusion is directly observed.
Owner:JIANGYIN XINGCHENG SPECIAL STEEL WORKS CO LTD

Preparation method of IN718 alloy spherical powder

The invention discloses a preparation method of IN718 alloy spherical powder. The method comprises the following steps of step 1, smelting an IN718 alloy master ingot; step 2, processing the IN718 alloy master ingot into an IN718 alloy electrode bar with the diameter of 50 to 90mm and the length of 600 to 800mm, wherein the straightness of the electrode bar is controlled to be smaller than or equal to 0.1mm / m; step 3, placing the IN718 alloy electrode bar in a sealed furnace chamber protected by inert gas, rotating the IN718 alloy electrode bar at high speed, and heating the end part of the electrode bar by using a plasma gun to melt the electrode bar; step 4, atomizing the melted metal under the action of centrifugal force to enable melted metal to fly to form fine liquid droplets, wherein the liquid droplets are quickly cooled in inert gas to form spherical particles, and the spherical particles fall into a collector at the bottom of the furnace chamber to form the IN718 alloy spherical powder; step 5, under the protection of the inert gas, performing electrostatic separation processing on the prepared IN718 alloy spherical powder to remove non-metal impurities from the powder to obtain the pure IN718 alloy spherical powder. The method has the characteristics of good sphericity degree, fine particle size, low oxygen content and few impurities.
Owner:SINO EURO MATERIALS TECH OF XIAN CO LTD

Method for controlling non-metallic inclusions in steel

The invention discloses a method for controlling non-metallic inclusions in steel, and belongs to the field of steelmaking and refining control. Two-section calcium treatment and soft blow are adopted during the refining, and the calcium treatment and the soft blow are performed at the end of LF refining and RH vacuum treatment respectively, so that the non-metallic inclusions in a casting blank are classified into two types: 70 to 90 percent of non-metallic inclusions with CaS as main components, and 10 to 30 percent of oxide type non-metallic inclusions, wherein all the non-metallic inclusions in the casting blank are spherical; the particle diameters of all the non-metallic inclusions in the casting blank are controlled within a range of 0 to 5 microns; and the number of the non-metallic inclusions with the diameter of greater than 3 microns in the casting blank is controlled within the range of 0 to 5/cm<2>. Thus, the problem that the calcium aluminate type non-metallic inclusion produced after the calcium treatment cannot be discharged out of molten steel due to insufficient time, so the content of calcium aluminate type non-metallic inclusions in the casting blank is high is solved. The rejection rate caused by super-standard non-metallic inclusion of the low alloy structural steel is reduced.
Owner:SHOUGANG CORPORATION

Method for observing in-situ morphologies of nonmetallic inclusions in steel

InactiveCN102879412ATrue form completeThe real shape is fully presentedPreparing sample for investigationMaterial analysis by measuring secondary emissionSpectroscopyGlycerol
The invention relates to a method for observing the in-situ morphologies of the nonmetallic inclusions in steel. The method is characterized by comprising the following steps: a metallographic specimen is prepared and a surface to be observed is polished to be a plane; the superficial electrolytic corrosion is performed on an electrochemical polishing apparatus, an electrolyte is as follows: 5% (v/v) HCl (hydrogen chloride)+5%(v/v) glycerol+1% (v/v) citric acid methanol solution, and the setup parameters of the electrochemical polishing apparatus are as follows: the current density is 0.02A to 0.10A/cm<2>, the electrolytic temperature is from below 15 DEG C to below 5 DEG C, and the electrolytic time is 20 to 40s; a rubber rod is utilized for slightly wiping off the corrosive products on an electrochemical polishing surface of a test sample after the electrochemical polishing, the surface of the test sample is dried by a blow drier, and the nonmetallic inclusions are highlighted on an electrolytic etched surface of the test sample, so that the true morphologies of the nonmetallic inclusions with the different dimensions are completely displayed; and the morphologies of the nonmetallic inclusions are observed by a scanning electron microscope and an energy disperse spectroscopy. The method for observing in-situ morphologies of nonmetallic inclusions in steel provided by the invention has the advantages that the sample is prepared simply, the period is short, the analysis speed is fast, and the constituents and the varieties of the nonmetallic inclusions can be determined accurately by observing the three-dimensional morphologies and dimensions of the nonmetallic inclusions.
Owner:INNER MONGOLIA BAOTOU STEEL UNION

Pressurizing induction and pressurizing electroslag remelting duplex high-nitrogen steel smelting method

ActiveCN106011371AEasy to loosenImprove composition segregation and other problemsIncreasing energy efficiencyElectric furnaceNon-metallic inclusionsNitrogen gas
The invention belongs to the technical field of high-nitrogen steel smelting and particularly relates to a pressurizing induction and pressurizing electroslag remelting duplex high-nitrogen steel smelting method. The method is suitable for smelting high-nitrogen steel including smaller than or equal to 0.6% of C, smaller than or equal to 30% of Mn, 12%-30% of Cr, smaller than or equal to 1% of Si, 0%-4.5% of Mo, 0.1%-2% of N, 0%-4.5% of Ni, 0%-1% of V, smaller than or equal to 0.015% of S, smaller than or equal to 0.05% of P and the balance Fe. During smelting, a pressurizing induction furnace is used for smelting electrode base metal meeting the nitrogen content requirement according to steel grade components; an solid-state arcing method is used for arcing slagging under the nitrogen condition; and afterwards, the pressure of a smelting room and the pressure of cooling water are increased, and smelting is conducted with the voltage of 35 V to 40 V and the current of 2000 A to 3000 A. A technical guarantee is provided for developing high-nitrogen stainless steel which is low in sulfur content, few in nonmetallic inclusion, even and dense in structure and even in nitrogen distribution.
Owner:NORTHEASTERN UNIV

Method for extracting and observing three-dimensional appearance of non-metallic inclusion in steel in full-scale mode

The invention is applied to the technical field of steel making and continuous casting and discloses a method for extracting and observing three-dimensional appearance of non-metallic inclusion in steel in full-scale mode. A steel sample is processed into a thin sheet of (100mm-160mm length)*(50-90mm width)*(3mm-5mm thickness) to be used as an electrolysis anode, a stainless steel thin sheet is used as a cathode, and an organic solution comprising, by weight percentage, 1% -3.0% of tetramethylammonium chloride, 5%-10% of triethanolamine and the balance propylene carbonate is adopted as electrolyte. Current density is controlled to be 0.05A/cm<2>-0.08A/cm<2>, and electrolysis time is controlled to be 24h to 72h. The non-metallic inclusion with different grain size ranges can be obtained after multiple filtrations and separations. The three-dimensional appearance of the non-metallic inclusion with the different grain size ranges can be observed clearly under a scanning electron microscope or a field emission electron microscope. The method is simple in operation, short in cycle and comprehensive in information for reflecting inclusion and has important meaning for understanding and controlling the non-metallic inclusion in the steel.
Owner:UNIV OF SCI & TECH BEIJING

Method for manufacturing spherical niobium and titanium-based alloy powder with small particle size

The invention discloses a method for manufacturing spherical niobium and titanium-based alloy powder with a small particle size. The spherical niobium and titanium-based alloy powder is manufactured by the aid of vacuum induction melting, hydrogen treatment and plasma spheroidization technologies. The method includes firstly, manufacturing niobium and titanium-based spherical alloy ingots by the aid of the vacuum induction melting technology to realize a purification melting effect, reducing the quantity and the size of non-metallic inclusion to the greatest extent and performing homogenization thermal treatment on the niobium and titanium-based spherical alloy ingots to obtain ingots with uniform alloy contents; secondly, performing hydrogen treatment on the ingots to acquire hydrogen absorption niobium and titanium alloy powder; thirdly, sieving the hydrogen absorption niobium and titanium alloy powder, and then performing plasma spheroidization on the hydrogen absorption niobium and titanium alloy powder. The method has the advantages that output power, the powder feeding rate and the airflow rate are optimized in spheroidization procedures, accordingly, hollow powder can be prevented, and the fine powder yield can be increased; the spherical powder obtained by the method is excellent in dispersibility and flowability and uniform in particle size; the niobium and titanium-based alloy powder finally manufactured by the method is small in particle size, uniform in composition, good in flowability, high in spheroidization rate and low in oxygen content and is applicable to the technical field of injection molding, quick molding and thermal spraying.
Owner:UNIV OF SCI & TECH BEIJING

Smelting process of Cr-Mn series spring steel

ActiveCN104745765AImprove liquiditySolve the problem of high alkalinity slag and difficult adsorption and inclusionElectric furnaceProcess efficiency improvementNon-metallic inclusionsSmelting process
The invention belongs to the field of metallurgy and discloses a smelting process of Cr-Mn series spring steel. The smelting process of Cr-Mn series spring steel comprises the following steps: (1) by taking a low-sulfur molten iron and a high-quality steel scrap as the electric furnace smelting iron and steel materials, controlling the electric furnace end point carbon content to greater than 0.15%; (2) adding active lime and composite refining slag in the electric furnace tapping process, and adding calcium carbide to perform pre-deoxidation in the tapping process; (3) feeding an Al line in an argon station before LF refining; (4) producing high basicity white slag in the refining earlier stage and controlling the basicity of slag in the refining middle and later stages to 1.5-2.5; (5) controlling the ultimate vacuum front argon flow to 15-25 L/min and controlling the ultimate vacuum late argon flow to 30-45 L/min; (6) adding a granular alkaline covering agent and a carbonized rice hull to perform double protection by VD emptying; and (7) stabilizing the speed of continuous casting to 0.8-0.9 m/min, and controlling the degree of superheat to 20-30 DEG C. By adopting the process, the non-metallic inclusion content in the molten steel is reduced.
Owner:ZENITH STEEL GROUP CORP +1

Purification smelting method for nickel-based high-temperature alloy master alloy

A purification smelting method for a nickel-based high-temperature alloy master alloy comprises the following steps: (1) carrying out hydrochloric acid and ultrasonic treatment of a metal raw material; preparing CaO-CaF2 pre-melted slag; and uniformly mixing the pre-melted slag and a pure nickel powder, and pressing into a block; (2) placing the raw material and the press block together into a crucible, and vacuumizing; adding C, Nb, Ti and Al after melting; filling with argon gas, adding B and Zr until an alloy liquid is molten again, and pouring into a steel mold, to obtain a high temperature alloy ingot; and removing oxide scale and risers of the ingot, to obtain a high temperature alloy concentrate; and (3) putting the concentrate into a copper crucible; vacuumizing, melting, and rapidly solidifying, to obtain the high temperature alloy master alloy. Slag refining is performed during vacuum induction smelting, and the sulfur and phosphorus content is low; the copper crucible can avoid the pollution of the crucible to an alloy melt; magnetic suspension can promote non-metallic inclusions to float upwards; the content of oxygen and nitrogen is low, so the amount of non-metallic inclusions formed in the cooling and solidification processes of the alloy liquid is reduced; the conventional mature smelting device is used, and the operation is convenient.
Owner:UNIV OF SCI & TECH BEIJING

Smelting method of high-carbon chromium bearing steel

InactiveCN102634732ASolve aggregation phenomenonElectric arc furnaceHigh carbon
The invention relates to a smelting method of high-carbon chromium bearing steel, which is used for solving the phenomena of distribution and congregation of B non-metal inclusions in steel by controlling slag system and inclusions through controlling the Ti content in the refining process, carrying out slag exchange during refining mildly stirring and adding carbonized rice hull. The smelting method comprises the specific steps of: in EAF (electric arc furnace) process, controlling [S] in molten supernatant being less than or equal to 0.030% during burdening; in EAF tapping process, inhibiting the oxidizing slag flowing into a steel ladle and using low-Ti-content alloy; in LF (ladle furnace) process, carrying out online slag sample analysis (carrying out first LF analysis before hoistingthe ladle), and controlling the alkalinity of the low-alkalinity slag to be 2.0-3.0 with buhrstone according to the slag sample analysis before pouring the slag out of LF furnace; after VD (vacuum degassing) furnace vacuum treatment, carrying out online slag sample analysis to control hydrogen being less than or equal to 1.5ppm and no larger than 2.0ppm; after VD furnace vacuum treatment, closingthe cover and stirring mildly for 15-20 minutes; and in die casting process, using FZ-2 covering slag and adding an inlet heating agent after casting. According to the invention, by bluing fracture test measurement, the content of low-multiple inclusions is less than or equal to 2.5mm/dm<2>, the maximum length of single inclusion is less than or equal to 3mm; and the coarse system rating in B inclusions is less than or equal to 1.0.
Owner:宝钢特钢有限公司
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