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72 results about "Hydrogen absorption" patented technology
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The absorption spectrum for Hydrogen, arises when we view white light coming through hydrogen gas, as is typically observed by astronomers when they analyse the light coming from distant stars; the light from those stars passing through clouds of cold hydrogen gas.
The invention discloses a hydrogenstorage material variable temperature hydrogen absorption and desorption cycle test method based on a Sieverts constant volume method. In a cycle test of the variable-temperature hydrogen absorption and desorption cycle test method, a single hydrogen absorption and desorption process comprises temperature-dependent hydrogen absorption and temperature-dependent hydrogen desorption of a hydrogen storage material in a closed system, namely, the single hydrogen absorption and desorption process comprises a cooling hydrogen absorption reaction and a heating hydrogen desorption reaction of the hydrogen storage material along with temperature change; the closed system is a constant-volume closed system without hydrogen material exchange with the outside. According to the invention, the hydrogen absorption and desorption cycle test efficiency of the reversible hydrogen storage material can be obviously improved, and the method has the advantages of controllable hydrogen absorption and desorption depth, temperature and hydrogen back pressure, simple process flow, high system adaptability, good controllability, good repeatability and the like. By optimizing and matching the loading capacity of the hydrogen storage material, the intrinsic thermodynamic PCT characteristic, the test temperature and the system volume, the hydrogen storage material can complete rapid hydrogen absorption and desorption circulation under the conditions of controllable hydrogen absorption and desorption depth, temperature and hydrogen back pressure.
This invention relates to a solid-state hydrogenstorage tank and its preparation and filling / discharging methods, belonging to the field of hydrogen storage and transportation technology. It solves the technical problem that the low thermal conductivity of granular and powdered hydrogen storage alloys leads to reduced hydrogen absorption and discharging rates, while existing solid-state hydrogen storage tanks with internal heat exchange structures suffer from complex manufacturing processes and high costs. A solid-state hydrogen storage tank includes a valve, a tank body, a metal mesh array, and granular hydrogen storagealloy dispersedly filled within the metal mesh array. The tank body is a cylindrical, straight-sided bottle shape. The valve fits into the bottle opening of the tank body. The metal mesh array is densely filled inside the tank body and tightly adheres to the inner wall of the tank body. The solid-state hydrogen storage tank of this invention constructs a metal mesh array through the combination of single metal mesh tubes, forming a dense and continuous metal meshheat transfer network with high thermal conductivity. This reduces the high / low temperature levels of the hydrogen storage alloybed, especially in the core area, and significantly shortens the hydrogen filling time.
The present application belongs to the hydrogen energy utilization technology field in the clean energy and new energy field, and relates to a hydrogen storage reactor for increasing the contact area between hydrogenstorage material and hydrogen, which comprises a reactor main body and a screen assembly, the screen assembly is arranged in the reactor main body, the screen assembly comprises an upper screen, a lower screen and a weighted fixing piece, the upper screen and the lower screen are fixed through the weighted fixing piece, and the upper screen, the lower screen and the weighted fixing piece form a hydrogen storage material sample powder particle reaction space. The reactor adopts the screen assembly to realize convenient sample loading, simple operation, non-blowing, zero sample loss and zero accumulation. The reactor is designed to be through from top to bottom, so that the powder sample particles are contacted with hydrogen in all directions, the reaction with hydrogen is fully realized, hydrogen can quickly enter the interstitial space of the alloy lattice, the hydrogen absorption speed is improved, and the hydrogen storage kinetic performance is improved. At the same time, the error experiment error is minimized, and the data accuracy is improved.
The detachable solidhydrogen storage device comprises a shell and a hydrogen storage container arranged in the shell, a sealable gas inlet and outlet is formed in the shell, a cavity is formed between the shell and the hydrogen storage container, and a heat exchange mechanism and a supporting framework are arranged in the hydrogen storage container; the supporting framework divides the interior of the hydrogen storage container into a plurality of dot matrix units and a heat exchange mechanism containing space, a plurality of through holes are formed between every two adjacent dot matrix units, and the dot matrix units are all used for containing hydrogen storage materials. According to the hydrogen storage device, by arranging the dot matrix units internally communicated with one another, the heat exchange performance of the hydrogen storage device can be enhanced, transmission and distribution of hydrogen in the device can be remarkably improved, expansion stress generated in the hydrogen absorption and desorption process of a hydrogen storage material is shared, and therefore the problem that the reaction kinetics performance of the hydrogen storage material in a local area is reduced is effectively solved; and the deformation or fracture risk caused by stress concentration of the hydrogen storage device is remarkably reduced, and the hydrogen storage device is suitable for solid hydrogen storage.
The present invention discloses a method, system, device, medium, and program product for quantifying the progress of hydrogen absorption and desorption reactions, relating to the fields of materials science and image processing technology. The method comprises: preprocessing a reaction process image to obtain a feature image; extracting grayscale features or crack texture features related to the progress of the hydrogen absorption and desorption reactions based on the feature image; determining a reaction fraction based on the grayscale features or crack texture features, as well as the features of hydrogen absorption and desorption in equilibrium, thereby obtaining a quantified result of the progress of the hydrogen absorption and desorption reactions. Based on the different color and texture morphology of the hydrogen storage material before and after hydrogen absorption and desorption, the grayscale features and crack texture features in the reaction process image are extracted. By establishing a mapping relationship between the image features and the reaction progress, a quantified result is obtained based on the image features, thereby achieving real-time, in-situ, non-invasive monitoring of the reaction progress and avoiding interference with the reaction process.
The application belongs to the technical field of hydrogen storage and transportation, and discloses a magnesium-based hydrogenstorage materialhydrogen absorption and release system using air as a heat medium, which comprises a hydrogen storage heat exchange box, at least one hydrogen storagebottle which can be detachably installed in the hydrogen storage heat exchange box, an air circulation heating unit and an air circulation cooling unit; the air circulation heating unit comprises an air duct heater and a first air fan, and forms a heating circulation loop with the hydrogen storage heat exchange box; the air circulation cooling unit comprises an air duct cooler and a second air fan, and sends cooling air into the hydrogen storage heat exchange box. In the hydrogen absorption working condition, the hydrogen storage bottle is heated to a reaction temperature by the heating unit first, and then the cooling unit is switched to reduce the temperature after hydrogen absorption heat is released; in the hydrogen release working condition, only the heating unit is needed to heat to a decomposition temperature. The application significantly improves the hydrogen storage density of the magnesium-based hydrogen storage equipment, and reduces the equipment cost.
The invention discloses an alloyhydrogen storage hydrogen absorption and desorption control method and system based on an agent model. The method comprises the steps that leakage detection of an alloyhydrogen storage system and activation of an adsorbent are conducted; setting a hydrogen absorption / desorptionmass flow rate, taking the hydrogen absorption / desorptionmass flow rate as a target value of a hydrogen absorption / desorption rate, and determining initial hydrogen pressure and temperature according to the proxy model; according to the real-time hydrogen pressure and temperature in the hydrogen storage reactor, the real-time adsorption / desorption rate is rapidly predicted; and the temperature of the hydrogen storage reactor is adjusted by adopting a PID control algorithm. The agent model based on data driving is obtained through training by adopting a small sample learning technology, and the problem of model training accuracy caused by insufficient data volume is solved. The model is small in scale and quick in response, and can be quickly deployed in a control algorithm, so that thermal environment parameter control is effectively implemented in an easy-to-implement temperature parameter control mode, and the stability of hydrogen absorption and desorption is improved.
Provided are a heating module, a heating device, and a gas introduction device capable of causing a heating element to generate heat with a simple structure and at low cost. A heating module 10 comprises: a hollow airtight container 16; a connection portion 17 detachably connected to an external device; a heating element 18 for generating heat through hydrogen absorption and release; and a heat source 19 for heating the heating element 18. The external device includes: a power supply device for supplying power to the heat source 19; and a gas introduction device for introducing, into a space 21 inside the airtight container 16, a sealed gas containing at least one of an inert gas and a hydrogen-based gas that contains hydrogen. The connection portion 17 includes: a power connector 26 connected to the heat source 19 and detachably connected to the power supply device; and a sealing valve 28 for opening and closing the space 21 and detachably connected to the gas introduction device. The sealing valve 28 is closed to close the space 21. In the closed space 21, the heating element 18 that has absorbed hydrogen is provided, and the sealed gas is enclosed.
The invention discloses a solidhydrogen storage device and a hydrogen storage method.The solidhydrogen storage device comprises a device rack, a plurality of hydrogen storage tanks are arranged in the device rack at equal intervals, each hydrogen storage tank is composed of a hydrogen storagebarrel, a first flange and a second flange, and the hydrogen storage barrels are fixedly installed in the device rack; a first flange and a second flange are fixedly installed at the two ends of each hydrogen storage barrel respectively, the outer sleeves are coaxially and fixedly installed outside the hydrogen storage barrels, and interlayers exist between the inner walls of the outer sleeves and the outer walls of the hydrogen storage barrels; and a heat exchange assembly is installed in an interlayer between the interior of each outer sleeve and the hydrogen storage barrel, a temperature controlassembly is installed on the device rack, and a communication assembly is installed on the device rack, so that the problem that in the prior art, due to the fact that the heat exchange efficiency is limited, heat generated in the hydrogen absorption process is difficult to transfer away rapidly, and the hydrogen storage capacity is affected is solved.
The invention relates to an AB2 type hydrogen storage alloy and a preparation method and application thereof, the preparation method comprises the following steps: (1) performing first mixing on Cr and Mn according to the proportion of each element to obtain a first mixed metal material, and performing second mixing on Ti and Zr to obtain a second mixed metal material; and (2) carrying out first smelting treatment on the first mixed metal material until the first mixed metal material is partially or completely smelted, then adding the second mixed metal material into the first mixed metal material, carrying out second smelting treatment until the fusible components are completely smelted, and then sequentially carrying out refining treatment and cooling treatment to obtain the flaky alloy. According to the method, secondary feeding and rapid hardening smelting are combined, the AB2 type hydrogen storage alloy which is small in hydrogen absorption and desorption PCT curve slope and still can keep high hydrogen storage capacity after 100 times of hydrogen absorption and desorption circulation is prepared, and the service life of a smelting crucible is prolonged.
According to one embodiment, a hydrogen concentration measuring element (100, 100a, 100b) comprises: a wire-shaped detection part (110) comprising a first metal wire (111) whose electrical resistance value is changed by hydrogen absorption and a first protective coating layer (112) having hydrogen permeability and covering the first metal wire (111); a plate-shaped fixing part (130); two first terminal parts (151, 152) each provided on one of two surfaces of the fixing part (130); and a plurality of guides (140) which are provided on at least one surface of the fixing part (130) to protrude from the surface and enable the detection part (110) to be laid between the two first terminals while changing a direction. Figure for abstract: Fig 2
This invention relates to the field of hydrogen-powered drone technology, specifically to a liquid hydrogen cylinder for drones with active thermal management and an adaptive heat exchange system. The cylinder includes a cylinder body, a hydrogen storage box, a heating element, a heat exchange element, and a management system. The inner liner of the cylinder body provides a storage environment for liquid hydrogen, while a hydrogen supply channel on the outer shell stably supplies hydrogen to the drone's hydrogen fuelsystem. The hydrogen storage box within the interlayer is filled with a hydrogen storagealloy, which utilizes the hydrogen absorption and release properties of liquid hydrogen at low temperatures, using the hydrogen within the interlayer as a heat transfer medium to achieve controllable heat transfer. The flow guide and heat exchange element form a heat exchange assembly, utilizing the slipstream generated by the drone's propellers for passive heat exchange. The management system can communicate with the drone's flight control system, predicting hydrogen demand based on flight conditions and controlling the heating element accordingly. This enables controllable switching between heat conduction and insulation states within the interlayer, resolving the core contradiction between storage and vaporization in existing liquid hydrogen cylinders.
A TiFe-based hydrogen storage alloy and a preparation method thereof belong to the field of metalhydrogen storage materials. The chemical general formula of the TiFe-based hydrogen storage alloy is: Ti a Nd b Zr c Fe d Ni e Mn f wherein the atomic percentage of each element satisfies: the atomic percentage of Ti element is 46-53at%, the atomic percentage of Nd element is 0.1-1.5at%, the atomic percentage of Zr element is 1-6.5at%, the atomic percentage of Fe element is 27-40at%, the atomic percentage of Ni element is 2-10at%, and the atomic percentage of Mn element is 4.5-12at%; wherein Ti, Nd and Zr are first metal elements, Fe, Ni and Mn are second metal elements, and the ratio of the total atomic percentage of the first metal elements to the total atomic percentage of the second metal elements is 1.05-1.20. The TiFe-based hydrogen storagealloy can be activated at room temperature, has suitable hydrogen absorption and desorption platform pressure, and simultaneously maintains high hydrogen storage capacity and fast hydrogen absorption and desorption rate.
The application provides a hydrogen filling method and system of a solid-state hydrogen storage device, the method comprising the following steps: connecting a hydrogen filling gun to an inlet end of the solid-state hydrogen storage device, and filling hydrogen into the solid-state hydrogen storage device at a first rate, so that a solid-state hydrogen storage material in the solid-state hydrogen storage device absorbs and stores hydrogen; acquiring a real-time temperature in the solid-state hydrogen storage device at a preset acquisition period; when the real-time temperature in the solid-state hydrogen storage device is greater than a first temperature threshold, discharging hydrogen subjected to heat exchange from an exhaust end of the solid-state hydrogen storage device, and filling hydrogen into the solid-state hydrogen storage device at a second rate, wherein the second rate is greater than the first rate; and stopping hydrogen filling until the solid-state hydrogen storage material in the solid-state hydrogen storage device reaches a hydrogen absorption saturation state. The method can control the hydrogen absorption temperature to be optimal, reduce the hydrogen filling time, and take out the heat generated by the hydrogen absorption of the hydrogen storage material in the solid-state hydrogen storage device through cold hydrogen, so that the heat exchange efficiency is improved.
The application discloses a metalhydridehydrogen storage device and belongs to the technical field of hydrogenenergy storage. The device comprises a pressure-resistant tank body, a hydrogenpipe and hydrogen storagealloypowder. A plurality of hub-type fins with radial fan-shaped through holes are fixed in the pressure-resistant tank body. The hydrogen storagealloypowder is supported in layers, the hydrogen flow channel is optimized, and the heat transfer in the bed body is strengthened. A heat exchange tank jacket is arranged outside the pressure-resistant tank body, a plurality of independent fluid channels extending in the axial direction are arranged on the heat exchange tank jacket, and a forced airconvection heat exchange air duct is formed. Through the synergistic effect of the internal hub-type fins and the external forced air fluid channels, the hydrogen storagealloypowder pulverization and collapse are effectively inhibited, the stress of the tank body is relieved, the heat transfer and masstransfer efficiency of the device are significantly improved, the hydrogen absorption / release response time is shortened, the overall structure of the system is lightened and simplified, and the manufacturing cost and maintenance complexity are reduced.
The application relates to an AB5 type alloy with high hydrogen storage performance and a preparation method and application thereof. 0.6 Ni 3.45 Mg a Nd b ; wherein a=0.2-0.4, b=0.1-0.2. The preparation method comprises the following steps: (1) ingredients are prepared according to the formula, and then mixed materials are obtained by smelting in a vacuum arc furnace; (2) the mixed materials obtained in the step (1) are absorbed into a water-cooled copper mold by a vacuum suction casting method to obtain a rod-shaped alloy, namely the obtained alloy. The high hydrogen storage performance alloy provided by the application optimizes the alloy performance by adjusting the element ratio and changing the preparation process, significantly improves the effective hydrogen release amount, hydrogen absorption and release kinetics and hydrogen absorption rate, and has the advantages of simple and rapid preparation method, low preparation cost, large-scale production and application.
A hydrogen storage alloy filling system is provided that can stably transfer hydrogen from a hydrogen supply tank to a hydrogen absorption tank. [Solution] A hydrogen storagealloy filling system 1 is provided with a supply-side medium circuit 2 equipped with a hydrogen supply-side tank 21, an absorption-side medium circuit 3 equipped with a hydrogen absorption-side tank 31, and a hydrogen transfer path 4 connecting the hydrogen supply-side tank 21 and the hydrogen absorption-side tank 31. The absorption-side medium circuit 3 is provided with a cooler 36 for further cooling the medium. The cooling amount of the cooler 36 is controlled so that the amount of heating for the hydrogen supply-side tank 21 and the amount of cooling for the hydrogen absorption-side tank 31 are in a predetermined ratio.
The utility model discloses a hydrogen absorption and desorption pressure and capacity testing device for a solidhydrogen storage bottle, and relates to the technical field of industrial automation control, the hydrogen absorption and desorption pressure and capacity testing device comprises a base, the top of the base is provided with a testing device, the top of the base is provided with a dustproof mechanism for dust prevention, and the dustproof mechanism comprises a shell unit; according to the disassembly and assembly unit, the shell unit is arranged, an inverted-T-shaped block is inserted into an inverted-T-shaped groove in a sliding mode, a front shell and a rear shell are driven to be combined, meanwhile, an insertion column is inserted into an insertion hole, the influence of dust on the device is avoided, and a dustproof net is installed on the front side of the front shell, so that the interior of the rear shell and the interior of the front shell are cooled while the dust is blocked; by adopting the PLC control system and matching with upper computer software, the system has high reliability and stability, can stably work for a long time in a severe industrial environment, greatly reduces the development and debugging cost and difficulty of a small-scale test device, and has good maintainability and expandability.