465results about "Fixed capacity gas holders" patented technology

1.1 Storage system for the storage and transport of hydrogen, based on hollow microspheres in whose closed shells metal particles are embedded, which can be heated inductively. 2.1. Various hydrogen storage and transport systems exist, which either have limited storage capacities or require significant energy input, and are therefore generally not economically viable for a broad hydrogen economy. The new system aims to provide large storage capacities with the lowest possible energy consumption. 2.2. The storage system is characterized by the fact that metal, metal alloy, or metal composite particles are embedded in the closed shells of hollow microspheres, which can be inductively heated, thus allowing rapid hydrogen permeation into and out of the hollow spheres even at low temperatures during the loading and unloading process. 2.3. Hydrogen storage and transport system.

The utility model discloses an inerting and discharging combined safety protection device for a solid hydrogen storage tank, and belongs to the technical field of hydrogen storage and supply. The device comprises a solid hydrogen storage tank main body, a pressure and temperature sensing module, an inert gas injection system, a flameless relief device and a hydrogen treatment unit, the pressure and temperature sensing module monitors parameters in the tank in real time, when the parameters exceed a preset threshold value, the inert gas injection system injects inert gas from the lower portion of the tank body at constant pressure, the air pressure is stabilized through flow control, and meanwhile hydrogen is pumped out of an opening in the upper portion of the tank body to the processing unit; and a discharge port is formed in the side surface of the tank body and is linked with the flameless discharge device. According to the device, through the design of inerting inhibition and safe release, the potential safety hazard of overtemperature and overpressure in the solid hydrogen storage process is solved, the stability and safety of a hydrogen storage system are improved, and the device is convenient to operate and adapts to transformation of an existing solid hydrogen storage tank.

The invention relates to the technical field of hydrogen energy solid hydrogen storage, and discloses a metal hydride hydrogen storage tank and a circulating hydrogen charging and discharging method.The metal hydride hydrogen storage tank comprises a tank body, the top end of the tank body is communicated with a gas inlet pipe, and the bottom end of the gas inlet pipe extends into the tank body and is rotationally provided with a connecting pipe through a rotating connector; a plurality of circular heat dissipation fins are fixedly connected between the inner walls of the tank body, the bottom end of the connecting pipe penetrates through the heat dissipation fins to be rotationally connected with the bottom end of the tank body, and a plurality of air holes are formed in the surface of each heat dissipation fin; four telescopic rods are fixedly connected to the top wall of the interior of the tank body, the hydrogen storage tank drives the transmission assembly to drive the connecting pipe and the stirring plate to rotate through movement of the piston, metal hydride is prevented from caking, hydrogen is dispersed more evenly through inclined air outlet holes, and the hydrogen storage efficiency is improved; the circular heat dissipation fins are provided with air holes, so that heat dissipation is achieved, and circulation of hydrogen is not blocked.

The invention aims to provide a solid hydrogen storage hydrogen closed cycle hydrogen source generator for an underwater vehicle, which belongs to the field of dehydrogenation devices and comprises a reactor, a pressure stabilizing common rail pipe, a hydrogen storage material delivery pump, a solid hydrogen storage material storage unit, a solid hydrogen storage material spraying device, a product collecting device and a hydrogen storage unit. The hydrogen storage material conveying pump is connected with the pressure stabilizing common rail pipe, the solid hydrogen storage material storage unit and the solid hydrogen storage material spraying device, the hydrogen storage unit is connected with the pressure stabilizing common rail pipe, and the reactor is connected with the hydrogen storage unit. The solid hydrogen storage material is used for releasing hydrogen, one part of hydrogen is conveyed to the fuel cell to react for power output of the underwater vehicle, the other part of circulating hydrogen assists the hydrogen storage material in injection, and an underwater closed circulation mode suitable for the underwater vehicle is achieved. The solid hydrogen storage material conveying module and the circulating hydrogen supply module are matched, and rapid mixing of the solid hydrogen storage material and hydrogen and large-flow injection of the solid hydrogen storage material are achieved.

The invention belongs to the technical field of hydrogen energy, and particularly relates to a solid hydrogen storage system with two charging and discharging ends and a working method.The solid hydrogen storage system comprises at least two independent solid hydrogen storage units, and each solid hydrogen storage unit independently communicates with an upstream hydrogen supply pipeline through a first valve set and independently communicates with a downstream hydrogen using pipeline through a second valve set; each solid hydrogen storage unit is selectively communicated with the thermal circulation loop or the cold circulation loop through a third valve group; the first valve group, the second valve group and the third valve group are controlled, so that when the upstream hydrogen supply pipeline has a hydrogen supply demand and the downstream hydrogen use pipeline has a hydrogen use demand, the first solid hydrogen storage unit is configured to be in a hydrogen charging mode, and meanwhile, the second solid hydrogen storage unit is configured to be in a hydrogen discharging mode; the solid hydrogen storage unit in the hydrogen charging mode is communicated with the upstream hydrogen supply pipeline and the cold circulation loop for charging hydrogen, and the solid hydrogen storage unit in the hydrogen discharging mode is communicated with the downstream hydrogen supply pipeline and the hot circulation loop for discharging hydrogen.

The invention discloses a high-temperature solid hydrogen storage device capable of being quickly started at normal temperature. The high-temperature solid hydrogen storage device consists of a hydrogen storage unit, a heating system, a gas supply system, a shell and a temperature control device, the hydrogen storage unit is composed of a solid hydrogen storage material bed layer trigger area, a solid hydrogen storage material bed layer sweep area and a bed layer support; the heating system consists of a power supply channel and an electric heating element; the gas supply system consists of a gas inlet / outlet, a filter screen and a clearance space; the shell is composed of a hydrogen storage tank barrel, a hydrogen storage tank end cover, a sealing gasket and a threaded sleeve. The temperature control device exchanges heat through heat exchange fluid. The invention discloses a control method of a high-temperature solid hydrogen storage device based on normal-temperature quick start. The control method comprises the following steps: 1, preparation before hydrogen absorption; 2, starting a hydrogen absorption process; and 3, controlling the hydrogen absorption process.

The invention discloses a hydrogen charging system and method for a magnesium-based solid hydrogen storage reaction kettle. A hydrogen storage tank is placed in each placement position in an inner cavity of the reaction kettle, and a heat exchange coil pipe is arranged outside each placement position; the hydrogen charging system comprises a hydrogen charging part, a temperature control part and a safety protection part; the hydrogen filling part comprises a hydrogen filling main pipeline; a hydrogen flow controller and a hydrogen heat exchanger are arranged on the hydrogen filling main pipeline; the temperature control part comprises an external heat-conducting oil circulating system, the external heat-conducting oil circulating system comprises a heat-conducting oil tank, a flow bypass pipeline is arranged between the oil inlet pipeline and the oil return pipeline, and a heat-conducting oil shunting automatic switch valve is arranged on the flow bypass pipeline; the safety protection part comprises a safety valve arranged on the reaction kettle, the safety valve is externally connected with an emptying pipeline, a pressure relief bypass pipeline is arranged between the emptying pipeline and the hydrogen filling main pipeline, and an automatic opening and closing pressure relief valve is arranged on the pressure relief bypass pipeline. The system has the advantages that the hydrogen storage tanks in the reaction kettle can be quickly and efficiently filled with hydrogen, and the safety of the system is ensured.

The present application provides a solid-state hydrogen storage material and a preparation method and application thereof. Specifically, the preparation method comprises the following steps: (1) ball-milling a magnesium-based alloy powder, a light metal hydride, a nano-carbon material, a composite catalyst powder and an interface modifier to obtain a mixed powder; and (2) sintering the mixed powder under vacuum at 200-350 DEG C for 2-5 hours to obtain a sintered body, wherein: the magnesium-based alloy powder is a Mg-Mn-Al alloy powder; the light metal hydride is a mixture of LiAlH4 and NaBH4; the nano-carbon material is selected from one or more of graphene and carbon nanotubes; the composite catalyst powder is a mixture of TiO2, Fe3O4, CeO2 and La2O3; and the interface modifier is selected from one or more of a silane coupling agent and a titanate coupling agent. The solid-state hydrogen storage material has high hydrogen storage capacity, fast hydrogen absorption and desorption rate and good cycle stability.

The invention belongs to the technical field of hydrogen storage, and particularly relates to a vehicle-mounted hydrogen storage device and a hydrogen absorption and desorption method thereof. A vehicle-mounted hydrogen storage device comprises a hydrogen storage reactor arranged in a vehicle-mounted high-pressure container and filled with vanadium-based hydrogen storage alloy; the refrigerating system is used for providing a first fluid medium for the solid hydrogen storage reactor in a hydrogen absorption process so as to cool the hydrogen storage reactor to a preset hydrogen absorption temperature; the heating system is connected with a waste heat source of a vehicle-mounted engine and used for providing a second fluid medium for the hydrogen storage reactor in the hydrogen desorption process so as to heat the hydrogen storage reactor to the preset hydrogen desorption temperature; and the fluid conveying loop comprises a pipeline and a valve and is used for selectively communicating the refrigerating system or the heating system with the hydrogen storage reactor so as to convey the first fluid medium or the second fluid medium.

The invention relates to a solid hydrogen storage bottle with an internal heat exchange coupling heat pipe, which comprises a bottle body, a heat conduction part and a gas guide part, the heat conduction part is movably arranged in the bottle body, and a material storage cavity is formed in the bottle body; the air guide part keeps the material storage cavity communicated with the outside of the bottle body in the moving process; wherein the gas guide part synchronously moves along with the heat conduction part, and the heat conduction part keeps the hydrogen absorption material deviating from the gas guide part in the static process. The heat conduction part is movably arranged in the bottle body, so that when the heat conduction part moves, the hydrogen absorption material is thrown away from the gas guide part, the material cannot escape outwards, smooth flowing of hydrogen is kept, the number of the storage cavities is not limited by the structure, the multiple storage cavities can be arranged, the hydrogen absorption material is fully separated, and the hydrogen absorption effect is improved. And the whole structure keeps a good heat conduction effect on the hydrogen absorption material, and meanwhile, sufficient flow of hydrogen between the inside and the outside is ensured, so that the hydrogen absorption and hydrogen desorption efficiency is effectively ensured.

The invention belongs to the technical field of electricity-hydrogen coupling system control, and provides a voltage-air pressure stability control method and system for an electricity-hydrogen coupling system. The voltage-air pressure stability control method for the electricity-hydrogen coupling system comprises the steps that a battery energy storage system serves as an execution unit, and a voltage regulation model is constructed based on the dynamic relation between voltage and current; a solid hydrogen storage system is used as an object, and an air pressure adjusting model is constructed based on the relation between flow and pressure; constructing a hydrogen production / hydrogen consumption model based on hydrogen production / hydrogen consumption behaviors of the electrolytic cell and the fuel cell; on the basis of real-time sharing of state variables of an electricity-hydrogen coupling system, charging and discharging of a battery energy storage system in a millisecond period are adjusted according to a voltage adjusting model, so that rapid and stable control over the voltage of a direct-current bus is achieved. And regulating and controlling the hydrogen charging and discharging flow of the solid hydrogen storage system in a second-level time scale according to the air pressure regulation model to ensure the stable pressure of the buffer tank and continuous hydrogen supply, regulating the electrolysis and fuel cell power according to the hydrogen production / consumption model to ensure the balance of energy supply and demand, and finally realizing the voltage-air pressure stability coordinated regulation and control between the electric domain and the hydrogen domain.

The invention provides an extended-range solid hydrogen storage hydrogen fuel cell hydrogen thermal coupling power system, which comprises a proton exchange membrane hydrogen fuel cell power generation module used for converting hydrogen and oxygen into electric energy through electrochemical reaction; the alloy solid hydrogen storage and supply module is used for storing hydrogen in a low-pressure safe and high-density manner, releasing heat during hydrogen charging and exchanging heat with external cooling fluid; heat is absorbed during hydrogen desorption and exchanges heat with waste heat of the hydrogen fuel cell, so that hydrogen-heat coupling in the hydrogen supply process is realized; and the hydrogen thermal coupling thermal management module is used for transferring waste heat of the fuel cell to the solid hydrogen storage device so as to support the hydrogen desorption and heat absorption process of the solid hydrogen storage device. The technical problem of alloy solid hydrogen storage in hydrogen supply stability is solved, gas hydrogen can be stably and rapidly supplied to a fuel cell under the working conditions of vehicle starting, climbing or rapid power increasing and the like, power output stability of a system is maintained, and the strict requirement of the traffic power field for power performance is met.

The invention discloses a solid hydrogen storage and hydrogenation system and a control method. The technical problems that an existing solid hydrogen storage and hydrogenation device is complex in structure and low in hydrogen storage and hydrogen desorption efficiency are mainly solved. The solid hydrogen storage and hydrogenation system comprises a solid hydrogen storage unit which is arranged in a hydrogen storage skid and is correspondingly communicated with a hydrogen source through a parallel branch unit, a hydrogenation gun group which is correspondingly communicated with the solid hydrogen storage unit through the parallel branch unit, and a purging and diffusing unit which is connected to an argon source, comprising a vacuumizing unit of a vacuum pump, an expansion interface used for being connected with an external solid hydrogen storage unit, and a cold and hot water circulation unit arranged in the cold and hot water skid and used for correspondingly exchanging heat with the solid hydrogen storage unit. Therefore, by means of the system, ordered and efficient hydrogen charging and discharging operation of the solid hydrogen storage unit can be achieved, meanwhile, hydrogen charging and discharging testing of the external solid hydrogen storage unit can be achieved, and the system has the advantages of being high in utilization rate and working efficiency, good in safety, convenient and fast to operate and the like.

The invention relates to the technical field of hydrogen energy, in particular to a control system of a solid hydrogen storage device. The hydrogen amount monitoring module comprises a flow meter, accumulates the hydrogen amount in the hydrogen charging and / or hydrogen discharging process through the flow meter, and controls starting and stopping of the hydrogen charging and / or hydrogen discharging process; the pressure monitoring and regulating module comprises a pressure sensor and a pressure regulator, and the pressure regulator is used for regulating the pressure in the hydrogen charging and / or hydrogen discharging process according to the pressure monitored by the pressure sensor; and the heat management module is used for providing heat required by hydrogen desorption for the hydrogen storage container. The hydrogen charging and discharging processes of the solid hydrogen storage device are controlled through cooperation of the hydrogen amount monitoring module, the pressure monitoring and adjusting module and the heat management module, so that the hydrogen charging and discharging processes are more efficient and intelligent, and a hydrogen pipeline is timely closed to stop the hydrogen charging / discharging process from hydrogen leakage and hydrogen charging / discharging pressure through the safety monitoring module. And the safety of the solid hydrogen storage device is improved.

The utility model provides a solid hydrogen storage system, which comprises a hydrogen storage module, a waste heat recovery module and a waste heat export module, and the hydrogen storage module is respectively connected with a hydrogen source and a user side and is used for storing and releasing hydrogen; the waste heat recovery module is connected to the hydrogen storage module and can recover heat released in the hydrogen filling stage and store the heat through a heat storage working medium. The waste heat leading-out module is connected to the waste heat recovery module, heat stored by the waste heat recovery module is released and utilized, the waste heat leading-out module can be connected with the hydrogen storage module to serve as a heat source in the hydrogen desorption stage, and the waste heat leading-out module can also be connected with other systems with heat energy requirements. Waste heat in the hydrogen charging process is recycled, energy waste is avoided, efficient utilization of energy is achieved through system circulation, the conversion efficiency of a fuel cell can be fully exerted, good market applicability is achieved, the stored waste heat can serve as a heat source to be used for various ways, and the system is simple in overall structure, low in cost, high in practicability and suitable for popularization and application. The application range is wide.

A heat generating device includes: a sealed container; a tubular body provided in a hollow portion of the sealed container; a heat generating element provided on an outer surface of the tubular body and configured to generate heat by occluding and discharging hydrogen supplied to the hollow portion; and a flow path formed by an inner surface of the tubular body and through which configured to allow a fluid that exchanges heat with the heat generating element to flow. The heat generating element includes a base made of a hydrogen storage metal, and a multilayer film provided on the base. The multilayer film has a first layer made of a hydrogen storage metal and having a thickness of less than 1000 nm, and a second layer made of a hydrogen storage metal, which is different from that of the first layer, and having a thickness of less than 1000 nm.

The invention provides a low-pressure normal-temperature physical adsorption type hydrogen storage tank, and belongs to the technical field of hydrogen storage equipment, the low-pressure normal-temperature physical adsorption type hydrogen storage tank comprises a fractal flow channel supporting structure, a carbon nano tube block and a sealing tank body, the fractal flow channel supporting structure is arranged in the sealing tank body, and the fractal flow channel supporting structure comprises a main flow channel supporting body and a plurality of branch flow channel supporting bodies; a plurality of branch flow channel supporting bodies are communicated with the main flow channel supporting body, carbon nano tube blocks are arranged on the branch flow channel supporting bodies, the carbon nano tube blocks are in a cup shape, and a hydrogen conveying pipeline and a hydrogen discharging pipeline are arranged at the two ends of the sealed tank body respectively. A coupling system of a fractal flow channel supporting structure and a cup-shaped carbon nano tube module is constructed, hydrogen can be efficiently stored under the normal temperature and low pressure through the physical adsorption effect, the surface of a carbon nano tube can provide a larger surface area, the adsorption sites of the hydrogen can be increased, and the breakthrough improvement of the hydrogen storage performance under the working conditions of low pressure and normal temperature is achieved.

The invention discloses a hydrogen storage reactor based on synergistic heat management of a phase change material and a spiral heat exchange tube. The hydrogen storage reactor comprises an outer cylinder, a middle cylinder, an inner cylinder, a sealing cover and the spiral heat exchange tube. The outer cylinder, the middle cylinder and the inner cylinder divide the hydrogen storage reactor into three layers from inside to outside, and the inner layer and the outer layer are filled with phase change materials; the spiral heat exchange tube is arranged on the middle layer, and metal hydride is filled around the spiral heat exchange tube; in the hydrogen storage process, hydrogen flows into the middle layer of the reactor from an inlet in the center of the top end of the reactor and reacts with metal hydride; heat exchange fluid flows into the spiral heat exchange tube from a top inlet of the reactor, absorbs heat generated by reaction and flows out from a bottom outlet of the reactor; the phase change materials filled in the inner layer and the outer layer absorb heat generated by reaction and store the heat. The spiral heat exchange pipe is adopted for accelerating heat exchange, and the hydrogen storage and release rate is increased; the phase change material can store part of heat generated by the hydrogen storage reaction and release the heat during hydrogen release, the interlayer type arrangement can increase the heat exchange area, and the heat storage and release efficiency is improved.

The invention discloses a modular container type electric heat hydrogen co-production device, which belongs to the technical field of renewable energy sources and comprises a box body, and an electrical device, a hydrogen production device, a hydrogen storage device, a fuel cell, an explosion-proof wall, an isolation plate and a grating platform which are integrated in the box body, the interior of the box body is sequentially divided into a cabin A, a cabin B and a cabin C from one end to the other end in the length direction; the cabin A and the cabin B are separated through an explosion-proof wall, and the cabin B and the cabin C are separated through a separation plate; the grating platform is arranged in a cabin C, and the cabin C is divided into an upper space and a lower space; the electrical device is located in the cabin A, the hydrogen production device is located in the cabin B, the hydrogen storage device is located on the lower portion of the cabin C, and the fuel cell is located on the upper portion of the cabin C and arranged on the grating platform. According to the invention, an efficient and compact alkaline hydrogen production device is realized, a compact fuel cell system and a high-density solid hydrogen storage device are integrated, and a compact electric-thermal-hydrogen co-production system which can be flexibly deployed is formed.

The present invention relates to a hydrogen storage pellet that allows the production of compact, modular, safe and energy-efficient hydrogen storage. The pellet of the present invention comprises a peripheral ring (4) of an outer diameter of expanded natural graphite (ENG) of a predetermined height, surrounding a wafer of metal hydride (5) in the form of a compressed powder.

The utility model relates to the technical field of hydrogen storage, in particular to a hydrogen adjusting system based on solid hydrogen storage, which comprises a solid hydrogen storage tank, a high-temperature heating medium storage tank, a low-temperature heating medium storage tank, a first circulation pipeline, a first valve, a second circulation pipeline, a first adjusting valve, a third circulation pipeline and a second valve, the high-temperature heat medium storage tank communicates with a heat exchange cavity of the solid hydrogen storage tank through a first circulation pipeline, and the first valve is arranged on the first circulation pipeline. The low-temperature heat medium storage tank communicates with the heat exchange cavity of the solid hydrogen storage tank through a second circulation pipeline, and the first adjusting valve is arranged on the second circulation pipeline. The low-temperature heat medium storage tank communicates with the high-temperature heat medium storage tank through a third circulation pipeline, and the second valve is arranged on the third circulation pipeline. According to the efficient hydrogen storage system, supply and demand balance of hydrogen production and hydrogen use is achieved, through the dynamic hydrogen adjusting effect of the solid hydrogen storage system, the defects that green energy hydrogen production is unstable and discontinuous can be overcome, and the continuous and stable production working condition of the hydrogen use end is met.

The invention belongs to the technical field of hydrogen storage, and particularly relates to a solid hydrogen storage tank and an explosion suppression control method thereof. The solid hydrogen storage tank comprises a tank body, at least one monitoring module, at least one explosion suppression device and a control module, the tank body comprises a tank shell and an airflow speed limiter, an inner cavity is formed in the tank shell, and the airflow speed limiter is arranged in the tank shell. The monitoring module is arranged on the peripheral wall of the tank shell and used for collecting pressure and temperature in the inner cavity. And the at least one explosion suppression device is arranged on the peripheral wall of the tank shell and can spray an explosion suppression material towards the inner cavity. The control module is connected with the monitoring module and the explosion suppression device and controls the explosion suppression device according to monitoring information sent by the monitoring module. Wherein the airflow speed limiter is connected with a hydrogen output pipeline and is used for adjusting the flow of hydrogen entering the hydrogen output pipeline according to the pressure in the inner cavity. According to the solid-state hydrogen storage tank provided by the invention, the safety level of the solid-state hydrogen storage tank is greatly improved in a mode of combining active safety defense and passive safety adjustment.

The present invention relates to a gas hydrate stable storage device, system and method, comprising: an upper shell, which has a first cylinder and a top cover, the bottom of the first cylinder is open and is equipped with a switch valve; a piston, which reciprocates inside the first cylinder, a first pressure chamber is defined between one side of the piston and the first cylinder, and a second pressure chamber is defined between the other side of the piston and the first cylinder, the second pressure chamber receives pressurized liquid, a first channel and a second channel are provided inside the piston, and a spray head is provided at the bottom of the second channel; a lower shell, which has a second cylinder and a bottom plate located on the second cylinder, the top of the second cylinder is open and is detachably connected to the switch valve, pressurized liquid is injected into the second pressure chamber to drive the piston to move to an extended position, so that the gas hydrate in the first pressure chamber is compressed and formed under the pressure of the piston to obtain solid gas hydrate, and then the switch valve is opened to transfer the solid gas hydrate to the lower shell for low-pressure storage.

The invention discloses a vortex channel hydrogen storage reactor of a fluid streaming gradual change hydrogen storage tank unit, and belongs to the field of chemical reactor design. The whole reactor is a cylindrical shell, a heat exchange fluid inlet is formed in the center of the upper side of the shell, a hydrogen inlet is formed in a left end shell cover, and a heat exchange fluid outlet is formed in a right end shell cover; the heat exchange fluid channel is in a vortex shape, the multiple hydrogen storage tank units are sequentially arranged in the center of a flow channel of the vortex channel, and the diameter of the hydrogen storage tank is evenly reduced from the shell to the center position. Hydrogen enters the bed layer through a hydrogen pipe in the hydrogen storage tank and reacts with the metal hydride; meanwhile, the heat exchange fluid in the vortex channel flows around the hydrogen storage tank unit in the axial direction for heat exchange and then flows out through an outlet; the hydrogen storage tank has the advantages of excellent heat and mass transfer performance, uniform bed temperature of the hydrogen storage tank, small pressure-bearing stress of the tank body, synchronous reaction process of each hydrogen storage tank, high reliability and long service life, and is suitable for hydrogenation / dehydrogenation reaction of metal hydride with high hydrogen storage capacity requirement and larger reaction heat effect.

The invention discloses a graphene-containing carrier material, a negative pressure container containing the same and used for storing electronic gas, and a use method and a preparation method of the graphene-containing carrier material. The negative pressure container comprises a bottle body, a valve and a carrier material filled in the bottle body, and the carrier material comprises graphene. By utilizing the characteristics that the selected carrier material has a relatively high specific surface area and a relatively large pore volume, the whole negative pressure container is filled with the carrier material so as to load and unload electronic gases including arsine, phosphorane, boron trifluoride and the like, and excellent loading capacity and unloading capacity are shown; the product type of the negative pressure container capable of containing the electronic gas is expanded, and the benign development of the negative pressure container market is guaranteed.

The invention relates to a wingspan photovoltaic power generation fuel cell power supply system, which comprises a photovoltaic power generation unit, a DC / AC unit, a DC / DC unit, a fuel cell unit, a hydrogen production unit, a hydrogen storage unit and a heat exchanger, the photovoltaic power generation unit is respectively connected with the DC / AC unit and the DC / DC unit; the fuel cell unit is respectively connected with the DC / AC unit and the DC / DC unit; the hydrogen production unit is respectively connected with the hydrogen storage unit and the DC / DC unit; the hydrogen storage unit is respectively connected with the fuel cell unit and the heat exchanger; and the fuel cell unit is connected with the heat exchanger. Through the system, the space can be effectively saved, the cost is reduced, the operation is simplified, the energy utilization rate is improved, the heating of the fuel cell to the shell is reduced, the service life of the fuel cell is prolonged, and the stability and reliability of the whole system are improved.

The invention discloses an integrated solid hydrogen storage and supply device and a using method thereof, and relates to the technical field of solid hydrogen storage, the integrated solid hydrogen storage and supply device comprises a heat exchange box body, the heat exchange box body is provided with a cavity used for containing a cooling medium, and the cavity is internally provided with a heat exchange cavity; a water inlet and a water outlet which are communicated to the cavity are formed in the side wall of the heat exchange box body; the cavity has a length direction, a width direction and a height direction which are mutually vertical in pairs; the hydrogen storage pipes are fixedly arranged in the cavity, the hydrogen storage pipes are distributed in multiple rows in the width direction and the height direction of the cavity, and the hydrogen storage pipes in the adjacent rows in at least one direction are arranged in a staggered mode. The hydrogen storage pipes are arranged in a staggered mode, so that the advantages of small size and large flow of an integrated device are better exerted; hydrogen is collected in a limited space to achieve certain hydrogen absorption and desorption performance, and large-scale integration and large-flow hydrogen supply can be achieved.

This invention relates to a method for producing organometallic coordination polymers and materials obtained using the provided method. The organometallic coordination polymer synthesized according to this method has a gel structure, characterized by an effective diameter of 0.75-0.80 nm and a specific area of ​​1300-1700 m². 2 / g, micropore volume of 0.5-0.6cm³ 3 The method yields nanopores per g and improved thermal stability. The synthesis method allows for reduced material consumption during the process by using a single solvent in both the synthesis and activation stages, thus shortening the production time of the polymer gel, which is characterized by active mesopores and micropores. This makes it suitable as a matrix in various absorption processes, including natural gas storage systems.

To enable the amount of hydrogen absorbed in a hydrogen storage alloy to be specified. [Solution] A parameter acquisition unit acquires a variation parameter (step S101). In step S102, an identification unit identifies the remaining amount of hydrogen absorbed in the hydrogen storage alloy based on the variation parameter acquired by the parameter acquisition unit and relationship information stored in a storage unit (step S102). In step S103, the identification unit registers the remaining amount of hydrogen in the cartridge identified in step S102 in a management table (step S103).

The hydrogen storage system (1) comprises a casing (2), a plurality of storage-compression vessels (6) forming at least one multi-container unit (4), and a metal hydride (MH) configured for hydrogen storage contained within each of the storage-compression vessels. The storage-compression vessels of the at least one multi-container unit are interconnected in direct fluid communication by gas flow tubes such that gas pressures within the plurality of vessels are substantially identical. The storage-compression vessels are mounted within a chamber (16) of the casing, the casing being configured to maintain a vacuum within the chamber for leak testing the at least one multi-container unit.