The invention discloses a process for synthesizing high-purity
tetrabutylammonium fluoride trihydrate, which comprises the following steps: S1, dissolving tetrabutylammonium salt and
fluoride serving as raw materials, and performing
microwave radiation enhanced reaction; s2, after the reaction, cooling to induce the formation of an initial
crystal nucleus, and crystallizing in
microwave and electromagnetic fields; s3, adding the centrifuged crystals into water, adding an adsorbent, carrying out
nanofiltration after heating and dissolving, and carrying out cooling recrystallization and
centrifugation on the filtrate in
microwave and electromagnetic fields to obtain
tetrabutylammonium fluoride cage-shaped
hydrate; s4, mixing the cage-shaped
hydrate with a non-polar
solvent, and dehydrating in a microwave and
electromagnetic field; and S5, dehydrating, cooling, crystallizing, filtering in an
inert atmosphere, and desolventizing under reduced pressure to obtain the high-purity
tetrabutylammonium fluoride trihydrate. The method overcomes the technical bottlenecks of insufficient
conversion reaction of
tetrabutylammonium chloride, difficult control of
crystallization process, low product purity, long process period and the like in the traditional synthesis
route, and has the advantages of few three wastes, short process flow, stable performance, good
repeatability and the like.