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54 results about "Clathrate hydrate" patented technology

Clathrate hydrates, or gas clathrates, gas hydrates, clathrates, hydrates, etc., are crystalline water-based solids physically resembling ice, in which small non-polar molecules (typically gases) or polar molecules with large hydrophobic moieties are trapped inside "cages" of hydrogen bonded, frozen water molecules. In other words, clathrate hydrates are clathrate compounds in which the host molecule is water and the guest molecule is typically a gas or liquid. Without the support of the trapped molecules, the lattice structure of hydrate clathrates would collapse into conventional ice crystal structure or liquid water. Most low molecular weight gases, including O₂, H₂, N₂, CO₂, CH₄, H₂S, Ar, Kr, and Xe, as well as some higher hydrocarbons and freons, will form hydrates at suitable temperatures and pressures. Clathrate hydrates are not officially chemical compounds, as the sequestered molecules are never bonded to the lattice. The formation and decomposition of clathrate hydrates are first order phase transitions, not chemical reactions. Their detailed formation and decomposition mechanisms on a molecular level are still not well understood. Clathrate hydrates were first documented in 1810 by Sir Humphry Davy who found that water was a primary component of what was earlier thought to be solidified chlorine.

Method and system for preventing clathrate hydrate blockage formation in flow lines by enhancing water cut

The present invention includes a method for inhibiting hydrate formation blockage in a flow line used to transport hydrocarbon containing fluids. Water is added to a hydrocarbon containing fluid to produce a water cut enhanced hydrocarbon containing fluid. Salt may be added to the hydrocarbon containing fluids as well. Hydrate formation blockage is inhibited from forming within the flow line by the addition of the water and / or the salt. Sufficient water may be added such that the hydrocarbon containing fluid is converted from a water in oil emulsion to a water continuous emulsion. A system for preventing the formation of hydrate blockage in conduits is also provided. The system includes a flow line for transporting a hydrocarbon containing fluid and a water injection conduit fluidly connected to the flow line to add water to the flow line to increase the water cut of a hydrocarbon containing fluid flowing through the flow line. A salt dispenser may also be included which is used to increase the salinity of the hydrocarbon containing fluid. The system may further include a water separator to separate hydrocarbons from water which receives fluids from the flow line. The flow line, water separator and water injection conduit may cooperate to form a loop wherein water from the flow line may be separated by the water separator and a portion of the separated water is delivered back to the water injection conduit to be reinjected into the flow line.
Owner:CHEVROU USA INC

Clathrate hydrate modular storage, applications and utilization processes

Methods, apparatuses and systems directed to clathrate hydrate modular storage, applications and utilization processes. In one implementation, the present invention provides a method of creating scalable, easily deployable storage of natural gas and thermal energy by assembling an array of interconnecting, modular gas clathrate hydrate storage units.
Owner:SOLID GAS TECH

Method and apparatus for characterizing clathrate hydrate formation conditions employing microfluidic device

A test method and test apparatus is provided that employs a microfluidic device to characterize properties of a fluid. The microfluidic device has a first inlet port, an outlet port, and a microchannel as part of a fluid path between the first inlet port and the outlet port. While generating a flow of the fluid through the microchannel of the microfluidic device, fluid pressure at the first inlet port of the microfluidic device is measured and recorded in conjunction with varying the controlled temperature of the microchannel of the microfluidic device to characterize the properties of the fluid that flows through the microchannel of the microfluidic device. The properties of the fluid can relate to the clathrate hydrate formation condition of the fluid at the pressure of the flow through the microchannel of the microfluidic device.
Owner:SCHLUMBERGER TECH CORP

Method for gas storage, transport, and energy generation

The invention provides semi-clathrate hydrate compositions formed from water, a semi-clathrate hydrate forming compound and a gas. The semi-clathrate hydrate forming compounds can be ammonium salts, sulphonium salts, phosphonium salts or amines. The semi-clathrate hydrate compositions can be used to store gases including hydrogen, methane and carbon dioxide. Methods of manufacture of the compositions and their uses in energy storage and generation, and for the separation of gases are also described.
Owner:HERIOT WATT UNIV

TBAB (tetra-n-butyl-ammonium bromide) phase change cool-storing/cool-carrying air-conditioning system with independent temperature and humidity treatment

The invention relates to a TBAB(tetra-n-butyl-ammonium bromide) phase change cool-storing / cool-carrying air-conditioning system with independent temperature and humidity treatment, which comprises a refrigeration link, a CHS (clathrate hydrate slurry) making and cool-storing link, and a cool transferring and using link, wherein the refrigeration link comprises a water-cooling cold water unit; the CHS making and cool-storing link comprises a CHS making system and a CHS slurry storage slot; the cool transferring and using link comprises a cold emission top plate capillary tube and a fresh air dehumidifier surface cooling section at a user side; the water-cooling cold water unit is connected with the CHS making system, so that a loop is formed; the CHS making system is connected with the cold emission top plate capillary tube and the fresh air dehumidifier surface cooling section at the user side in parallel respectively; and the CHS slurry storage slot is connected with the CHS making system, and is connected with both the cold emission top plate capillary tube and the fresh air dehumidifier surface cooling section at the user side, so that another loop is formed. The air-conditioning system of the invention greatly improves the COP (coefficient of performance) of a refrigerator, reduces transferring energy consumption, has good utilization effect of the cool-carrying amount of secondary refrigerant, realizes a concept of independent temperature and humidity control, and has good energy-saving effect.
Owner:SHANGHAI JIAO TONG UNIV

Method and apparatus for producing clathrate hydrate slurry, and method for operating the same apparatus

A method of producing a clathrate hydrate slurry, includes a step of heat-exchanging an aqueous solution of a guest compound for the clathrate hydrate or a slurry of the clathrate hydrate dispersed or suspended in an aqueous solution or water with a refrigerant thereby generating the clathrate hydrate in the aqueous solution or the slurry, in which a part of the clathrate hydrate deposited on the heat transfer surface in the process of heat exchange with the refrigerant is removed by adjustment of a temperature of the refrigerant and flow force of the aqueous solution or the slurry and the rest is kept remained as it covers the heat transfer surface.
Owner:JFEENG CORP

Method for simulating TBPB half-cage type hydrate membrane separation mixed gas

The invention provides a method for simulating TBPB half-cage type hydrate membrane separation mixed gas. The method comprises the following steps of: establishing a TBPB half-cage type hydrate unit cell and a mixed gas model by adoption of computer simulation software, and superposing the TBPB half-cage type hydrate unit cell and the mixed gas model to obtain an initial structure of TBPB half-cage type hydrate membrane separation mixed gas; and setting simulation parameters, obtaining a stable structure through carrying out energy minimization and position restrictive pre-equilibrated simulation in sequence, carrying out molecular dynamic calculation to obtain molecular track coordinate information, and carrying out image analysis and calculation analysis on the molecular track coordinateinformation. According to the method, a process that gas molecules enter TBPB half-cage type hydrates is quantitatively observed in real time from a molecule angle, so that single components in mixedgas can be separated and enriched preferably.
Owner:SOUTH CHINA UNIV OF TECH

Clathrate Hydrate Modular Storage, Applications and Utilization Processes

Methods, apparatuses and systems directed to clathrate hydrate modular storage, applications and utilization processes. In one implementation, the present invention provides a method of creating scalable, easily deployable storage of natural gas and thermal energy by assembling an array of interconnecting, modular gas clathrate hydrate storage units.
Owner:CARSTENS CHRISTOPHER +3

Dual Function Gas Hydrate Inhibitors

The present invention involves inhibiting clathrate hydrate formation by adding ionic liquids that are soluble in water. Properly tailored ionic liquids shift the hydrate-aqueous liquid-vapor equilibrium curve to a lower temperature and, at the same time, retard the hydrate formation by slowing down the hydrate nucleation rate. This dual function makes this type of inhibitors perform more effectively. The present invention is useful for the production, processing, and transportation in oil and gas industry, especially for deep-sea exploration and production where the operating temperature and pressure become in favor of hydrate formation.
Owner:UNIVERSITY OF WYOMING

Process and apparatus for producing clathrate hydrate slurry and method of operating the production apparatus

A technique by which a clathrate hydrate slurry can be stably produced over long while maintaining a merit that a clathrate hydrate adherent to the heat exchange surface of a heat exchanger has the effect of accelerating the fresh formation of a clathrate hydrate. It is a process for producing a clathrate hydrate slurry which comprises a step in which either an aqueous solution of a guest compound for a clathrate hydrate or a slurry obtained by dispersing or suspending the clathrate hydrate in the aqueous solution or water is caused to flow in a heat exchanger tube to yield the clathrate hydrate in the aqueous solution or the slurry through heat exchange with a refrigerant surrounding the outer periphery of the heat exchanger tube. The process is characterized in that the amount of the clathrate hydrate adhering to the inner wall surface of the heat exchanger tube in the course of heat exchange with the refrigerant is inhibited from increasing by means of the force of flow of the aqueous solution or slurry running in the heat exchanger tube.
Owner:JFEENG CORP

Method and system for preventing clathrate hydrate blockage formation in flow lines by enhancing water cut

The present invention includes a method for inhibiting hydrate formation blockage in a flow line used to transport hydrocarbon containing fluids. Water is added to a hydrocarbon containing fluid to produce a water cut enhanced hydrocarbon containing fluid. Salt may be added to the hydrocarbon containing fluids as well. Hydrate formation blockage is inhibited from forming within the flow line by the addition of the water and / or the salt. Sufficient water may be added such that the hydrocarbon containing fluid is converted from a water in oil emulsion to a water continuous emulsion. A system for preventing the formation of hydrate blockage in conduits is also provided. The system includes a flow line for transporting a hydrocarbon containing fluid and a water injection conduit fluidly connected to the flow line to add water to the flow line to increase the water cut of a hydrocarbon containing fluid flowing through the flow line. A salt dispenser may also be included which is used to increase the salinity of the hydrocarbon containing fluid. The system may further include a water separator to separate hydrocarbons from water which receives fluids from the flow line. The flow line, water separator and water injection conduit may cooperate to form a loop wherein water from the flow line may be separated by the water separator and a portion of the separated water is delivered back to the water injection conduit to be reinjected into the flow line.
Owner:CHEVROU USA INC

Clathrate hydrate containing quaternary ammonium salt as guest compound

InactiveUS20100004487A1Increasing heat storing rate of heat storageLow costDomestic cooling apparatusOrganic compound preparationQuaternary ammonium cationPhosphate
An aqueous solution containing a quaternary ammonium salt as a guest compound of a clathrate hydrate, having a property of producing the clathrate hydrate when cooled, and further containing a phosphate of an alkali metal added thereto. A clathrate hydrate produced by cooling an aqueous solution containing a quaternary ammonium salt and a phosphate of an alkali metal, wherein the quaternary ammonium salt is the guest compound.
Owner:JFEENG CORP

Method of using nitrate hydrate to prepare bisphosphonate nitro compound

The invention discloses a method of using nitrate hydrate to prepare a bisphosphonate nitro compound. The method includes: in an organic solvent, taking nitrate hydrate as a nitro source, an oxygen-containing compound as an additive and 1, 6-diyne as a substrate for nitration-cyclization-oxidation tandem reaction, and performing aftertreatment after reaction is finished to obtain the bisphosphonate nitro compound. The compound is synthesized by direct nitration of 1, 6-diyne; the method is simple, and the nitrate hydrate is used as the nitro source, so that the compound is low in cost, easy toobtain, safe and stable. The method can be used for synthesizing a series of bisphosphonate nitro compounds, and nitric oxide release ability and drug activity of synthesized products can be furtherstudied.
Owner:ZHEJIANG UNIV

Stratigraphic modeling device and method for suspended state hydrates

The invention relates to a stratigraphic modeling device and method for suspended state hydrates. The stratigraphic modeling device is composed of a vacuum saturation device, a freezing device, a microwave heating device, an air compression water drainage device and a hydrate synthesis device in a combined mode. A stratigraphic sample is heated evenly, the relative height of a waveguide tube and the stratigraphic sample can be adjusted, and the entire stratigraphic sample can be placed in a relatively even electromagnetic field. Rock ore particles with the microwave absorption capacity far higher than that of ice are used as the stratigraphic modeling sample. The microwave heating power and the heating time are adjusted to control the saturability of natural gas hydrates. Surface treatment is conducted on the stratigraphic sample of porous media, so that the stratigraphic sample has hydrophobicity, the hydrates only exist in the gap of the stratigraphic sample, and the fact that the surfaces of the stratigraphic sample particles are wrapped with a hydrate layer is avoided. A multilayer stacking mode is used for acquiring the suspended state hydrate stratigraphic sample with large diameter and high thickness, and a simulated stratum is provided for simulating well drilling, well measuring and hydrate mining.
Owner:JILIN UNIV

Clathrate hydrate with latent heat storing capability, process for producing the same, and apparatus therefor, latent heat storing medium, and method of increasing amount of latent heat of clathrate hydrate and processing apparatus for increasing amount of latent heat of clathrate hydrate

An apparatus for production of a clathrate hydrate with enhanced latent heat storing capability includes a gas supplier for supplying a gas to an aqueous solution containing a quaternary ammonium compound, and a cooler for cooling the aqueous solution, the apparatus producing the clathrate hydrate with enhanced latent heat storing capability including both the quaternary ammonium compound and the gas as guests by supplying the gas to the aqueous solution with the gas supplier in the stage of cooling with the cooler.
Owner:JFEENG CORP

Method and System for Preventing Clathrate Hydrate Blockage Formation in Flow Lines by Enhancing Water Cut

The present invention includes a method for inhibiting hydrate formation blockage in a flow line used to transport hydrocarbon containing fluids. Water is added to a hydrocarbon containing fluid to produce a water cut enhanced hydrocarbon containing fluid. Salt may be added to the hydrocarbon containing fluids as well. Hydrate formation blockage is inhibited from forming within the flow line by the addition of the water and / or the salt. Sufficient water may be added such that the hydrocarbon containing fluid is converted from a water in oil emulsion to a water continuous emulsion. A system for preventing the formation of hydrate blockage in conduits is also provided. The system includes a flow line for transporting a hydrocarbon containing fluid and a water injection conduit fluidly connected to the flow line to add water to the flow line to increase the water cut of a hydrocarbon containing fluid flowing through the flow line. A salt dispenser may also be included which is used to increase the salinity of the hydrocarbon containing fluid. The system may further include a water separator to separate hydrocarbons from water which receives fluids from the flow line. The flow line, water separator and water injection conduit may cooperate to form a loop wherein water from the flow line may be separated by the water separator and a portion of the separated water is delivered back to the water injection conduit to be reinjected into the flow line.
Owner:CHEVROU USA INC

Ionic liquid type hydrate inhibitor

The invention relates to an ionic liquid type hydrate inhibitor. The inhibitor is a dilute solution or a mixture prepared by dissolving one ionic liquid, two ionic liquids or more than two ionic liquids in a solvent; the ionic liquid is added to a solvent The mass concentration is 0.005~0.05wt%; the ionic liquid is composed of organic cations and organic or inorganic anions in a molar ratio of 1:1 combined by ionic bonds; the solvents are water, brine, alcohols and their mixtures, because the inhibitor has a unique The unit structure can form steric hindrance and electric barrier steric hindrance to the formation of clathrate hydrate in the fluid, which can inhibit the nucleation, growth and agglomeration of hydrate, has high inhibitory activity, and can reduce the viscosity of the fluid. Improve the fluidity of the fluid. Compared with the commonly used thermodynamic inhibitors, the inhibition performance and inhibition time are improved, the dosing dosage is greatly reduced, the dosing conditions are mild, the recovery is convenient, the solvent loss is small, and it is environmentally friendly.
Owner:CHINA UNIV OF PETROLEUM (BEIJING)

Method used for preparing tetrabutylammonium fluoride trihydrate

The invention relates to a method used for preparing tetrabutylammonium fluoride trihydrate. According to the method, a tetrabutylammonium salt and potassium fluoride are dissolved in water; low temperature crystallization is carried out; pumping filtration is carried out so as to obtain tetrabutylammonium fluoride clathrate hydrate; and tetrabutylammonium fluoride trihydrate is obtained via vacuum drying. Reaction conditions of the method are mild; reaction processes are carried out in water; no organic solvent is used; the method is green and friendly to the environment; tetrabutylammonium fluoride trihydrate is obtained via crystallization separation of the tetrabutylammonium fluoride clathrate hydrate; steps are short; operation is simple and convenient; hydrofluoric acid is not used; no ion exchange column is used; no special requirement on equipment is proposed; cost is low; yield is high; and the method is suitable for industrialized production.
Owner:DONGGUAN DONGYANG SOLAR SCI RES & DEV CO LTD

Method for treating an aqueous solution containing dissolved materials by crystallization of clathrates hydrates

A method is disclosed for treating an aqueous solution containing dissolved materials that are crystallisable by crystallization of clathrates hydrates of a host molecule which crystallize at atmospheric pressure at temperatures higher than the temperature of ice crystallization. This method allows purified water and solid materials or solutions which are highly concentrated in dissolved materials to be produced simultaneously. The disclosure also relates to the implementation of this method.
Owner:BGH

Oxygen clathrate hydrate and oxygen solution containing the same

ActiveCN107207296AFlow mixersTransportation and packagingOxygen clathrate hydrateDissolution
The issue of the invention is to provide a novel substance containing dissolved oxygen that could not be measured using prior-art measurement methods, and an oxygen solution containing said substance. According to a solution, an oxygen clathrate hydrate containing dissolved oxygen is formed, the state of dissolution in solution being maintained even under heating to 100 DEG C.
Owner:MEDISCI ESPOIR CO LTD

Supported type semi-cage type aquo-complex phase change heat storage material and preparing method and application thereof

The invention belongs to the technical field of phase change heat storage materials and discloses a supported type semi-cage type aquo-complex phase change heat storage material and a preparing method and application thereof. The phase change heat storage material is prepared from, by mass, 100 parts of water, 10-110 parts of tetraisoamyl quaternary ammonium salt and 0.01-20 parts of supporting materials. The supported type semi-cage type aquo-complex phase change heat storage material has the advantages of being stable in room temperature, proper in phase change temperature, large in phase change latent heat and large in heat conducting coefficient, the size changes little in the phase change process, supercooling and separation phenomena are avoided, chemical performance is stable, and the material can be applied to the field of phase change heat storage.
Owner:SOUTH CHINA UNIV OF TECH

Semi-clathrate hydrate stable at room temperature and application thereof to carbon dioxide capture

The invention belongs to the technical field of environmental protection material, and discloses a semi-clathrate hydrate stable at room temperature and application thereof to carbon dioxide capture. The semi-clathrate hydrate is obtained by evenly mixing 100 parts by weight of water and 25-100 parts by weight of tetraisoamyl quaternary ammonium salt. The application is as below: placing the semi-clathrate hydrate in an autoclave, introducing high-pressure carbon dioxide gas at a certain temperature, and reacting to obtain a solid carbon dioxide hydrate with high gas storage density, so as to realize the capture of carbon dioxide. The invention adopts tetraisoamyl quaternary ammonium salt as a stabilizer and promoter to promote the formation of carbon dioxide hydrate, and has the advantages of low formation pressure, good stability at room temperature and high CO2 capture efficiency, and provides technical support for industrial application of carbon dioxide hydrate capture.
Owner:SOUTH CHINA UNIV OF TECH

Method and apparatus for controllable storage of hydrogen

A method and apparatus for controlling hydrogen gas storage in a clathrate hydrate structure through application of an electromagnetic field. The applied field can be used to control release of gas from the clathrate hydrate structure and / or uptake of gas into the clathrate hydrate structure. The electromagnetic field is arranged to promote “hopping” of gas molecules between and out of retaining pockets in the clathrate lattice by stimulating vibrations in the lattice that cause apertures into the retaining pockets to flex open. Advantageously, the electromagnetic field may have properties that are selected to promote an increase in the rate gas release or gas uptake without causing dissociation of the lattice. In this scenario, the invention can provide an energy-efficient, rechargeable on-demand supply system for any gas that can be retained within a clathrate hydrate structure.
Owner:UNIV COLLEGE DUBLIN NAT UNIV OF IRELAND DUBLIN

Method for inhibiting hydrate formation

A method for inhibiting the formation of clathrate hydrates in a fluid having hydrate-forming constituents involves treating the fluid with an inhibitor comprising a substantially water soluble polymer having a polymer backbone with a pendant C1-C3 alkyl group; the polymer having an average molecular weight between about 1,000 and about 6,000,000. Preferably, the pendant alkyl group is a methyl group. The rate of nucleation, growth, and / or agglomeration of gas hydrate crystals in a petroleum fluid stream is reduced using the alkylated polymer backbone inhibitor, thereby inhibiting the formation of a hydrate blockage in the pipe conveying the petroleum fluid stream. Test results are disclosed which unexpectedly show that alkylating the polymer backbone with a methyl group will produce a subcooling for the alkylated polymer that is at least about 2 DEG F. (about 1.1 DEG C.) greater than its nonalkylated counterpart. The inhibitor can be used conveniently at low concentrations, for example in the range of from about 0.01% to about 5% by weight of the water present in the oil or gas stream, to effectively treat a petroleum fluid having a water phase.
Owner:EXXON PROD RES CO

Method and system for extracting stranded gas from underwater environments, converting it to clathrates, and safely transporting it for consumption

The invention provides a method and system for extracting stranded gas (such as natural gas or hydrogen) or a mixture of oil and natural gas from a subterranean environment such as beneath the ocean floor and converting it into a solid hydrate such as a clathrate featuring a) extracting stranded gas (such as natural gas or hydrogen) or a mixture of oil and natural gas; b) optionally separating the natural gas from the mixture of oil and natural gas in a first tank or vessel; c) transporting the stranded gas to a second tank or vessel; d) introducing sea water into the second tank or vessel; e) mixing the stranded gas and water to form a clathrate hydrate / water slurry; f) removing excess water from the clathrate hydrate slurry to form a solid comprising a clathrate hydrate; and g) processing the solid comprising a clathrate hydrate into a transportable form; and h) optionally collecting the gas into a transportable vessel.
Owner:CENTURY FATHOM INC

Heat storage medium, cooling pack, logistics package, and cooling unit

It is an object to provide a heat storage medium capable of maintaining the latent heat capacity even if a supercooling inhibitor is added. A heat storage medium according to an aspect of the present invention is a heat storage medium which undergoes a phase change at a predetermined temperature and contains water, a main agent made of a quaternary ammonium salt forming a semi-clathrate hydrate, a pH adjustor maintaining alkalinity, and a nucleating agent generating cations exhibiting positive hydration. The heat storage medium separates into a first liquid layer containing the main agent and a second liquid layer containing the nucleating agent in an environment with a temperature exceeding the phase change temperature.
Owner:SHARP KK
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