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10 results about "Clathrate hydrate" patented technology

Clathrate hydrates, or gas clathrates, gas hydrates, clathrates, hydrates, etc., are crystalline water-based solids physically resembling ice, in which small non-polar molecules (typically gases) or polar molecules with large hydrophobic moieties are trapped inside "cages" of hydrogen bonded, frozen water molecules. In other words, clathrate hydrates are clathrate compounds in which the host molecule is water and the guest molecule is typically a gas or liquid. Without the support of the trapped molecules, the lattice structure of hydrate clathrates would collapse into conventional ice crystal structure or liquid water. Most low molecular weight gases, including O₂, H₂, N₂, CO₂, CH₄, H₂S, Ar, Kr, and Xe, as well as some higher hydrocarbons and freons, will form hydrates at suitable temperatures and pressures. Clathrate hydrates are not officially chemical compounds, as the sequestered molecules are never bonded to the lattice. The formation and decomposition of clathrate hydrates are first order phase transitions, not chemical reactions. Their detailed formation and decomposition mechanisms on a molecular level are still not well understood. Clathrate hydrates were first documented in 1810 by Sir Humphry Davy who found that water was a primary component of what was earlier thought to be solidified chlorine.

Apparatus and method for forming semi-cage hydrates

PendingCN121569002AHeat storage plantsHeat-exchange elementsEngineeringClathrate hydrate
An apparatus and method for forming semi-cage hydrates. An apparatus for forming a semi-cage hydrate (SCH) is provided. The apparatus may include a first tank, a heat exchanger in fluid connection with the first tank, a cooling unit connected to the heat exchanger, and a second tank for collecting and / or storing the formed SCH. Also provided is a method of forming a half-cage hydrate, the method comprising feeding a half-cage hydrate-based solution into a heat exchanger, cooling the heat exchanger to form the half-cage hydrate-based solution into an SCH.
Owner:NATIONAL UNIVERSITY OF SINGAPORE

System and method for the treatment of biogas and wastewater

The present disclosure relates to a system and method for treating wastewater, the method comprising the steps of: providing a vessel for receiving wastewater and a gas, wherein the gas comprises one or more constituent gas components; directing the wastewater and a first gas component of the gas to the vessel; reducing the temperature of the contents of the vessel from a first temperature to a second temperature to facilitate the formation of clathrate hydrates comprising the wastewater and the first gas component; increasing the temperature of the contents of the vessel with respect to the second temperature to facilitate melting of the clathrate hydrates; and removing clean water and / or the first gas component from the vessel.
Owner:UNIV COLLEGE DUBLIN NAT UNIV OF IRELAND DUBLIN

Clathrate heat storage material

Disclosed herein are phase change materials (PCMs) comprising clathrate hydrates and pH modulation agents. More specifically, claimed herein are PCMs comprising tetra- alkylammonium and tetra-alkylphosphonium salt hydrate clathrates and pH modulation agents which comprise common cations or anions to the salt hydrate clathrates. Also disclosed herein are methods of preparing the PCMs and thermal energy storage devices for use with the PCMs.
Owner:SUNAMP LIMITED

Heat pump system

ActiveJP2025116371ARefrigeration machinesSlurryClathrate hydrate
To provide technique for improving energy consumption efficiency in a heat pump system.SOLUTION: The heat pump system comprises: a generation portion where clathrate hydrate is generated; a decomposition portion where the clathrate hydrate is decomposed and the decomposition product is delivered; a first main flow path where heating medium flows from the generation portion to the decomposition portion; a second main flow path where the heating medium flows from the decomposition portion to the generation portion; a gas-liquid separation portion separating gas in the decomposition product delivered from the decomposition portion, from mixed solvent; and a heat exchange portion where slurry including the clathrate hydrate flowing out from the generation portion and the mixed solvent separated by the gas-liquid separation portion are flown and heat- exchanged.SELECTED DRAWING: Figure 1
Owner:KK TOYOTA CHUO KENKYUSHO

Clathrate hydrate generator and heat pump system

To provide a technology for improving energy consumption efficiency in a heat pump system.SOLUTION: A clathrate hydrate generator for generating a clathrate hydrate using water and gas comprises: a reaction vessel having an internal reaction surface on which a clathrate hydrate is generated; a water film forming part that forms a water film, which is a film of water, on the reaction surface; a sliding part disposed in the reaction vessel and moving while rubbing against the reaction surface; a gas supply path for supplying gas into the reaction vessel; a temperature adjustment part for adjusting a temperature of the reaction surface; and a through-hole having an opening on a portion of the reaction surface and penetrating the reaction vessel. The clathrate hydrate formed on the reaction surface is scraped off by the sliding part and discharged to the outside of the reaction vessel through the through-hole.SELECTED DRAWING: Figure 6
Owner:KK TOYOTA CHUO KENKYUSHO

A method for preparing hydrogen gas clathrate hydrate based on hydrogen bonding

PendingCN122326297AEngineeringHydrogen molecule
This invention introduces a method for preparing hydrogen-based combustible ice based on hydrogen bonding. Currently, the successful preparation of hydrogen-based combustible ice globally is difficult primarily because the core value of hydrogen bonds in water molecules is generally overlooked in the industry. To successfully produce this type of combustible ice, a deep understanding of the unique functions and powerful forces of hydrogen bonds is essential. This invention uses the characteristics of hydrogen bonds as its core research focus, relying on hydrogen bonds to construct a cage-like structure of water molecules, encapsulating hydrogen molecules, thereby synthesizing structurally stable hydrogen-based combustible ice. This invention corrects past misconceptions about the technology, opens up a completely new research direction, and possesses significant scientific research value and practical application potential.
Owner:仇胜利

Heat pump system

To provide a technique for improving energy consumption efficiency in a heat pump system.SOLUTION: A heat pump system includes: a generation part for generating an inclusion hydrate; a decomposition part where the inclusion hydrate is decomposed and a decomposition product is sent out; a first main passage in which a heat medium flows from the generation part to the decomposition part; a second main passage in which the heat medium flows from the decomposition part to the generation part; a mixed solvent separation part for separating a mixed solvent from the heat medium flowing in the first main passage; a liquid-liquid separation part in which an auxiliary agent in a water-soluble liquid in the mixed solvent separated by the mixed solvent separation part is separated by a reverse osmosis membrane or an ion exchange membrane; a gas-liquid separation part for separating the gas in the decomposition product sent out from the decomposition part from the mixed solvent; and a first sub passage for supplying, to the generation part, the mixed solvent in which the auxiliary agent separated by the liquid-liquid separation part is added.SELECTED DRAWING: Figure 1
Owner:KK TOYOTA CHUO KENKYUSHO

Process for synthesizing high-purity tetrabutylammonium fluoride trihydrate

PendingCN122036521AAmino compound purification/separationAmino compound preparation from photochemical reactionSolventClathrate hydrate
The invention discloses a process for synthesizing high-purity tetrabutylammonium fluoride trihydrate, which comprises the following steps: S1, dissolving tetrabutylammonium salt and fluoride serving as raw materials, and performing microwave radiation enhanced reaction; s2, after the reaction, cooling to induce the formation of an initial crystal nucleus, and crystallizing in microwave and electromagnetic fields; s3, adding the centrifuged crystals into water, adding an adsorbent, carrying out nanofiltration after heating and dissolving, and carrying out cooling recrystallization and centrifugation on the filtrate in microwave and electromagnetic fields to obtain tetrabutylammonium fluoride cage-shaped hydrate; s4, mixing the cage-shaped hydrate with a non-polar solvent, and dehydrating in a microwave and electromagnetic field; and S5, dehydrating, cooling, crystallizing, filtering in an inert atmosphere, and desolventizing under reduced pressure to obtain the high-purity tetrabutylammonium fluoride trihydrate. The method overcomes the technical bottlenecks of insufficient conversion reaction of tetrabutylammonium chloride, difficult control of crystallization process, low product purity, long process period and the like in the traditional synthesis route, and has the advantages of few three wastes, short process flow, stable performance, good repeatability and the like.
Owner:SHANGHAI WOKAI BIOTECH

Continuous production of clathrate hydrates from aqueous and hydrate-forming streams, methods and uses thereof

The present disclosure relates to a novel improved method for continuous crystallization of highly crystalline clathrate hydrates. The novel improved method utilizes a novel hydrator capable of overcoming heat and mass transfer limitations that usually constrain crystallization rate and thus reduces process productivity. The disclosed method and hydrator are for production of crystalline clathrates in general, CO2 capture, capture of other clathrate forming compounds, CO2 storage and transportation, storage and transportation of any clathrate forming compound in a solid lattice, gas separation or water desalination or purification purposes.
Owner:PETROGAL SA