2198 results about "Hydrogen storage" patented technology

The invention relates to the technical field of hydrogen energy aviation, and discloses a hydrogen energy aviation fuel storage-supply system and method based on solid hydrogen storage, and the hydrogen energy aviation fuel storage-supply system and method based on solid hydrogen storage are characterized in that the hydrogen release amount adjusting range of a hydrogen storage material is matched with the hydrogen fuel demand adjusting range of a power device by adjusting the hydrogen release catalytic reaction environment temperature of the solid hydrogen storage material; by adopting the pressure stabilizing device, the problem of flow and pressure fluctuation caused by hysteresis of hydrogen release adjustment is solved, and hydrogen release flow adjustment and engine throttling control can be carried out through the thrust rod.

The invention relates to the technical field of automobile energy supply, in particular to a solid hydrogen storage-fuel cell integrated power assembly system based on dual-mode hydrogen supply, which comprises a hydrogen supply path identification module, a hydrogen storage unit state monitoring module, a linkage path switching module, a fuel cell load matching module and a safe hydrogen discharge regulation and control module. According to the method, the hydrogen supply pressure difference value is obtained by dynamically comparing the pressure of the cavity of the hydrogen storage tank with the pressure of the hydrogen inlet of the fuel cell, the current hydrogen supply path state can be accurately recognized in the early stage, rapid judgment of the hydrogen supply mode and accurate control of path switching are achieved, whether the risk of hydrogen supply interruption exists or not can be effectively screened, and the reliability of hydrogen supply is improved. The switching reliability of a hydrogen supply channel is improved through cross comparison of key state signals of a main channel and a standby channel, and instant response and energy consumption optimization of hydrogen discharge safety regulation and control are guaranteed through a linkage feedback mechanism between the hydrogen concentration change rate in unit time and catalytic converter control power.

The invention discloses a high-capacity composite material hydrogen storage cylinder layering design method considering the strength of a transition section, and relates to the technical field of hydrogen storage cylinders. Establishing a finite element model of the hydrogen storage cylinder, inserting a cohesion unit with zero thickness between adjacent layers, and performing damage evolution on the cohesion unit to obtain a hydrogen storage cylinder simulation result considering the interlayer failure in the composite material layer; according to the fiber stress of the composite material layer and the damage state of the cohesion unit, determining a weak position under the current layering design, determining to-be-optimized parameters of the weak position, and formulating a layering optimization strategy; according to the method, sensitivity analysis of layering parameters is carried out on a transition section, so that a layering optimization strategy of the transition section is formulated; and according to the layering optimization strategy, parameters to be optimized in the layering design are gradually adjusted until no fiber damage exists in the whole composite material layer. According to the invention, the layering design of the high-capacity composite hydrogen storage cylinder considering the strength of the transition section is realized.

The invention belongs to the technical field of metal composite materials and hydrogen storage and transportation materials, and particularly relates to a high-strength hydrogen-embrittlement-resistant layered metal composite material for hydrogen storage and a preparation method and application of the high-strength hydrogen-embrittlement-resistant layered metal composite material. According to the preparation method, the nickel-saving austenitic stainless steel (NEASS) and the 30CrMo steel are alternately overlapped in a multi-layer mode, and the processes of vacuum electron beam welding, high-temperature hot rolling, accumulative ply rolling, multi-stage heat treatment and the like are combined, so that the composite board with the layer number reaching hundreds of layers, firm interface bonding, excellent mechanical performance and good hydrogen embrittlement resistance is prepared; the technical problem that strength, toughness and hydrogen brittleness resistance of an existing metal material in a high-pressure hydrogen environment are difficult to consider at the same time is solved. The obtained composite material has high strength, high plasticity and excellent hydrogen embrittlement resistance, and is suitable for structural materials of high-pressure hydrogen storage tanks, hydrogen conveying pipelines and other key hydrogen energy equipment.

The invention discloses a photovoltaic-electrolytic cell cooperative power control method and a medium, and the method comprises the steps: constructing a photovoltaic electrolytic hydrogen production system which comprises a photovoltaic module, a battery energy storage module, an electrolytic cell module and a hydrogen storage tank; calculating the planned operation number of electrolytic baths based on the photovoltaic electrolytic hydrogen production system; dividing electrolytic bath operation scenes based on the photovoltaic output, the photovoltaic electrolytic hydrogen production system and the planned operation number of the electrolytic bath, wherein the electrolytic bath operation scenes comprise an electrolytic bath full-load operation scene, an electrolytic bath and battery load mixed operation scene and a self-adaptive adjustment load operation scene; executing a corresponding power scheduling and operation control strategy on the photovoltaic electrolytic hydrogen production system based on the electrolytic cell operation scene and the planned operation number of the electrolytic cells; and based on the objective function under the constraint condition, carrying out optimization solution on the power scheduling and operation control strategy to obtain the reference power of the electrolytic cell. The method can adapt to different photovoltaic wide power fluctuations by dividing different electrolytic cell operation scenes.

The invention belongs to the field of power system operation and control, and particularly relates to an operation control method for a wind-light hydrogen storage multi-energy complementary system, which comprises the following steps: performing empirical mode decomposition on an original output sequence to obtain an IMF component, training parameters by combining a hidden Markov chain model and a forward-backward algorithm and solving an optimal state sequence, and fusing a predicted value by using Bayesian estimation to obtain an optimal state sequence; outputting a wind and light output and load demand global prediction value; by taking the minimum comprehensive operation cost, the minimum carbon emission intensity and the minimum power supply shortage rate as targets, obtaining equipment, power balance and hydrogen storage capacity constraints through a constraint verification algorithm, and constructing a multi-target optimization model; a scene trigger function identifies four types of typical scenes, a chaos particle swarm optimization algorithm is improved to solve a model, and density peak clustering is carried out to obtain a global scheduling scheme containing output of an electrolytic cell and a fuel cell and energy storage charge and discharge power. According to the invention, through scene adaptive optimization and intelligent clustering screening, the randomness and volatility of wind and light output are dealt with.

The invention provides an off-grid synthetic ammonia park electrolytic bath column level-energy storage-hydrogen storage collaborative optimization method based on rolling optimization, and relates to the technical field of energy storage and hydrogen storage collaboration. The method comprises the following steps: constructing an off-grid system architecture comprising wind-solar power generation, a plurality of rows of electrolytic cells, energy and hydrogen storage equipment and a synthesis ammonia device; a multi-device collaborative optimization strategy based on an eight-hour rolling time domain is designed, the system operation state is divided into high, medium and low working conditions through a working condition recognition mechanism, a current device operation scheme is actively adjusted according to wind and light power information of a next scheduling period, and collaborative regulation and control of energy storage and hydrogen storage are achieved. Compared with a traditional scheduling strategy, the collaborative optimization strategy provided by the invention improves the consumption rate of renewable energy sources of the system, reduces abandoned wind and light, improves the yield of synthetic ammonia, and verifies the effectiveness of the strategy.

The invention relates to the field of multi-energy collaborative scheduling of an electric power system, and particularly discloses a wind-light-fire-hydrogen coupling system electric quantity balance method considering an electric power price factor, which is realized based on an optimization model construction module, a scene generation module, a scene reduction module, a dynamic adjustment module and a solving module. Comprising the steps that S1, a wind-light-fire-hydrogen multi-energy coupling system joint optimization hydrogen storage model is constructed, and a dynamic electricity-hydrogen conversion and virtual bidding arbitrage mechanism is combined; s2, an initial scene set is generated through Latin hypercube sampling according to photovoltaic Beta distribution, wind power Weibull distribution and real-time electricity price logarithmic normal distribution; s3, performing staged mixed reduction to extract a typical scene set; s4, executing two strategies to adjust the bidding scale and the electricity purchasing and selling behavior; and S5, converting a KKT condition by using a nonlinear complementary function, and solving a Nash equilibrium solution to realize market clearing. According to the method, price fluctuation is effectively stabilized, the new energy consumption capability is improved, and an efficient and stable electric quantity balance solution is provided for a high-proportion new energy power system.

A system and method for hydrogen storage, and delivery. The system includes a hydrogen storage tank, a first pump disposed within the hydrogen storage tank, and a second pump disposed outside of the hydrogen storage tank. The hydrogen storage tank is to store gaseous hydrogen and liquid hydrogen. The first pump is to pump out liquid hydrogen out of the storage tank, producing a low pressure flow. The second pump is to receive this low pressure flow and produces a high pressure flow of liquid hydrogen. The system can also include a thermal device disposed within the hydrogen storage tank to heat gaseous hydrogen when a pressure within the hydrogen storage tank drops below a predetermined minimum pressure. The system can also include a heat exchanger to receive the high pressure flow of liquid hydrogen from the second pump.

The invention discloses a megawatt electric hydrogen energy hub peak regulation capability evaluation method and system, and the method comprises the steps: constructing an electric-hydrogen-heat multi-physics field coupling model, outputting a megawatt electric hydrogen energy hub dynamic digital twin body, carrying out the peak regulation demand feature extraction, outputting a peak regulation demand matrix with a timestamp, and carrying out the hydrogen energy storage dynamic feature analysis. And outputting a hydrogen energy storage peak regulation capability map, carrying out multi-objective optimization decision-making to obtain a peak regulation optimization scheduling scheme, implementing Monte Carlo reliability simulation, outputting a risk-efficiency balance scheme, and determining a megawatt electric hydrogen energy hub peak regulation capability evaluation result based on a toughness index. According to the method, the electric-hydrogen-thermal multi-physics field coupling model and the dynamic digital twins are constructed, and Monte Carlo reliability simulation and toughness index evaluation are combined, so that the peak regulation capability can be comprehensively and accurately evaluated, complex working conditions and extreme scenes are effectively considered, and the evaluation reliability and accuracy are improved.

The invention discloses a hydrogen refueling station compressor bypass current-limiting pressure-stabilizing pressurization system and method, and belongs to the technical field of hydrogen energy storage and filling. The technical problems that when an existing hydrogen refueling station switches hydrogen storage bottle sets of different pressure grades, due to the fact that the pressure of an outlet of a compressor suddenly changes instantly, equipment operation is unstable, the service life is shortened, the operation efficiency is low, and equipment abrasion is serious are solved. The bypass pipeline is arranged between the compressor outlet pipeline and the multi-stage hydrogen storage bottle group, so that a temporary flow limiting system is constructed; the intelligent controller adopts a PLC (Programmable Logic Controller), a DCS (Distributed Control System) or a special controller, is equipped with a human-computer interface, and accurately and automatically regulates and controls the opening and closing of valves on the main hydrogen supply pipeline and the bypass pipeline, so that the outlet pressure of the compressor is stably transited during switching, and the automatic control and operation convenience of the system are realized. Pressure fluctuation can be greatly inhibited, stable operation of the compressor is guaranteed, the service life of the compressor is prolonged, the equipment failure rate can be reduced, the overall operation efficiency of the hydrogen refueling station is improved, and stable development of the hydrogen energy industry is promoted.

The invention relates to the technical field of hydrogen energy solid hydrogen storage, and discloses a metal hydride hydrogen storage tank and a circulating hydrogen charging and discharging method.The metal hydride hydrogen storage tank comprises a tank body, the top end of the tank body is communicated with a gas inlet pipe, and the bottom end of the gas inlet pipe extends into the tank body and is rotationally provided with a connecting pipe through a rotating connector; a plurality of circular heat dissipation fins are fixedly connected between the inner walls of the tank body, the bottom end of the connecting pipe penetrates through the heat dissipation fins to be rotationally connected with the bottom end of the tank body, and a plurality of air holes are formed in the surface of each heat dissipation fin; four telescopic rods are fixedly connected to the top wall of the interior of the tank body, the hydrogen storage tank drives the transmission assembly to drive the connecting pipe and the stirring plate to rotate through movement of the piston, metal hydride is prevented from caking, hydrogen is dispersed more evenly through inclined air outlet holes, and the hydrogen storage efficiency is improved; the circular heat dissipation fins are provided with air holes, so that heat dissipation is achieved, and circulation of hydrogen is not blocked.

The invention discloses an emergency energy storage cabin with a multi-source power generation intelligent switching function and a power supply control method thereof, and relates to the field of emergency energy storage, and the energy storage cabin comprises a photovoltaic power generation device which is arranged at the top and can stretch and unfold a photovoltaic panel, a hydrogen energy storage power generation device connected with a bus, and an energy storage battery pack, in cooperation with the voltage and current sampling circuit and the illumination sensor, the controller controls switching among the power supplies according to acquired signals. The switching priority is photovoltaic power generation priority, the energy storage battery pack is subordinate, and the hydrogen energy storage power generation device is the last standby; the system is provided with a current limiting element, a pre-charging control unit and a graded load management function, and can cut off non-critical loads and supply critical loads in turns when a power supply is insufficient. The interior of the cabin can integrate water purification, hydrogen production, hydrogen storage and air conditioning modules. According to the method and the system, intelligent switching of multi-source energy, key load guarantee and continuous energy supply in an emergency environment are realized.

The invention relates to a self-repairing hydrogen barrier composite coating for a hydrogen storage or transportation device as well as a preparation method and application of the self-repairing hydrogen barrier composite coating, and belongs to the technical field of hydrogen energy storage and transportation materials. The coating is of a double-layer structure and is composed of a bottom coating and a humidity response microcapsule self-repairing barrier layer. The humidity response microcapsule is composed of a capsule core containing a polyurethane prepolymer and a hybrid capsule shell formed by polyurethane and siloxane, and has good hydrogen barrier performance and environmental response characteristics. In a certain humidity environment, the microcapsule is stimulated to release the capsule core material, and in-situ self-repairing is achieved. The problem that a traditional hydrogen-resistant coating is short of repairing capacity is solved, and the hydrogen-resistant coating has a wide application prospect in the aspect of improving the safety of a hydrogen conveying and storage system.

The invention discloses a green synthesis ammonia and organic liquid hydrogen storage combined device. The device comprises a water electrolysis hydrogen production device, a nitrogen production device, an organic liquid hydrogen storage device, a low-pressure gas compressor, a synthesis gas compressor and an ammonia synthesis device, the water electrolysis hydrogen production device produces hydrogen and conveys the hydrogen to the organic liquid hydrogen storage device and the synthesis gas compressor; the nitrogen making device is used for making nitrogen and conveying nitrogen to the organic liquid hydrogen storage device and the synthesis gas compressor; the organic liquid hydrogen storage device reacts hydrogen-poor organic liquid with hydrogen generated by the water electrolysis hydrogen production device to generate hydrogen-rich organic liquid, nitrogen is introduced into the hydrogen-rich organic liquid for dehydrogenation reaction, and the hydrogen and the nitrogen are input into the low-pressure gas compressor; the low-pressure gas compressor and the synthesis gas compressor compress hydrogen and nitrogen and input the compressed hydrogen and nitrogen into the ammonia synthesis device; and the ammonia synthesis device generates ammonia under the action of the catalyst. The gas-liquid mass transfer efficiency and the hydrogen desorption rate are improved, the energy consumption and the operation and maintenance cost of the compressor are reduced, and accurate adjustment of the hydrogen-nitrogen ratio is achieved.

The invention belongs to the technical field of hydrogen energy, and particularly relates to a solid hydrogen storage system with two charging and discharging ends and a working method.The solid hydrogen storage system comprises at least two independent solid hydrogen storage units, and each solid hydrogen storage unit independently communicates with an upstream hydrogen supply pipeline through a first valve set and independently communicates with a downstream hydrogen using pipeline through a second valve set; each solid hydrogen storage unit is selectively communicated with the thermal circulation loop or the cold circulation loop through a third valve group; the first valve group, the second valve group and the third valve group are controlled, so that when the upstream hydrogen supply pipeline has a hydrogen supply demand and the downstream hydrogen use pipeline has a hydrogen use demand, the first solid hydrogen storage unit is configured to be in a hydrogen charging mode, and meanwhile, the second solid hydrogen storage unit is configured to be in a hydrogen discharging mode; the solid hydrogen storage unit in the hydrogen charging mode is communicated with the upstream hydrogen supply pipeline and the cold circulation loop for charging hydrogen, and the solid hydrogen storage unit in the hydrogen discharging mode is communicated with the downstream hydrogen supply pipeline and the hot circulation loop for discharging hydrogen.

The invention discloses a preparation method of a high-capacity magnesium-based composite material based on MOF structure modification, and belongs to the technical field of hydrogen storage materials, the preparation method comprises the following steps: (1) preparing an M-MOF guest material; (2) modifying an aperture structure of the M-MOF guest material; and (3) preparing the MgH2 (at) S-M-MOF compound by a wet impregnation nano confinement method. Compared with a pure MgH2 hydrogen storage material, the MgH2 (at) S-M-MOF compound magnesium-based hydrogen storage material prepared by the nano confinement method has the advantages that the hydrogen absorption and desorption reaction temperature is obviously reduced, and the dynamics is greatly improved; compared with a traditional nano confinement hydrogen storage material preparation process, the preparation method has the advantages that the comprehensive hydrogen storage performance of a compound is enhanced by modifying a pore structure and introducing catalytic elements, the operability is high, the effective loading rate is high, the preparation period is short, and the yield is high; the required raw materials are cheap and easy to obtain, and the preparation process is low in cost, high in safety and suitable for industrial production and popularization.

The invention discloses a hydrogen storage cylinder safety detection device, and relates to the technical field of hydrogen storage, the hydrogen storage cylinder safety detection device comprises a detection box, the detection box is fixedly arranged, a gas cylinder body is arranged in the detection box, a sealing cover is hermetically assembled at an opening part of the detection box, a safety cylinder is fixed on one side of the detection box, and the detection box is hermetically communicated with the safety cylinder; at least two detection assemblies are slidably arranged on the periphery of the gas cylinder body, a driving assembly is arranged in the detection box, the driving assembly is provided with two output ends, a first transmission assembly is arranged at the first output end of the driving assembly and used for driving the two detection assemblies to move horizontally, and a second transmission assembly is arranged at the second output end of the driving assembly. A second transmission assembly is arranged at the second output end of the driving assembly and used for driving the two detection assemblies to move in the circumferential direction.

The present disclosure provides a hydrogen decrepitation apparatus and a hydrogen recycling method. The hydrogen decrepitation apparatus comprises a hydrogen decrepitation furnace, a solid hydrogen-storage device, a first hydrogen recovery pipeline, a second hydrogen recovery pipeline, a hydrogen reuse pipeline, a first discharge pipe, a second discharge pipe, an inert gas pipeline, and a bypass pipeline. The hydrogen decrepitation apparatus enables hydrogen used in hydrogen decrepitation to be reused, thereby reducing costs of hydrogen decrepitation and lowering energy waste.

The invention relates to the technical field of hydrogen energy preparation, in particular to hydrogen storage equipment for a hydrogen production and hydrogenation all-in-one machine, which comprises a machine body, a hydrogen production machine module and a hydrogen storage module, the hydrogen storage module is fixed in the machine body, and the hydrogen storage module is composed of a plurality of gas storage tanks; the hydrogenation module is arranged at the top of the hydrogen storage module, the hydrogenation module is a filling pump, and the inlet end of the hydrogenation module is connected with the hydrogen storage module; the dynamic design that a rotating frame carries a multi-fan-shaped filter screen body is adopted in a filtering air inlet assembly of the hydrogen production machine module, efficient anti-blocking and continuous air inlet in the catkin season are achieved in combination with a brush disc cleaning structure of a cleaning assembly, the rotating frame drives a vertical rod to rotate through a driving motor, the filter screen body is driven to do circular motion through bevel gear transmission, and the filter screen body does circular motion; and meanwhile, the transverse rotating rod drives the brush disc to brush and sweep the surface of the filter screen in real time, it is guaranteed that holes are smooth, the air pump assembly stably sucks sufficient air so that the whole filling and storing equipment can normally operate, water electrolysis hydrogen production can be continuously and efficiently conducted, and the supply amount of the hydrogen storage tank is guaranteed.

The invention relates to an energy management method and system for a green electricity hydrogen production and hydrogenation all-in-one machine, and relates to the technical field of hydrogen energy application, the system comprises an upper layer control system and a communication interface module, collaborative optimization scheduling is executed in the day-ahead stage, the rolling stage and the real-time stage; the communication interface module supports IEC104, private UDP and other industrial protocols, and realizes real-time data interaction with a green electricity prediction system and a hydrogen production DCS system. The method comprises the following steps: making an electrolytic cell start-stop and power plan in a day-ahead stage; periodically correcting prediction and demand errors in a rolling stage; the power of the electrolytic cell is dynamically adjusted to fluctuate along with green electricity in the real-time stage. According to the invention, cross-section and multi-time scale coordination control is realized, and the green power consumption rate, the system operation economy and the hydrogen energy supply reliability are improved.

The invention relates to the technical field of vehicle power systems, in particular to a solid hydrogen storage device containing a low-temperature cold-start hydrogen storage cylinder and a fuel cell collaborative power assembly, and the device comprises a heat flow modulation module, a balance driving module, a release coordination module, a power matching module and a power assembly control module. In the hydrogen storage process, through real-time linkage judgment of the interface temperature difference and the heat flux change, directional feedback of energy in different areas is achieved, the stable hydrogen release condition of the hydrogen storage material is maintained, differentiated distribution is conducted on heating power according to the heat flux density deviation, invalid energy consumption and local energy accumulation are avoided, and the energy storage efficiency is improved. Dynamic balance is constructed between the hydrogen release rate and the phase change medium energy absorption rate, the hydrogen supply process is corrected through filtering estimation, the release flow is more stable and controllable, finally, the hydrogen supply stability and the load requirement are combined in the power output link, dynamic matching of the galvanic pile power and the external working condition is achieved, and the energy efficiency is improved. And the response flexibility and the energy conversion efficiency of the power system are improved.

The present application provides a solid-state hydrogen storage material and a preparation method and application thereof. Specifically, the preparation method comprises the following steps: (1) ball-milling a magnesium-based alloy powder, a light metal hydride, a nano-carbon material, a composite catalyst powder and an interface modifier to obtain a mixed powder; and (2) sintering the mixed powder under vacuum at 200-350 DEG C for 2-5 hours to obtain a sintered body, wherein: the magnesium-based alloy powder is a Mg-Mn-Al alloy powder; the light metal hydride is a mixture of LiAlH4 and NaBH4; the nano-carbon material is selected from one or more of graphene and carbon nanotubes; the composite catalyst powder is a mixture of TiO2, Fe3O4, CeO2 and La2O3; and the interface modifier is selected from one or more of a silane coupling agent and a titanate coupling agent. The solid-state hydrogen storage material has high hydrogen storage capacity, fast hydrogen absorption and desorption rate and good cycle stability.

The invention discloses a safety monitoring system and monitoring method for a hydrogen storage device, and relates to the technical field of hydrogen storage, and the system comprises an energy supply module which supplies power to a data collection device through an intelligent power management system; the data acquisition module is used for collecting real-time operation data from a sensor of the hydrogen storage device; the intelligent analysis module is used for performing real-time analysis on the collected data based on a machine learning algorithm, establishing a safety risk assessment model and obtaining a risk development trend; the early warning control module is used for judging whether abnormity occurs or not based on the risk development trend; and the remote monitoring module communicates with the subsystems through a network and provides remote data monitoring. According to the method, key data of the hydrogen storage device are collected in real time, intelligent analysis is conducted through machine learning, environment changes are monitored in real time, safety risks are recognized in advance, leakage and pressure anomalies are recognized through deep learning and an anomaly detection algorithm, the risk development trend is predicted, and safe operation of equipment is guaranteed.

The utility model relates to a liquid hydrogen storage system which comprises an integrated hydrogen storage device and a hydrogen storage medium, the integrated hydrogen storage device comprises a liquid storage tank for storing a hydrogen storage medium, a gas storage tank for storing hydrogen, a reactor connected with the output ends of the liquid storage tank and the gas storage tank, a condenser connected with the reactor, a gas-liquid separator connected with the output end of the condenser, a gas compressor and a gas buffer tank, and one or more unsaturated aromatic hydrocarbons or heterocyclic unsaturated compounds with a saturated vapor pressure of more than 1 kPa and a temperature of 20 DEG C. The gas-phase storage medium of the liquid hydrogen storage system sequentially passes through the condenser, the gas-liquid separator, the gas compressor and the gas buffer tank, so that a hydrogen pressurizing, cooling and refluxing process is realized, a liquid hydrogen storage material can be effectively recycled, and the purity of hydrogen can be ensured.

The invention relates to the technical field of renewable energy consumption, in particular to a vehicle-hydrogen-steel collaborative green hydrogen fluctuation stabilizing method and system, a physical layer is provided with a wind-solar power generation device, an electrolytic hydrogen production device, a hydrogen storage buffer tank, a steel heat supply device, an electric vehicle and a V2G charging pile which are connected with one another through a hydrogen conveying pipeline and a power cable; the information layer takes the central regulation and control platform as a core, collects wind-solar power, hydrogen yield, steel hydrogen consumption and electric vehicle SOC by using sensors, and transmits the collected power, hydrogen yield, steel hydrogen consumption and electric vehicle SOC to the central regulation and control platform; the central regulation and control platform executes a hierarchical dynamic fluctuation regulation and control mechanism; when the fluctuation range of the hydrogen yield does not exceed a set value, the hydrogen is stabilized by controlling the hydrogen storage buffer tank to charge and discharge hydrogen; and when the fluctuation amplitude exceeds a set value, a V2G system is started, and stabilizing is carried out by controlling charging and discharging of the electric vehicle. On the premise that the special energy storage cost is not greatly increased, stable and low-cost supply of green hydrogen is achieved, and energy conservation and emission reduction of steel and other high-energy-consumption industries are achieved.

The invention discloses a collaborative operation method, system, equipment and medium for an electricity-hydrogen storage integrated system, and relates to the technical field of electricity-hydrogen storage, comprising the steps of generating total output power based on environmental parameters by integrating photovoltaic power generation and wind power generation, performing electric energy conversion treatment on the total output power, and supplying the converted electric energy to a water electrolysis hydrogen production process. Hydrogen is generated by electrolyzing water, the hydrogen production rate is monitored in real time, the generated hydrogen is stored, the hydrogen storage pressure is adjusted according to a dynamic pressure model, the stored hydrogen is supplied to the fuel cell power generation process, electric energy is generated according to the load requirement, and through the cooperative control process and based on a multi-stage optimization control framework, the power generation efficiency of the fuel cell is improved. And power generation, conversion, hydrogen production, storage and power generation processes are cooperatively controlled in real time. According to the method, the problems of renewable energy fluctuation absorption and efficient conversion are solved, the breakthrough improvement of millisecond-level real-time response is realized, and the safety and economy of long-term operation of the system are guaranteed.

The invention discloses a distributed plasma and electrocatalytic synthesis ammonia device which comprises a plasma nitrogen fixation unit, an electrocatalytic synthesis ammonia unit and a power supply module, and the plasma nitrogen fixation unit comprises an air pump, a plasma discharge reactor, a plasma power supply and an aeration head. The electro-catalytic ammonia synthesis unit comprises a cathode side liquid storage tank, a cathode side liquid pump, an ammonia production electrolytic bath, an anode side liquid pump, a direct-current power supply and an anode side liquid storage tank, and the power supply module is a clean energy module. The aeration head is immersed in the cathode side liquid storage tank, and electrolyte is stored in the cathode side liquid storage tank and the anode side liquid storage tank; the device takes air and water as raw materials and carries out a synthesis ammonia process at normal temperature and normal pressure. The method has the beneficial effects that the method adapts to clean energy, can realize on-site absorption and adapts to the volatility of the clean energy; raw materials are cheap and easy to obtain, hydrogen storage and transportation risks and extra cost pollution are avoided, and zero carbon is generated in the whole process; the device is small in scale and modularized, does not depend on large-scale facilities, and assists ammonia and chemical fertilizer production in regions deficient in resources.

The preparation method of the Ni-Mn bimetallic oxide modified magnesium-based hydrogen storage composite material comprises the steps that 1, under the protection of an argon atmosphere, pure magnesium powder is placed in a reaction kettle, and a product MgH2 is obtained; step 2, dissolving nickel nitrate hydrate and manganous nitrate hydrate in absolute ethyl alcohol, adding urea into the mixed solution, continuously stirring at room temperature, and then carrying out constant-temperature reaction in a tetrafluoropolyvinyl chloride high-pressure reaction kettle in a drying oven; after the reaction is finished, cooling to room temperature, and carrying out centrifugal washing; supernate obtained after centrifugal washing is poured out, precipitates are reserved and transferred into a vacuum drying box, and vacuum drying is conducted; grinding a block obtained after drying, and transferring the block into a tubular furnace for heat treatment to obtain a bimetallic oxide NiMn2O4; 3, MgH2, NiMn2O4 and stainless steel ball milling beads are weighed and put into a mechanochemical reaction ball milling kettle, intermittent ball milling is conducted for a certain time under the protection of a specific atmosphere, and then a composite sample MgH2-NiMn2O4 is collected. The practical application benefit of the magnesium-based hydrogen storage technology can be greatly improved.

The invention discloses a multi-type resource participation power grid frequency modulation method based on a consistency algorithm, and the method comprises the steps: firstly constructing an improved frequency response model fusing distributed optical storage equipment, hydrogen storage and energy storage equipment and a DC flexible load, identifying system parameters, solving a multi-resource comprehensive adjustment coefficient, constructing a directed graph model, employing a grouping consistency algorithm, and obtaining a multi-type resource participation power grid frequency modulation model; the optimal adjustment coefficient of each resource is solved through distributed optimization of an augmented Lagrange function and a consistency index, and primary frequency modulation of a multi-type resource collaborative response system is driven. According to the multi-type resource participation power grid frequency modulation method based on the consistency algorithm, by driving a multi-type resource collaborative response system to perform primary frequency modulation, collaborative regulation and control of light storage, hydrogen storage and flexible load are realized, economy and operation constraints are considered through distributed optimization, and communication complexity is reduced through a clustering iteration mechanism; and the frequency stability of the high-proportion new energy power grid is obviously improved.