The invention relates to a coke oven gas hydrogen generation process. The process comprises the following steps of: firstly, treating coke oven gas in a pre-purification process step and a refined naphthalene process step, and then feeding the coke oven gas into a PSA-1 system mainly comprising 12 adsorption towers for removing most of carbon dioxide in an adsorption manner; then delivering the coke oven gas into a PSA-2 system mainly comprising 10 adsorption towers for remove most of methane gas in an adsorption manner, then increasing the pressure of the obtained hydrogen-rich gas to 2.6MPa, and deoxidizing and cooling in a deoxidation system by using the compression heat of the gas; and finally, and finally carrying out hydrogen purification in a system to obtain product hydrogen. According to the coke oven gas hydrogen generation process, the coke oven gas is subjected to mature processes including PSA hydrogen extraction, methane steam conversion, transformation and the like which are scientifically combined together, 40110Nm<3>/h of hydrogen of which the purity is 99.9% can be generated from 50000Nm<3>/h of the coke oven gas, the yield rate is high, 22508Nm<3>/h of a mixed desorption gas of which the caloric value is 4276-4636kcal/Nm<3> is generated secondarily and returned to a coking unit, and the demand on coke fuel is met. According to the coke oven gas hydrogen generation process, the hydrogen output is doubled, the waste gas discharge is reduced, and the process adjustment is flexible.