Method of producing fuel oil by coal tar hydrogenation modifying

A hydrogenation reforming and coal tar technology, which is applied in the fields of hydrogenation treatment process, petroleum industry, gasoline stabilization, etc., can solve the problems of unguaranteed long-term operation, unresolved strong exothermic effect, high asphaltenes and benzene insolubles, and achieves The effect of improving product quality, reducing olefin and aromatic content, and reducing total temperature rise

A hydrogenation reforming and coal tar technology, which is applied in the fields of hydrogenation treatment process, petroleum industry, gasoline stabilization, etc., can solve the problems of unguaranteed long-term operation, unresolved strong exothermic effect, high asphaltenes and benzene insolubles, and achieves The effect of improving product quality, reducing olefin and aromatic content, and reducing total temperature rise

CN1903994AActive Publication Date: 2007-01-31HUNAN CHANGLING PETROCHEM SCI & TECH DEV CO LTD
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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021]The raw material oil is a mixture of catalytic diesel oil and medium and low temperature full-distilled coal tar I in a weight ratio of 1:10. The properties are shown in Table 1. The first hydrogenation reactor is filled with HG-1 hydrogenation protection agent from top to bottom, the self-made pre-hydrogenation catalyst, and the second hydrogenation reactor is filled with the self-made main hydrogenation catalyst, the filling volume of the three catalysts The ratio is 2:3:10, and the hydrogenation reaction conditions and test results are shown in Table 2 and Table 3. The products were cut into light oil fraction (≤205°C), diesel fraction (205°C to 325°C), and heavy oil fraction (>325°C). The composition of gasoline, diesel, and heavy oil after cutting is shown in Table 4.

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Embodiment 2

[0027] The raw material oil is a mixture of hydrogenated diesel oil and medium and low temperature full-cut coal tar II in a weight ratio of 1:1 and 10:1 respectively. The properties are shown in Table 5. The first hydrogenation reactor is filled with HG-1 hydrogenation protection agent from top to bottom, the self-made pre-hydrogenation catalyst, and the second hydrogenation reactor is filled with the self-made main hydrogenation catalyst, the filling volume of the three catalysts The ratio is 3:3:10, and the hydrogenation reaction conditions and test results are shown in Table 6 and Table 7. The products were cut into gasoline fraction (≤205°C), diesel fraction (205°C~325°C), and heavy oil fraction (>325°C). The composition and properties of gasoline, diesel, and heavy oil after cutting are shown in Table 8, Table 9, and Table 10. And table 11.

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Embodiment 3

[0036] The feedstock oil is a mixture of hydrogenated diesel oil and high-temperature full-distillate coal tar III in a weight ratio of 1:1. The first hydrogenation reactor is filled with HG-1 hydrogenation protection agent from top to bottom, the self-made pre-hydrogenation catalyst, and the second hydrogenation reactor is filled with the self-made main hydrogenation catalyst, the filling volume of the three catalysts The ratio is 3:3:10, and the hydrogenation reaction conditions and test results are shown in Table 12 and Table 13.

[0037] Test number

[0038] Item

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Abstract

The present invention relates to a method for producing fuel oil by utilizing coal tar. It is characterized by that said method includes the following steps: after the whole coal tar in which the moisture and ash are removed and diluting oil are mixed according to a certain mixing ratio, making the obtained mixture be successively passed through a shallow hydrogenation unit with hydrogenation protecting agent and prehydrogenation catalyst and a deep hydrogenation unit with main hydrogenation catalyst, then making the product obtained after deep hydrogenation undergo the processes of high-pressure separation, low-pressure separation and fractionation so as to obtain light-oil fraction, medium-oil fraction and tail-oil fraction, namely obtain low-sulfur low-nitrogen fuel oil and light oil product.

Description

1. Technical Field: [0001] The invention belongs to the field of fuel chemical industry, and specifically relates to a method for producing fuel oil by hydrogenation and upgrading of coal tar. 2. Background technology: [0002] Coal tar is a by-product of coking, coal chemical and coal gasification industries. In recent years, my country's mechanical coke output has grown rapidly, and the total output in 2003 has reached 138.79 million tons (National Bureau of Statistics Express, coke output is only the output of enterprises above designated size). If the coal tar production rate is calculated on the basis of 3% to 4% of coking coal into the furnace, the annual output of coal tar will reach 5.6-7 million tons. In the next few years, China's local coke production will be completely cancelled. Based on the analysis of the world's coke trade, my country's mechanical coke production will increase year by year. The steady growth of mechanical coke will produce a large amount of coal t...

Claims

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Application Information

Patent Timeline
31 Jan 2007
Publication
CN1903994A
IPC
C10G65/04; C10G7/02
Inventors
李庆华; 郭朝辉