The invention belongs to the technical field of photoelectric devices, and discloses an organic-inorganic planar heterojunction solar cell prepared through solutions and a preparing method of the solutions. The solar cell comprises a substrate, an anode, an anode interface layer, a photoactivity layer, a cathode interface layer and a cathode which are all sequentially stacked, wherein the material of the photoactivity layer is an inorganic material which is soluble in a solvent and is of a perovskite structure, and performance of the material can be improved by adding polymer additives. The invention provides a planar heterojunction solar cell device with the photoactivity layer made of the perovskite organic-inorganic hybrid material capable of being prepared through the solutions, and according to the planar heterojunction solar cell device, the anode interface layer and the cathode interface layer are prepared through organic material solutions. According to the method, the problem that energy consumption is high in the cell device machining process is effectively solved, large-scale production is achieved, and high efficiency is achieved; the defects that in the prior art, the inorganic material needs to be machined at high temperature and the cost of the materials in the organic solar cell is high are overcome. The novel material and the new method can be applied to solar cells.