The invention belongs to the technical field of
energy materials, and particularly relates to a non-stoichiometric
bismuth telluride-based thermoelectric material and a preparation method thereof. Thematerial disclosed by the invention has a
chemical composition shown as the following general formula: BixSb2xTe3+y, and the preparation method comprises the following steps: firstly, weighing Bi simple substance
powder, Sb simple substance particles and Te simple substance
powder raw materials according to the
chemical composition of the general formula, carrying out ball milling treatment to obtain
powder, and carrying out cyclic
discharge plasma sintering treatment on the obtained powder for 1-5 times to obtain a block sample. The
bismuth telluride-based thermoelectric material prepared bythe method is good in
crystallinity and compact in structure, and compared with a sample prepared by a traditional mechanical alloying and
sintering combined method, the
bismuth telluride-based thermoelectric material is obviously increased in grain size and introduces a large number of dislocations, so that the electrical property is improved, the
lattice thermal conductivity is reduced, and thethermoelectric property is excellent. Meanwhile, the preparation method is simple and convenient to operate, short in period, free of high-temperature risk and low in
energy consumption, and has a wide application prospect.