The invention discloses a PbSe
quantum dot medium-
long wave infrared photoelectric
detector based on in-band transition, and a manufacturing method thereof. PbSe nanometer
colloid shows a good
exciton structure, and energy
exciton tuning ranges from 0.5 eV to 1 eV, which is a size function. When band-edge
fluorescence is observed from 1.2 m to 24 m, the
Stokes shift is small, and the sub-ns service life is close to the unified
quantum yield. During 1.064 nm pumping, first
exciton attenuation is consistent with
radiation relaxation under low pumping intensity and
Auger recombination under high pumping intensity. Optically induced absorption is observed at approximately the middle gap.
Lead selenide (PbSe)
quantum dots have the characteristics of wide
infrared spectrum regulation and control range, high
fluorescence quantum yield, solution processability and the like, and
coating of a shell layer is one of strategies for effectively improving optical characteristics and
chemical stability of the PbSe quantum dots and is a research direction for promoting application and development of the PbSe quantum dots. The PbSe core-shell quantum dots designed by the invention have very high application value in the fields of photoelectric detection, solar cells, lasers,
photocatalysis and the like.