The invention relates to the technical field of nano composite materials, and discloses a flexible
polymer composite thermoelectric material with a multilevel structure and a preparation method thereof, the material is a flexible self-supporting film, and comprises an MOF matrix, a single-walled
carbon nanotube and a
conductive polymer coating layer; the material has a hierarchical pore structure of micropores, mesopores and macropores. A mesoporous / macroporous structure is regulated and controlled through a PS
microsphere template, a micropore-mesoporous-macroporous hierarchical pore structure is constructed in combination with Cu3 (BTC) 2 intrinsic micropores, the pore size, the pore size distribution and the
porosity are systematically regulated, the
scattering effect on phonons with different wavelengths is enhanced, and accurate regulation and control of the
thermal conductivity of the material are realized. According to the design, the limitation that the
thermal conductivity of an existing MOFs thermoelectric material depends on an inherent structure is broken through, the problem that the
thermal conductivity lacks an active regulation and control mechanism is solved, a basis is provided for subsequent optimization of the
conductivity and the
Seebeck coefficient, and implementation of a high
power factor and a ZT value is facilitated.