A method of manufacturing a thermoelectric conversion material expressed by a chemical formula X3T3Z4 (X comprises one or more elements selected from Zr, Hf, Y, La, Nb, and Ta, while including at least Zr or Hf; T comprises one or more elements selected from Ni, Co, Cu, Rh, Pd, Ir, and Pt, while including at least Ni; Z comprises one or more elements selected from Sb, Ge, and Sn, while including at least Sb), the method comprising: preparing materials containing elements, which are the X including selected elements, the T including selected elements, and the Z including selected elements; forming an alloy A by melting the materials containing the all selected elements except for Sb; and forming an alloy B by melting the alloy A and the material containing Sb.