48 results about "Organic electronics" patented technology

The invention discloses a method for synthesizing an n-type conductive conjugated polymer and screening a catalyst, and belongs to the technical field of synthesis of conductive polymer materials. Redox potentials of various metal compounds are studied, the screening method of the catalyst in synthesis of the n-type conductive conjugated polymer is provided, and the n-type conductive conjugated polymer such as poly (benzodifuran diketone) (PBFDO) is efficiently synthesized by introducing a trace and cheap metal compound as the catalyst. The method has the advantages that the problem that a large amount of catalyst is left in a conventional synthesis method is solved, the operation is simple, the conductivity of the synthesized PBFDO exceeds # imgabs0 #, the problem that most n-type organic conductive polymers are low in conductivity is solved, high-performance conductivity matched with p-type organic conductive polymers can be realized, and the method can be widely applied to various organic functional materials and organic electronic devices.

The invention belongs to the technical field of organic functional materials and organic electronics, and particularly relates to a modified stretchable electrode and a preparation method and application thereof. Silver nanowire dispersion liquid is spin-coated on a substrate, an obtained silver nanowire film is patterned, the obtained patterned silver nanowire film is soaked in a modifier (a small molecule compound containing a group capable of being combined with silver and a hydrogen supply group) for modification, the upper portion of the obtained modified silver nanowire film is coated with an organic polymer solution, and after annealing, the silver nanowire film is obtained. And stripping from the substrate to obtain the modified stretchable electrode. Through the interaction between the modified and enhanced silver nanowire film and the organic polymer, the tensile property is improved, the situation that the sheet resistance of the modified stretchable electrode is increased due to breakage of the silver nanowires is avoided, and the modified stretchable electrode has high conductivity, high transparency and high fatigue resistance at the same time.

The invention belongs to the technical field of organic electronics, and provides a compound, a mixture and a composition for further improving the performance of an organic EL device, and the organic EL device with further improved device performance. The compound has a structure as shown in a formula (1), has an asymmetric structure, can inhibit molecular aggregation and reduce exciton quenching, and shows a high triplet state energy level. The driving voltage of the prepared organic electronic device is reduced, and the luminous efficiency is obviously improved. In addition, the compound provided by the invention also has relatively high thermal stability and contains a certain content of deuterium atoms, so that the service life of the organic electronic device is prolonged. The organic electronic device can be applied to the fields of display and illumination.

The invention belongs to the technical field of organic electronics, and discloses a preparation method of a spatially conjugated organic molecule based on a bis-hexaphenylbenzene anchoring group and application of the spatially conjugated organic molecule in the field of organic monomolecular wires. The space conjugated organic molecule based on the bis-hexaphenylbenzene anchoring group has a structure shown as I-II as follows: # imgabs0 # hexaphenylbenzene has a unique space conjugated structure, so that electrons can be transmitted not only along a valence bond conjugated channel, but also along a space conjugated channel, and the space conjugated organic molecule has a plurality of electric conduction channels, so that the space conjugated organic molecule can be used as a space conjugated organic molecule. Hexaphenylbenzene and a gold electrode are anchored through Van der Waals' force, and a molecular wire is constructed. The preparation method is simple and applicable, and has a good application prospect in the field of organic monomolecular wires.

The invention belongs to the technical field of organic electronics, and provides a compound, a mixture and a composition for further improving the performance of an organic EL device, and the organic EL device with further improved device performance. The compound has a structure as shown in a formula (2) or a formula (3), and the compound has an asymmetric structure, so that molecular aggregation can be inhibited, and exciton quenching can be reduced. The driving voltage of the prepared organic electronic device is reduced, and the luminous efficiency is obviously improved. The compound provided by the invention also has relatively high thermal stability and contains a certain content of deuterated benzene rings, so that the service life of the organic electronic device is prolonged. The organic electronic device can be applied to the fields of display and illumination.

The present invention relates to hydroxyaminophosphinic acid derivatives of formula I, in which the groups and parameters occurring have the meanings defined in claim 1, to processes for the preparation of said compounds, and to the use thereof in the production of self-assembled monolayers (SAM), in particular in the production of switchable SAMs for electronic devices. The invention also relates to an electronic device comprising said SAM, preferably in the field of organic electronics, in particular for memories, sensors, in addition for organic light emitting diodes (OLEDs), photovoltaics (OPVs), field effect transistors (OFETs) and Josephson junctions, very particularly for memristive components such as memristive crossbar arrays. # imgabs0 #

This invention relates to the fields of organic synthesis and organic electronics, particularly to cyanobutadiene derivatives and their preparation methods and applications, and polymer semiconductor materials and their preparation methods and applications. The cyanobutadiene derivatives have the following general structural formula (1) or (2): This invention develops a series of cyanobutadiene derivative-based electron-deficient building blocks with simple structures, strong electron-withdrawing capabilities, and easy synthesis. These electron-deficient building blocks can be used as acceptor units in the development of organic photovoltaic, organic thermoelectric, and organic field-effect transistor materials.

The present application relates to a carbon paste composition and a method of producing the same. The carbon paste composition comprises polyvinylcarbazole (PVK) and a tailored mixture of solvents. The PVK is used as a semiconducting binder replacing the conventionally used poly(vinyl acetate) found in commercial carbon-based pastes. This carbon paste composition is suitable for use in the preparation of perovskite solar cells or other types of organic electronics. This application also discloses a method to deposit the carbon paste composition in a perovskite solar cell.

The application discloses a nerve synapse biomimetic photoelectric slowly-varying memristor and a preparation method thereof, and belongs to the field of organic electronics and photoelectric information technology. The device structure of the slowly-varying memristor is a cross structure, and comprises a bottom electrode, a functional layer and a top electrode from bottom to top on a conductive glass. The functional layer is a poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylene vinylene] MEH-PPV layer. The bottom electrode is indium tin oxide ITO, and the top electrode is Ag. The MEH-PPV layer is a continuous and smooth amorphous thin film. The MEH-PPV layer is prepared by a solution spin coating method, and has the advantages of good sustainability, good solubility, simple preparation, excellent photoelectric performance and the like. The prepared nerve synapse biomimetic photoelectric slowly-varying memristor can perform various nerve morphological simulation and has different responses to light with different wavelengths and different intensities. The application has low cost, good repeatability and can be used in an artificial nerve morphological computing system, and provides more possibilities for constructing a visual perception system.

The invention relates to the technical field of organic chemical molecular design and organic photoelectric materials, in particular to an acceptor unit with a skeleton containing thiophene modified benzoxadiazole derivatives, side chain alkyl substitution and main chain vinyl bridging, and preparation and application of the acceptor unit. According to the present invention, the skeleton contains the thiophene-modified benzoxadiazole derivative, the side chain alkyl substituted and main chain vinyl bridged acceptor unit is the strong electron-deficient acceptor unit with high main chain planarity, and further, the n-type polymer is prepared through the improved co-catalysis direct arylation polymerization process based on the acceptor unit, and the commercialization process of organic electrons is greatly promoted. According to the invention, the n-type polymer with a unique electron-structure synergistic effect is used as an organic semiconductor layer, and the prepared organic field effect transistor shows a creative electron mobility.

The invention belongs to the technical field of organic electronics, and discloses a preparation method of an indanone-based photoresponse organic molecule and application of the indanone-based photoresponse organic molecule in the field of organic single-molecule wires. The indanone-based photo-responsive organic molecule has a structure shown as I-II as shown in the specification, and through-bond coupling (TBC) and through-space coupling (TSC) channels of the indanone-based photo-responsive organic molecule can be regulated and controlled through molecular structure engineering. By means of introducing electron donating / withdrawing groups into molecules, adjusting the length of a pi-conjugated chain, introducing steric hindrance and the like, the molecules are subjected to reversible photoisomerization under ultraviolet irradiation, and meanwhile, adjustment of a charge transfer channel can be realized at a single molecule level. The preparation method is simple and applicable, and has a good application prospect in the field of organic monomolecular wires.

To provide an organic electronics material containing a charge-transporting polymer which can form an organic layer capable of improving characteristics such as conductivity and is obtained by a simple method using an inexpensive material.SOLUTION: The organic electronics material contains the charge-transporting polymer having a branched structure. The charge-transporting polymer contains a trivalent structural unit represented by the following formula (a) and a divalent structural unit represented by the following formula (b), has a structure represented by formula (I) formed by directly bonding at least one binding site in the trivalent structural unit and at least one binding site in the divalent structural unit, and has a weight average molecular weight of 2,000-500,000.SELECTED DRAWING: Figure 1

To provide an organic electronics material containing a charge-transporting polymer which is excellent in curability, can form an organic layer capable of improving conductivity, and is obtained by a simple method using an inexpensive material.SOLUTION: The organic electronics material contains the charge-transporting polymer having a branched structure. The charge-transporting polymer contains a trivalent structural unit represented by the following formula (a), a divalent structural unit represented by the following formula (b) and a polymerizable functional group, has a structure represented by formula (I) formed by directly bonding at least one bond in the trivalent structural unit and at least one bond in the divalent structural unit, and has a weight average molecular weight of 2,000-500,000.SELECTED DRAWING: Figure 1

The invention belongs to the technical field of monomolecular organic electronics, and discloses a preparation method, performance research and application of imidazole-based organic molecules. On the basis of imidazole organic molecules, methylthio is used as an anchoring group, and the imidazole organic molecules have the following structure: # imgabs0 #. The methylthio anchoring groups are introduced into the unique conjugated structure and two ends of the imidazole molecules, and under certain conditions, the molecules change from a single molecular system to a bimolecular system, so that the molecular weight is increased, and the molecular weight is increased. And the conductivity value, the molecular pulling length and other corresponding characteristics can also change correspondingly. Due to the fact that free ions in imidazole molecules can react with adjacent molecules to a certain extent under specific conditions, the imidazole molecules can serve as molecular devices related to molecular switches and the like to be applied in monomolecular devices, and the imidazole molecules can also be used for information storage and encryption due to the performance of response under the specific conditions. Therefore, the molecule has a good application prospect in the field of organic single-molecule wires.

A process for producing nanoclusters of silicon and / or germanium exhibiting a permanent magnetic and / or electric dipole moment for adjusting the work function of materials, for micro- and nano-electronics, for telecommunications, for “nano-ovens”, for organic electronics, for photoelectric devices, for catalytic reactions and for fractionation of water.

The invention discloses an organic semiconductor material containing a sulfuryl structure as shown in a formula (I) as well as a preparation method and application of the organic semiconductor material. According to the invention, a bromine-substituted sulfuryl-containing condensed ring structure is taken as a substrate, substituent groups are reasonably selected, and the organic semiconductor material with strong luminescence characteristic as shown in the formula (I) is prepared through Suzuki coupling reaction. The organic semiconductor material containing the sulfuryl structure has typical bipolar electrical characteristics, and has practical application value in the organic electronics fields of organic light-emitting diodes, organic field effect transistors, organic light-emitting transistors and the like.

The present invention relates to electronically doped semiconductor materials and electronic components comprising cerium-ethylenediamine ketone-type and cerium-salen-type composites. The present invention also relates to the use of the cerium-ethylenediamine ketone-type and cerium-salen-type composites as electron acceptors, particularly as p-dopants and electron transport materials in organic electronic components. Furthermore, the present invention relates to novel cerium-ethylenediamine ketone-type and cerium-salen-type composites.

An organic electronics material includes a charge transport polymer which has a branched structure, includes a trivalent structural unit represented by formula (a) below, and a divalent structural unit represented by formula (b) below, has a structure represented by formula (I) and is formed through a direct bonding of at least one bonding site in the trivalent structural unit and at least one bonding site in the divalent structural unit, and has a weight average molecular weight of 2,000 to 500,000. In the formulas, Ar' represents a trivalent organic group derived from an aromatic hydrocarbon or aromatic heterocycle of 2 to 30 carbon atoms, or triarylamine, Ar2 represents a monovalent organic group derived from an aromatic hydrocarbon of 6 to 30 carbon atoms which has an electron-withdrawing group or an electron-donating group, and * represents a bonding site with another structure.

The present invention relates to heteroleptic complexes comprising a phenylimidazole or phenyltriazole unit bonded via a carbene bond to a central metal atom, and phenylimidazole ligands attached via a nitrogen-metal bond to the central atom, to OLEDs which comprise such heteroleptic complexes, to light-emitting layers comprising at least one such heteroleptic complex, to a device selected from the group consisting of illuminating elements, stationary visual display units and mobile visual display units comprising such an OLED, to the use of such a heteroleptic complex in OLEDs, for example as emitter, matrix material, charge transport material and / or charge blocker.

The present invention relates to compounds of formula (I) as well as to their use as organic doping agent, as transport layer, as hole injection layer, as organic semiconductor itself, or as hole transport layer. The invention also relates to organic semiconductive materials, electronic components, semiconductor units, and doped semiconductor layers comprising the compounds of formula (I) as well as to a method to produce such a doped semiconductor layer.

The application discloses a conjugated two-dimensional polymer film and a preparation method and application thereof. The preparation method comprises the following steps: placing a copper substrate in a mixed solution containing an organic monomer and a polar solvent, then adding a ligand and performing an interfacial polycondensation reaction, so as to in-situ grow the conjugated two-dimensional polymer film on the surface of the copper substrate. The preparation method provided by the application can in-situ obtain various conjugated two-dimensional polymer films with different bonding connections on the surface of copper. The prepared conjugated two-dimensional polymer film has adjustable pores, a smooth morphology, a controllable thickness and a strong interlayer pi-pi interaction force, and can be widely applied in selective adsorption and separation, photo / electric catalysis, chemical sensing, organic electronics and other fields. Meanwhile, the conjugated two-dimensional polymer film / metal copper composite material prepared in the application can be directly used as an active electrode and applied in electrolytic water, carbon dioxide reduction electrocatalytic reaction and electrochemical seawater uranium extraction.

The invention belongs to the technical field of organic electronics, and discloses a space conjugated organic molecule based on a hexaphenylbenzene anchoring group as well as preparation and application of the space conjugated organic molecule. The space-conjugated organic molecule based on the hexaphenylbenzene anchoring group has a structure shown as I-III: the unique space-conjugated structure of the space-conjugated organic molecule enables electrons not only to be transmitted along a valence bond conjugation channel, but also to be transmitted along a space conjugation channel, and the space-conjugated organic molecule has a plurality of electric conduction channels, so that the space-conjugated organic molecule has a good application prospect. The low conductivity phenomenon caused by insufficient valence bond conjugation of meta-position modified molecules is effectively compensated. The preparation method is simple and applicable, and has a good application prospect in the field of organic monomolecular wires.

The present invention relates to an electronic component comprising a cerium IV complex, a doped semi-conductor matrix material comprising the cerium IV complex and at least one electron donor, the use of the cerium IV complex, especially as an organic semi-conductor, as a dopant in organic semiconductor matrix materials and as a charge injector in a charge injection layer, and new cerium IV complexes.

The invention discloses a single-channel vertical complementary amplifying circuit based on an organic electrochemical transistor and a preparation method of the single-channel vertical complementary amplifying circuit, and belongs to the technical field of organic electronics. The single-channel vertical complementary amplification circuit based on the organic electrochemical transistor comprises a substrate, a bottom electrode, a single-component bipolar semiconductor channel layer, a top electrode VDD, a top electrode VSS and a packaging layer from bottom to top, wherein the top electrode, the bottom electrode and the semiconductor channel layer are vertically and oppositely arranged. According to the single-channel vertical complementary amplification circuit provided by the invention, the n / p type conductive function is integrated through the single-component bipolar semiconductor material, a vertical stacking framework is matched, multiple precise photoetching steps are omitted, function stability can be guaranteed without designing a complex alignment structure and additionally optimizing process parameters, the preparation process is greatly simplified, the equipment cost is reduced, and the production efficiency is improved. The mass production yield is obviously improved, and the method has a wide application prospect.

The invention discloses a thermoelectric elastomer and a preparation method thereof, and relates to the technical field of organic thermoelectric material new energy. In the presence of a dopant and a cross-linking agent, a conjugated polymer and an elastomer material react in a solvent to obtain the thermoelectric elastomer. The thermoelectric elastomer prepared by the invention has the characteristics of high stretch rate, high strain recovery, high thermoelectric performance, low Young modulus and unique strain enhanced thermoelectric performance, and a thermoelectric integrated module based on the thermoelectric elastomer has excellent skin conformity, can accurately perceive the temperature change of a human body, generates electricity by utilizing the skin heat of the human body, and has the characteristics of high tensile strength, high strain recovery rate, high thermoelectric performance, low Young modulus and unique strain enhanced thermoelectric performance. And stable voltage output can be realized in thousands of stretching-releasing cycle processes. The preparation method has universality, and has good application prospects in the fields of organic electronics, wearable electronics, energy recovery and the like.

The present invention belongs to the technical field of organic electronics, and discloses a method for preparing a class of spatially conjugated organic molecules based on a naphthalene skeleton and their application in the field of organic optoelectronics. The spatially conjugated organic molecules based on a naphthalene skeleton of the present invention have the following structure shown in I-III: Its unique spatial conjugated structure enables electrons to be transmitted not only along the valence bond conjugation channel, but also along the spatial conjugation channel, and has multiple conductance channels, which effectively compensates for the low conductance phenomenon caused by insufficient valence bond conjugation of meta-modified molecules. The preparation method of the present invention is simple and applicable, and has good application prospects in the field of organic optoelectronics.

The invention belongs to the technical field of semiconductor industry storage technology and organic electronics and information, and particularly relates to a dynamic reconfigurable organic photosensitive field effect transistor and a manufacturing method thereof. The dynamic reconfigurable organic photosensitive field effect transistor comprises a gate electrode, a gate insulating layer, an electrolyte layer, an organic photosensitive charge trapping layer, an organic photosensitive semiconductor layer and source and drain electrodes from bottom to top. The organic photosensitive field effect transistor is based on a double-photosensitive-layer structure, an electrolyte layer is additionally introduced, and the dynamic reconfiguration of light current is successfully realized by utilizing a photon-electron-ion multi-mechanism coupling effect; by changing the grid voltage and the source-drain voltage, the volatility-to-non-volatility reconfigurability of the light current is realized; according to the organic photosensitive field effect transistor, the spectral range of a device can be expanded through a double-photosensitive-layer structure, and sensing from ultraviolet light to visible light is achieved. In addition, the organic photosensitive field effect transistor utilizes a negative photoconductive effect to sense light information in a weaker light environment.

The present invention relates to hydroxyamino phosphinic acid derivatives of formula Iin which the occurring groups and parameters have the meanings defined in claim 1, to a method for their preparation and to their use for the fabrication of self-assembled monolayers (SAM), in particular for the fabrication of switchable SAM for electronic devices. The invention further relates to electronic devices comprising said SAM, preferably in the field of organic electronics, in particular for use in memory, sensors, furthermore in organic light-emitting diodes (OLEDs), photovoltaics (OPVs), field-effect transistors (OFETs) and Josephson junctions, very particularly in memristive components such as memristive crossbar-arrays.

Described herein are non-aqueous ink compositions comprising a polythiophene having repeating units conforming to Formula (I) as described below, one or more metalloid nanoparticles, and a liquid carrier having one or more organic solvents. The invention also relates to the use of the non-aqueous ink composition, for example, in organic electronic devices. In formula (I), R1 and R2 are each independently H, alkyl, fluoroalkyl, alkoxy, aryloxy or-O-[Z-O] p-Re; wherein Z is an optionally halogenated alkylene group, p is equal to or greater than 1, and Re is hydrogen, alkyl, fluoroalkyl or aryl. (I)

The present invention relates to the field of organic electronics, and specifically to an organic hot electron transistor, a preparation method thereof, and a LUMO energy level detection method. The organic hot electron transistor described in the present invention includes an emitter, a base, and a collector; wherein an insulating layer is provided between the emitter and the base, and an organic semiconductor layer is provided between the base and the collector. The present invention realizes the application of hot electron transistors in the detection technology of the LUMO energy level of organic semiconductor materials for the first time by improving the structure of existing hot electron transistors. At the same time, the present invention also provides a method for obtaining a hot electron energy spectrum using the hot electron transistor, and proposes a method for in-situ and accurate extraction of the LUMO energy level of an organic semiconductor material from the hot electron energy spectrum. The present invention not only fills the gap in research in this field, but also provides guidance for the study of charge transport behavior in organic electronic devices.