39 results about "Organic nonlinear optical materials" patented technology

The invention relates to organic photoelectric functional material based on six-substitution three-indene structons and the application thereof, belonging to the technical field of photoelectric material and particularly relating to photoelectric material with definite conjugated branching structure and the application of the material in the field of organic electronics, like organic electrofluorescence and organic laser. The material contains novel 2,3,7,8,12,13-substituted three-combined indene structons, has definite branching three dimensional spatial structure and has good film forming property, excellent thermal stability and enhanced light emission capability. The organic photoelectric functional material has potential application in the field of organic electronics, like organic electrofluorescence, organic laser and organic nonlinear optical material. Specifically, an electrophosphorescence device made with the functional material as blue-fluorescence material is improved in color purity and spectrum stability, and a light pumped organic laser device used as laser medium has low threshold value and high conversion efficiency.

The invention relates to the field of organic nonlinear optical materials and relates to methyl pyridinium with an organic two-photon absorption material, and a preparation method and the application of the methyl pyridinium. The structural formula of the product is described in structural formula (I); the preparation method comprises the steps of taking 2,6-dimethyl pyridine as a raw material and finally obtaining a compound (I) by conducting oxidizing reaction, esterification reaction, methylolation reaction, halogenation reaction, nucleophilic addition reaction, Wittig reaction and the final methylation reaction. The raw materials are easy to access, and the synthesis steps are simple. The compound (I) has excellent two-photon absorption performance and good water solubility and is an ideal biological fluorescence probe; an obvious solvatochromism phenomenon easily occurs, the compound can be used for detecting water content in a common organic solvent, can also be used as a fluorescent probe for detecting the PH value in a solution system, has a series of advantages of high sensibility, quick response, identification by naked eyes and the like, and has an excellent application prospect.

The invention relates to spirofluorene xanthene phosphine oxide electro-phosphorescent main materials and synthesis and application methods thereof, belongs to the field of photoelectric material science and technology, and in particular relates to four spirofluorene xanthene organic phosphine oxide materials and application of the materials in the field of organic electronics such as organic electroluminescent materials, organic solar cells, organic field-effect tubes, dye laser, organic nonlinear optical materials, fluorescent probes and the like. The series of materials are obtained by introducing diphenyl phosphine oxide groups to the 2nd site, the 2nd and 7th sites, the 2nd' site and the 2nd' and 7th' sites of spirofluorene xanthene respectively. The series of compounds have good charge transfer performance, thermal stability and high triplet energy level (ET=-2.86eV), and can be used as main materials and applied in phosphorescent devices. When the series of compounds are applied in the organic electro-phosphorescent devices, the maximum external quantum efficiency is 10.78 percent and the maximum brightness is 8,582cd/m<2> in the blue phosphorescent device; and in the green phosphorescent device, the maximum external quantum efficiency is 19.1 percent, and the maximum brightness is 16,943cd/m<2>.

The invention relates to a blue light emitting functional material and the application, which relates to star shooting shape oligomer blue light emitting functional material and the application. The material is monodisperse star shooting shape oligomer on the basis of minami carbazolyl element, the oligomer has the structure of a general formula 1, the material contains minami carbazolyl element, has monodisperse star shooting shape three-dimensional space structure, is easy to form stable amorphous state, and displays excellent filming property and light emitting property. The material has potential application in the fields such as organic electroluminescence, organic laser, organic non-linear optical material and the like. Particularly, organic electroluminescent devices which utilize the functional material to be blue luminescent material have improved luminescent brightness, device efficiency, color purity and spectroscopic stability.

The invention belongs to the field of organic nonlinear optical materials, and particularly relates to a triphenylamine two-photon fluorescence probe compound and a preparation method and an application thereof. The preparation method of the triphenylamine two-photon fluorescence probe compound comprises the following steps of: injecting anhydrous benzene into 4-nitrapyrin-2, 6-dimethyl isophthalate and triphenylphosphine under the protection of nitrogen; increasing temperature, refluxing, and cooling; filtering and washing to obtain chlorination-4-methylene triphenylphosphine group-pyridine-2,6-dimethyl isophthalate, and dissolving into methanol; mixing and stirring tri(4-formylphenyl)amine and absolute methanol; adding the methanol solution of the chlorination-4-methylene triphenylphosphine group-pyridine-2,6-dimethyl isophthalate and the methanol solution of sodium methylate; stirring at 0-5 DEG C for 1-2 hours, stirring at normal temperature for 3-4 hours; separating through column chromatography. The triphenylamine two-photon fluorescence probe compound disclosed by the invention has the advantages of outstandingly enhanced two-photon absorption section, good water solubility, higher reaction activity and very high coordination capacity and can be applied to silver ion detection and pH detection.

The invention relates to a fluorene derivative containing macro conjugated molecules and a method for preparing the same. The macro conjugated molecule fluorene derivative has 2, 3, 6, 7-tetraamino-9, 9'-dialkyl fluorene as a raw material which is added to an organic solvent respectively together with phenanthrenequinone, acenaphthene quinone or bis-carbonyl pyrene derivatives and strong base; under the protection of inert gas, reflux reaction is carried out to the materials, so as to prepare a series of trapezoidal conjugated molecules containing fluorine structures. Alkyl surrounding the molecules helps to overcome solubility reduction caused by the high-plane rigid structure of the molecules, which improves the dissolution processing performance of material molecules. Meanwhile, the conjugation of pi electrons on a skeleton of the trapezoidal conjugated molecules is intensified further, which can reduce the energy gaps of the molecules, increase the nonlinear optical coefficients of the molecules remarkably, play a certain role in overcoming the disadvantages that the prior organic nonlinear micromolecule material is poor in chemical stability and mechanical strength, etc. The fluorene derivative can be widely applied to the organic nonlinear optical material field.

The invention provides a third-order nonlinear optical material, namely a tetrabutyl ammonium fullerene ball and a synthesizing method thereof, which belongs to the field of functional materials. The prior inorganic and organic nonlinear optical materials have the problems of easy deliquescence, poor thermal stability, complicated preparation and the like respectively. The molecular formula of the tetrabutyl ammonium fullerene ball provided by the invention is (NH4)18[(C16H36N)4]24[Mo132O372(H2O)72(CH3COO)30].ca.7NH4CH3COO.ca.173H2O. In the method, after {Mo132} and tetrabutyl ammonium bromide are dissolved in water respectively according to the mass ratio of 1 to 42, and are adjusted by acetic acid respectively until the pH value is between 3.5 and 4.5, the {Mo132} and the tetrabutyl ammonium bromide are mixed to obtain the tetrabutyl ammonium fullerene ball. The third-order nonlinear optical material has the advantages of uneasy deliquescence, high thermal stability, larger nonlinear absorption and non-linear refraction coefficient, self-defocusing property and simple preparation.

The invention belongs to the field of organic nonlinear optical materials, and particularly relates to a sandwiched phthalocyanine rare-earth complex with a two-photo absorption property and a preparation method thereof. The molecular structural formula of the sandwiched phthalocyanine rare-earth complex is as shown in the specification, wherein M is Y, Ho or Er. The complex has good solubility, stability and large two-photo absorption cross section and is expectably applied to the fields of two-photo photodyrnamic therapy, three-dimensional micro-manufacturing, two-photo optical amplitude limitation, three-dimensional optical data storage and the like.

A red fluorescent dye with star structure is preparde through proportionally adding trianilinoaldehyde and catalyst to the solution of substituted 4-dicyanomethenyl-20methyl-4H-pyran, thermal reflux, distilling for removing solvent, leaching the solid by solvent and drying. It can be used for organic optical conductor, organic non-linear optical material, and luminescent material.

There is provided an organic nonlinear optical material including a polymer binder and a compound represented by the following Formula (I):

The invention belongs to the technical field of organic non-linear optical materials, and particularly relates to a self-assembly porphyrin nano fiber material. Experiment data show that the self-assembly porphyrin nano fiber material has a regular appearance shape, is bar-shaped or strip-shaped, has high hyperpolarizability, has the characteristic of reverse saturable absorption and can be applied to non-linear optical and laser protection.

Disclosed are molybdenum oxide base third-order nonlinear optical materials and a synthetic method thereof, which belong to the field of function materials. Existing inorganic nonlinear optical materials and organic nonlinear optical materials have the problems that the materials are easy to deliquesce, poor in heat stability, small in nonlinear coefficient and the like. According to the novel materials, each of anions is in a spherical structure and is represented by the molecular formula of (NH4)42[{(MoVI)MoVI5O21(H2O)6}12{MoV2O4}30(CH3COO)5(HOOC(CH2)2COO)25] =100H2O. According to the molybdenum oxide base third-order nonlinear optical materials, ammonium succinate is added into a {Mo132Ac} aqueous solution in a ratio of 1:40, stirred, acidized with HCI, rested and crystallized, so that the novel materials are obtained. The third-order nonlinear optical materials are easy to prepare and not likely to deliquesce, have no obvious nonlinear absorption property under the effect of 5ns laser pulses with the laser wavelength of 532nm, and have a large nonlinear refraction coefficient and the self-defocusing property.

The present invention provides an organic nonlinear optical material including an organic compound having nonlinear optical activity dispersed in or bonded to a polymer binder, wherein the material contains a tertiary amine derivative represented by the following formula (1) as the organic compound having nonlinear optical activity, and an organic nonlinear optical element using the same.

In the formula, Z¹ to Z³ are independently aromatic groups optionally having a substituent; L is a π conjugated group optionally having a substituent; A is a π conjugated electron-attractive group which includes a ring structure optionally having a substituent; m denotes 0 or 1; a π conjugated system denoted by Z³-L_m has, from one terminal thereof to the other terminal, five or more unsaturated bonds which form one conjugated system; and at least two of Z¹ to Z³, L and A may be connected so as to form at least one ring structure.

The invention relates to a glutamic acid-derived chiral metal-organic nonlinear optical material. The invention discloses a metal-complex nonlinear optical crystal material containing a chiral center. The chemical formula of the material is [ML(H2O)]n, wherein M=Mn or Cd; and L is a chiral ligand. A preparation method of the material comprises the step of complexing an L-glutamic acid derivative as a ligand with metals, such as cadmium or manganese and the like in an aqueous solution to form the material. The material has the characteristic that the existence of a non-central space group necessary for a second-order nonlinear optical crystal material is ensured through a chiral group. The material has simple preparation method, and the prepared compound crystal has stable performance and better second-order nonlinear optical property and is expected to be widely applied to the field of developing a short-wave laser, a light modulator and the like.

A kind of cross-linked phthalocyanine-epoxy resin polymer and its transparent uniform film is disclosed. Said film features high resistance to acid, alkali and organic solvent, high high-temp (200 deg.C) stability, and the absorbed wavelength up to 800 nm or more. It can be used for organic optical storage and non-linear optical materials.