The invention relates to spirofluorene
xanthene phosphine oxide electro-phosphorescent main materials and synthesis and application methods thereof, belongs to the field of photoelectric material science and technology, and in particular relates to four spirofluorene
xanthene organic
phosphine oxide materials and application of the materials in the field of
organic electronics such as organic electroluminescent materials, organic solar cells, organic field-effect tubes,
dye laser,
organic nonlinear optical materials, fluorescent probes and the like. The series of materials are obtained by introducing diphenyl
phosphine oxide groups to the 2nd site, the 2nd and 7th sites, the 2nd' site and the 2nd' and 7th' sites of spirofluorene
xanthene respectively. The series of compounds have good charge transfer performance,
thermal stability and high triplet
energy level (ET=-2.86eV), and can be used as main materials and applied in phosphorescent devices. When the series of compounds are applied in the organic electro-phosphorescent devices, the maximum external
quantum efficiency is 10.78 percent and the maximum brightness is 8,582cd / m<2> in the blue phosphorescent device; and in the green phosphorescent device, the maximum external
quantum efficiency is 19.1 percent, and the maximum brightness is 16,943cd / m<2>.