265 results about "Nonlinear optical crystal" patented technology

Apparatuses, systems and methods for all-optical computing are disclosed. An optical computing apparatus includes a nonlinear optical crystal, at least one light source, and a detector. The at least one light source is configured to spatially modulate vectors of operand values onto coherent optical radiation and to direct the spatially modulated coherent optical radiation into the nonlinear optical crystal, thereby exciting propagating modes in the nonlinear optical crystal corresponding to a computational result of linear and nonlinear operations performed over the vectors. The detector is coupled to receive and sense the coherent optical radiation that has propagated through the nonlinear optical crystal so as to decode the computational result.

The invention relates to a nonlinear optical crystal structure, a preparation method thereof and optical equipment. The nonlinear optical crystal structure comprises a plurality of material layers which are stacked in the direction perpendicular to the two-dimensional plane of the material layers. Each material layer is of a crystal structure with y-weight rotational symmetry and has a predetermined crystal lattice direction in a direction parallel to a two-dimensional plane; a non-zero deflection angle is formed between the adjacent material layers, and the deflection angle is an included angle of the preset crystal lattice directions of the adjacent material layers; wherein y is 1, 2, 3, 4 or 6. According to the nonlinear optical crystal structure and the preparation method thereof, the rotational symmetry crystals are stacked, and nonlinear enhancement of second harmonics and even higher harmonics is achieved by controlling the deflection angle between the material layers. Compared with a traditional nonlinear metasurface scheme, the nonlinear optical crystal structure can achieve higher accuracy, higher operability and higher efficiency.

The invention provides a preparation method and application of a compound cesium ammonium fluoborate and a cesium ammonium fluoborate nonlinear optical crystal. The chemical formula of the compound is CsNH4B8O12F2; the chemical formula of the crystal is CsNH4B8O12F2, the crystal belongs to a trigonal system, the space group is P321, and the unit cell parameters are as follows: a = b = 6.5858 (4) + / -0.02, c = 7.8163 (6) + / -0.02, alpha = beta = 90 degrees, gamma = 120 degrees and Z = 1. The crystal is grown by adopting a vacuum high-temperature solution method, a room-temperature solution method or a hydrothermal method, and the ultraviolet transmission cut-off edge of the crystal is lower than 190 nm. The nonlinear optical effect of the crystal is about 2.5 times of that of KH2PO4 (KDP), and the shortest I-type phase matching wavelength is 175.5 nm. The crystal has the advantages of simple preparation method, low toxicity of used initial raw materials, small harm to human bodies, stable physical and chemical properties, uniaxial crystal, easiness in application and the like. The method can be widely applied to nonlinear optical devices such as ultraviolet and deep ultraviolet all-solid-state lasers, optical parametric oscillators and the like.

The invention relates to a nonlinear optical crystal and crystal combined adhesive and a preparation method thereof. The nonlinear optical crystal and crystal combined adhesive comprises the following components in parts by weight: 40-70 parts of hydrogenated bisphenol A type acrylate monomer; 20 to 40 parts of a polyfunctional thiol compound; the core of the core-shell structure nanoparticles is ZrO2, the shell of the core-shell structure nanoparticles is SiO2, the particle size of the core is 20-50nm, and the thickness of a shell layer is 3-8nm; and 0.1 to 0.5 part of a coupling agent containing a phosphate group. Through accurate regulation and control of the ZrO2atSiO2 core-shell nanoparticles, the refractive index of the adhesive can be adjusted in a range of 1.65-2.10, and is highly matched with the refractive index 1.7-2.2 of nonlinear optical crystals such as KTP, BBO and LBO, so that the Fresnel loss of a bonding interface is reduced to be less than or equal to 0.5 dB / cm, the laser frequency conversion efficiency is remarkably improved, agglomeration is effectively inhibited by the core-shell structure of the nanoparticles, and the laser frequency conversion efficiency is improved. The light transmittance of a cured adhesive layer under common laser wavelengths such as 1064 nm, 532 nm and 355 nm is larger than or equal to 99.5%, the adhesive layer is suitable for a high-power laser system, by adding the quantum dot material, the refractive index matching of the specific wavelength can be further optimized, and the application scene is expanded.

The invention belongs to the technical field of biomedical detection, and discloses a Raman spectrum analysis device for quantitative detection of hematologic tumor markers, which comprises a blood collection centrifugal unit with a self-adaptive load regulation mechanism for monitoring blood density and components in real time, centrifugal force and time parameters are automatically adjusted according to the blood density and components; the optical fiber Raman spectrometer is provided with an automatic wavelength calibration system, and an ultrafast laser pulse transmitter and a high-sensitivity photon counting detector are integrated on the optical fiber Raman spectrometer. Raman scattering signals are enhanced by adopting a quantum entanglement light source and a nonlinear optical crystal; according to the invention, the detection capability on low-concentration tumor markers can be obviously improved. Due to the improvement, the device can accurately detect the existence of the tumor marker at the early stage of cancer, and powerful support is provided for early treatment of a patient.

This invention relates to a compound, magnesium gallium selenide (MgHgGa4Se8), and a magnesium gallium selenide (MgHgGa4Se8) infrared nonlinear optical crystal, along with their preparation methods and applications. The compound has the molecular formula MgHgGa4Se8 and a molecular weight of 1135.46 g / mol. The crystal, also with the molecular formula MgHgGa4Se8 and a molecular weight of 1135.46 g / mol, lacks a center of symmetry, belongs to the tetragonal crystal system, and has a space group of MgHgGa4Se8. Its cell parameters are α = β = γ = 90°, Z = 1, and its volume is determined by the high-temperature melt method, chemical vapor transport method, or crucible lowering method. This crystal exhibits advantages such as significant nonlinear optical effects, good crystal growth habit, good mechanical properties, high hardness, resistance to breakage and deliquescence, and ease of processing and storage. It can be used to fabricate infrared nonlinear optical devices, which have important applications in optoelectronic warfare, laser communication, and medical fields.

The invention discloses a method for growing a large-size CLBO crystal by using a new fluxing agent, and belongs to the field of nonlinear optical crystals. The adopted new fluxing agent is Cs2O-Li2O-B2O3-YF3, and the large-size CLBO crystal can be obtained through growth by a high-temperature solution top oriented seed crystal growth method. According to the novel fluxing agent, the solution viscosity can be effectively reduced, and crystal defects are reduced; and the grown large-size CLBO crystal has the advantages of high transmittance, strong deliquescence resistance and the like, and can be used as a frequency doubling device of an ultraviolet laser.

The invention relates to a novel second-order nonlinear optical crystal-potassium cadmium germanate (K4Cd3Ge4O13), and belongs to the field of optical crystal materials. The crystal is prepared by adopting a high-temperature solid-phase method and a high-temperature solution method, belongs to an orthorhombic crystal system and a C2 space group, is accurate in measurement of cell parameters, and shows excellent nonlinear optical characteristics and a wide light transmission range. The ultraviolet cut-off edge of the crystal is 261 nm, the infrared spectrum permeability is not obviously reduced in the range of 4000-714 cm <-1 >, the transmission range of the crystal can effectively cover a key atmosphere transmission window of 3-5 microns, and the crystal has powder frequency doubling response equivalent to that of a KDP crystal and can be applied to an all-solid-state laser as a mid-infrared nonlinear optical crystal.

The present invention relates to the technical field of lasers, and particularly relates to an all-solid-state continuous-wave vacuum ultraviolet laser using a double resonant cavity. A first cavity mirror M1, a first laser crystal C1, a fourth cavity mirror M4, a fifth cavity mirror M5, and a sixth cavity mirror M6 form a first laser resonant cavity; a second cavity mirror M2, a second laser crystal C2, a third cavity mirror M3, the fourth cavity mirror M4, the fifth cavity mirror M5, and the sixth cavity mirror M6 form a second laser resonant cavity; a first nonlinear optical crystal O1 is disposed between the fifth cavity mirror M5 and the sixth cavity mirror M6 to frequency-double the 526-nm laser generated by the first resonant cavity into a 263-nm frequency-doubled laser; a second nonlinear optical crystal O2 is disposed between the fourth cavity mirror M4 and the fifth cavity mirror M5 to sum-frequency the 725-nm fundamental-frequency laser generated by the second resonant cavity and the 263-nm frequency-doubled laser generated by the first nonlinear optical crystal O1 to generate a 193-nm vacuum ultraviolet laser, which is output through the fourth cavity mirror M4. The present invention has a simple internal structure and requires fewer frequency conversion times.

The invention belongs to the technical field of nonlinear optical crystals, and particularly relates to a zeolite-like structure nitrogen oxide silicate nonlinear optical crystal and a preparation method and application thereof, the chemical general formula of the crystal is Ba3Si3N5OCl, the crystal belongs to a hexagonal system, the cell parameters of the crystal are as follows: a is 9.5147 (6), c is 5.5002 (4), V is 431.22 (6) 3, Z is 2, the space group is P-62c, and the crystal has a non-centrosymmetric structure. The Ba3Si3N5OCl crystal provided by the invention is used as a novel zeolite-like structure nitrogen oxide silicate, successfully integrates nonlinear optical activity and phase matching capability, can generate frequency doubling response which is about 0.2 times of KDP (potassium dihydrogen phosphate) under 1064 nm laser pumping, and can realize phase matching, so that the Ba3Si3N5OCl crystal becomes a nonlinear optical material with practical device application potential.

This invention relates to a potassium hydroxyborate nonlinear optical crystal, its preparation method, and its applications. The crystal has the chemical formula K₂B₅O₈(OH), a molecular weight of 277.26, belongs to the orthorhombic crystal system, and has a space group of [missing information]. Pca 21, with unit cell parameters a=8.5523(8)Å, b=7.3326(7)Å, c=12.9739(10)Å, α=β=γ=90°, V=813.60(13)Å. 3 A nonlinear optical crystal composed of potassium hydroxyborate can be obtained using a mild hydrothermal (solvothermal) method through programmed or natural cooling. The frequency doubling effect of this crystal powder is approximately twice that of KDP (KH₂PO₄), and its ultraviolet cutoff edge is below 200 nm, making it suitable as a deep-ultraviolet nonlinear optical crystal. The crystal growth process offers advantages such as simple operation, low raw material toxicity, short growth cycle, low cost, and stable physicochemical properties. It has been widely applied in the fabrication of nonlinear optical devices such as frequency doubling generators, up- or down-frequency converters, or optical parametric oscillators.

This invention discloses a samarium-lanthanum co-doped calcium oxyborate yttrium nonlinear optical crystal material, its preparation method, and its applications. The samarium-lanthanum co-doped calcium oxyborate yttrium nonlinear optical crystal material belongs to the monoclinic crystal system, has a space group of Cm, and a chemical formula of Sm. 0.3 La 0.1 :Y 0.6 Ca4O(BO3)3 has a second harmonic response intensity of 0.89 × KDP, and exhibits transmittance exceeding 80% in the 500–1000 nm and 1600–2400 nm wavelength ranges. It also has a strong absorption peak in the 1000–1600 nm wavelength range. Therefore, the samarium-lanthanum co-doped calcium oxyborate yttrium nonlinear optical crystal can be considered as a nonlinear optical crystal material with broad application prospects in the field of optics.

The present invention relates to a rubidium fluoro-scandium borate compound, a rubidium fluoro-scandium borate nonlinear optical crystal, and a preparation method and application thereof. The rubidium fluoro-scandium borate compound has a chemical formula Rb2ScB3O6F2, does not contain a symmetry center and has a molecular weight of 382.33 g / mol. The rubidium fluoro-scandium borate nonlinear optical crystal belongs to the monoclinic crystal system, and belongs to the non-centrosymmetric space group P21, and the unit cell parameters are: a=4.0372(10) Å, b=11.800(3) Å, c=8.823(2) Å, α=γ=90°, β=98.327(11)°, Z=2. The present invention adopts a high-temperature vacuum packaging method or a solid-state synthesis method to prepare rubidium fluoro-scandium borate compounds. The present invention adopts a fluxing agent method to prepare a rubidium fluoro-scandium borate nonlinear optical crystal, which have the advantages of short absorption cutoff edge, large nonlinear optical effect, good thermal stability, and stable physical and chemical properties. The rubidium fluoro-scandium borate nonlinear optical crystal of the present invention can be used to fabricate nonlinear optical devices, which have important applications in fields such as optics, military, laser lithography, and communication, etc.

The invention discloses an optical crystal preparation device and method. The optical crystal preparation device comprises a supporting structure, and a material displacement platform, a laser coupling microscopic system and a signal monitoring and processing system which are arranged on the supporting structure, and the material displacement platform comprises a first crystal sample table for placing a first material crystal and a second crystal sample table for placing a second material crystal; at least one of the first crystal sample table and the second crystal sample table can move in multiple directions so as to adjust the relative positions of the first material crystal and the second material crystal; and the laser coupling microscopic system and the signal monitoring and processing system are respectively used for collecting the nonlinear signal intensity in real time when the first material crystal and the second material crystal are butted. According to the invention, a method for monitoring a nonlinear signal in real time by coupling laser during transfer is adopted, so that a transfer angle error is eliminated, and a low-cost solution is provided for preparing a corner phase matching nonlinear optical crystal with high efficiency and low cost.

To provide an SHG (second harmonic generation) capable of emitting a laser beam having a wave length shorter than that of 215nm.SOLUTION: The SHG device 1 has an optical crystal layer made of a nonlinear optical crystal, a lower DBR layer disposed on the lower surface of the optical crystal layer, and an upper DBR layer disposed on the upper surface of the optical crystal layer. The lower DBR layer has a double structure of a lower first 1DBR layer disposed on the optical crystalline layer side and a lower second 1DBR layer disposed under the lower first 2DBR layer. The second harmonic reflectivity of the lower 1DBR layer is higher than the second harmonic reflectivity of the lower 2DBR layer. The lower 2DBR layer has a reflectivity for the fundamental wave higher than that of the lower 1DBR layer. The second harmonic generated in the optical crystal layer is emitted through the upper DBR layer.SELECTED DRAWING: Figure 1

A method for fabricating a nonlinear optical waveguide with gradient refractive index distribution, in which a nonlinear optical crystal is prepared; a type of first heavy ions, a type of second heavy ions and parameters related to an irradiation process are determined; the first heavy ions are accelerated to generate a first ion beam; the nonlinear optical crystal is bombarded with the first ion beam to obtain a primary processed crystal; the second heavy ions are accelerated to generate a second ion beam; the primary processed crystal is bombarded with the second ion beam to obtain a secondary processed crystal; and the secondary processed crystal is segmented to obtain the desired optical waveguide.

The present application relates to a nonlinear optical crystal structure, a preparation method thereof and an optical device. The nonlinear optical crystal structure includes a plurality of material layers stacked in a direction perpendicular to a two-dimensional plane thereof. Each of the material layers has a crystal structure with y-fold rotational symmetry, and has a predetermined lattice direction parallel to the two-dimensional plane, where y is an integer in a range from 1 to 20. Adjacent material layers have a nonzero twist angle therebetween, and the twist angle is an angle between the predetermined lattice directions of the adjacent material layers.

The invention relates to the technical field of temperature control devices, in particular to a nonlinear optical crystal temperature control device which comprises an outer frame with two open ends, a partition temperature control assembly is rotatably connected in the outer frame, a clamping assembly is mounted in the partition temperature control assembly, and a C-shaped plate is mounted in the outer frame; the partition temperature control assembly comprises a round frame rotationally connected with the outer frame, a plurality of partition plates are fixedly connected between the two sides of the round frame, a temperature control cavity is formed between every two adjacent partition plates, a dynamic ventilation assembly is installed on one side of each partition plate, and a rotary knob movably extending out of the outer frame is arranged at a rotary shaft of the round frame. The dynamic ventilation assembly comprises a ventilation hole, a sealing block and an elastic rope, the ventilation hole is formed in one side of the partition plate, and the sealing block corresponds to the ventilation hole. The crystal temperature control device solves the technical problems that when an existing crystal temperature control device cools a crystal, surrounding hot air can prevent cold air from approaching, the hot air in a cavity is difficult to discharge quickly, and the contact effect of the cold air and the crystal is difficult to enhance.

The invention relates to a sulfur-gallium-silver-sodium compound and a sulfur-gallium-silver-sodium infrared nonlinear optical crystal as well as a preparation method and application thereof, the molecular formula of the compound is NaAg3Ga8S14, the molecular weight is 1353.20 g / mol, the compound has an asymmetric center and is crystallized in a Cm space group of a monoclinic system, and the cell parameters are as follows: a is equal to 12.2616 (8), b is equal to 11.0956 (7), c is equal to 9.2131 (6), beta is equal to 114.981 (2) degrees, Z is equal to 2, and the volume is 1136.18 (13) 3. The crystal is prepared by a high-temperature melt method, a chemical vapor transport method or a Bridgman-Stockbarger method. The crystal has the advantages of being high in laser damage resistance, moderate in nonlinear optical effect, wide in light-transmitting wave band, large in hardness, good in mechanical performance, not prone to fragmentation and deliquescence, easy to process and store and the like, and can be used for manufacturing infrared nonlinear optical devices.

The invention relates to a nonlinear optical crystal cavity and a preparation method thereof. The nonlinear optical crystal cavity comprises at least two layers of Van der Waals material layers which are arranged in a stacked mode and spaced, and the materials of the Van der Waals material layers comprise Van der Waals materials with center inversion asymmetry; the optical resonant cavity comprises two layers of distributed Bragg reflectors which are oppositely arranged, and the two layers of distributed Bragg reflectors are arranged on the two surfaces of the outermost side in the stacking direction of the Van der Waals material layer respectively; the driving assembly is connected to the Van der Waals material layers, and the driving assembly is used for adjusting the rotating angle between the adjacent Van der Waals material layers and the interval between the adjacent Van der Waals material layers. The nonlinear optical crystal cavity provided by the invention has the capabilities of adjustable function and wide-band working, and can realize high nonlinear conversion efficiency under different wavelengths at the same time.

The invention discloses a sulfur-arsenic-strontium-sodium compound and a sulfur-arsenic-strontium-sodium nonlinear optical crystal as well as a preparation method and application thereof. The chemical formula of the sulfur-arsenic-strontium-sodium nonlinear optical crystal is Na4SrAs2S8, the sulfur-arsenic-strontium-sodium nonlinear optical crystal is of a non-centrosymmetric structure and belongs to a tetragonal system, and a space group is that cell parameters are alpha = beta = gamma = 90 degrees, Z = 2 and V = 701.57 (5). The sulfur-arsenic-strontium-sodium nonlinear optical crystal provided by the invention has a relatively large nonlinear optical coefficient and relatively wide transmission wave band and band gap. Meanwhile, the crystal meets the same-component melting characteristic, is easy to grow, cut, grind, polish and preserve, is stable in air, is not easy to deliquesce and is insoluble in water, so that the crystal is expected to become a new-generation novel middle-infrared band nonlinear optical material with excellent comprehensive performance, and can be effectively applied to a wide-spectrum-range tunable laser system.

The present invention provides a compound guanidine fluoborate and a guanidine fluoborate nonlinear optical crystal and a preparation method and use thereof. The chemical formula of the compound is [C(NH2)3]3B3O3F6, and the molecular weight is 370.66. The guanidine fluoborate nonlinear optical crystal is prepared by a room temperature solution method, and the molecular weight is 370.66. The crystal belongs to the monoclinic system and the space group is P c, the unit cell parameters are a=8.5366(10), b=11.5066(12), c=9.2274(9), α=90°, β=122.682°, γ=90°, and the unit cell volume is 762.88Å 3 The crystal is grown using a room temperature solution method or a hydrothermal method. The crystal has good chemical stability and can be used as a short-wavelength nonlinear optical crystal in all-solid-state lasers.

A laser assembly and a method for generating continuous-wave (CW) light at approximately 193 nm (between 180 nm and 200 nm) and at a power of 1W or higher using two CW laser sources: one laser source generating first fundamental light that is twice frequency doubled or otherwise converted into first CW light having a first deep-ultraviolet (DUV) wavelength between 250 nm and 275 nm, the other laser source generating second CW light having an infrared (IR) wavelength between 1300 nm and 1700 nm. A resonant cavity receives the second CW light and generates enhanced CW light at 100 W or higher. A first non-linear optical (NLO) crystal mixes a first enhanced CW light portion and the first CW light to generate sum-frequency generation (SFG) light having a second DUV wavelength. A second NLO crystal mixes a second enhanced CW light portion and the SFG light to generate output CW light at approximately 193 nm.

The invention discloses a processing method of a CLBO crystal with high surface shape precision, and belongs to the field of nonlinear optical crystals. The method comprises three procedures of cutting, heat treatment and polishing. The method comprises the following steps: firstly, cutting an oriented CLBO crystal under the cooling of cutting oil, then, carrying out heat treatment annealing on the cut crystal in an inert atmosphere, and finally, carrying out rough polishing, fine polishing and cleaning on the CLBO crystal subjected to heat treatment annealing to obtain the CLBO crystal with high surface shape precision. According to the processing method disclosed by the invention, the problems of deliquescence cracking and low processing surface shape precision in the processing of the CLBO crystal are effectively solved through a method for eliminating processing stress through heat treatment, inhibiting deliquescence by combining anhydrous polishing and water polishing and improving the polishing precision.

The invention relates to a niobium tantalum oxyfluoride acid ammonium salt second-order nonlinear optical crystalline material and preparation and application thereof, the chemical formula of the material is (NH4) 5 (NbOF4) (TaF7) 2, the crystalline material belongs to a tetragonal system, the space group is I4cm, and the cell parameters are alpha = beta = gamma = 90 degrees and Z = 2. Under 1064nm laser irradiation, the powder frequency-doubled effect of the nonlinear optical crystal (NH4) 5 (NbOF4) (TaF7) 2 can reach 3.5 times that of a KH2PO4 (KDP) crystal, under 532nm laser irradiation, the powder frequency-doubled effect of the nonlinear optical crystal (NH4) 5 (NbOF4) (TaF7) 2 is 0.35 times that of a beta-BaB2O4 (BBO) crystal, and phase matching can be realized. In addition, the ultraviolet absorption cutoff edge of the crystalline material is less than 195 nm, and the crystalline material shows moderate birefringence (0.095 at-546 nm). The crystalline material provided by the invention has important application value in the photoelectric fields of solid-state lasers, spectral analysis, precision manufacturing, optical communication and the like.

The invention discloses a water-soluble dye functionalized potassium hydrogen phthalate nonlinear optical crystal as well as a preparation method and application thereof. The chemical formula of a potassium hydrogen phthalate crystal matrix is C8H5O4K, the water-soluble dye functionalized potassium hydrogen phthalate nonlinear optical crystal belongs to an orthorhombic system, the space group is Pca21, the cell parameters are # imgabs 0 # alpha = beta = gamma = 90 degrees, # imgabs 1 #, and the crystal material has good third-order nonlinear optical performance and shows a remarkable saturated absorption effect; the large-size water-soluble dye functionalized potassium hydrogen phthalate nonlinear optical crystal is grown by adopting a constant-temperature evaporation method, the preparation method is simple and convenient to operate, low in cost and less in pollution, and the used raw materials are low in toxicity and short in growth cycle; the water-soluble dye functionalized potassium hydrogen phthalate nonlinear optical crystal does not deliquesce in air, has stable physical and chemical properties, is easy to cut and polish, and is suitable for manufacturing nonlinear optical devices.

The present invention relates to compounds and their nonlinear optical (NLO) crystals of A3B11P2O23 (A=K, Rb, Cs, NH4), their producing method and uses thereof. The series of compounds have a chemical formula of A3B11P2O23 (A=K, Rb, Cs, NH4), which are namely K3B11P2O23, Rb3B11P2O23, Cs3B11P2O23 and (NH4)3B11P2O23. The series of NLO crystals having the chemical formula of A3B11P2O23 (A=K, Rb, Cs, NH4), belong to rhombohedral crystal system, and have a space group of R3, crystal cell parameters of a=b=10.016(5)-12.591(5) Å, c=12.105(6)-14.905(6) Å, Z=3. A3B11P2O23 (A=K, Rb, Cs, NH4) compounds were prepared by a solid-state reaction method or a hydrothermal method, and A3B11P2O23 (A=K, Rb, Cs, NH4) NLO crystals were prepared by a high-temperature solid-state reaction method, a hydrothermal method, or a solution method. T They meet the requirements for the frequency conversion of UV wavelength lasers and could be used to prepare nonlinear optical devices.

The invention discloses a preparation method of a large-size nonlinear optical crystal NaI3O8, and belongs to the technical field of nonlinear optical crystal preparation. The large-size nonlinear optical crystal NaI3O8 is successfully prepared by taking iodine pentoxide and sodium nitrate as raw materials and adopting a hydrothermal synthesis method by controlling the raw material ratio and the cooling rate, the preparation method is simple, and the crystal is short in growth cycle, large in size and high in purity. Hazardous substances such as nitric acid are not adopted, the preparation process is safe, meanwhile, the method does not increase structural and process complexity, preparation is convenient, and environmental pollution is not increased. A Q-switched Nd: YAG laser is used for outputting laser with the wavelength of 1064nm as fundamental frequency light, the obtained NaI3O8 crystal material is subjected to a powder frequency doubling test, and a result shows that the crystal material has a relatively strong frequency doubling effect.

The invention relates to a polymorphic nonlinear optical crystal material of 3-amino-1, 2, 4-triazole nitrate and preparation and application of the polymorphic nonlinear optical crystal material, the chemical formula of the polymorphic material is (C2H5N4) (NO3), the molecular weight is 147.11, and the polymorphic material specifically comprises two crystal forms: (1) alpha-(C2H5N4) (NO3) belongs to a triclinic system, the space group is P1, the cell parameters are alpha = 110.44-114.63 degrees, (2) beta = 93.04-97.71 degrees, gamma = 93.49-97.64 degrees and Z = 2, and compared with the prior art, the cell volume of the polymorphic nonlinear optical crystal material is larger than that of the prior art, and the cell volume of the polymorphic nonlinear optical crystal material is larger than that of the prior art The polymorphic alpha-(C2H5N4) (NO3) and beta-(C2H5N4) (NO3) materials involved in the invention have a relatively large frequency-doubled effect at 1064nm, and phase matching can be realized by the polymorphic alpha-(C2H5N4) (NO3) materials and the polymorphic beta-(C2H5N4) (NO3) materials. In addition, the ultraviolet absorption cut-off edges of the crystal material are 240 nm and 248 nm respectively, and the crystal material has wide application prospects in the photoelectric technical fields of laser frequency conversion, high-speed optical signal modulation, holographic storage systems and the like.

An alkali metal monohydrogen cyanurate compound of the chemical formula AM(HC3N3O3)·nH2O (specifically such as KLi(HC3N3O3)·2H2O, RbLi(HC3N3O3)·2H2O, RbNa(HC3N3O3)·2H2O) and a nonlinear optical crystal thereof are related to optoelectronic functional materials. Measured using a powder frequency doubling test method, and the powder frequency doubling effect of the nonlinear optical crystal is about 2-3 times that of KH2PO4 (KDP). The ultraviolet absorption edge of the nonlinear optical crystal is shorter than 250 nm. The nonlinear optical crystal can achieve the harmonic generator of double, triple, or quadruple frequency for Nd: YAG (λ=1.064 μm). Moreover, the nonlinear optical crystal is of a single crystalline structure, is colorless and transparent, and does not deliquesce in air.