34 results about "Semiconducting polymer" patented technology

The invention relates to the technical field of new energy materials, in particular to a thermoelectric composite material and a preparation method and application thereof.The thermoelectric composite material comprises 2D TMDs, a P-type semiconductor polymer and a conductive polymer, the P-type semiconductor polymer and the conductive polymer are cross-linked to form a composite conductive polymer, and the 2D TMDs are dispersed in the composite conductive polymer. The composite conductive polymer has the effects of forming a thermoelectric loop, regulating and modifying the interface of the 2D TMDs and protecting the 2D TMDs dispersed in the composite conductive polymer, and the 2D TMDs and the P-type semiconductor polymer convert heat energy into electric energy under the Seebeck effect. The thermoelectric building material additive comprises a thermoelectric composite material combined on an inorganic silica gel carrier. The thermoelectric cement-based material comprises cement and a thermoelectric building material additive. The thermoelectric cement-based material has good thermoelectric performance, stability and durability, and is suitable for scenes with obvious temperature difference or urgent energy recovery requirements.

A water-swellable semiconducting material is provided, comprising a semiconducting layer and a semiconducting water-swellable polymer layer on which the semiconducting layer is arranged. The semiconducting water-swellable polymer layer consists of conductive particles dispersed in a crosslinked superabsorbent polymer matrix. This material can be formed into tapes or other structures for insulating and protecting cables. The water-swellable semiconducting material can be applied to cables or other conductive materials to insulate them and protect the cables from water ingress.

The present application provides a semiconductor polymer, a preparation method and application thereof, a semiconductor doped composite and application thereof. The general structural formula of the semiconductor polymer is: #imgabs0#R is an alkyl group, A1 is a nitrogen-containing first electron acceptor unit, A2 is a nitrogen-containing second electron acceptor unit, the structures of A1 and A2 are different, and n is a positive integer. The semiconductor polymer provided in the present application is a bipolar semiconductor material having both p-type and n-type transport properties. At the same time, the semiconductor polymer introduces a quinone pyrazine structure into the main chain of the dual-acceptor polymer molecule. The quinone pyrazine structure has multiple active sites and is highly stable, which can support the modification of the dual-acceptor polymer structure. This makes the semiconductor polymer not only extremely easy to achieve effective chemical doping, but also highly compatible with different types of chemical dopants.

The invention relates to a method for manufacturing a medium or high voltage electrical cable, of the type comprising:- a core formed from an elongated electrically conductive element and an insulating system comprising at least one layer comprising at least one crosslinked polyethylene, said at least one layer being arranged coaxially around the elongated electrically conductive element, and- a tape enveloping the core, the tape being formed from a semiconducting polymer material, characterized in that the method comprises at least one step of extracting at least one chemical species from the tape, said chemical species being a chemical species capable of reaching the insulating system by migration from the tape and of reducing the dielectric performance of the insulating system. Figure for abstract: None

A power cable comprising: a power core including: a conductor, an insulation system including an inner semiconducting layer arranged around the conductor, an insulation layer arranged around the inner semiconducting layer, and an outer semiconducting layer arranged around the insulation layer, a first metallic water blocking layer arranged concentrically with and around the outer semiconducting layer, a semiconducting polymer layer arranged concentrically with and around the first metallic water blocking layer, and a second metallic water blocking layer arranged concentrically with and around the semiconducting polymer layer; and an outer sheath arranged around the second metallic water blocking layer.

The present application relates to the technical field of new energy materials, and in particular to thermoelectric composite materials, preparation methods and applications thereof. The thermoelectric composite materials include 2D TMDs, P-type semiconductor polymers, and conductive polymers. The P-type semiconductor polymers and conductive polymers are cross-linked to form a composite conductive polymer, and the 2D TMDs are dispersed in the composite conductive polymer. The composite conductive polymer has the functions of forming a thermoelectric circuit, regulating and modifying the interface of 2D TMDs, and protecting the 2D TMDs dispersed therein. The 2D TMDs and the P-type semiconductor polymer convert thermal energy into electrical energy under the Seebeck effect. Thermoelectric building material additives include thermoelectric composite materials combined with inorganic silica gel carriers. Thermoelectric cement-based materials include cement and thermoelectric building material additives. The thermoelectric cement-based material has good thermoelectric performance, stability and durability, and is suitable for scenarios with significant temperature differences or urgent energy recovery needs.

The present invention provides a near-infrared light-induced semiconductor polymer and its hydrolysis product, side-chain modified polymer, drug delivery system, light-stimulated responsive nanodelivery system, and preparation methods and applications, relating to the field of biomedical technologies. The near-infrared light-induced semiconductor polymer and its hydrolysis product, side-chain modified polymer, drug delivery system (OPTC), and light-stimulated responsive nanodelivery system (OPTC-RNP) provided by the present invention all have low spontaneous background fluorescence, deep tissue penetration, and high signal-to-noise ratio during near-infrared second-window imaging, with excellent near-infrared second-window imaging effects, and the accumulation of the nanodelivery system at the tumor site can be observed. Moreover, the photosensitizer in the delivery system can generate singlet oxygen under the irradiation of near-infrared light, realizing tumor photodynamic therapy while breaking the chemical bond connecting OPTC and RNP to release ribonucleoprotein complex (RNP), thus realizing light-controllable gene therapy.

The invention discloses a composite nanomaterial based on a semiconductor polymer-fullerene derivative and a preparation method and application of the composite nanomaterial, and relates to the field of nano biomedical materials and technologies.The preparation method comprises the steps that a conjugated polymer PCPDTBT and a fullerene C60 derivative PCBM are dissolved in chloroform and mixed, the mixed solution and a CTAB aqueous solution are mixed and subjected to ultrasonic emulsification, and the composite nanomaterial is obtained; removing the chloroform to obtain a nanometer core dispersion liquid; coating the surface of the nano core with a mesoporous silicon dioxide layer; and modifying polyethylene glycol on the surface of the mesoporous silica layer to obtain the composite nanoparticles based on the semiconductor polymer-fullerene derivative. The composite nanoparticle can efficiently generate < 1 > O2 and. OH under the irradiation of 660 nm laser, realizes I-type and II-type photodynamic therapy, has photothermal therapy performance and fluorescence imaging capability, can meet the requirement of near-infrared two-region imaging, and can be used as an optical therapy reagent guided by near-infrared fluorescence imaging.

The invention relates to a method for manufacturing a medium- or high-voltage electric cable, of the type comprising:a core formed of an elongate electrically conductive element and of an insulating system comprising at least one layer comprising at least one cross-linked polyethylene, said at least one layer being arranged coaxially around the elongate electrically conductive element, anda tape enveloping the corethe tape being formed of a semiconductor polymer material.,characterised in that the method comprises at least one step of extracting at least one chemical species from the tape, said chemical species being a chemical species able to reach the insulating system by migration from the tape and to decrease the dielectric performance of the insulating system.

The invention discloses an ROS (reactive oxygen species) response nanoparticle, which is characterized by mainly comprising an oxaliplatin-containing poly-prodrug OTP (one time programmable) and a semiconductor polymer SP (semiconductor polymer), the molecular structure of the oxaliplatin poly-prodrug comprises oxaliplatin, a molecule containing an ROS sensitive response bond, a connecting molecule and a polyether derivative. The semiconductor polymer has a molecular structure as shown in a formula I: # imgabs0 #, r in the formula I is an organic group for increasing solubility and compatibility. The invention is suitable for ovarian cancer treatment, and has the advantages of targeted enrichment, response release and synergistic treatment.

The invention discloses a novel high-brightness near-infrared two-region semiconductor polymer and application thereof in preparation of an endometriosis focus near-infrared two-region imaging guided operation diagnosis and treatment reagent, and relates to the technical field of medicinal chemistry. The novel high-brightness near-infrared two-region semiconductor polymer P-BPTI provided by the invention has excellent optical performance, can absorb 808nm laser and emit near-infrared two-region light, passively targets an endometriosis site through an EPR effect, and is high in penetration depth and high in quantum yield. The nanoparticles based on the polymer can passively target a plurality of focuses in the abdominal cavity of a mouse through an EPR effect, the focuses can be effectively removed, inflammation is reduced, the cytotoxicity is low, and reliable technical support is provided for clinical diagnosis, treatment and transformation of endometriosis.

The invention discloses a graft copolymer compatibilizer containing a semiconducting polymer and an elastomer fragment, and preparation, separation and application of the graft copolymer compatibilizer. The structural formula of the compatilizer is shown in the formula 1. According to the invention, a metal coupling reaction (Stille reaction or Suzuki reaction) is utilized to seal the end of a semiconductor polymer, and then the semiconductor polymer is grafted to an elastomer flexible segment to prepare a grafted copolymer compatibilizer containing semiconductor and elastomer segments, and the grafted copolymer compatibilizer is directly blended with a semiconductor material under the condition of not adding the elastomer segments, so that the p-type performance of the material can be inhibited, and the service life of the material is prolonged. Meanwhile, the n-type performance and the tensile property of the material are improved. Based on a'compatibility 'and'mixing' strategy, the problem of collaborative improvement of electrical and mechanical properties is solved. The strategy is designed and regulated according to the material microstructure and intermolecular interaction, electrical and mechanical properties are closely combined and unified, and a foundation is built for application of flexible electronic devices.

The invention provides preparation of an ultra-small nano probe with efficient biomarker performance and super-resolution imaging application of the ultra-small nano probe. The nanodot is of a core-shell structure, and the core-shell structure comprises a fluorescent core, a fluorescent layer and a fluorescent layer, wherein the fluorescent core is composed of a single-chain semiconductor polymer; the shell layer is composed of an amphiphilic compound, a hydrophobic part of the amphiphilic compound is combined with the semiconductor polymer, a hydrophilic group is located on the surface of the shell layer to serve as an active group, the average particle size of the nanodot is smaller than 5 nm, and the nanodot is of a glassy structure. The nanodot can realize high-density specific marking of various subcellular organelles and nano-scale biological fluorescence imaging.

This invention provides an activatable semiconductor polymer, its preparation method, and its applications. The activatable semiconductor polymer of this invention can efficiently accumulate at tumor sites. Due to the presence of electron-withdrawing groups on its side chains, the polymer's fluorescence is quenched. Upon response to tumor markers—biothiols, reactive oxygen species, and cathepsin B—the polymer's fluorescence recovers, enabling precise imaging and sonodynamic therapy at the tumor site. Simultaneously, the activatable semiconductor polymer of this invention can label immune cells (such as dendritic cells and macrophages) and track their metastasis from the tumor to the draining lymph nodes.

The invention relates to the field of organic electrochemical transistors (OECT), in particular to a modified organic semiconductor material, a composite film, a preparation method, application and an organic electrochemical transistor, and the preparation method of the modified organic semiconductor material comprises the following steps: carrying out gradient thermal polymerization modification treatment on a semiconductor polymer material and a modifier in a formula 1 (1), the modified organic semiconductor material is prepared; the gradient thermal polymerization modification treatment comprises a low-temperature heat preservation polymerization process and a high-temperature heat preservation polymerization process; wherein the temperature in the low-temperature heat preservation polymerization process is 100-150 DEG C; the temperature in the high-temperature insulation polymerization process is 200-280 DEG C. According to the material prepared by the method and the constructed film, the optimal balance is achieved between the mechanical flexibility and the volume stability, the Young modulus is remarkably reduced, and swelling and stress concentration caused by ion embedding are effectively relieved; therefore, the operation stability and the service life of the organic electrochemical transistor in long-time electrochemical circulation and air environment are remarkably improved, and meanwhile, the basic electrical performance of a device is not influenced.

The application belongs to the technical field of nanobiomaterials, and particularly relates to a hypochlorous acid responsive fluorescent compound, a ratio type semiconductor polymer quantum dot fluorescent probe for detecting hypochlorous acid, and further discloses a preparation method and application thereof. The ratio type semiconductor polymer quantum dot fluorescent probe for detecting hypochlorous acid is mainly prepared by a nanocomprecipitation method through energy donors CNPPV and energy receptors MeOTPATBT fluorescent compounds. In the fluorescent probe, the presence of hypochlorous acid can oxidize the sulfur atom of MeOTPATBT, and then block the energy transmission from CNPPV to MeOTPATBT, so that the fluorescent spectrum of the Pdots probe changes in ratio, the ratio detection of hypochlorous acid is realized, and the fluorescent probe has the advantages of high specificity, anti-interference and high stability.

Implantable bioelectronic semiconducting polymers including thiophene and / or selenophene are provided. Films including the polymers coated on substrates are further provided. Organic electrochemical transistors including channels including the polymers are further provided. Methods of preparing the polymers are further provided. Bioelectronic implant comprising polymers coated on substrates are further provided.

Disclosed are a stretchable semiconductor film having biocompatibility and an electronic device using the same. The stretchable semiconductor film having biocompatibility of the present disclosure includes a biocompatible elastomer matrix; and a semiconducting polymer of an interconnected semiconductor nanofiber network embedded in the elastomer matrix, wherein the semiconducting polymer of the interconnected semiconductor nanofiber network embedded in the elastomer matrix provides stretchability. The electronic device using the stretchable semiconductor film having biocompatibility of the present disclosure is characterized by using a bilayer electrode composed of gold and silver, providing excellent corrosion resistance in vivo.

Devices and methods relating to stretchable electronics. A stretchable electronic film includes an insulating polymer and less than 1 wt % of a semiconducting polymer. Manufacturing a multi-layered, stretchable electronic device characterized by a single peel-off step for integrating the components of the device rather than a multi-peel synthesis of the device.

Herein disclosed is a water-degradable conjugated polymer material comprising: a semiconducting polymer; and a crown ether, wherein the crown ether resides in an interstitial region of the semiconducting polymer, wherein the interstitial region is defined by polymer chains of the semiconducting polymer. A method for forming the water-degradable conjugated polymer material, and devices including the water-degradable conjugated polymer material, are also disclosed herein. No suitable figure to be published with abstract

A semiconductor device, including at least one organic semiconductor (OSC) polymer and at least one photosensitizer, such that the at least one OSC polymer is a diketopyrrolopyrrole-fused thiophene polymeric material, and the fused thiophene is beta-substituted.

A force sensing system, article of manufacture and method of sensing and locating force impacts include resistive sensing elements. The pressure sensing matrix includes multiple force sensing devices for detecting a location of an applied force. Each force sensing device includes a resistive sensing element (RSE). The RSE includes a closed cell foam structure having a cavity for receiving a core portion. The core portion an open-cell foam having a semiconductive polymeric structure. The RSE generates a voltage signal in response to a force impacting the RSE. A conductive layer is disposed on each of the opposing sides of the RSE for conducting the voltage signal to a conductor. The conductor is in electrical communication with the respective foil layer for transmitting voltage data to an external microprocessor device for processing. Spreadsheet applications on the microprocessor device of a laptop process received voltage data.

An intrinsically stretchable organic electrochemical transistor with overall performance benchmarkable to a rigid device. The high performance was realized by reducing the oxygen level (PO2) of the stretchable substrates, which facilitates the de-doping of the conducting polymer channel. The high-performance intrinsically stretchable OECT is usable not only as a new device paradigm to impact the field of soft bioelectronics and promote the use of tissue-like stretchable OECTs in areas such as epidermal biosensing, soft neuromorphic computing and soft human-machine interfaces, but also to reveal a new critical parameter to alter the performance of stretchable conducting polymer-based devices.

The invention discloses an n-type semiconductor polymer composite material with high environmental stability and a preparation method thereof. The method comprises the following steps: mixing a PBFDO solution with an ionic micromolecule additive solution to form a uniform precursor solution, forming a film from the precursor solution, and performing thermal annealing treatment in a nitrogen environment to obtain the PBFDO composite material. The PBFDO composite material disclosed by the invention has excellent environmental stability, thermal stability and high electronic conductivity, and can meet the strict requirements of organic thermoelectric and high-temperature electronic devices and the like on material stability.

This application relates to the field of semiconductor fabrication technology and discloses an all-polymer elastic transistor and its fabrication method. The all-polymer elastic transistor includes an elastic substrate layer, a functional layer disposed on the elastic substrate layer, and a top protective layer disposed on the functional layer. The functional layer includes a source, a drain, a gate, a semiconductor layer, and a composite dielectric layer located between the semiconductor layer and the gate. The source and drain have an interdigitated structure. The source, drain, and gate are all made of a photolithographically patternable conductive composite material. The semiconductor layer is made of a photolithographically patternable semiconductor polymer composition. The composite dielectric layer is made of a photolithographically patternable polymer layer. Its advantages are that it realizes an all-polymer elastic transistor with high-resolution patterning, excellent mechanical elasticity, high electrical performance, and high structural stability.

This invention discloses a stretchable organic phototransistor based on a stable bulk heterojunction and its fabrication method. The transistor has a bottom-gate-top-contact top electrode structure and, from bottom to top, comprises a stretchable substrate, a stretchable gate electrode, a stretchable insulating layer, a stretchable organic active layer, coplanar stretchable source / drain electrodes, and a stretchable encapsulation layer. This invention uses a mixture of semiconductor polymers and elastomer polymers as the stretchable electron donor and highly photosensitive organic small molecules as the electron acceptor. An organic heterojunction is formed through solution blending to serve as the stretchable organic active layer. All functional layers are fabricated using stretchable materials, and the device is assembled using a thermal bonding transfer method. This phototransistor achieves a balance between stretchability and photoelectric performance, exhibiting not only high carrier mobility and high photoresponse sensitivity but also maintaining stable photoelectric performance under high mechanical stretching deformation.

The present application relates to a kind of gradient doped semiconductor polymer film and its preparation method and application, belong to organic thermoelectric material field.The gradient doped semiconductor polymer film includes semiconductor polymer film, and the dopant attached on all regions of the semiconductor polymer film;The doping degree of the dopant in each region of semiconductor polymer film overall presents ladder change, and the ladder change includes the gradient change of single dopant content formed on semiconductor polymer film or the gradient change of dopant kind.

The present application relates to the technical field of fluorescent probe, in particular to a ratio fluorescent probe and its preparation method and application. The ratio fluorescent probe is prepared from isothiocyanate dye modified semiconductor polymer quantum dots, and has strong fluorescence emission peaks at 530 nm and 581 nm, respectively. The isothiocyanate dye is rhodamine B isothiocyanate, the semiconductor polymer quantum dots are composed of polystyrene maleic anhydride copolymer and poly[(9,9-dioctylfluorenyl-2,7-diyl)-alt-(benzo[2,1,3]thiadiazole-4,8-diyl)], and the particle size of the ratio fluorescent probe is 10-200 nm. The detection limit of the ratio fluorescent probe for tyramine is 1.023 μM, which is lower than the allowable limit of tyramine residue, and meets the detection requirements of freshness and safety of aquatic products. The ratio fluorescent probe can be used for real-time / onsite visual quantitative detection of tyramine, and makes the detection process portable, fast and low-cost.

A semiconductive polymer composition comprising: (a) an ethylene C1-2-alkyl (meth)acrylate copolymer having an MFR2 of 4.5 g / 10 min or more and a C1-2-alkyl (meth)acrylate content of at least 9.0 wt % based on the total weight of the ethylene C1-2-alkyl alkyl (meth)acrylate copolymer; (b) 35.0 to 48 wt % carbon black having an iodine adsorption number of 85 to 140 mg / g (ASTM D 1510-19a), an oil absorption number of 90 to 110 ml / 100 g (ASTM D 2414-19) and an average primary particle size of 29 nm or less (ASTM D 3849-14a); and (c) 0.05 to 2.0 wt % of at least one antioxidant; all weight percentages being based on the total weight of the semiconductive polymer composition, unless mentioned otherwise.

The invention discloses a bionic chelerythrine-loaded semiconductor polymer dot. The bionic chelerythrine-loaded semiconductor polymer dot comprises a functional polymer, a luminous polymer, chelerythrine, a 4T1 cell membrane and bacterial outer membrane vesicles. The invention also discloses a preparation method of the bionic chelerythrine-loaded semiconductor polymer dot and application of the bionic chelerythrine-loaded semiconductor polymer dot in preparation of antitumor drugs and as an imaging agent. The bionic chelerythrine-loaded semiconductor polymer dot disclosed by the invention has excellent optical performance, high biocompatibility and a remarkable anti-tumor treatment effect.