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Naphthalene diimide containing 2-(1,3-dithio/seleno-2-subunit)ethylcyanide conjugate structure unit and derivatives thereof
ActiveCN104230953ASynthetic preparation is simpleHigh purityOrganic chemistrySolid-state devicesDevice PropertiesStructural unit
The invention provides a naphthalene diimide containing 2-(1,3-dithio / seleno-2-subunit)ethylcyanide conjugate structure unit and derivatives thereof, particularly compounds disclosed as Formula (A), wherein the groups are defined in the specification. The monomer can be used for preparing a series of polymers (dimers or polymers) with favorable device properties; and the polymers can be used for preparing organic photoelectric devices with favorable properties.
Owner:SHANGHAI INST OF ORGANIC CHEM CHINESE ACAD OF SCI
Semiconductor conjugated polymer and preparation method thereof
The invention relates to a semiconductor conjugated polymer and a preparation method thereof. The invention discloses a solution-processable polymer semiconductor material and particularly relates to a semiconductor conjugated polymer based on two-dimensional conjugated dibenzothiophene and (2-oxyindole-3-subunit)dibenzofuran-diketone and preparation thereof. The synthesized semiconductor conjugated polymer has wide absorption peak which covers visible light, even extends to a near infrared region; in addition, the synthesized semiconductor conjugated polymer has low lowest unoccupied molecular orbital (LUMO) energy level and can replace fullerene derivative (PCBM) to serve as a photovoltaic receptor material applied to the organic photovoltaic field. The introduced side chain serves as a solubilized alkyl chain. The semiconductor conjugated polymer prepared by the method can be subjected to solution processing, and has a certain application prospect in the organic photovoltaic field.
Owner:HEFEI UNIV OF TECH
Triphenyl phosphorus oxide-based thermal excitation delayed fluorescent blue light guest material and its preparation method and use
ActiveCN105924472ABalance injectionBalanced transmissionGroup 5/15 element organic compoundsSolid-state devicesElectron donorTriplet state
The invention relates to a fluorescent blue light guest material and its preparation method and use and especially relates to a triphenyl phosphorus oxide-based thermal excitation delayed fluorescent blue light guest material and its preparation method and use. The triphenyl phosphorus oxide-based thermal excitation delayed fluorescent blue light guest material solves the problem that because of large difference of an electron donor and an acceptor, when the electron donor is increased, guest emission wavelength produces red shift so that stable and efficient blue guest luminescence cannot be realized. The blue light guest material has a structural formula shown in the description. The preparation method comprises 1, preparing PXZPhBr, PXZPhBr, PTZPhBr and DMACPhBr, 2, mixing the products obtained through the step 1 and tetrahydrofuran, adding n-butyllithium and diphenylphosphinous chloride into the mixture, adding hydrogen peroxide into the mixture, carrying out stirring and carrying out chromatography and recrystallization. The triphenyl phosphorus oxide-based thermal excitation delayed fluorescent blue light guest material is used for preparation of a thermal excitation delayed fluorescent electroluminescent device. The material utilizes short-axis modification strategy, effectively keeps a matrix triplet state energy level, has a donor-acceptor (D-A)-type molecular structure and balances carrier injection and transmission. The preparation method belongs to the field of fluorescent material preparation.
Owner:HEILONGJIANG UNIV
Organic dye and photoelectric conversion device with same
ActiveCN101928471AGood application effectIncrease developmentLight-sensitive devicesSolid-state devicesArylHydrogen
The invention provides an organic dye and a photoelectric conversion device with the same. The organic dye has a structure shown in the specification, wherein n is an integer from 3 to 11; a plurality of Xes are independent respectively and are selected from groups consisting of the following components and combinations thereof; R is respectively independent H, halogen atoms, C1 to C18 alkyl, C1 to C18 alkoxy, C3 to C18 heterocyclic alkyl, C3 to C20 aryl, C3 to C20 heterocyclic aryl, C3 to C20 alcyl or C3 to C20 cycloalkyl; R1 and R2 are respectively independent the H, the halogen atoms, the C1 to C18 alkyl, the C1 to C18 alkoxy, the C3 to C18 heterocyclic alkyl, the C3 to C20 aryl, the C3 to C20 heterocyclic aryl, the C3 to C20 alcyl or the C3 to C20 cycloalkyl, or the R1 is connected with the R2 to form a loop with 5 to 14 elements; R3 is respectively independent the H, the halogen atoms, nitryl, amido, the C1 to C18 alkyl, the C1 to C18 alkoxy, C1 to C18 alkyl sulfide, the C3 to C18 heterocyclic alkyl, the C3 to C20 aryl, the C3 to C20 heterocyclic alkyl, the C3 to C20 alcyl or the C3 to C20 cycloalkyl; and Z is hydrogen, alkali metal or quaternary ammonium salt.
Owner:IND TECH RES INST
Preparation method and application A-D-A type organic molecule/amphiphilic polymer composite nanoparticles
ActiveCN110898222AStrong and wide absorptionInduced transferPhotodynamic therapyGeneral/multifunctional contrast agentsFluorescenceReceptor
The invention discloses a preparation method and an application of A-D-A type organic molecule / amphiphilic polymer composite nanoparticles, and relates to an application of organic molecules in the field of biological medicines. A non-fullerene receptor with an A-D-A structure, widely used in the organic photovoltaic field, has the unique advantages of easiness in structure adjustment, strong near-infrared light absorption capacity and low fluorescence quantum efficiency, and has the huge potential of being used as a photosensitizer for photo-thermal / photodynamic combined treatment. The organic molecule with the A-D-A structure is coated with an amphiphilic macromolecule to form the water-soluble composite nanoparticles, the composite nanoparticles show a high photothermal conversion efficiency and a high reactive oxygen generation capacity under irradiation of near-infrared laser with a certain wavelength, and mouse in-vivo experiments show that the water-soluble composite nanoparticles have an obvious inhibition effect on tumors. Therefore, the composite nanoparticles have great practical prospects and social values in the field of novel tumor treatment.
Owner:TIANJIN UNIVERSITY OF TECHNOLOGY
Conjugated polymer photoelectric material containing quinoxaline imide condensed ring and application thereof
ActiveCN108976392AImprove fill factorEffective absorptionSolid-state devicesSemiconductor/solid-state device manufacturingQuinoxalineSolubility
The invention discloses a conjugated polymer photoelectric material containing a quinoxaline imide condensed ring and an application thereof. The material has conjugated main chain and side chain groups, wherein the conjugated main chain contains a quinoxaline imide condensed ring structure and other copolymerized units and the side chain groups comprise alkyl chains R which enhance polymer solubility. As the polymer has the conjugated main chain structure, electron clouds can be delocalized on the polymer main chain, so that the polymer shows a semiconductor characteristic and has a rich photoelectric property; meanwhile, the polymer can be dissolved in an organic solvent as a result of the hydrotropic group R on the polymer side chain, so that the polymer is suitable for preparing a photoelectric apparatus by way of printing, reel-to-reel or ink-jet printing solution processing method. The conjugated polymer containing the quinoxaline imide condensed ring can be used as a carrier transmission layer, an N-type material, a light emitting layer or a photovoltaic active layer to be applied to photovoltaic, light-emitting or field effect transistor photoelectric apparatuses.
Owner:SOUTH CHINA NORMAL UNIVERSITY
Dibenzo-heterocyclic compound and preparation method and applications thereof
InactiveCN109651423ALower LUMO levelImprove hole transport abilitySilicon organic compoundsSolid-state devicesElectron injectionHigh energy
Owner:NINGBO LUMILAN NEW MATERIAL CO LTD +1
Spirofluorene group containing organic small molecule non-fullerene receptor material as well as preparation method and application thereof
ActiveCN110452241AGood film shape stabilityLower LUMO levelOrganic chemistrySolid-state devicesStructural formulaFullerene
The invention belongs to the technical field of organic photovoltaic and discloses a spirofluorene group containing organic small molecule non-fullerene receptor material as well as a preparation method and application thereof. The structural formula of the organic small molecule non-fullerene receptor material is a formula I shown in the description. A 9,9'-spirobifluorene group is adopted as a core, furthermore a diazosulfide and alkly chain substituted thiophene group is introduced, cyanoindanone groups with intensive electron-withdrawing are connected with both ends of the group, and thusthe film morphology stability of the organic small molecule non-fullerene receptor material can be promoted. Due to introduction of the diazosulfide group, the energy level of a lowest unoccupied molecular orbital can be further reduced; and due to introduction of the thiophene group, on one hand, light absorption can be enhanced, and on the other hand, synthesis preparation can be facilitated. The molecule designing has the advantages of being simple in synthesis and simple and convenient in purification.
Owner:SOUTH CHINA UNIV OF TECH
Organic electroluminescence material and preparation method and application
InactiveCN104177409AEasy to prepareEasy to operateGroup 8/9/10/18 element organic compoundsSolid-state devicesOrganic electroluminescenceEnergy level
The invention belongs to the field of a photoelectric material and specifically relates to an organic electroluminescence material. The structural formula of the material is as defined in the specification, wherein R is a C1-C20 alkoxy group. The organic electroluminescence material has high LUMO energy level and low HOMO energy level and is beneficial to blue shift of emission wavelength of the material. The material also has high phosphorescence quantum efficiency and good dissolving property and processability. The invention also provides a preparation method of the organic electroluminescence material and an application of the organic electroluminescence material in an organic electroluminescent device.
Owner:OCEANS KING LIGHTING SCI&TECH CO LTD +2
A-A type conjugated polymer based on isoindigo-blue and preparation method and application thereof
ActiveCN105732957AImprove solubilityStrong absorbanceSolid-state devicesSemiconductor/solid-state device manufacturingSolubilityAlkane
The embodiment of the invention relates to an A-A type conjugated polymer based on isoindigo-blue and a preparation method and application thereof.The structural general formula of the A-A type conjugated polymer based on isoindigo-blue is shown in the description, wherein Ar is an aromatic compound fragment, and R is alkane of C1-C32, alkenyl of C2-C32 and alkyne or ether oxygen or alkyl chain amines or sulfydryl of C2-C32; n is an integer larger than or equal to 4 and smaller than or equal to 100.According to the A-A type conjugated polymer based on isoindigo-blue, the solubility is good, the light absorbance is strong, the absorption range is wide, the sunshine utilization rate is high, the LUMO energy level is low, the A-A type conjugated polymer can replace fullerene and derivatives thereof as an acceptor material for preparing a full-polymer organic light detector and an organic solar cell.
Owner:UNIVERSITY OF CHINESE ACADEMY OF SCIENCES
Pyrrolodione-thiophene quinone compound, and preparation method and application thereof
ActiveCN103044430ARegulating SolubilityLower LUMO levelMethine/polymethine dyesOrganic chemistryKetoneSodium hydride
The invention discloses a pyrrolodione-thiophene quinone compound, and a preparation method and an application thereof. The pyrrolodione-thiophene quinone compound is as shown in a formula I. The preparation method comprises the following steps: mixing and performing a nucleophilic substitution reaction for sodium hydride, alpha-bromine-substituted pyrrolodione-thiophene oligomer as shown in a formula II and malononitrile sodium salt under a catalysis effect of tetra(triphenylphosphine) palladium (0) (Pd(PPh3)4) to generate di-anion intermediates, and adding saturated bromine water into the reaction system for an oxidation reaction, thereby obtaining the compound as shown in the formula I after the reaction completes. The compound is excellent in field-effect performance, and has an electron mobility of over 0.1cm<2>V<-1>s<-1>, wherein in an embodiment 1, for a material (a), an electron mobility of a field effect device of a semiconductor layer prepared by a vacuum vaporization method can reach to 0.3 cm<2>V<-1>s<-1>, and in an embodiment 2, for a material (b), an electron mobility of a field effect device with a semiconductor layer prepared by a spin coating method can reach to 0.35 cm<2>V<-1>s<-1>. A current on / off ratio of the compound is up to 10 <5>. The compound has stable performances in the air and has important application values.
Owner:INST OF CHEM CHINESE ACAD OF SCI
P-type organic semiconductor material, preparation method and display panel
InactiveCN111620886ALower LUMO levelDegree of planarization of polymer structureOrganic chemistrySolid-state devicesHole injection layerOrganic semiconductor
The invention provides a P-type organic semiconductor material, a preparation method and a display panel. According to the P-type organic semiconductor material, substituent groups are used for replacing hydrogen on a ring in a molecular structure, and the LUMO energy level of the obtained P-type organic semiconductor material is reduced. When the P-type organic semiconductor material is used as ahole injection layer and a hole transport layer of a light emitting device, the ability of the hole transport layer to form holes is enhanced, the injection of the holes from an anode to the hole transport layer is improved, and the hole mobility is improved accordingly, so that the driving voltage of the light emitting device can be reduced. On the other hand, the molecular structure planarization degree of the P-type organic semiconductor material is high, the hole mobility can be further improved, and hole injection and transmission are facilitated. The preparation method of the P-type organic semiconductor material provided by the invention is simple in synthesis steps and low in cost.
Owner:WUHAN CHINA STAR OPTOELECTRONICS SEMICON DISPLAY TECH CO LTD
1, 2, 4-oxadiazole micromolecule main body material as well as preparation method and application thereof
InactiveCN103951662ANovel structureEasy to purifyOrganic chemistrySolid-state devicesSolubilityElectron donor
The invention discloses a 1, 2, 4-oxadiazole micromolecule main body material. The 1, 2, 4-oxadiazole micromolecule main body material contains one or multiple electrophilic 1, 2, 4-oxadiazoles which serve as electron acceptor units, wherein the tail ends of molecules are connected to electron donor units. The invention also discloses a preparation method of the micromolecule main body material. The preparation method is characterized in that a dibromo substituted intermediate, namely a 1, 2, 4-oxadiazole compound is prepared by using bromobenzonitrile as a reaction raw material, and then electron donor units are connected to the dibromo substituted intermediate, namely the 1, 2, 4-oxadiazole compound through Suzuki coupling reaction. The invention also discloses an application of the 1, 2, 4-oxadiazole micromolecule main body material. The 1, 2, 4-oxadiazole micromolecule main body material has relatively good solubility and film-forming property, relatively strong eletrophilicity, relatively low LUMO (Lowest Unoccupied Molecular Orbital) energy level and relatively high electronic mobility.
Owner:SOUTH CHINA UNIV OF TECH
Trifluoromethyl carbonyl isoindigo derivative and synthesis method for same
InactiveCN102993190ALower LUMO levelPotential for applicationOrganic chemistrySolid-state devicesOrganic field-effect transistorCombinatorial chemistry
The invention relates to a trifluoromethyl carbonyl isoindigo derivative and a synthesis method for the same. The LUMO (lowest unoccupied molecular orbital) energy level of the compound is greatly lowered by introducing trifluoromethyl and carbonyl which strongly absorb electrons. The synthesis method for the compound is simple and high in reaction yield and has an application potential for organic field effect transistors. The structural formula of the compound prepared by the method is shown in the specification.
Owner:HUZHOU TEACHERS COLLEGE
Quinoid compounds and preparation method and applications thereof
ActiveCN108774119AGood planarityLower LUMO levelOrganic compound preparationSolid-state devicesOrganic solar cellSemiconductor materials
Quinoid compounds and a preparation method and applications thereof are disclosed. The general structure of the compounds is shown in the description. The structures of the compounds can be easily modified, and the compounds have characteristics of good molecular skeleton planarity, high self-assembling capability, low energy level of the highest unoccupied orbit (LUMO), narrow band gaps, and insensitivity to water and oxygen, and therefore the compounds as organic semiconductor materials can greatly improve hole and electron transmission capability so that the compounds are applied as n type(electron transmitting) materials and bipolar materials (capable of transmitting holes and electrons) into organic field effect transistors, organic solar cells, perovskite solar cells, organic thermoelectric and organic light-emitting devices, and the like.
Owner:TIANJIN UNIV
Blue ray organic electroluminescent material and preparation method and application thereof
InactiveCN104178116ASimple manufacturing methodEasy to operateGroup 8/9/10/18 element organic compoundsSolid-state devicesQuantum efficiencyHydrogen atom
The invention belongs to the field of photoelectric materials, and in particular relates to a blue ray organic electroluminescent material with the structural formula shown as P, wherein R is hydrogen atom or C1-C20 alkyl. The blue ray organic electroluminescent material has higher LUMO (lowest unoccupied molecular orbital) energy level and lower HOMO (highest occupied molecular orbital) energy level, is conducive to blue shift of material luminescent wavelength, and also has higher phosphorescence quantum efficiency and better dissolution properties and processing properties. The invention also provides a preparation method of the blue ray organic electroluminescent material and application of the blue ray organic electroluminescent material in organic electroluminescent devices.
Owner:OCEANS KING LIGHTING SCI&TECH CO LTD +2
Blue ray organic electroluminescent material and preparation method and application thereof
InactiveCN104178118ASimple manufacturing methodEasy to operateGroup 8/9/10/18 element organic compoundsSolid-state devicesQuantum efficiencyHydrogen atom
The invention belongs to the field of photoelectric materials, and in particular relates to a blue ray organic electroluminescent material with the structural formula shown as P, wherein R is hydrogen atom or C1-C20 alkyl. The blue ray organic electroluminescent material has higher LUMO (lowest unoccupied molecular orbital) energy level and lower HOMO (highest occupied molecular orbital) energy level, is conducive to blue shift of material luminescent wavelength, and also has higher phosphorescence quantum efficiency and better dissolution properties and processing properties. The invention also provides a preparation method of the blue ray organic electroluminescent material and application of the blue ray organic electroluminescent material in organic electroluminescent devices.
Owner:OCEANS KING LIGHTING SCI&TECH CO LTD +2
Annulated indigo receptor, and polymer, preparation method and applications thereof
ActiveCN110872376AThe synthetic route is simpleLower LUMO levelSolid-state devicesSemiconductor/solid-state device manufacturingPolymer scienceOrganic field-effect transistor
The invention discloses an annulated indigo receptor, and a polymer, a preparation method and applications thereof, wherein the structure of the polymer is represented by a formula I, and in the formula I, R is C1-C40 straight-chain or branched-chain alkyl. The invention also provides a preparation method of the polymer represented by the formula I. According to the invention, the raw materials are commercial products, the synthesis route is simple, and the synthesis method has universality; and the organic field effect transistor prepared by taking the novel annulated indigo polymer as an organic semiconductor layer has the highest hole mobility of 1.83 cm<2>V<-1>s<-1> and the highest electron mobility of 1.21 cm<2>V<-1>s<-1>, and has good application prospect in bipolar organic field effect transistor devices.
Owner:INST OF CHEM CHINESE ACAD OF SCI
Phosphine-containing fused heterocyclic compound as well as preparation method and application thereof
ActiveCN110483576AStrong electron-withdrawingLower LUMO levelGroup 5/15 element organic compoundsSolid-state devicesHigh electronOxygen
The invention provides a phosphine-containing fused heterocyclic compound as well as a preparation method and an application thereof. The phosphine-containing fused heterocyclic compound has a structure as shown in a formula I, a formula II, a formula III, a formula IV or a formula V. The phosphine-containing fused heterocyclic compound provided by the invention has double phosphorus-oxygen bonds,and an electron-withdrawing or large-volume Ar3 group and an Ar4 group are introduced; therefore, the material has a low LUMO energy level, a high electron transport capability and a high thermal decomposition temperature, can be used as an electron transport material of a photoelectric device, reduces the driving voltage of the device, improves the current efficiency, maintains thermal stabilityin the preparation and use processes of the device, and prolongs the service life of the device.
Owner:NINGBO LUMILAN NEW MATERIAL CO LTD
Organic electroluminescent material, preparation method of organic electroluminescent material and organic electroluminescent device
InactiveCN104560023AIncrease LUMO levelLower LUMO levelGroup 8/9/10/18 element organic compoundsSolid-state devicesIridiumPhotochemistry
The invention provides an organic electroluminescent material, a preparation method of the organic electroluminescent material and an organic electroluminescent device. The organic electroluminescent material has a general formula (P) as shown in the specification, wherein R1 is hydrogen atom, C1-20 linear alkyl, C1-20 branched alkyl, C1-20 linear alkoxy or C1-20 branched alkoxy. According to the organic electroluminescent material, 2-(2',4'-difluoro-3'-cyanophenyl) pyrimidine serving as a cyclometalated ligand and acetylacetone serving as an auxiliary ligand are adopted to synthesize a blue-light organic electroluminescent material iridium complex, and the illuminating color of the material is adjusted through chemical modification performed by introducing alkyl chain on the pyrimidine ring of the cyclometalated ligand, so that phosphorescence emission having blue emission wavelength and high luminescence efficiency can be obtained.
Owner:OCEANS KING LIGHTING SCI&TECH CO LTD +2
Polymer having unit obtained by condensation of difluorocyclopentanedione ring and aromatic ring, organic thin film using the same, and organic thin film device
InactiveUS8114956B2Good electron transport propertiesLower LUMO levelOrganic chemistryFinal product manufactureOrganic filmPolymer science
A polymer having a repeating unit represented by the following general formula (I) and a ferrocene-based reduction potential of −1.5 to −0.5 V as measured by a cyclic voltammetry methodwherein Ar1 represents a divalent aromatic hydrocarbon group or a divalent heterocyclic group, and these groups may be substituted by a substituent.
Owner:SUMITOMO CHEM CO LTD
Dithiophene compound as well as preparation method and application thereof
ActiveCN109836436AExtended conjugation propertiesStrong modifiabilityOrganic chemistrySolid-state devicesSolubilityOrganic electroluminescence
The invention belongs to the technical field of display, and particularly relates to a dithiophene compound as well as a preparation method and an application thereof. The dithiophene compound has a structure as shown in formula I) or formula II), dithiophene is used as a mother nucleus, the conjugated performance is good, an electron withdrawing group increasing the modification property of the mother nucleus is introduced, the LUMO energy level of the dithiophene compound is reduced, the thermal stability of the dithiophene compound is improved, and the solubility is improved; the preparation method is simple, the yield is high, the cost is reduced, the dithiophene compound can be applied to a n-type doping material, promotes the hole generation and carrier combination, can be applied toa hole transport material, promotes hole generation, improves the hole transport speed, and can be applied to an organic electroluminescent device to reduce driving voltage and keep use stability andthe luminous efficiency of the device, and a produced product is good in luminescence property and long in service life and has a good application prospect.
Owner:NINGBO LUMILAN NEW MATERIAL CO LTD +1
Thienopyrrole quinone compound, preparation method and semiconductor device comprising the material
ActiveCN105837598BGood planarityStrong self-assembly abilityOrganic chemistrySolid-state devicesOrganic field-effect transistorDevice material
Owner:DALIAN UNIV OF TECH
Polymer having unit obtained by condensation of difluorocyclopentanedione ring and aromatic ring, organic thin film using the same, and organic thin film device
InactiveUS20100084640A1Good electron transport propertiesLower LUMO levelOrganic chemistryFinal product manufactureReduction potentialPolymer
A polymer having a repeating unit represented by the following general formula (I) and a ferrocene-based reduction potential of −1.5 to −0.5 V as measured by a cyclic voltammetry methodwherein Ar1 represents a divalent aromatic hydrocarbon group or a divalent heterocyclic group, and these groups may be substituted by a substituent.
Owner:SUMITOMO CHEM CO LTD
Blue phosphorescent iridium metal complex and preparation method thereof and organic electroluminescent device
InactiveCN104327833AImprove luminous efficiencyIncrease LUMO levelGroup 8/9/10/18 element organic compoundsSolid-state devicesIridiumStructural formula
The invention relates to a blue phosphorescent iridium metal complex and a preparation method thereof and an organic electroluminescent device. The blue phosphorescent iridium metal complex has a structural formula as shown in the specification, wherein R is hydrogen, alkyl with the carbon atom number of 1-20 or alkoxy with the carbon atom number of 1-20. The blue phosphorescent iridium metal complex uses 2-(2 ', 6'-di (trifluoromethyl) pyridine-4 '-yl) pyrimidine as a ring metal ligand body structure, 2 ,4-di (trifluoromethyl)-5-( pyridine-2 '-yl) pyrrole as an auxiliary ligand, pyrimidinyl is conducive to enhancement of the LUMO (lowest unoccupied molecular orbital) level, pyridyl and electron withdrawing trifluoromethyl groups on the ring are conducive to the reduction of the HOMO (highest occupied molecular orbital) level, the luminescence wavelength can be effectively shifted to blue, the mulecular luminescence efficiency is improved, and trifluoromethyl and the high field strength auxiliary ligand 2 ,4-di (trifluoromethyl)-5-( pyridine-2 '-yl) pyrrole can improve the luminescent properties. The complex used in the organic electroluminescent device can improve the light emitting performance of the organic electroluminescent device.
Owner:OCEANS KING LIGHTING SCI&TECH CO LTD +2
Phosphorescence-emitting composition, and light-emitting element utilizing the composition
InactiveCN102066523AImprove luminous efficiencyImprove luminosityGroup 8/9/10/18 element organic compoundsElectroluminescent light sourcesPolycyclic compoundHydrogen atom
Disclosed is a composition comprising a compound having residues of at least two nitrogenated polycyclic compounds selected from the group consisting of nitrogenated polycyclic compounds represented by formulae (1-1), (1-2), (1-3) and (1-4) [wherein R's independently represent a hydrogen atom or a substituent and may be the same as or different from one another] and a phosphorescence-emitting compound.
Owner:SUMITOMO CHEM CO LTD
A-[pi]-A type conjugated semiconductor polymer based on pyridazino pyrroledione, and preparation method thereof
The present invention discloses an A-[pi]-A type conjugated semiconductor polymer based on pyridazino pyrroledione, and a preparation method thereof, wherein the structure formula of the conjugated polymer is defined in the specification, R1 is a C8-C24 alkyl chain, R2 is H or a C6-C12 alkoxy chain, and n is more than or equal to 1. According to the preparation method, a bithiophene-pyridazino pyrroledione dibromo monomer and a benzothiadiazole diboronic acid bis(pinacol)ester monomer are subjected to a Suzuki coupling reaction to prepare the conjugated polymer. According to the present invention, the advantages of the two units such as PPD and benzothiadiazole are combined, and the novel A-[pi]-A type semiconductor conjugated polymer capable of being subjected to solution processing is provided; and the molecule design of the semiconductor conjugated polymer is reasonable, the polymer has strong electron affinity and is expected to exhibit single electron transport property, and the semiconductor polymer can be used for organic thin film transistor devices.
![A-[pi]-A type conjugated semiconductor polymer based on pyridazino pyrroledione, and preparation method thereof](https://images-eureka.patsnap.com/patent_img/c6951539-4bd6-42af-8b48-39949111764d/HDA0000726893650000011.PNG "A-[pi]-A type conjugated semiconductor polymer based on pyridazino pyrroledione, and preparation method thereof")
![A-[pi]-A type conjugated semiconductor polymer based on pyridazino pyrroledione, and preparation method thereof](https://images-eureka.patsnap.com/patent_img/c6951539-4bd6-42af-8b48-39949111764d/HDA0000726893650000012.PNG "A-[pi]-A type conjugated semiconductor polymer based on pyridazino pyrroledione, and preparation method thereof")
![A-[pi]-A type conjugated semiconductor polymer based on pyridazino pyrroledione, and preparation method thereof](https://images-eureka.patsnap.com/patent_img/c6951539-4bd6-42af-8b48-39949111764d/HDA0000726893650000021.PNG "A-[pi]-A type conjugated semiconductor polymer based on pyridazino pyrroledione, and preparation method thereof")
Owner:黄山市开发投资集团有限公司
Novel benzo[b]thieno[3,2-b]benzo[b]thiophene disulfone monomer as well as copolymer and application of novel benzo[b]thieno[3,2-b]benzo[b]thiophene disulfone monomer
InactiveCN105778061ALower LUMO levelBroad absorption spectrumOrganic chemistrySulfoneOrganic semiconductor
The invention belongs to the field of synthesis of organic compounds, relates to a novel polymer applied to the field of organic semiconductor materials, and in particular relates to a benzo[b]thieno[3,2-b]benzo[b]thiophene disulfone monomer and a copolymer of the benzo[b]thieno[3,2-b]benzo[b]thiophene disulfone monomer. The benzo[b]thieno[3,2-b]benzo[b]thiophene disulfone monomer is a highly-symmetrical heteroatom-containing compound; sulfone is a strong electron withdrawing group and has very good planeness, so that the monomer can be used as a very good small-molecular acceptor material and can be applied to organic solar cells; the monomer has a very good luminous effect, so that the monomer can also be applied to light-emitting diodes.
![Novel benzo[b]thieno[3,2-b]benzo[b]thiophene disulfone monomer as well as copolymer and application of novel benzo[b]thieno[3,2-b]benzo[b]thiophene disulfone monomer](https://images-eureka.patsnap.com/patent_img/d8f99cb2-48c4-4712-a4c6-20ab6bb4a5b1/HDA0000952000180000011.PNG "Novel benzo[b]thieno[3,2-b]benzo[b]thiophene disulfone monomer as well as copolymer and application of novel benzo[b]thieno[3,2-b]benzo[b]thiophene disulfone monomer")
![Novel benzo[b]thieno[3,2-b]benzo[b]thiophene disulfone monomer as well as copolymer and application of novel benzo[b]thieno[3,2-b]benzo[b]thiophene disulfone monomer](https://images-eureka.patsnap.com/patent_img/d8f99cb2-48c4-4712-a4c6-20ab6bb4a5b1/HDA0000952000180000012.PNG "Novel benzo[b]thieno[3,2-b]benzo[b]thiophene disulfone monomer as well as copolymer and application of novel benzo[b]thieno[3,2-b]benzo[b]thiophene disulfone monomer")
![Novel benzo[b]thieno[3,2-b]benzo[b]thiophene disulfone monomer as well as copolymer and application of novel benzo[b]thieno[3,2-b]benzo[b]thiophene disulfone monomer](https://images-eureka.patsnap.com/patent_img/d8f99cb2-48c4-4712-a4c6-20ab6bb4a5b1/BDA0000952000170000021.PNG "Novel benzo[b]thieno[3,2-b]benzo[b]thiophene disulfone monomer as well as copolymer and application of novel benzo[b]thieno[3,2-b]benzo[b]thiophene disulfone monomer")
Owner:WUHAN UNIV OF TECH
Organic electroluminescent material, and preparation method and application thereof
InactiveCN104178110ASimple manufacturing methodEasy to operateOrganic chemistrySolid-state devicesQuantum efficiencySolubility
The invention belongs to the field of photoelectric materials, and specifically relates to an organic electroluminescent material. A structural formula is shown in the description. In the formula, R represents alkyl of C1-C20. The organic electroluminescent material has a relatively high LUMO energy level and relatively low HOMO energy level, and is beneficial to blue shift of luminescent wavelengths of the material. The organic electroluminescent material also has relatively high phosphorescence quantum efficiency, relatively good solubility and processability. The invention also provides a preparation method of the organic electroluminescent material, and an application of the organic electroluminescent material in an organic electroluminescent device.
Owner:OCEANS KING LIGHTING SCI&TECH CO LTD +2
Organic electroluminescent material, and preparation method and application thereof
InactiveCN104177423ASimple manufacturing methodEasy to operateGroup 8/9/10/18 element organic compoundsSolid-state devicesSolubilityQuantum efficiency
The invention belongs to the field of photoelectric materials, and specifically relates to an organic electroluminescent material. A structural formula is shown in the description. In the formula, R represents alkyl of C1-C20. The organic electroluminescent material has a relatively high LUMO energy level and relatively low HOMO energy level, and is beneficial to blue shift of luminescent wavelengths of the material. The organic electroluminescent material also has relatively high phosphorescence quantum efficiency, relatively good solubility and processability. The invention also provides a preparation method of the organic electroluminescent material, and an application of the organic electroluminescent material in an organic electroluminescent device.
Owner:OCEANS KING LIGHTING SCI&TECH CO LTD +2
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