689 results about "Sodium hydride" patented technology

The invention discloses an efficient combined regulator for easily-argillized copper oxide cobalt ore and a beneficiation method. The efficient combined regulator comprises the following components in parts by weight: 250-350 parts of sodium citrate and 1100-1200 parts of sodium hydrosulfide. Sodium citrate has high dispersing capacity, and the efficiency of selective adsorption between the argillization copper-cobalt ore and the medicament can be improved; meanwhile, the complexing ability of sodium citrate on ions, such as Fe, Ca and Mg, influencing agent adsorption on the surface of the ore is high, in addition, products obtained after complexing of the Fe, Ca and Mg ions can be dissolved in water, and action sites are provided for selective adsorption of a vulcanizing agent (NaHS) and a collecting agent amyl xanthate (PAX). According to the combined regulator and the beneficiation method provided by the invention, the problem of poor reagent selectivity in the flotation process of the argillization copper-cobalt ore can be obviously improved, the vulcanization effect of a vulcanizing agent is enhanced, and selective adsorption of a collecting agent is promoted, so that the recovery rate of copper and cobalt metals in the copper-cobalt oxide ore under the condition of serious ore argillization is improved.

The invention discloses a preparation method of high-purity diiodosilane, which comprises the following steps: firstly, preparing a p-phenylsilane solution from phenyl trichlorosilane and sodium hydride as raw materials, rectifying and purifying the p-phenylsilane solution, directly reacting the p-phenylsilane solution with iodine to generate diiodosilane, and reacting phenylsilane with iodine to directly generate diiodosilane; in the process of preparing diiodosilane from phenylsilane, conditions are mild, the reaction process is controllable, the reaction time is shortened by controlling the temperature in the synthesis process and increasing the pressure of a reaction system, hydrogen iodide overflow is reduced, sodium hydride is adopted as a reducing agent in the reaction process, and the yield of diiodosilane is increased. The solid waste can be recycled, the cost can be effectively reduced, and industrialization of diiodosilane is facilitated.

The invention relates to the technical field of biomedical treatment, and particularly discloses a biological valve treatment method and a biological valve dry piece. The bioprosthetic valve treatment method provided by the invention comprises the following steps: pretreatment, crosslinking, degreasing, anti-calcification and drying. In the anti-calcification step, an anti-calcification solution is used for treatment; the anti-calcification solution is a 0.08 to 0.12 M PBS (Phosphate Buffer Solution) containing 0.5 to 6 weight percent of ethanolamine and 0.1 to 0.5 weight percent of sodium borohydride; furthermore, the anti-calcification solution is a 0.08 to 0.12 M PBS (Phosphate Buffer Solution) containing 2 to 4 weight percent of ethanolamine and 0.2 to 0.4 weight percent of sodium borohydride; the invention further provides the bioprosthetic valve dry piece obtained through the bioprosthetic valve processing method. According to the bioprosthetic valve treatment method, the anti-calcification performance of the bioprosthetic valve can be improved, and the obtained bioprosthetic valve dry piece has good stability and storage performance.

The invention discloses a preparation method of nano silver powder, which comprises the following steps: under a stirring condition, respectively dissolving silver nitrate, a complexing agent and a reducing agent in deionized water to respectively obtain a silver nitrate solution, a complexing agent solution and a reducing agent solution with the concentration of 150-400g / L, dropwise adding the complexing agent solution into the silver nitrate solution, and stirring to obtain a nano silver powder solution; the preparation method comprises the following steps: adding a reducing agent solution into a reaction kettle, reacting to obtain a silver complexing solution, dropwise adding the silver complexing solution into the reducing agent solution, reacting to generate a silver simple substance, and carrying out solid-liquid separation, washing and drying on the silver simple substance to obtain spherical nano silver powder; according to the preparation method, reaction is carried out in a water system, a high-molecular compound is not used as a dispersing agent, potassium borohydride, sodium borohydride and vitamin C are used as reducing agents to reduce the silver complex, the prepared silver powder is good in dispersing performance, particles are spherical, the purity is high, the sintering resistance is low, the preparation method is simple, and the yield of the silver powder is as high as 97% or above.

The invention discloses low-VOC (volatile organic compound) environment-friendly end-capped mercapto silane as well as a preparation method and application thereof.The preparation method comprises the following steps: by taking chloroalkyl trialkoxysilane and linear alkyl polyether alcohol as raw materials, reacting to form an intermediate c; reacting alkyl acyl chloride with sodium sulfide or sodium hydrosulfide to form an intermediate e; and reacting the intermediate c with the intermediate e to obtain a final product. Silane is used as a rubber auxiliary agent, so that the volatilization amount of alcohols in the internal mixing process of a rubber compound can be greatly reduced, the emission amount of VOC during operation is reduced, meanwhile, the vulcanization performance of a rubber material can be improved, the scorching time of the rubber material can be prolonged, the reinforcing effect of vulcanized rubber can be improved, the physical and mechanical properties of the vulcanized rubber can be improved, and the wet skid resistance of tread rubber can be improved; therefore, the environment-friendly rubber auxiliary agent is a multifunctional environment-friendly rubber auxiliary agent.

The invention relates to an antistatic film and a preparation method thereof, and belongs to the technical field of polymer film materials. The antistatic film is prepared from the following components in parts by weight: 100 parts of PP resin, 5 to 8 parts of hydrogenated petroleum resin, 4.5 to 5.5 parts of conductive filler, 1.2 to 1.6 parts of antistatic additive, 0.1 to 0.12 part of antioxidant, 0.08 to 0.1 part of light stabilizer and 2.5 to 3 parts of lubricant, the preparation method comprises the following steps: carrying out amine ester exchange on methyl acrylate and diethylenetriamine under the catalysis of sodium hydride to prepare a double-bond-terminated amide compound, namely an amidated matrix, carrying out addition on mercaptopropyltrimethoxysilane and the amidated matrix under the initiation of ultraviolet radiation, and introducing a methoxysilane structure to the end part of the amidated matrix for modification, so as to obtain the antistatic additive. Finally, bromopropane and residual amido of the silanization intermediate are subjected to quaternization treatment, and the antistatic auxiliary is obtained. The film material is endowed with good antistatic performance and packaging performance through the interaction of the antistatic auxiliaries.

The invention discloses an arsenic removal method for purifying waste acid, and belongs to the technical field of sulfuric acid preparation. The method comprises the following steps: settling wastewater, and carrying out filter pressing on slurry through a first filter press; in the first-stage reaction tank, the waste acid reacts with a desulfurizing agent from a sodium hydrosulfide preparation tank, and after the reaction is completed, the waste acid is sent to a first-stage FBL filter to be filtered; in the second-stage reaction tank, the waste acid reacts with a desulfurizing agent from the sodium hydrosulfide preparation tank, and after the reaction is completed, the waste acid is sent to a second-stage FBL filter to be filtered; the filtrate of the second-stage FBL filter is sent to a dynamic wave scrubber for recycling; a flocculating agent is added into the first-stage FBL filter and the second-stage FBL filter; tail gas of the first-stage reaction tank, the first-stage FBL filter, the second-stage reaction tank, the first-stage FBL filter and the sodium hydrosulfide preparation tank is sent to a spray tower, washing liquid containing sodium hydrosulfide and sodium sulfide in the spray tower is sent to the sodium hydrosulfide preparation tank, and sodium hydrosulfide solids are added into the sodium hydrosulfide preparation tank.

The invention relates to the technical field of catalysts and methanol preparation through CO2 hydrogenation, in particular to a preparation method of a catalyst, a product and application. The preparation method of the catalyst comprises the following steps: adding a copper-zinc-aluminum catalyst into a cerous nitrate aqueous solution, uniformly mixing, and stirring in a water bath to obtain a mixed solution; adding an alkali solution of NaBH4 into the mixed solution, and reacting to obtain a precipitate; and carrying out ultrasonic treatment on the precipitate, washing, drying, grinding and roasting to obtain the catalyst. The assistant Ce is introduced into the copper-zinc-aluminum catalyst, sodium borohydride (NaBH4) is used for reduction, Ce < 4 + > / Ce < 3 + > and Cu < 2 + > / Cu < delta + > / Cu < 0 > redox electron pairs are constructed, an electron transfer pathway is established, and the catalytic performance of methanol preparation through CO2 hydrogenation is improved.

The present invention relates to the technical field of nanofiltration membranes, and particularly relates to a preparation method for a nanofiltration membrane for regulating and controlling membrane surface charges. The preparation method comprises: step 1: (1) sequentially adding piperazine, a fiber additive, an ionic liquid and polyvinyl pyrrolidone into deionized water to obtain a water phase; and (2) adding trimesoyl chloride into normal hexane to serve as an oil phase; step 2, dipping a base membrane in the water phase for 1-3 minutes, and removing the redundant water phase; transferring same into the oil phase and subjecting same to polymerization for 2-3 minutes, and removing the redundant solution; and curing same at 80-85ºC for 5-6 minutes, and dipping same in deionized water for 1-2 days, so as to obtain a composite base membrane; and step 3, firstly placing the composite base membrane in a sodium hypochlorite solution for a primary post-treatment, and cleaning same; and transferring same into a sodium hydrosulfide solution for a secondary post-treatment, washing same until neutral, soaking same in deionized water for 1-3 days, and drying same to obtain a nanofiltration membrane.

The utility model provides a sodium hydrosulfide concentration and purification device, and belongs to the technical field of sodium hydrosulfide processing. Comprising an evaporation tank and a separator, a heating chamber is fixed on the inner wall of the evaporation tank, a large flow channel is arranged close to the center of the heating chamber, a small flow channel is arranged on one side of the heating chamber close to the inner wall of the evaporation tank, a central circulating pipe is fixed on the inner wall of the large flow channel, and the evaporation tank is connected with the separator through a pipeline. Through the arrangement of the waterproof motor, the driving fan blade, the driven fan blade and the scraping plate, the waterproof motor drives the driving fan blade to rotate to enable sodium hydrosulfide in the central circulating pipe to forcibly flow downwards, so that the circulating efficiency of the sodium hydrosulfide in the evaporating tank is enhanced, and the evaporating efficiency of the sodium hydrosulfide is improved; sodium hydrosulfide drives the driven fan blades to rotate, the driven fan blades drive the scraping plates to rotate on the inner walls of the small flow channels, the scraping plates scrape off sodium hydrosulfide crystals in the small flow channels, the crystals are prevented from affecting heat transfer, and the evaporation efficiency is further guaranteed.

The invention relates to the technical field of electro-catalysis materials, and discloses an iron-doped copper oxide catalyst, a preparation method thereof and application of the iron-doped copper oxide catalyst in electro-catalysis of nitrate to synthesize ammonia. The method comprises the steps that CuCl2 serves as a metal precursor, ascorbic acid serves as a reducing agent, and Cu2O nanoparticles are obtained through a hydrothermal precipitation method; then, Cu2O is added into a solution containing FeSO4, sodium borohydride is added, centrifugal washing and drying are carried out, and the iron-doped copper oxide nitrate electroreduction catalyst which is rich in defects and uniform in metal dispersion is obtained through a programmed heating pyrolysis reduction method. The electro-catalytic material obtained by adopting the method disclosed by the invention has a relatively large catalytic active area and relatively abundant defect sites and oxygen vacancies, the nitrate adsorption and activation effects are improved, the supply of active hydrogen is promoted by constructing stable heterogeneous active sites, the product selectivity and Faraday efficiency in NO3RR are improved, and the electro-catalytic material has good durability.

The invention provides a GelMA microneedle patch loaded with chromogenic gold nano bipyramids and a preparation method thereof.The method comprises the steps that citric acid, chloroauric acid and a CTAC solution are mixed, then sodium borohydride is added, and a seed solution is obtained through stirring and standing; mixing chloroauric acid, silver nitrate, hydrochloric acid and CTAB (cetyltrimethyl ammonium bromide), and sequentially adding ascorbic acid and the seed solution to obtain a growth solution; carrying out centrifugation, morphology regulation and chemical etching purification to obtain a chromogenic gold nano bipyramid solution; the preparation method comprises the following steps: reacting gelatin with methacrylic anhydride in PBS, dialyzing and freeze-drying to obtain GelMA; dissolving GelMA in the gold nanoparticle bipyramid solution, and adding a photoinitiator LAP to obtain a mixed precursor solution; and the GelMA microneedle patch loaded with the gold nano bipyramid is prepared through mold casting, centrifugation, ultraviolet light crosslinking and drying demolding. The microneedle extraction and gold nano bipyramid color development integrated scheme is initiated, blood sampling is not needed, the dermis interstitial fluid is extracted in a minimally invasive mode through the microneedle, detection pain and trauma are reduced, the cross infection risk of blood treatment is avoided, and the microneedle microneedle microneedle microneedle microneedle microneedle microneedle microneedle microneedle microneedle microneedle microneedle microneedle microneedle microneedle microneedle microneedle microneedle microneedle microneedle microneedle microneedle microneedle microneedle

The invention discloses a synthesis and purification method of electronic-grade diborane, and relates to the technical field of diborane synthesis, and the synthesis and purification method has the advantages that cation 1-ethyl-3-methylimidazole in ionic liquid has a relatively large volume and a specific spatial configuration; the ionic liquid can be close to reactants sodium borohydride and hydrogen through intermolecular force, meanwhile, the anion bis (trifluoromethanesulfonyl) imide salt has high polarity and can attract reactant molecules with opposite charges, so that the ionic liquid makes full contact with the reactants, sulfolane has high dissolving capacity and can well dissolve sodium borohydride and hydrogen, and the ionic liquid can be separated from the reactants. Sodium borohydride and hydrogen are uniformly distributed in a mixed solvent, the sodium borohydride and hydrogen are efficiently reacted at proper temperature and pressure to generate high-purity diborane under the synergistic effect of the sodium borohydride and the hydrogen, sufficient contact of reactants is ensured by timely stirring in the reaction process, the reaction efficiency and the diborane yield are greatly improved, and the yield of the diborane is increased. And favorable conditions are created for subsequent preparation of electronic-grade diborane.

The invention discloses a preparation method of platinum-based multi-metal aerogel and application of the platinum-based multi-metal aerogel in an electro-catalysis hydrogen evolution reaction. The method comprises the following steps: firstly, sequentially adding platinum salt and other metal salts into pure water, uniformly mixing, then adding a sodium borohydride solution, uniformly mixing, quickly freezing the reaction solution with liquid nitrogen, melting to obtain wet gel, and then washing and drying the wet gel to obtain the aerogel. The obtained metal aerogel is applied to a hydrogen evolution electrocatalyst and shows excellent catalytic activity under an alkaline condition. The preparation method has the advantages that the synthesis process is simple, convenient and efficient, regulation and optimization of an electronic structure can be realized through interaction among multiple metals, so that the catalytic performance is improved, the porous structure of the aerogel effectively provides a high-speed mass transfer channel, the catalytic activity is improved, and the preparation method is suitable for industrial production. And a solid foundation is laid for wide application of the metal aerogel material in the field of industrial chemical engineering.

The invention discloses a synthesis method of 2, 4, 5-trifluorophenylacetic acid, which comprises the following steps: by taking cheap and easily available o-chloronitrobenzene as a raw material, reacting with sodium nitrate in a sulfuric acid and trifluoroacetic acid system, separating generated 2, 4-dinitrochlorobenzene through melt crystallization, and continuing to synthesize 2, 4-dinitrochlorobenzene in methyl chloroacetate to obtain 2, 4, 5-trifluorophenylacetic acid. The method comprises the following steps: carrying out indirect aromatic nucleophilic substitution reaction on 2, 4-dinitrophenylacetic acid under the condition of sodium hydride to generate 5-chloro-2, 4-dinitrophenylacetic acid methyl ester, separating, carrying out fluorination reaction on the 5-chloro-2, 4-dinitrophenylacetic acid methyl ester and potassium fluoride under the action of a phase transfer catalyst, carrying out rectification separation to obtain 2, 4, 5-trifluorophenylacetic acid, and carrying out hydrolytic acidification on the 2, 4, 5-trifluorophenylacetic acid in a sodium hydroxide aqueous solution to obtain 2, 4, 5-trifluorophenylacetic acid. And the process route is safer, more environment-friendly, more efficient and lower in cost.

The present invention discloses a nano copper-based catalyst, its preparation method, and its application in the electrocatalytic reduction of carbon dioxide and carbon monoxide. Copper chloride (or copper nitrate, copper acetate) is dissolved in ultrapure water, and a sodium borohydride solution is added dropwise. Stir at room temperature for 5-60 min, filter, and dry to obtain a nano copper catalyst. Further, through a displacement reaction, nano copper-palladium and copper-silver catalysts are obtained. The present invention is applied to the electrocatalytic reduction of carbon monoxide. In a membrane electrode assembly (MEA) electrolyzer, the Faraday efficiency of multi-carbon products (C2+) reaches up to 95%, the partial current density reaches up to 3 A cm-2, and the overall electrolyzer energy efficiency reaches up to 39%. It can stably electrolyze for 30 hours at 1 A cm-2. This nano copper catalyst is applied to the electrocatalytic reduction of carbon dioxide. In an MEA electrolyzer, the Faraday efficiency of C2+ reaches up to 66%, and the partial current density reaches up to 331 mA cm-2.

The invention relates to a method for continuously producing 2, 5-dihydroxy-1, 4-dithiane, which comprises the following steps: pre-cooling a chloroacetaldehyde solution and a sodium hydrosulfide solution, mixing in a pipeline mixer, reacting in a reaction kettle, continuously producing, and post-treating to obtain a finished product, the molar yield is more than 95%, the content is more than 98%, the melting point is 140-145 DEG C, and the appearance is white granular crystal. And the requirements of downstream products can be better met. The method has the characteristics of high efficiency, continuous production, stable process, high product quality, high yield, low cost, environmental friendliness and convenience in industrial popularization.

The invention relates to the technical field of chemical intermediates, and particularly discloses a preparation method of a givelastat intermediate.According to the preparation method, an initiator compound 5 can be synthesized by adopting cheap 2-hydroxy-6-naphthoic acid (CAS: 16712-64-4, 141 yuan / kg), and the preparation method is different from a method in the prior art. A gemvelastat intermediate compound 4 is synthesized from a compound 5 through a three-step reaction, compared with the prior art, the yield is high, industrial amplification production is more facilitated, in the process of synthesizing a compound 6 from the compound 5, acetonitrile can be adopted as a cyanide source in a reaction system, activated hydroxyl is subjected to a coupling reaction, and the yield is high. In the process of synthesizing a compound 6 from a compound 7 instead of a traditional metal cyanide, or in the process of synthesizing a compound 6 from another compound 5, a cheap cuprous cyanide and cuprous iodide system is adopted for a coupling reaction, and in the process of synthesizing a compound 4 from a compound 7, an acetic acid and sodium triacetoxyborohydride reaction system is adopted, so that the compound 6 is synthesized. And the important intermediate of the givelastat can be obtained with high yield.

The invention provides a continuous high-phosphorus chemical nickel plating method, which comprises the following steps: preparing a chemical plating solution containing nickel salt, a complexing agent and an additive, adding a first reducing agent and a second reducing agent into the plating solution according to a mass ratio of (3-5): (1-2), the second reducing agent is one or more of lithium aluminum hydride, sodium borohydride, propionic acid or succinic acid; and the PH value of the plating solution needs to be adjusted to 4.5-5.5, the temperature of the plating solution is controlled to be 80-90 DEG C, and then continuous plating operation is conducted. The first reducing agent can stably release active phosphorus atoms at a low temperature, a rich phosphorus source is provided for the plating layer, and it is guaranteed that the plating layer reaches the high phosphorus content; the second reducing agent can effectively promote the reduction deposition process of nickel ions, and the deposition rate is increased. The two reducing agent components cooperate with each other, so that the plating solution keeps high stability, fluctuation of the plating solution components is effectively inhibited, and the consistency and stability of the plating layer quality are obviously improved.

The invention discloses an amino alcohol nickel complex as well as a preparation method and application thereof, and belongs to the technical field of organic metal synthesis. The molecular formula of the amino alcohol nickel complex is Ni [OCR1R2 (CH2) mNR3R4] 2, comprising the following raw materials: a nickel-containing complex, 60wt.% of NaH and HOCR1R2 (CH2) mNR3R4, the preparation method specifically comprises the following steps: (1) under the protection of nitrogen, mixing a nickel-containing complex, 60wt.% NaH, HOCR1R2 (CH2) mNR3R4 and toluene, carrying out heating reaction, and carrying out heating reaction again; and (2) filtering, concentrating, cooling, filtering again, and washing to obtain the product. The nickel-containing complex, sodium hydride and amino alcohol are synthesized into the amino alcohol nickel complex through a one-pot method, the raw materials are simple, easy to obtain and convenient to store, expensive active intermediates do not need to be synthesized or purchased, and the cost and risk of amplified production are reduced. Meanwhile, the purification method of the product is improved, the high-purity amino alcohol nickel complex is obtained through a low-temperature crystallization method, operation is safe and convenient, the industrial purification efficiency is improved, and the purity of the obtained product is as high as 6N-7N through ICP-MS testing.

The invention discloses a seawater initiation preparation method of metal wet gel and aerogel and application of the seawater initiation preparation method in electro-catalysis ethylene glycol oxidation. Comprising the following steps: 1) sequentially adding a metal salt, sodium citrate and a reducing agent into pure water, 2) adding seawater into a reaction solution to obtain wet gel, and 3) washing and drying the wet gel to obtain the aerogel. Seawater can be used for replacing expensive drugs used in a large amount in a salting-out method and an excessive sodium borohydride method, so that the metal nanoparticle solution is unstable, the metal aerogel material is prepared, and the preparation cost of the metal aerogel is greatly reduced. The metal aerogel obtained by the invention shows excellent catalytic performance in the application of electro-catalysis of ethylene glycol oxidation.

The invention discloses a synthesis method of N, N '-bis-(2, 2, 6, 6-tetramethyl-4-piperidyl)-1, 6-hexamethylenediamine, which comprises the following steps: dropwise adding hexamethylenediamine into a mixture of 2, 2, 6, 6-tetramethyl-4-piperidone and an organic solvent, heating to react, cooling after the reaction is completed, adding a sodium borohydride solid into the mixture in batches, and heating to continue the reaction, so as to obtain the N, N'-bis-(2, 2, 6, 6-tetramethyl-4-piperidyl)-1, 6-hexamethylenediamine, namely the N, N '-bis-(2, 2, 6, 6-tetramethyl-4-piperidyl)-1, 6-hexamethylenediamine. After the reaction is finished, decompressing and spin-drying; the preparation method comprises the following steps: adding 1, 2, 6, 6-tetramethyl-4-piperidinyl-1, 6-hexamethylenediamine into an organic solvent, pulping residues, filtering, washing a filter cake with dichloromethane, combining filtrate, and spin-drying to obtain the N, N '-bis-(2, 2, 6, 6-tetramethyl-4-piperidinyl)-1, 6-hexamethylenediamine. The molar ratio of the 2, 2, 6, 6-tetramethyl-4-piperidone to the hexamethylenediamine to the sodium borohydride is (2.0 to 2.1): 1.0: (1.2 to 2.5); sodium borohydride is adopted to replace a traditional noble metal catalyst, high-pressure hydrogenation reaction is avoided, reaction conditions are mild, operation is safe, and cost is low; the purity and the yield of the product are effectively improved.

A method for hydrogen (H2) generation includes contacting a graphite-phase carbon nitride cobalt oxide and magnesium aluminum oxide nanocomposite (g-C3N4@CoO / MgAl2O4) with sodium borohydride (NaBH4) in water (H2O) and hydrolyzing the sodium borohydride to generate hydrogen. The g-C3N4@CoO / MgAl2O4 nanocomposite comprises a graphite-phase carbon nitride (g-C3N4) in an amount of 5 to 15 percent by weight (wt. %), cobalt oxide in an amount of 1 to 10 wt. %, and magnesium aluminum oxide (MgAl2O4) in an amount of 75 to 95 wt. % based on a total weight of the g-C3N4@CoO / MgAl2O4 nanocomposite.

This application provides a method for preparing compound I-b or a pharmaceutically acceptable salt thereof, wherein (S)-N-methylamino-1-(2-thiophene)-1-propanol reacts with 4-fluorobenzo[1,3]dioxolane in a system containing sodium hydride and potassium benzoate to obtain compound I-b. This method has short steps, mild reaction conditions, and is simple to operate, making it suitable for industrial scale-up; moreover, the obtained product has high purity and low isomer content.

The invention discloses a zinc / cobalt-based spinel oxide composite material catalyst as well as a preparation method and application thereof. The zinc / cobalt-based spinel oxide compound catalyst is prepared by taking zinc sulfate, cobalt nitrate and potassium oxalate as metal nodes and ligands through hydrothermal treatment and calcination. The ZnCo2O4 disclosed by the invention is applied to reduction of p-nitrophenol as a high-efficiency catalyst, and under the condition of room temperature, sodium borohydride is used as a reducing agent, and the efficiency of converting p-nitrophenol into p-aminophenol within 4 minutes can reach 100%. The zinc / cobalt-based spinel oxide composite material catalyst is synthesized by adopting a simple and environment-friendly method, the sodium p-borohydride has extremely high catalytic activity in reduction of p-nitrophenol, p-nitrophenol with relatively high toxicity can be reduced into p-aminophenol with relatively low toxicity, and the zinc / cobalt-based spinel oxide composite material catalyst has a potential application prospect in the fields of sewage treatment and the like.

The invention relates to the technical field of chemical synthesis, and discloses a method for preparing 2, 5-furandicarboxylic acid, which comprises the following steps: dispersing cobalt nitrate and nickel sulfate into an aqueous solution of polyvinylpyrrolidone at room temperature; adding a sodium borohydride solution to obtain nano colloid; preparing an aqueous suspension of cerium oxide, and adding the aqueous suspension into the nano colloid; centrifugally filtering, and recovering a solid product; washing the solid product; centrifuging, putting solid powder obtained after centrifuging into a drying oven, and drying; and calcining and grinding the solid powder to finally prepare the Co-Ni / CeO2 catalyst. And dissolving 5-hydroxymethylfurfural in water at normal temperature, adding the prepared Co-Ni / CeO2 catalyst and a sodium hypochlorite solution, reacting, and filtering to remove the catalyst, thereby obtaining the 2, 5-furandicarboxylic acid. The method disclosed by the invention has the advantages of no use of strong base, low reaction temperature, short reaction time, few byproducts, greenness and sustainability.

The invention relates to the technical field of medicines, in particular to a preparation method of calcium L-5-methyltetrahydrofolate. According to the method, N-(4-aminobenzoyl)-L-glutamic acid, 2, 4, 5-triamino-6-hydroxypyrimidine sulfate and propane trihalide are adopted as starting raw materials, and tetrahydrofolic acid is synthesized through a one-pot method; compared with synthesis of L-5-methyl calcium tetrahydrofolate by using high-purity folic acid as an initial raw material, the process route does not involve use of chemical reagents such as sodium borohydride, zinc powder and some noble metal catalysts any more, the reaction is easier to control, the cost is lower, the safety is higher, the method is more environmentally friendly, and industrial production is easier to carry out.

The invention discloses a preparation method of an amino-functionalized FeOOH nanosheet for treating uranium-containing wastewater, and particularly relates to the technical field of adsorption materials. The preparation method comprises the following steps: adding deionized water into a precursor of CTAB and iron, adjusting the pH value of the solution to be acidic, and stirring to obtain a first solution; dissolving sodium borohydride in deionized water, and stirring to form a sodium borohydride solution, so as to obtain a second solution; dropwise adding the second solution into the first solution and stirring; centrifuging the mixed solution, cleaning for multiple times, and carrying out vacuum drying to obtain an alpha-FeOOH sample; adding methylbenzene into the alpha-FeOOH and carrying out ultrasonic treatment; adjusting the pH value of the mixed solution by using an acid regulator, then heating, slowly dropwise adding APTES, and continuously stirring; and centrifuging the mixed solution, cleaning for multiple times, and carrying out vacuum drying to obtain an alpha-FeOOH-NH2 sample. By the adoption of the technical scheme, the problem that adsorption of the FeOOH to uranium is seriously limited due to the hydrophobic characteristic and poor selectivity of the FeOOH is solved, and wide application prospects are achieved in the radioactive uranium extraction technology of the product.

The invention relates to a RuSe2-MoSe2 / NF heterojunction bifunctional catalyst for fully hydrolyzed seawater as well as a preparation method and application of the RuSe2-MoSe2 / NF heterojunction bifunctional catalyst, and belongs to the technical field of seawater electrolysis electrocatalysis. The preparation method of the bifunctional catalyst comprises the following steps: (1) mixing deionized water and absolute ethyl alcohol, and magnetically stirring to obtain a mixed solvent; then adding sodium borohydride and selenium powder into the mixed solvent, and stirring until the mixture is completely dispersed to obtain a mixed solution; adding sodium molybdate dehydrate and ruthenium trichloride into the mixed solution, introducing high-purity nitrogen, replacing air, and continuing magnetic stirring to obtain a dark brown precursor mixed solution; and (2) completely immersing the pretreated nickel foam NF in the precursor mixed solution, carrying out hydrothermal reaction, cooling to room temperature after the reaction, taking out the nickel foam NF, washing with deionized water for 3-5 times, then washing with absolute ethyl alcohol for 3-5 times, and drying to obtain the nickel foam NF. The bifunctional catalyst provided by the invention can efficiently catalyze a hydrogen evolution reaction and an oxygen evolution reaction in seawater at the same time.

The invention relates to the technical field of high-molecular polymer synthesis, and particularly discloses a cracking method of high-alkalinity polysulfide rubber latex, which comprises the following steps: S1, carrying out mother liquor separation on polysulfide rubber latex, and then washing for 0-2 times to obtain the high-alkalinity polysulfide rubber latex; and S2, cracking the high-alkalinity polysulfide rubber latex into liquid polysulfide rubber by using a cracking agent composed of sodium sulfite, sodium hydrogen sulfite and sodium hydrosulfide, wherein the molecular weight of the liquid polysulfide rubber is 1000-5000. Compared with the prior art, the cracking agent composed of sodium sulfite, sodium hydrogen sulfite and sodium hydrosulfide is adopted, high-alkalinity polysulfide rubber latex can be cracked, the washing frequency is reduced, the process efficiency is improved, and the overall polysulfide rubber production efficiency is indirectly improved; meanwhile, the wastewater discharge amount is reduced, and the subsequent wastewater treatment cost is reduced. The raw materials required by the cracking agent are easy to obtain and low in cost.