The invention provides a ligand compound and a preparation method thereof, a complex and a preparation method and application thereof, and belongs to the technical field of
polyolefin, the ligand compound has a structure as shown in formula (I) or formula (II): # imgabs 0 # formula (I) and # imgabs 1 # formula (II); b1, b2, b3, R1 and R2 are respectively and independently selected from any one of
hydrogen, substituted or unsubstituted
alkyl with 1 to 5 carbon atoms, alkenyl with 2 to 6 carbon atoms, alkynyl with 2 to 6 carbon atoms, alkoxy with 1 to 5 carbon atoms,
aryl with 6 to 30 carbon atoms and fused ring
aryl with 10 to 50 carbon atoms; r1 and R2 are connected to form a ring or are not connected to form a ring; b1, b2, b3, b4 and b5 are respectively and independently selected from any one of
hydrogen, substituted or unsubstituted C1-C5
alkyl, C2-C6 alkenyl, C2-C6 alkynyl and C1-C5 alkoxy; c1, c2 and c3 are respectively and independently selected from any one of
hydrogen, substituted or unsubstituted
alkyl with 1 to 5 carbon atoms, alkenyl with 2 to 6 carbon atoms, alkynyl with 2 to 6 carbon atoms, alkoxy with 1 to 5 carbon atoms and phenoxy; r1, R2, R3 and R4 are respectively and independently selected from any one of hydrogen, substituted or unsubstituted C1-C5 alkyl, C3-C10 cycloalkyl and substituted phenyl.