The invention belongs to the technical field of nano material preparation, discloses a zero-dimensional
perovskite nanocrystalline large-scale preparation method based on a room-temperature self-
assembly strategy, and aims to solve the technical problems that in the prior art, the uniformity of a product is poor, high luminous efficiency and
conductivity are difficult to achieve at the same time, and the
wavelength cannot be accurately regulated and controlled. According to the method, a water-in-oil
microemulsion system is adopted as a
nanoreactor, and the high uniformity of
nanocrystal growth is fundamentally guaranteed through a confinement reaction. The composition creatively comprises two ligands: one ligand is a pi-conjugated conductive main functional ligand with surface
passivation and charge transfer functions, which solves the problem of poor
conductivity caused by the traditional insulating ligand while ensuring high
photoluminescence efficiency, and the other ligand is a competitive tuning ligand which forms dynamic competitive balance with the main ligand. The key problems of product uniformity,
conductivity,
wavelength controllability and the like are synergistically solved, and the prepared
nanocrystal has high optical purity, high
quantum yield and excellent conductivity.