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121 results about "Mercuric ion" patented technology

Magnetic nano composite adsorbent as well as preparation method and application thereof

The invention belongs to the technical field of wastewater treatment, and discloses a magnetic nano composite adsorbent as well as a preparation method and application thereof. The preparation method comprises the following steps: dissolving a divalent iron salt and a trivalent iron salt in water, adding ammonia water under a protective gas, and carrying out a stirring reaction at a rotating speed of 350-600 rpm to prepare Fe3O4 nanoparticles; the preparation method comprises the following steps: dispersing Fe3O4 nanoparticles in a mixed solution of acrylic acid and ethidene diamine, then adding an initiator, and carrying out a stirring reaction at a rotating speed of 150-300 rpm to prepare the magnetic nano composite adsorbent. The magnetic nano-composite adsorbent provided by the invention can efficiently remove lead ions in wastewater, is not influenced by mercury ions and copper ions, also has relatively good adsorption capacity on the mercury ions and the copper ions, and can treat various heavy metal ions in the wastewater at the same time. The magnetic nano composite adsorbent is easy to separate and good in reusability.
Owner:CHENGDU HUIBIAO TESTING TECH CO LTD

Quinoline matrix-based mercury ion detection fluorescent probe as well as preparation method and application thereof

The invention discloses a mercury ion detection fluorescent probe based on quinoline as well as a preparation method and application of the mercury ion detection fluorescent probe. The fluorescent probe and a structural formula of the fluorescent probe are shown as a formula I in the specification. A quinoline derivative, namely 2-methyl-7-hydroxyquinoline, is used as a fluorescent chromophore, a thioester group is used as a recognition group, and the prepared fluorescent probe shows high sensitivity and high selectivity on Hg < 2 + > in a solution. The preparation method of the fluorescent probe is simple in steps, raw materials are easy to obtain, and the obtained product is a white flocculent solid, is easy to store, has a wide application prospect and can be produced and applied on a large scale.
Owner:JIANGSU UNIV OF SCI & TECH

Method for detecting metal mercury in food

The invention discloses a method for detecting metal mercury in food, and relates to the technical field of food detection. Comprising the following steps: extracting a mercury-containing solution from a to-be-detected food sample, preparing a ferrous sulfate / graphene oxide nano composite material, enriching mercury ions in the mercury-containing solution by using the nano composite material, and quantitatively analyzing the mercury ions on the nano composite material by adopting atomic fluorescence spectrometry. According to the method, the collected food sample is subjected to digestion pretreatment, the mercury-containing solution is prepared, metal mercury in the food can be fully and effectively extracted, the ferrous sulfate / graphene oxide nanocomposite is prepared, mercury ions on the nanocomposite are quantitatively analyzed through atomic fluorescence spectrometry, metal mercury detection is achieved, and the detection accuracy is high. The mercury ions in the mercury-containing solution can be fully adsorbed and enriched in the whole detection process, pollution source introduction and mercury loss are avoided, the accuracy of the detection result is ensured, the detection process is simple and clear and easy to operate, and the detection period is shortened to a certain extent.
Owner:AGRI PRODS PROCESSING RES INST CHINESE ACAD OF TROPICAL AGRI SCI

Machine learning enhanced silver-based covalent organic framework nanozyme colorimetric detection method and application thereof

The application discloses a machine learning enhanced silver-based covalent organic framework nanoscale enzyme colorimetric detection method and application thereof, and constructs a covalent organic framework loaded with silver nanoparticles to form a nanoscale enzyme with oxidase-like activity, which is used for rapid visual detection of mercury ions. When mercury ions exist, silver ions in the COF-AgNPs can form silver amalgam with the mercury ions, thereby catalyzing the colorless substrate 3,3',5,5'-tetramethylbenzidine to generate a blue oxidation product oxTMB. The content of mercury can be judged by detecting the absorbance and RGB value changes of the color development reaction. Meanwhile, a machine learning data analysis strategy of a support vector machine model is adopted to perform five-fold stratified cross-validation analysis on the obtained absorbance and RGB values, so that the detection range is expanded and the detection sensitivity is improved.
Owner:JIANGSU OCEAN UNIV

An organic polymer for rapid detection and degradation of mercury ions and a preparation method and application thereof

The application relates to an organic polymer for rapid detection and degradation of mercury ions, and belongs to the technical field of preparation and application of organic functional materials. The structural formula of the organic polymer is shown as formula (IV); the luminescence performance of the polymer is derived from a conjugated organic polymer skeleton, and the recognition function for mercury ions is derived from a sulfur hydrocarbon chain embedded in the organic polymer skeleton. The polymer has high chemical stability and thermal stability, and can be repeatedly used for multiple cycles. The organic polymer is used for detecting and degrading mercury ions, and has the advantages of simple operation, low cost, short detection and degradation time, real-time detection, field detection and the like, and is easy to popularize and apply.
Owner:YUNNAN ELECTRIC POWER TESTING & RES INST (GRP) CO LTD

Machine learning enhanced silver-based covalent organic framework nano-enzyme colorimetric detection method and application thereof

The invention discloses a machine learning enhanced silver-based covalent organic framework nano-enzyme colorimetric detection method and application thereof, and constructs a nano-enzyme which is formed by loading silver nanoparticles on a covalent organic framework and has oxide-like enzyme activity, and the nano-enzyme is used for rapid visual detection of mercury ions. When mercury ions exist, silver ions in the COF-AgNPs can form silver amalgam with the mercury ions, so that a colorless substrate 3, 3 ', 5, 5'-tetramethyl benzidine is catalyzed to generate a blue oxidation product oxTMB. And the mercury content can be judged by detecting the absorbance and RGB value change of the chromogenic reaction. And meanwhile, a machine learning data analysis strategy of a support vector machine model is adopted to carry out five-fold layered cross validation analysis on the obtained absorbance value and RGB value, so that the detection range is expanded, and the detection sensitivity is improved.
Owner:JIANGSU OCEAN UNIV

Bimodal sensor and preparation method and application thereof

The invention discloses a bimodal sensor and a preparation method and application thereof. The bimodal sensor comprises functionalized nanogold, wherein the functionalized nanogold comprises nanogold; the surface of the nanogold is modified with 4-mercaptobenzoic acid and thymine; the thymine is modified by cysteamine. The functionalized nanogold can realize specific recognition of mercury ions in matrixes such as food and drugs, so that output of a colorimetric / surface enhanced Raman spectrum dual-mode detection result is realized, the purpose of self-correction detection is achieved, the selectivity, accuracy and efficiency of detection are improved, and the detection cost is reduced. The method can be applied to detection of mercury ions in natural environment, food, medicines and cosmetics.
Owner:KUNMING UNIV OF SCI & TECH

Bis-cyano isophorone derivative fluorescent probe and application thereof in Hg < 2 + > detection

The invention discloses a dicyanoisophorone derivative fluorescent probe and application of the dicyanoisophorone derivative fluorescent probe in Hg < 2 + > detection. The structure of the double-cyano isophorone derivative fluorescent probe is shown as follows: # imgabs0 #. The Hg < 2 + > detection fluorescent probe HPQ-Hg is designed and synthesized, and the fluorescence intensity of the HPQ-Hg can be remarkably improved after the HPQ-Hg responds to Hg < 2 + > by introducing double recognition group thiocarbonate. Through a series of analysis tests, the probe HPQ-Hg shows ultrahigh sensitivity and selectivity, and the detection limit is only 0.52 nM. In addition, the fluorescence intensity of the probe and the mercury ion concentration show a good linear relationship (R2 = 0.9962). Development of the fluorescent probe HPQ-Hg provides a powerful tool for rapid detection of the Hg < 2 + > content in the electronic cigarette atomizer.
Owner:ANHUI PROVINCIAL CO OF CHINA NAT TOBACCO CORP

Preparation of sulfur-rich amino acid protein cmd-copper nanoclusters and method for detecting mercury ions by using the same

The present application mainly relates to a kind of preparation of sulfur-rich amino acid protein CMd-copper nanoclusters and its detection mercury ion method, comprising: a) by prokaryotic expression obtains CMd protein, and the protein concentration of 5 mg / mL-25 mg / mL CMd protein solution is obtained by purification.b) CMd is reacted with reducing agent TCEP after opening protein disulfide bond.c) the protein solution after reduction is reacted with anhydrous copper sulfate, and preparation high fluorescence CMd-copper nanocluster.d) CMd-copper nanocluster is applied to detect heavy metal mercury ion.The application method can be synthesized under mild aqueous conditions by "one-step method" structure controllable, stable CMd-copper nanocluster, widens the raw material of copper nanocluster synthesized with protein as template, avoids the use of organic solvent and strong reducing agent, and reduces the cost and environmental burden brought by noble metal raw material, and also has higher selectivity to mercury ion.
Owner:CHINA AGRI UNIV

A modified montmorillonite for synergistically repairing heavy metals and organic pollutants in soil, and a preparation method and application thereof

The application belongs to the technical field of contaminated soil remediation, and particularly relates to modified montmorillonite for synergistically remediating heavy metals and organic pollutants in soil as well as a preparation method and application thereof. Hexadecyl trimethyl ammonium bromide (CTAB) and dodecyl trimethyl ammonium bromide (DTAB) are used as modifiers to prepare organic modified montmorillonite, and mercury ions (Hg 2+ ) and acetochlor (ACR) are used as representative substances of heavy metals and organic pollutants to study the effects of the two kinds of organic modified montmorillonite on remediation of Hg 2+ and ACR compound contaminated soil. The results show that the two kinds of organic modified montmorillonite have good removal effects on Hg 2+ and ACR in real soil samples, and can simultaneously remove Hg 2+ and ACR in soil. The removal rates of CTAB modified montmorillonite and DTAB modified montmorillonite can both reach more than 90%. The organic modified montmorillonite prepared by using CTAB and DTAB as modifiers can simultaneously remove Hg 2+ and ACR in soil, and can synergistically remediate Hg 2+ and ACR compound contaminated soil.
Owner:HUBEI UNIV FOR NATITIES

Mercury ion detection method based on paper chip

The invention provides a mercury ion detection method based on a paper chip, and belongs to the technical field of mercury ion detection. The mercury ion detection method based on the paper chip comprises the following steps: firstly preparing nanogold, then preparing graphene quantum dots, mixing the nanogold and the graphene quantum dots to obtain a nanogold-graphene quantum dot compound, and then dropwise adding the nanogold-graphene quantum dot compound to filter paper to obtain a nanogold-graphene quantum dot paper chip, the paper chip is used for detecting the mercury ion concentration of a to-be-detected sample. According to the invention, sodium borohydride is used as a reducing agent and sodium citrate is used as a stabilizer to prepare nanogold, so that the particle size of the nanogold is more controllable, the particle size of the nanogold-graphene quantum dot compound obtained by combining with the graphene quantum dots is smaller, and the nanogold-graphene quantum dot compound is more tightly combined with mercury ions during detection; and finally, the result of measuring the mercury ion concentration by adopting the paper chip is more accurate.
Owner:XINYANG NORMAL UNIVERSITY

Hg < 2 + > detection method for enhancing inherent laccase-like activity of Hg < 2 + > based on ZIF-8-Au

The invention discloses an Hg < 2 + > detection method for enhancing Hg < 2 + > intrinsic laccase-like activity based on ZIF-8-Au. The invention finds that the mercury ions have laccase-like activity, the enzyme activity of the mercury ions is obviously enhanced under the action of ZIF-8-Au, and the color of the reaction catalyzed by the mercury ions is obviously changed along with the increase of the concentration of Hg < 2 + >, so that a colorimetric analysis method for detecting the mercury ions is developed on the basis, the Turn-On type visual analysis is realized, and the application prospect is wide. The method realizes simple, rapid, sensitive and high-selectivity detection of Hg < 2 + > residues in water and food. The invention provides a new method and principle for the fields of Hg < 2 + > environment monitoring and food safety, and provides a new direction for the development of a heavy metal ion detection technology.
Owner:JIANGSU OCEAN UNIV

Coupling method for removing ultra-low concentration mercury in wastewater of metal mine

PendingCN122277018AActivated carbonFlocculation
This invention belongs to the field of wastewater treatment in metal mines and proposes a coupled method for removing ultra-low concentration mercury from metal mine wastewater. It employs a combined process of "coupled chemical precipitation + flocculation precipitation + sulfur-loaded activated carbon adsorption." First, stannous chloride is added to generate a hydroxide gel, which is then chemically precipitated in conjunction with amorphous FeS nanoparticles. Next, hydrophobically modified cationic polyacrylamide is used for flocculation precipitation. Finally, modified sulfur-loaded activated carbon is used for deep adsorption. This treatment process has a specific removal effect on mercury ions, and the final effluent mercury meets the Class II surface water standard, with stable effluent quality. It also solves the problem of sulfur loss from ordinary sulfur-loaded activated carbon.
Owner:CHINA COAL TECH & ENG GRP HANGZHOU ENVIRONMENTAL PROTECTION INST +1

A benzothiadiazine-1,1-dione-quinoline derivative and its preparation method and application

The present invention discloses a benzothiadiazine-1,1-diketo-quinoline derivative, a preparation method, and an application thereof, belonging to the technical field of chemical optical materials. A benzothiadiazine-1,1-diketo-quinoline derivative is provided. The structural formula of the benzothiadiazine-1,1-diketo-quinoline derivative is: wherein R is -N(CH2CH3)2 or -OCH3. The present invention introduces a benzothiadiazine-1,1-diketo heterocycle at the 2-aldehyde position of quinoline to prepare the benzothiadiazine-1,1-diketo-quinoline derivative. The preparation cost is low, the operation is simple, and the method is simple. The obtained benzothiadiazine-1,1-diketo-quinoline derivative exhibits fluorescent properties and can be used as a probe for the detection of heavy metal copper and / or mercury ions. At the same time, the synthesis method can be used for synthesis in fine organic chemical fields such as printing and dyeing technology and analytical detection.
Owner:SHANTOU VOCATIONAL & TECH COLLEGE

Mercury ion detection electrochemical sensor, preparation method thereof and mercury ion detection method

The invention belongs to the field of mercury ion detection, and provides a mercury ion detection electrochemical sensor, a preparation method thereof and a mercury ion detection method. The mercury ion detection electrochemical sensor is composed of a basic electrochemical electrode, a vertical mesoporous silica nano-channel film uniformly deposited on a sensing interface of the basic electrochemical electrode, and mercury ion recognition molecules connected to the nano-channel film, the mercury ion recognition molecules are connected to the surface of the nano-channel membrane and in the nano-channel through a silane coupling agent; the mercury ion recognition molecule is 1-(6-(hydroxymethyl)-2, 2-dimethyl tetrahydrofuran [3, 4-d] [1, 3] dioxacyclo-4-yl)-5-methylpyrimidine-2, 4 (1H, 3H)-diketone. According to the invention, the specific recognition capability of the existing electrochemical sensor on the mercury ions can be enhanced, the preparation difficulty and the preparation cost are reduced, and convenient, low-cost, high-efficiency and high-selectivity detection of the mercury ions is realized.
Owner:SICHUAN UNIV

A quantitative detection method for mercury ions based on surface enhanced Raman scattering technology

ActiveCN114563386BRealize detectionhighly selective detectionRaman scatteringDNA SolutionsMercuric ion
The invention discloses a method for quantitatively detecting mercury ions based on surface enhanced Raman scattering technology, wherein a gold nano-finger array structure is first obtained by nano-imprinting, and then a specific single-stranded DNA is modified on the Au nano-finger array structure by sulfur-hydrogen bonds, and the finger array structure collapses during the volatilization of the DNA solution, and finally, the single-stranded DNA lying on the Au surface is converted into a double-stranded DNA spiral space structure perpendicular to the Au surface by titrating the mercury ion solution, so that the terminal base molecules in the DNA are away from the coupling enhanced electromagnetic field formed in the gap, and thus the SERS signal thereof is reduced. The invention can simultaneously realize the interference-free high selectivity and high sensitivity detection of Hg ions in a mixed solution.
Owner:ZHEJIANG UNIV OF TECH

A fluorescent sensitive membrane for detecting mercury ions in water and a preparation method thereof

This invention discloses a fluorescent sensitive membrane for detecting mercury ions in water and its preparation method. The sensitive membrane comprises a fluorescent probe and a physically cross-linked matrix. The fluorescent probe is prepared using 7-(diethylamino)coumarin-3-carboxaldehyde, 3-methyl-2-benzothiazolidinone hydrazone hydrochloride, and ethanol. Chitosan, glycerol, and acetic acid solutions are then added to a round-bottom flask and stirred until the chitosan is completely dissolved. Next, 4-(4,6-dimethoxytriazine-2-yl)-4-methylmorpholine hydrochloride is added, and stirring continues at room temperature to obtain a clear and transparent solution. The fluorescent probe is then added, and stirring continues. Finally, the solution is poured into a glass dish to evaporate the solvent, yielding the mercury ion detection solution. 2+ A fluorescently sensitive membrane. This membrane is sensitive to Hg in water. 2+ It has a detection function, requires no sample preparation during detection, and has the advantages of simple detection method and high detection efficiency.
Owner:LANZHOU UNIV

Application of a gold nanocluster / long-afterglow nanorod-based ratiometric fluorescent probe in mercury ion detection

The application aims to provide an application of a ratio fluorescent probe based on gold nanoclusters / long afterglow nanorods in mercury ion detection, and belongs to the technical field of fluorescent detection, which comprises synthesis of gold nanoclusters, preparation of long afterglow nanorods, and preparation and application of the ratio fluorescent probe. The ratio fluorescent probe comprises red light emitting gold nanoclusters and green light emitting long afterglow nanorods, and the fluorescent emission of the two materials has obvious spectral and color distinction. The responses of the gold nanoclusters and the long afterglow nanorods to mercury ions are completely opposite, mercury ions can quench the luminescence of the gold nanoclusters, while the luminescence of the long afterglow nanorods is enhanced to a certain extent. The response difference of the two fluorescent signals to different concentrations of mercury ions is utilized, and the ratio processing of the fluorescent intensity can be used for ratio fluorescent detection of mercury ions, and obvious composite fluorescent color change can be observed under the same excitation light irradiation, which is convenient for visual analysis of mercury ions.
Owner:TAIYUAN UNIVERSITY OF TECHNOLOGY

Biomass and hetero-calixarene-based degradable polymer material with micropores as well as preparation method and application thereof

The invention discloses an intrinsic micropore degradable polymer material based on biomass and hetero-calixarene and a preparation method and application thereof.The method comprises the steps that firstly, cyanuric chloride and resorcinol serve as raw materials, and oxygen atom bridged hetero-calixarene macrocyclic molecules are synthesized in one step under the alkaline condition through a one-pot method; then introducing the lignin derivative into oxygen atom bridged hetero calixarene by utilizing an aromatic nucleophilic substitution reaction on a triazine ring in a macrocyclic molecule, and carrying out a condensation reaction on the obtained multi-aldehyde functionalized oxygen atom bridged hetero calixarene and polyfunctional mercaptan under an acidic condition to obtain the target degradable polymer material. When in use, the material is directly put into an aqueous solution of elemental iodine, iodine negative ions and divalent mercury ions for adsorption. The removal rate of the material to low-concentration iodine simple substances, iodine negative ions and divalent mercury ions can reach 90% or above, and the material after adsorption can be repeatedly used after being washed by an acidic aqueous solution. The material can be degraded under an alkaline condition.
Owner:HUNAN INSTITUTE OF ENGINEERING

A preparation method of biochar composite material for efficiently removing mercury ions in the environment

The present invention discloses a method for preparing a biochar composite material for efficiently removing mercury ions in the environment, and belongs to the technical field of preparation of environmental functional materials. The present invention solves the technical problems that the synthesis of existing biochar composite materials is complex and costly, and the biochar composite material may cause secondary pollution to the environment during use. The present invention directly mixes Chlorella powder and ferric sulfate solution and dries and pre-oxidizes them, so that the ferric sulfate is evenly distributed in the algae powder, improves the uniformity of the product, and then pyrolyzes under nitrogen protection to directly prepare the biochar composite material. The obtained biochar composite material has a fast and efficient removal rate of mercury in the environment, with a minimum removal efficiency of 88% at a concentration of 40 mg / L, and the biochar composite material can efficiently remove mercury in a variety of water environments, and the removal rate is fast and there is no secondary pollution.
Owner:HARBIN INST OF TECH

Mercury-containing acid mud efficient recovery method and device based on difference frequency resonance coupling

The invention relates to a mercury-containing acid mud efficient recovery method and device based on difference frequency resonance coupling. The high-efficiency mercury-containing acid mud recovery method based on difference frequency resonance coupling comprises the following steps: step 1, acid mud pretreatment: crushing, screening and drying mercury-containing acid mud; 2, coupled field leaching is conducted, specifically, a product in the step 1 is conveyed into a reaction kettle, stirring is conducted after an oxidizing agent is added, an acid mud turbid liquid is obtained, an oxidation-reduction reaction is conducted through catalysis of a difference frequency resonance coupled field formed by two frequency-adjustable ultrasonic waves, and the difference frequency adjusting range delta f is 6-10 kHz; step 3, carrying out solid-liquid separation; leaching liquid containing mercury and selenium is obtained. According to the scheme provided by the invention, the standing wave effect can be formed through the difference frequency, and the crushing efficiency of the cavitation bubbles is improved, so that the oxidation reaction speed of the mercury-containing acid mud turbid liquid is improved; secondly, through the adjustable frequency, the situation that the ultrasonic frequency is not matched with the mercury ion concentration and the turbid liquid temperature, and consequently ultrasonic energy waste is caused is avoided.
Owner:KUNMING UNIV OF SCI & TECH

Cyanostilbene mercury ion fluorescent probe compound and preparation method thereof

The invention relates to a cyano-stilbene mercury ion fluorescent probe compound and a preparation method thereof. The molecular structure of the compound is shown in the specification.
Owner:JIANGXI UNIV OF SCI & TECH +1

Preparation method of ratio type fluorescent probe for detecting mercury ions

The invention belongs to the technical field of ion detection, and particularly relates to a preparation method of a ratio type fluorescent probe for detecting collected ions, which comprises the following steps: dissolving ethylenediamine and di-tert-butyl dicarbonate in perchloroform to obtain a product 1; dissolving the product 1 in absolute ethyl alcohol, and adding 4-Australio-1, 8-dianhydride to obtain a product 2; dissolving the product 2 in thousand dimethyl sulfoxide, and adding N-isothiazolyl phthaloyl to obtain a product 3; dissolving the product 3 in dichloromethane, and adding phenyl thiochloroformate to obtain the fluorescent probe NAP. The preparation method comprises the following steps: dissolving a fluorescent probe NAP in DMSO to prepare a mother liquor A, and dissolving methoxy chitosan CS-MeO in water to prepare a mother liquor B; and mixing the mother liquor A and the mother liquor B to prepare a Nano-NAP solution. The ratiometric fluorescent probe is used for detecting collected ions, has the advantages of high selectivity, small interference, low detection limit, good pH stability and the like, is high in use value, and has a wide application prospect.
Owner:BOHAI UNIV

A boron-sulfur doped fused ring aromatic containing a pyrrole ring, and a method of synthesis and use thereof

The application discloses a pyrrole ring-containing boron-sulfur doped fused ring aromatic hydrocarbon and a synthesis method and application thereof, and relates to a pyrrole ring-containing boron-sulfur doped fused ring aromatic hydrocarbon which is synthesized from simple raw materials such as 2,6-difluoronitrobenzene through a Clauson-Kaas pyrrole synthesis reaction and an electrophilic boronation reaction. Property research involves ultraviolet, fluorescence and CV tests, and mercury ion tests. The application has the characteristics of a short reaction path, a simple operation method and mild reaction conditions, and the compound has the potential of application in the field of photoelectric devices and can also be applied to mercury ion identification.
Owner:TIANJIN UNIVERSITY OF TECHNOLOGY

Tb-CeMOF (at) ATP (adenosine triphosphate) fluorescent probe as well as preparation method and application thereof

The invention relates to the technical field of chemical hazardous substance detection, in particular to a Tb-CeMOF (at) ATP fluorescent probe as well as a preparation method and application thereof. The fluorescent probe is obtained by taking a terbium / cerium bimetal organic framework Tb-CeMOF as a matrix and an aptamer as a recognition element and modifying the Tb-CeMOF framework with the aptamer through synthesis. The detection mechanism is as follows: when mercury does not exist, the aptamer enables the characteristic fluorescence of terbium to be excited. When a target object exists, the aptamer is specifically combined with mercury, and conformational change causes change of an energy transfer path: the characteristic fluorescence of terbium is quenched; characteristic fluorescence of cerium is obviously enhanced, and an'on-off-on 'type ratio fluorescence signal is formed. A standard curve is established by monitoring the linear relation between the ratio change of the fluorescence intensity and the mercury ion concentration, and accurate quantification of the mercury ion residual quantity in the sample is achieved. By means of simple operation and excellent sensitivity and selectivity, a reliable and efficient new strategy is provided for trace detection of mercury ions.
Owner:UNIV OF SHANGHAI FOR SCI & TECH

Peptide-based real-time ratiometric fluorescence sensor with excellent methylmercury ion and mercury ion selectivity and method for detecting methylmercury and mercury ions using the same

PendingKR1020260139455AMercuric ionPhotochemistry
One embodiment of the present invention provides a peptide-based real-time proportional fluorescence sensor with excellent selectivity for methylmercury ions and mercury ions, and a method for detecting methylmercury and mercury ions using the same. According to one embodiment of the present invention, the peptide-based real-time proportional fluorescence sensor with excellent selectivity for methylmercury ions and mercury ions dissolves well in a pure aqueous solution (1% DMSO), is excited by visible light, and can recognize Hg(II) and methylmercury with high sensitivity through proportional fluorescence behavior. In particular, it exhibits a fast detection speed for methylmercury and has high water solubility, but this fluorescence sensor penetrates well into cells and can sensitize Hg(II) and methylmercury inside the cell through a change in the ratio of red and green fluorescence.
Owner:INHA UNIV RES & BUSINESS FOUNDATION

Mitochondria-targeted coumarin mercury ion ratio fluorescent probe as well as preparation and application thereof

The invention relates to the technical field of fluorescent probes for metal ion detection, in particular to a coumarin mercury ion ratio fluorescent probe for targeting mitochondria as well as preparation and application of the coumarin mercury ion ratio fluorescent probe. The ratiometric fluorescent probe is applied to rapid detection of mercury ions and targeted imaging of mercury ions and mitochondria in living cells. At present, reported mercury ion fluorescent probes still have some limitations, such as complex synthesis, separation and purification, single-wavelength detection, no targeted positioning function and the like. The preparation method of the ratiometric fluorescent probe comprises the following steps: carrying out a reaction on O-(4-(bromomethyl) phenyl) diphenyl selenophosphonate and 7-diethylamino-3-(4-pyridyl) group coumarin in acetonitrile to generate 4-(7-(diethylamino)-2-oxo-2H-chromene-3-yl)-1-(4-((diphenyl selenophosphoryl) oxy) benzyl) pyridine-1-ammonium bromide. The fluorescent probe disclosed by the invention is simple to prepare, separate and purify, and fluorescent probe molecules have the advantages of good selectivity, high sensitivity, high response speed and the like in a coexistence system of mercury ions and other metal ions.
Owner:HEZHOU UNIV

A latex microsphere immunochromatographic test strip for detecting heavy metal mercury ions and its application

ActiveCN114518449BMeet the requirements of food safety standardsImmunoglobulinsTissue cultureMercuric ionMicrosphere
The present invention provides a latex microsphere immunochromatographic test strip for detecting heavy metal mercury ions, which belongs to the field of rapid heavy metal detection. The latex microsphere immunochromatographic test strip comprises the following components: a plastic shell, a sample pad, an immune probe binding pad, a nitrocellulose membrane and a water-absorbing pad; the immune probe binding pad is dripped with a latex microsphere immune probe labeled with an anti-mercury ion monoclonal antibody; the anti-mercury ion monoclonal antibody is an anti-Hg 2+ ‑ITCBE hapten is a monoclonal antibody secreted by mouse hybridoma cell line 7A1, mouse hybridoma cell line 7A1, with the deposit number of CGMCC No. 23879. The latex microsphere immunochromatographic test strip has a detection threshold of 100 ng / mL and a detection limit of 0.78 ng / mL. It has strong specificity, high sensitivity, good repeatability, stable performance, and low operating requirements. It is very suitable for rapid detection in grains and is of great significance for monitoring the residue of heavy metal mercury.
Owner:FUJIAN AGRI & FORESTRY UNIV

Water Monitoring with Solid State Nanopores

ActiveUS20250020623A1Testing waterAptamerCapacitance
A solid-state nanopore system includes a single-molecule chip that works on the principle of pore occlusion by the detected molecule, which then can be registered as a change in ionic current. Low-noise and low-capacitance glass chips are used with ultrathin (<20 nm) silicon nitride (SiN) nanopores of 1.5-5 nm diameter and a miniaturized nanopore reader are used as the nanopore sensor, which is capable of sensing the presence of mercury ion (Hg2+) and lead ion (Pb2+) at concentrations down to 0.5 nM and 5 nM, respectively. Detectable distinct electrical translocation characteristics between the two metal ions were enabled by short DNA molecules (aptamers) functioning as a carrier, binding via specific interactions with the metal ions to provide a selective nanopore sensor for water monitoring by identification of electrical fingerprints of the respective ions.
Owner:GOEPPERT LLC

A highly selective and sensitive fluorescent probe for mercury ions, its preparation method, and its applications.

PendingCN122301968AFluoProbesMercuric ion
This invention provides a highly selective and sensitive fluorescent probe for mercury ions, its preparation method, and its applications, belonging to the fields of chemical sensing materials and environmental monitoring technology. This invention connects 4-(1,2,2-triphenylvinyl)phenol, which exhibits aggregation-induced emission, and a guanosine derivative with multiple coordination sites, via a flexible chain to obtain a fluorescent probe with the structure shown in Formula I. This fluorescent probe not only overcomes the problems of large differences in solubility and reactivity between 4-(1,2,2-triphenylvinyl)phenol and guanosine derivatives, making coupling difficult, but also possesses high sensitivity and selectivity; its detection limit reaches 12.24 nM, effectively detecting trace mercury pollution in samples. It can also accurately identify mercury ions in water samples containing multiple high concentrations of metal ions, demonstrating high accuracy in real water samples. It is suitable for the accurate determination of mercury ions in complex environmental water samples and has good practical application value in the field of environmental monitoring. Formula I
Owner:WEST CHINA HOSPITAL SICHUAN UNIV