346results about How to "Improve microstructure" patented technology

The invention belongs to the technical field of biodegradable materials, and particularly relates to an environment-friendly degradable modified composite material, a preparation method and application. The material comprises PBAT, PBS, PLA, an inorganic mineral filler, natural plant fibers, PBAT-PTMO, nano-silica, an auxiliary agent and a plasticizer. In the preparation process, PLA is prevented from being hydrolyzed in vacuum drying, calcium carbonate and nano silicon dioxide are preheated and activated, natural plant fibers are dispersed through steam explosion and ethanol treatment, and raw material pretreatment comprises high-speed mixing and agglomeration breaking and medium-speed secondary premixing so as to realize uniform distribution. The co-rotating twin-screw extruder accurately controls the temperature, the speed, the rotating speed and the length-diameter ratio, and ensures melting plasticizing, uniform mixing and stable extrusion molding. According to the invention, by adopting accurate proportioning of multiple raw materials and a modification treatment process, the properties of mechanics, degradation, processing and the like of the material are synergistically improved, and the material is widely applied to multiple fields such as packaging bags, disposable tableware and agricultural plastic mulching films.

The invention relates to the technical field of electronic ceramic materials, and particularly discloses a high-purity aluminum oxide ceramic substrate and a preparation process thereof. The high-purity aluminum oxide ceramic substrate is prepared from the following raw materials in parts by weight: 0.20 to 0.25 part of magnesium oxide, 0.35 to 0.55 part of zirconium oxide, 1.2 to 1.5 parts of dispersing agent, 60 to 65 parts of ethanol, 99.7 to 99.8 parts of aluminum oxide, 12 to 15 parts of adhesive, 6 to 9 parts of plasticizer and 50 to 55 parts of n-butyl alcohol, the adhesive is a mixture of polyvinyl butyral, water glass and modified paraffin. The prepared high-purity aluminum oxide ceramic substrate has excellent chemical stability and mechanical strength, and the obtained aluminum oxide ceramic substrate has better density, mechanical property and thermal stability by mixing various raw material components, and is not easy to break when subjected to bending load.

The invention discloses a method for improving the high-cycle fatigue performance of a Ti6Al4V titanium alloy, and belongs to the technical field of metal material processing, and the method comprises the following steps: S1, determining shot peening strengthening parameters based on material performance parameters and related standards; according to the method, high-amplitude residual compressive stress is introduced through shot peening strengthening, the stress state of the surface and the depth direction of the material is changed, accordingly, crack extension can be restrained, the fatigue life is prolonged, in addition, a plastic deformation layer is induced to be generated under the surface depth in the shot peening process, the microstructure of the material is improved, and the anti-fatigue performance of the material is improved; through femtosecond laser shock, surface defects can be effectively removed, the surface compactness can be improved, microcracks can be reduced, and a refined grain structure can be generated, so that the strength and toughness of the material are further enhanced, the high-cycle fatigue performance of the material is further improved, the two are combined, the residual stress state is optimized, and the surface integrity is improved. The fatigue performance of the Ti6Al4V titanium alloy is remarkably improved.

The embodiment of the invention provides a Czochralski method crystal growth device and a regulation and control method, and relates to the technical field of crystal growth. The Czochralski method crystal growth device comprises a furnace body, a crucible, a first magnetic field device, a seed rod and a second magnetic field device, the crucible is arranged in the furnace body, and the first magnetic field device is arranged on the outer side of the crucible in a surrounding mode and located in the furnace body. The seed rod is arranged in the furnace body and is spaced from the crucible; the second magnetic field device is arranged on the seed crystal rod and is positioned in the furnace body; wherein the first magnetic field device is used for generating a magnetic field and acting on a melt in the crucible; the second magnetic field device is used for generating a magnetic field and acting on a growth interface of the melt. The Czochralski method crystal growth device can effectively inhibit convection of melt, so that solute distribution is uniform, and crystal defects are reduced; and the crystal structure can be optimized, and accurate regulation and control of solute are realized, so that the quality and the performance of the crystal are integrally improved.

The invention provides a composite exciting agent and application thereof, and relates to the technical field of exciting agents, and the composite exciting agent comprises an alkaline exciting agent, a calcium source exciting agent and an auxiliary exciting component. Industrial solid waste materials such as the slag, the fly ash and the steel slag can work cooperatively in the same system, the gelling performance, the mechanical strength and the durability of the material are remarkably improved, and the purposes of solid waste resource utilization and low-carbon environmental protection are achieved.

The invention relates to a high-performance polymer-cement-based composite repair material and a preparation method thereof, and the high-performance polymer-cement-based composite repair material comprises the following components by mass: 690-710 parts of cement; 130 to 150 parts of fly ash; 45 to 55 parts of silica fume; 200 to 210 parts of mixing water; 950 to 1050 parts of fine aggregate; 21-23 parts of a modified polymer; 9-10 parts of an expanding agent; 4-5 parts of a water reducing agent; 5-6 parts of modified fiber; and 0.16 to 0.18 part of a defoaming agent. The nano-toughened modified polymer and the modified fiber are used, the nano-modified polymer can improve the microstructure of the repair material, the modified fiber can limit shrinkage of the repair material and enhance the crack resistance of a matrix, the toughness and the mechanical property of the repair material can be effectively improved through the synergistic effect of the nano-modified polymer and the modified fiber, and it is guaranteed that the repair material does not crack in the early stage.

The invention provides a polyurethane material for leaking stoppage of coal mine spraying and a preparation method thereof, and belongs to the technical field of polyurethane. The preparation method comprises the following steps: pretreating a multi-walled carbon nanotube, coupling phytic acid and a silane coupling agent, reacting with UiO-66-NH2, coating the surface with a graphene oxide layer, mixing with polyether polyol, a catalyst and an antistatic agent, adding into water, adding a foaming agent and silicone oil, heating, stirring and mixing, transferring into a mold, adding diisocyanate, and after foaming is completed and the temperature of the material is reduced to room temperature, carrying out extrusion molding to obtain the composite material. And drying, heating and curing to obtain the polyurethane material for coal mine spraying air leakage stoppage. By adding the prepared wrinkled graphene oxide coated UiO-66-NH2 / modified multi-walled carbon nanotubes, the mechanical property and strength of the prepared polyurethane material for coal mine spraying air leakage stoppage can be obviously improved, the flame retardant property such as the oxygen index of the material is also obviously improved, the foam expansion is improved to a certain extent, the preparation method is simple, and the preparation method is suitable for industrial production. The flame-retardant and mechanical properties can be obviously improved, and the application prospect is wide.

The invention relates to the technical field of concrete preparation, in particular to moisturizing anti-cracking high-ductility concrete and a preparation method thereof. The moisturizing anti-cracking high-ductility concrete is prepared from the following components: 350 to 450 parts of ordinary Portland cement, 200 to 300 parts of fly ash, 30 to 50 parts of silica fume, 250 to 350 parts of quartz sand, 0.5 to 1 part of a water reducing agent, 10 to 20 parts of an expanding agent, 0.1 to 0.3 part of a retarder, 0.5 to 1 part of a thixotropic lubricant, 0.2 to 0.7 part of a modified nano material, 0.7 to 3 parts of a modified composite curing agent, 5 to 10 parts of an anti-cracking agent, 5 to 12 parts of polymer fiber and 180 to 220 parts of water. The high-moisture-retention high-water-retention concrete has the characteristics of high moisture retention and high water retention, is beneficial to maintaining the internal humidity balance, reducing cracks generated by drying shrinkage, improving the durability of the concrete, and remarkably reducing the cracking risk of the concrete in the hardening process, so that the concrete structure is more complete, the safety of the structure is improved, and the service life of the structure is prolonged.

The invention provides low-yield-ratio super-thick maritime work steel with excellent core low-temperature toughness and a manufacturing method of the low-yield-ratio super-thick maritime work steel, and belongs to the field of steel and iron material preparation. The low-yield-ratio super-thick marine steel with the excellent core low-temperature toughness comprises the following chemical components in percentage by mass: 0.10%-0.15% of C, 0.35%-0.45% of Si, 1.20%-1.50% of Mn, 3.00%-3.50% of Ni, 0.30%-0.50% of Mo, 0.15%-0.3% of Cr, 0.01%-0.02% of Ti, 0.030%-0.040% of V, 0.050%-0.060% of Nb, 0.0016%-0.0020% of B, 0.15%-0.25% of Cu, 0.060%-0.070% of Al, less than or equal to 0.010% of P, less than or equal to 0.004% of S, less than or equal to 0.39% of CET and the balance of Fe and inevitable impurities. According to the invention, a component design thought of a low-C, Ni-Nb-Mo-Al-B system is adopted, and a three-section rolling and quenching and tempering heat treatment process is combined. Through strict control of smelting continuous casting, controlled rolling and controlled cooling processes and quenching and tempering heat treatment parameters, the super-thick marine steel with excellent comprehensive mechanical properties is successfully prepared. The steel shows good low-temperature toughness in the core part, and meanwhile, the steel has a relatively low yield ratio. According to the low-yield-ratio super-thick maritime work steel with the excellent core low-temperature toughness, the thickness range is 80-150 mm, the yield strength is larger than or equal to 690 MPa, the tensile strength is larger than or equal to 920 MPa, the percentage elongation after fracture is larger than or equal to 20%, the yield ratio is smaller than or equal to 0.77, and the impact energy KV2 at the temperature of-60 DEG C is larger than or equal to 80 J.

The invention relates to a design method for the mix proportion of carbonized 3D printing concrete and the carbonized 3D printing concrete. Carbon dioxide is introduced into cement-based printing slurry, the introduction amount of the carbon dioxide is controlled, and when the carbon dioxide is introduced into the cement-based printing slurry, the use amount of magnesium chloride is calculated according to the content of a carbonization reaction product CaCO3 and the proportion of calcite to aragonite in a required concrete mixture. Magnesium chloride and carbon dioxide are added into the cement-based printing slurry at the same time for full reaction, and finally the 3D printing concrete material is prepared. By adding magnesium chloride and generating aragonite type calcium carbonate, the thixotropic behavior of the material is improved, the constructability of the cement slurry is higher, the orientation of the nano-scale aragonite fibers is arranged according to the printing direction, the reinforcing and toughening effects are excellent, and the bending resistance, bending resistance and compressive strength are all improved.

The invention relates to the technical field of aluminum alloy material pressure processing, in particular to an aluminum alloy material for preparing a steel-aluminum composite strip and a preparation method thereof.The aluminum alloy material comprises a steel layer and an aluminum alloy layer, and the aluminum alloy layer comprises, by mass, 100 parts of silicon (Si), iron (Fe), copper (Cu), manganese (Mn), magnesium (Mg), zinc (Zn) and the balance aluminum and inevitable impurity elements. According to the method, through the laser interface activation and ultrasonic-assisted rolling technology, the interface bonding degree and the microstructure of the steel-aluminum composite material are remarkably improved, and the stability of the steel-aluminum composite material at the high temperature is optimized. And microalloying elements such as scandium (Sc) are introduced, so that the mechanical property and the corrosion resistance of the material are enhanced. The service life is prolonged through a special high-temperature-resistant coating and an accurate heat treatment process, and the surface hardness and corrosion resistance are improved. The advanced processes ensure high performance and high quality of the composite material, and meet the requirements of high temperature and special environments.

The friction stir welding device based on battery shell manufacturing comprises a welding table, a positioning mechanism, a welding mechanism and a cooling mechanism, the welding table is provided with a material containing plane used for containing a plate, the positioning mechanism fixes the plate, the welding mechanism comprises a rotating part and a stirring part, the rotating part is controlled to move and drives the stirring part to conduct welding, and the cooling mechanism is used for cooling the stirring part. The cooling mechanism comprises a shell, a liquid source and a fan, a containing space is formed in the shell and connected with the liquid inlet, the air inlet and the air outlet, the opening covers the weld joint and is attached to the surface of the plate, a plurality of partition pieces are arranged in the containing space to form a first heat dissipation flow channel, and cooling liquid and airflow are guided to flow in order. According to the friction stir welding device, cooling liquid is supplied through the liquid source, airflow is provided through the fan, local cooling gradient control over the welding seam area and the periphery is achieved, the problems of stress concentration, cracks and strength reduction caused by the too large temperature gradient are solved, meanwhile, the joint hardness recovery effect is improved, and the welding quality is optimized.

The invention provides a high-strength low-stress continuous SiC fiber reinforced Ti3Al composite material as well as a preparation method and application thereof, and belongs to the technical field of aeronautical materials. The Mo interface layer with the thermal expansion coefficient matched with that of SiC and Ti3Al is introduced to the interface of the SiC / Ti3Al composite material, so that the stable transition of the thermal expansion coefficient is realized, the interface stress is dispersed, the interface bonding strength is further improved, and the stability of the material performance is guaranteed; meanwhile, an Nb element is introduced into a Ti3Al matrix to refine Ti3Al grains and optimize a microstructure, so that the strength and toughness of the material are enhanced, and a Ti3Al / Nb composite structure is constructed to relieve stress concentration and improve the tensile strength, so that the material failure is effectively prevented.

The invention discloses a fuel cell rapid activation method, and relates to the technical field of fuel cells, and the activation method comprises the steps of early-stage preparation, electrode pretreatment, activation reagent injection, activation treatment, post-treatment and evaluation and optimization. The method has the advantages that the electrochemical impedance spectrometer is used for state inspection of the electrode and other components in the electrode pretreatment stage, the reliability of the fuel cell to be detected is ensured, the surface of the electrode is deeply cleaned through the cleaning agent and the ultrasonic cleaning machine, dust, oil stains and impurities on the surface of the electrode can be effectively removed, and the detection accuracy is improved. Meanwhile, the microstructure and chemical composition of the surface of the electrode are improved by utilizing a plasma technology, and the catalytic activity and corrosion resistance of the electrode are improved, so that the activation efficiency and the operation stability of the fuel cell are improved, and potential abnormities can be found and treated in time by evaluating the performance in real time; and the fuel cell is ensured to operate in an optimal state.

The invention belongs to the related technical field of metal fuels, and discloses an aluminum-lithium alloy powder fuel and a preparation method thereof, the aluminum-lithium alloy powder fuel is prepared from the following raw materials in percentage by mass: 2-10% of Li, 0.1-5% of Mg, 0.1-3% of RE and the balance of Al. The added Mg element can separate out stable, fine and uniformly-distributed intermetallic compounds besides a micro-explosion effect, the activity of Li in the alloy can be reduced, the stability of the fuel can be improved, the added RE element can form an Al3 (Li, RE) precipitated phase with a core-shell structure by taking the precipitated intermetallic compound Al3RE as a heterogeneous nucleation particle of a metastable phase delta '(Al3Li), and the stability of the fuel can be improved. Through targeted component design, the structure regulation and control of the precipitated phase in the alloy powder can be realized, so that the microstructure of the precipitated phase is improved, and the combustion performance of the fuel is improved.

The invention belongs to the technical field of backfill materials, and particularly discloses a road shallow wet and soft foundation backfill material and a preparation method thereof. The road shallow wet and soft foundation backfill material is prepared from the following raw materials in parts by weight: 40 to 50 parts of building residue soil, 10 to 15 parts of modified diatomite, 15 to 20 parts of cement, 7 to 10 parts of modified chitosan, 60 to 70 parts of water and 5 to 9 parts of sodium carbonate. The road shallow wet and soft foundation backfill material prepared in the invention has relatively good strength, crack resistance and tensile strength, so that the bonding force between the building residue soil and other components is relatively good, and the structural strength and stability of the backfill material are improved.

The invention relates to an aluminum-silicon alloy and a die-casting process thereof. The die-casting process of the aluminum-silicon alloy comprises the following steps: melting alloy raw materials, degassing and refining, carrying out semi-solid pulping, adding a refiner in the semi-solid pulping process, stirring, reducing the temperature of a semi-solid alloy melt, and continuously stirring, so as to realize primary refinement and modification of primary crystal grains and broken dendrites formed in the semi-solid slurry; a semi-solid alloy melt is obtained; and chilling, solidifying and forming the semi-solid alloy melt, and quenching to obtain the aluminum-silicon alloy casting. The invention further provides the aluminum-silicon alloy prepared through the die-casting technology. The problem that an existing refiner cannot meet the good refining effect and the good modification effect at the same time is solved, and the problems that an existing aluminum-silicon alloy die casting is thick in structure and poor in tensile property are further solved.

The invention discloses UHPC based on carbon nanotube modified aggregate and a preparation method and application thereof, and belongs to the technical field of novel building materials. The raw materials comprise 1417 to 1517 parts of cement, 135 to 165 parts of silica fume, 35 to 43 parts of steel fiber, 800 to 1000 parts of sintered bauxite aggregate, 4.22 to 10.56 parts of carboxyl functionalized carbon nanotube, 410 to 510 parts of water and 6 to 12 parts of a water reducing agent; wherein the sintered bauxite aggregate is modified by carboxyl functionalized carbon nanotubes. The chemical reaction of oxygen-containing functional groups (carboxyl) in the carboxyl functionalized carbon nanotubes is utilized to form covalent bonds, the hydration reaction in cement is catalyzed and promoted, and the carboxyl functionalized carbon nanotubes provide more nucleation sites, so that the microstructure of the cement-based material is improved, and the integrity of the cement-based material is improved.

The invention relates to the field of metal material casting, and discloses a production method of green sand as-cast high-plasticity nodular cast iron QT800-5, which comprises the following steps: preparing pig iron, waste steel and foundry returns, and using auxiliary materials such as a silicon carbide pretreating agent, a high-temperature graphitization carburant, a rare earth magnesium silicon iron nodulizing agent, a silicon barium nucleating agent and a silicon strontium nucleating agent to prepare the green sand as-cast high-plasticity nodular cast iron QT800-5. The purity and component stability of molten iron are ensured; in the smelting process, purification and adjustment are carried out through temperature control and segmented addition of auxiliary materials, then spheroidizing is carried out through a pouring method, and the microscopic structure of a casting is optimized through ladle-to-ladle inoculation and stream inoculation; the final casting has excellent mechanical properties including the tensile strength larger than or equal to 800 MPa, the yield strength larger than or equal to 480 MPa, the elongation larger than or equal to 5% and the matrix pearlite content larger than or equal to 80%. The production process disclosed by the invention is simplified, is suitable for large-scale industrial production, and has a wide application prospect in lightweight application requiring high-strength and high-plasticity materials.

The invention relates to a high-precision and fast-response ultrahigh pressure adjusting method based on a real-time feedback control principle, and belongs to the technical field of ceramic manufacturing. The high-precision and fast-response ultrahigh pressure adjusting method based on the real-time feedback control principle comprises the steps that after a pressure adjusting device is started, a target pressure value is set; a high-precision pressure sensor is used for monitoring the pressure value in the forming process in real time; acquiring data of the pressure sensor in real time through a data acquisition system, and performing filtering and correction processing; the controller calculates the deviation between the current pressure and the set pressure according to the set pressure value and the pressure value collected in real time; by means of the real-time feedback control technology, high-precision adjustment of pressure is achieved, it is ensured that ceramic powder is subjected to uniform pressure in all directions, particles are tightly arranged, the forming density is improved, meanwhile, due to the fact that the pressure is applied in the same direction, the powder particles are subjected to the same compression force in all directions, and it is ensured that ceramic blanks are uniform in density and regular in shape.

The invention relates to an easily-activated Ti-Fe-Y-Mn-Zr-Co-Zn-based hydrogen storage alloy and a preparation method thereof, belongs to the technical field of hydrogen storage alloy materials, and solves at least one of the problems of high activation difficulty, long activation period, poor hydrogen absorption and desorption dynamic performance and the like of a Ti-Fe-based hydrogen storage alloy in the prior art. The invention provides a Ti-Fe-Y-Mn-Zr-Co-Zn based hydrogen storage alloy easy to activate, the chemical formula of the hydrogen storage alloy is Ti 1.15, Fe 0.8, Y 0.03, Mn 0.35-x-y-z ZrxCoyZnz, x, y and z are atomic ratios, x is larger than or equal to 0.05 and smaller than or equal to 0.15, y is larger than or equal to 0.02 and smaller than or equal to 0.1, and z is larger than or equal to 0.02 and smaller than or equal to 0.1. The Ti-Fe-Y-Mn-Zr-Co-Zn based hydrogen storage alloy provided by the invention obtains good activation performance and hydrogen absorption and desorption performance by means of component design and preparation process improvement, can be activated at one time under the conditions of 30 DEG C and 3 MPa, and has the hydrogen storage capacity of more than or equal to 1.69 wt.%, the hydrogen absorption platform pressure of more than or equal to 0.39 MPa and the hydrogen desorption platform pressure of more than or equal to 0.3 MPa.

The invention discloses a tundish cover castable, and relates to the technical field of tundish refractory materials. The tundish cover castable is prepared from the following raw material components in percentage by mass: 7.8 to 9.6 percent of alumina of 8 to 5mm, 2.6 to 4.3 percent of alumina of 5 to 3mm, 2.6 to 4.3 percent of alumina of 1 to 0mm, 17.4 to 20.8 percent of alumina of 200 meshes, 9.6 to 13 percent of mullite of 5 to 3mm, 22.6 to 26 percent of mullite of 3 to 1mm, 9.6 to 13 percent of mullite of 1 to 0mm, 7 to 8.7 percent of mullite of 200 meshes, 2.6 to 3.5 percent of composite binding agent, 0.8 to 1.7 percent of aluminum silicate, 0.05 to 0.07 percent of SiC nanowire, 0.2 to 0.3 percent of aluminum titanate and the balance of water. The invention discloses a tundish cover castable which comprises the following components in percentage by weight: 0.4-0.7% of alumina micro powder, 0.08-0.11% of sodium tripolyphosphate, 2.6-3.5% of silica fume, 0.87% of steel fiber and 1.3-1.7% of high-alumina cement. Compared with a traditional process, the tundish cover castable has the advantages that the overall performance of the tundish cover castable is remarkably improved, the breaking strength and compression strength of the castable are effectively enhanced, the service life is remarkably prolonged, and the production cost is reduced. And the production cost is greatly saved, and the economical efficiency and the operation rate of continuous casting operation are improved.

The invention relates to the technical field of metal heat treatment, in particular to a quenching process for improving the surface quality of a plate spring and reducing oxidation and decarburization, which comprises the following steps: putting the plate spring into a heating furnace, accelerating heating to 900-100 DEG C, and keeping the temperature for 30-35 minutes; the heated plate spring is placed in a quenching machine to be clamped and quenched; the tempering temperature is selected according to the hardness value required by the plate spring, and a continuous or periodic operation tempering furnace is adopted for tempering treatment; and the plate spring is relaxed, loaded, heated and subjected to heat preservation. By accurately controlling the heating temperature and time and combining the intelligent temperature control system to optimize the heating process, it is ensured that the plate spring is evenly heated within the optimal temperature range. In this way, the surface quality of the plate spring is improved, the performance difference caused by uneven heating is reduced, the oxidation and decarbonization phenomena are effectively reduced, the service life of the plate spring is prolonged, and the overall performance of the plate spring is improved.

The invention relates to the technical field of metal materials, and discloses an Al-Zn heat-treatment-free aluminum alloy and a preparation method and application thereof. The Al-Zn series heat treatment-free aluminum alloy is prepared from the following components in percentage by mass: 8.0 percent to 18.0 percent of Zn, 4.0 percent to 9.0 percent of Si, 0.5 percent to 4.0 percent of Cu, 0.3 percent to 1.2 percent of Mn, 0.1 percent to 0.5 percent of Zr, 0.1 percent to 0.9 percent of V, 0.1 percent to 0.4 percent of Er, 0.05 percent to 0.6 percent of Sr, 1.0 percent to 3.0 percent of TiC / TiB2 and the balance of Al and inevitable impurities. The Al-Zn heat-treatment-free aluminum alloy provided by the invention is compact in structure, fine in crystal grain, uniform in solute element distribution and excellent in mechanical property, and can meet the application requirements of the fields of automobiles and spaceflight on aluminum alloy materials.

The invention discloses a wear-resistant and corrosion-resistant rare earth copper alloy which comprises 0.05%-3% of titanium, 0.06%-1.4% of niobium, 0.06%-2% of tantalum, 0.1%-1.58% of chromium, 0.01%-0.2% of iridium, 0.12%-2.5% of molybdenum, 0.08%-0.8% of vanadium, 2.6%-4.8% of rare earth elements and the balance copper and inevitable impurities, the total weight percentage of all the raw materials is 100%, on the basis of a traditional alloy, a trace amount of titanium, niobium, tantalum, chromium, iridium, molybdenum, vanadium and rare earth elements are added, and the rare earth elements and the rare earth elements are evenly mixed. And the percentage content of each element in the copper alloy is adjusted, so that trace rare earth elements, titanium, niobium, tantalum, chromium, iridium, molybdenum and vanadium generate a synergistic effect, the crystal grains of the alloy can be refined, the microstructure of the material is improved, the wear resistance is improved, a firmer passive film can be formed, the corrosion resistance of the material in a severe environment is improved, and the service life of the material is prolonged. The alloy has high wear resistance and corrosion resistance, the strength and toughness of the alloy are improved, and the alloy has better performance under the dynamic load.

The invention discloses a method for preparing a metal casting mold based on steel grit 3D printing, and belongs to the technical field of metal casting mold machining. In order to solve the technical problem that in the prior art, the mechanical strength and collapsibility of a metal casting mold need to be further improved, the method for preparing the metal casting mold based on steel grit 3D printing comprises the following steps that a sand mold three-dimensional model is established according to a metal casting, then casting mold steel grit is filled in an operation box of sand mold 3D printing equipment, and the casting mold steel grit is obtained; the binder storage tank is filled with a binder; and according to the section formation of the sand mold three-dimensional model, a sand paving system of the sand mold 3D printing equipment paves cast steel sand on a printing platform. The casting steel sand and the binder are matched with each other, the metal casting mold blank is prepared through 3D printing and then dried, the normal-temperature mechanical property and high-temperature property of the metal casting mold are effectively improved, the application range of the metal casting mold is widened, and meanwhile the collapsibility of the metal casting mold is improved.

The invention discloses an additive spinning composite forming device and method for a thin-wall rotary body part. The additive spinning composite forming device comprises a lifting platform, a rotating platform is installed on the lifting platform, a claw-shaped clamp is connected to the rotating platform, an additive base body is clamped by the claw-shaped clamp, and the thin-wall rotary body part is arranged on the additive base body; the thin-wall rotary body part is located between the two spinning mechanisms and the laser cladding head, the spinning mechanisms and the laser cladding head are connected to the clamping mechanism, the clamping mechanism is connected to one end of the mechanical arm, and the other end of the mechanical arm is connected to the mechanical arm base body; additive manufacturing of the thin-wall rotary body part and spinning of the additive deposition layer are synchronously achieved, material grain refinement and rearrangement are promoted through spinning of the deposition layer, the microstructure is improved, and the part performance is improved; and meanwhile, pores possibly generated in the additive manufacturing process are effectively eliminated through spinning, the compactness of the part is improved, and therefore the microstructure and the mechanical property of the thin-wall rotary body part manufactured through additive manufacturing are comprehensively improved.

The invention relates to a lithium ion battery electrolyte additive 2, 4-dicarboxamido sulfonyl cyclobutanone and a corresponding high-temperature lithium ion battery electrolyte. The electrolyte comprises the following components: lithium salt, an anhydrous organic solvent and an electrolyte additive; wherein the electrolyte additive comprises 2, 4-dicarboxamido sulfonyl cyclobutanone, and the electrolyte additive comprises 2, 4-dicarboxamide sulfonyl cyclobutanone; the use amount of the 2, 4-dicarboxamido sulfonyl cyclobutanone in the electrolyte is 0.1%-10% of the total mass of the electrolyte. The high-temperature lithium ion battery electrolyte added with 2, 4-dicarboxamidosulfonyl cyclobutanone can improve the high-temperature discharge performance, the high-temperature charge performance, the high-temperature cycle performance and the safety performance of a lithium ion battery when the lithium ion battery works at 4.2 V, does not influence the first efficiency and the rate capability, and has a relatively good application prospect in a high-temperature system.

The invention relates to a simulation method for predicting the morphology of a corrosion pit by considering grain orientation, and belongs to the technical field of metal material calculation and simulation. The method comprises the following steps: firstly, constructing a model that an initial corrosion pit exists on the surface of a material and importing EBSD data of the material, secondly, setting a boundary condition and a control equation, introducing a relationship between crystal orientation and corrosion potential, and finally simulating movement of a corrosion pit interface in a corrosion process to predict the morphology of the corrosion pit. According to the method, by considering the influence of the actual crystal structure of the material on the pitting behavior, the obtained simulation result can be used for predicting the morphology of the pitting pit, and reference is provided for researching more complex corrosion phenomena involving a series of microstructure characteristics and various electrochemical mechanisms.

The invention discloses a bone cement composite material with collapse resistance and a preparation method thereof, and belongs to the technical field of biomedical materials. The composite material comprises a solid phase part and a liquid phase part, the liquid phase part and the solid phase part are mixed according to the liquid-solid ratio of 0.35 mL / g to 0.6 mL / g; the solid phase part is composed of calcium sulfate powder and calcium phosphate powder, and the mass ratio of the calcium sulfate powder to the calcium phosphate powder is 85: 15; the liquid phase part is selected from carboxymethyl chitosan or a combination of carboxymethyl chitosan and sodium alginate. The bone cement composite material prepared by the preparation method disclosed by the invention has good biocompatibility; due to a gel network formed by carboxymethyl chitosan and sodium alginate, the compressive strength of the bone cement is remarkably improved, and the collapse resistance and injectable performance are excellent; meanwhile, the bone cement composite material promotes the attachment and proliferation of osteoblasts, and can induce osteogenic differentiation in vitro.