The invention discloses a compound Janus colloid particle and a modified Janus colloid particle as well as preparation methods thereof. Inorganic particles are taken as seeds, and a silane coupling agent modification method, a seed emulsion polymerization method, an inorganic surface etching method, method for inducing recombination functional materials by using polymer gel, and the like are combined to prepare inorganic/polymer, inorganic/inorganic, inorganic/metallic, inorganic/metallic oxide Janus particles. The structure and the size of the Janus particle can be controlled by controlling the activity of reactants, feeding speed, and the concentration of reactants, and the compounding of various kinds of materials can be realized. The Janus particle provided by the invention not only has good dispersibility, but also has good strength and size stability.