1516 results about "Photothermal conversion" patented technology

The invention relates to a deicing super-hydrophobic coating based on MXene, a coating, a preparation method and application of the coating. The coating comprises the following components in percentage by mass: 2%-5% of a super-hydrophobic modified MXene photo-thermal material, 2%-5% of epoxy resin, 0.5%-1.5% of an epoxy resin curing agent, 0.5%-1.5% of PDMS, 0.05%-0.15% of a PDMS curing agent and 80%-90% of a diluent. Wherein the super-hydrophobic modified MXene photo-thermal material is MXene powder treated by fluorine-free long-chain silane, and the super-hydrophobic modified MXene photo-thermal material is a super-hydrophobic modified MXene photo-thermal material. MXene with excellent photo-thermal conversion performance is used as a photo-thermal material, fluorine-free long-chain silane is used for performing low-surface-energy hydrophobic modification on the MXene material, environmental pollution caused by perfluorinated or polyfluorinated organic compounds is avoided, photo-thermal performance and super-hydrophobic performance are integrated, the advantages of a super-hydrophobic coating and a photo-thermal coating are integrated, and the application prospect is wide. The deicing super-hydrophobic coating based on MXene can be used for passive ice prevention and active photo-thermal deicing.

The invention discloses a preparation method of a flexible material with double functions of radiation refrigeration and photothermal conversion storage, and relates to the field of composite phase change materials. The preparation method comprises the following steps: 1) preparing the flexible phase change material matrix by utilizing n-octadecane, SEBS and POE through hot pressing; 2) preparing a BaSO4 solution by using absolute ethyl alcohol, deionized water, a water-based defoaming agent, a water-based dispersing agent and an acrylic resin emulsion; (3) preparing an MXene solution; and 4) spraying the BaSO4 solution on the surface of one side of the flexible composite phase change material matrix by using a spray gun, and spraying the MXene solution on the surface of the other side of the flexible composite phase change material matrix to obtain the flexible composite phase change material. The radiation refrigeration layer can strongly reflect visible light and near-infrared light, has high emissivity in an infrared light area, especially in an atmospheric window wave band, reduces absorbed atmospheric heat radiation, reduces urban heat island effect caused by dense building groups in cities, and can effectively solve the problems of large day and night temperature difference and heat supply and demand in summer and winter.

The invention provides porous foam with a bionic lotus seedpod surface structure and a preparation method of the porous foam, belongs to the technical field of photothermal conversion materials, and aims to solve the technical problem that a solar evaporator is poor in water evaporation performance and salt resistance. According to the invention, a vacuum solution pouring technology / salt template method / template auxiliary technology is combined to prepare the composite foam, and the composite foam has a surface hemispherical pore structure and a lower layer honeycomb hierarchical pore structure at the same time, which is benefited from unique surface and internal pore structures; the solar evaporator shows efficient and stable evaporation performance, high salt resistance, good self-cleaning capacity and the like in NaCl solutions with different concentrations, and the double-layer hierarchical pore composite foam has wide application prospects in sewage treatment and seawater desalination. The preparation method has the advantages of being simple in process, convenient to operate, controllable in surface pore structure and internal pore shape, capable of forming evaporators in complex shapes and the like.

The invention belongs to the technical field of seawater desalination, and particularly relates to a solar efficient photo-thermal conversion type floating ball and seawater evaporation application thereof. Specifically, the solar efficient photo-thermal conversion type floating ball comprises a spherical inner core and a photo-thermal conversion material wrapping the spherical inner core, and the density of the spherical inner core is 25-500 kg / m < 3 >; wherein the photo-thermal conversion material is coated at least twice. According to the solar efficient photo-thermal conversion type floating ball, the photo-thermal conversion material is coated at least twice, the loading capacity is improved, meanwhile, a porous network structure is formed, and the seawater evaporation rate can be increased; sunlight irradiates on the floating ball, light energy is converted into heat energy under the action of the surface photo-thermal conversion material, salt is deposited on the floating ball along with water evaporation, and surface salt deposition is automatically and dynamically removed through the free rotating motion of the floating ball on the water surface under the action of centrifugal force and water flow scouring. And self-recovery of the evaporation process and continuous seawater evaporation are realized.

The invention discloses a preparation method and application of a pH-responsive controllable oil-water separation material, polyurethane sponge is used as a substrate, polypyrrole is attached to the sponge substrate through an in-situ polymerization method, a pH-responsive polymer is introduced into the sponge substrate through a soaking method, and finally the pH-responsive controllable oil-water separation material is obtained. The controllability of the material in the oil-water separation process is reflected as follows: due to the introduction of the pH responsive polymer, the surface of the material has pH responsiveness, the surface of the material has different wettability by adjusting the pH value, different types of oil-water mixtures can be controllably separated in a targeted manner, and the adsorption and desorption of oil products can be realized. Due to the introduction of polypyrrole, the material has good photo-thermal conversion capacity, the viscosity of crude oil can be effectively reduced, and the absorption rate of the crude oil can be improved. The material with pH responsiveness has wide application prospects in the fields of oil-water separation, oil product adsorption and desorption and crude oil absorption.

The invention discloses a porphyrin-based covalent organic framework nano material, a preparation method and application of the porphyrin-based covalent organic framework nano material in polyurethane, and belongs to the field of functional nano materials and antibacterial materials. The porphyrinyl covalent organic framework nano material is prepared from 5, 10, 15, 20-tetra (4-aminophenyl) porphyrin and bis-(5-formyl furfuryl) ether through a Schiff base reaction, and the structural formula of the porphyrinyl covalent organic framework nano material is # imgabs0. The porphyrinyl covalent organic framework nano material prepared by the invention has relatively high photothermal conversion efficiency when being used as a photothermal agent, and has a relatively good sterilization effect under the condition of relatively low concentration. Besides, based on the porphyrin-based covalent organic framework nano material, a WPUS / Por-COF composite film is prepared, the composite film has excellent mechanical properties and excellent photothermal conversion efficiency, and has a good sterilization effect under the condition of relatively low concentration, bacteria can be inactivated within a short time, and the sterilization rate can reach 99% or above.

The invention relates to a preparation method and application of a Janus structure photo-thermal-piezoelectric hydrogel dressing for infected wound repair, and the preparation method comprises the following steps: respectively dissolving phenylboronic acid grafted methacrylamide gelatin and dopamine grafted hyaluronic acid in deionized water, adding MXene coated CeO2 heterojunction, and ultrasonically dispersing uniformly, so as to obtain the Janus structure photo-thermal-piezoelectric hydrogel dressing for infected wound repair. After mixing, sodium hydroxide is used for adjusting the pH value to alkalescence, and a Janus structure inner layer is formed; respectively dissolving phenylboronic acid grafted gelatin and o-nitrobenzyl alcohol grafted hyaluronic acid in deionized water, adding BaTiO3, ultrasonically dispersing uniformly, and mixing to form a Janus structure outer layer; the Janus structure photo-thermal-piezoelectric hydrogel dressing prepared by the invention has the characteristic of space-time release so as to adapt to the wound repair process, in addition, the Janus structure photo-thermal-piezoelectric hydrogel dressing also has excellent photo-thermal conversion performance, bacteria infecting the wound are killed through photo-thermal heating, physiological electric signals are effectively simulated through the piezoelectric effect, cell behaviors are regulated and controlled, and the Janus structure photo-thermal-piezoelectric hydrogel dressing can be used for wound infection repair.

The invention discloses a carbon nanotube-aerogel-aluminum silicate super-hydrophobic anti-icing material and a preparation method thereof. The composite material comprises a photo-thermal carbon nanotube-aerogel super-hydrophobic composite solution and an aluminum silicate fiber substrate. The photo-thermal carbon nano tube-aerogel super-hydrophobic composite solution is a composite solution formed by mixing carbon nano tubes, aerogel particles, resin, a low-surface-energy modifier and a diluent, the material can improve the moisture-proof and heat-insulating capacity of aluminum silicate fibers used in an outdoor high-humidity environment, photo-thermal conversion loss is reduced due to the super-hydrophobicity of the surfaces of the aluminum silicate fibers, and the photo-thermal conversion efficiency is improved. Therefore, the photo-thermal deicing efficiency of the surface is improved.

The invention discloses a preparation method of a salt-resistant polyurethane sponge evaporator for a photo-thermal interface, which comprises the following steps: taking polyurethane sponge as a support framework, taking polyvinyl alcohol as a precursor solution, adding carbon black and PEDOT: PSS (poly (3, 4-ethylenedioxythiophene): poly (styrenesulfonate)) into the precursor solution as photo-thermal materials, and synthesizing the salt-resistant polyurethane sponge evaporator by an extrusion thermal crosslinking freeze-drying method. According to the obtained evaporator, the excellent photothermal conversion performance of carbon black / PEDOT: PSS and a porous framework structure mainly comprising polyurethane / polyvinyl alcohol are fully utilized, the water absorption, the mechanical performance and the photothermal conversion efficiency of the evaporator are effectively improved, the heat conductivity is reduced, it is guaranteed that salt crystals do not appear inside and on the surface of the evaporator while efficient interface evaporation is achieved, and the service life of the evaporator is prolonged. The device can be widely applied to solar interface evaporation in saline water, actual seawater or high-salinity wastewater so as to obtain clean water resources.

The invention discloses a biochar / carbon nanotube / myristic acid composite phase change material as well as a preparation method and application thereof, and belongs to the technical field of heat storage. The meat biochar / carbon nanotube / myristic acid composite phase change material is prepared by adopting a vacuum impregnation method. The original biochar is modified by KOH, so that the specific surface area and pore volume of a sample are increased, the specific surface area of the modified KBC3 reaches 813.56 m < 2 > / g, and the loading capacity of the KOH modified biochar on MA is increased to 63%. The result shows that the MA sample is successfully loaded into the porous material, and the structure is kept intact. In order to further improve the loading rate and the leakage resistance of the phase change material, carbon nanotubes are doped in the KBC / MA phase change material, and when the loading rate of MA is improved to 75%, KBC1.5 / MA severely leaks in a shape stability performance experiment, and the mass loss rate reaches 8.5%. And KBC1.5 / CNT1 / MA only has little leakage in the thermal stability test process, so that the leakage resistance of the composite phase change material is greatly enhanced. Through BC modification and CNTs introduction, the heat conduction capability and the photothermal conversion capability of the composite PCMs are greatly improved.

The invention discloses a super-hydrophobic road ice-inhibiting coating based on a photothermal effect and nano modified particles and a preparation method of the super-hydrophobic road ice-inhibiting coating. The preparation method comprises the following steps: introducing silane modified nano silicon dioxide (SiO2) and titanium dioxide (TiO2) particles into a polyaniline solution, and preparing the composite super-hydrophobic powder through a chemical oxidation polymerization method. The preparation method comprises the following steps: firstly, modifying the surfaces of SiO2 and TiO2 nanoparticles by adopting a silane coupling agent, and endowing the SiO2 and TiO2 nanoparticles with low surface energy and hydrophobic property; and then adding the modified nano-particles into an aniline monomer solution, reacting with doped acid and an oxidizing agent, so that polyaniline molecules are subjected to in-situ polymerization on the surfaces of the particles, and the composite super-hydrophobic powder with a micro-nano structure is formed. The obtained composite material has excellent photothermal conversion performance and super-hydrophobic performance at the same time, and the efficient photothermal material heat absorption ice melting effect and the synergistic ice restraining effect of the photothermal material and the super-hydrophobic material can be achieved. Compared with a traditional ice-inhibiting coating, the coating disclosed by the invention shows stronger ice-resisting capability in a low-temperature and high-humidity environment, has good durability, mechanical stability and environmental protection property, and is suitable for the field of ice prevention and ice inhibition in cold regions such as roads, bridges, airport runways and the like.

The invention discloses a carbon fiber-based solar photo-thermal conversion material as well as a preparation method and application thereof, relates to the technical field of solar photo-thermal conversion materials, and solves the problems of poor mechanical performance and photo-thermal conversion performance of an existing photo-thermal conversion material. The preparation method comprises the following steps: thermally mixing a polyvinyl alcohol sodium alginate mixed solution, a graphene oxide solution and a cross-linking agent aqueous solution to prepare a cross-linking precursor solution; the preparation method comprises the following steps: by taking a carbon felt as a substrate, injecting a crosslinking precursor solution into the substrate by utilizing a vacuum infusion process, infiltrating the carbon felt, performing aging crosslinking, and then performing directional freeze drying to obtain a modified carbon felt; preparing an electroplating solution by using copper sulfate, sodium potassium tartrate tetrahydrate, disodium hydrogen phosphate and formaldehyde, adjusting the pH value by using NaOH, growing copper on the surface of the modified carbon felt by using an electroplating process, and carrying out vacuum drying; and putting the modified carbon felt subjected to vacuum drying after electroplating into a tubular furnace to obtain the carbon fiber-based solar photothermal conversion material. The method has a wide application prospect in the field of seawater evaporation desalination.

The invention discloses a solar interface evaporator and a preparation method and application thereof. The evaporator comprises a porous cellulose supporting layer and a photo-thermal composite hydrogel layer loaded on the cellulose supporting layer, and the porous cellulose supporting layer and the photo-thermal composite hydrogel layer are combined in a gel in-situ cross-linking mode to form an integrated composite structure. The photo-thermal composite hydrogel layer is composite hydrogel formed by cross-linking polyvinyl alcohol, chitosan quaternary ammonium salt and carbon black. The preparation method comprises the following steps: adding polyvinyl alcohol and chitosan quaternary ammonium salt into a solvent to form a transparent mixed solution, adding the carbon-based photothermal conversion material, and continuously heating and stirring to prepare a hydrogel precursor solution; then adding glutaraldehyde and hydrochloric acid, and carrying out cross-linking reaction to form a hydrogel system; and immersing the cellulose sponge, standing, circularly and alternately freezing and unfreezing, and finally freeze-drying to obtain the product. The evaporator disclosed by the invention integrates highlight absorption, high heat utilization, water transportation, salt resistance and antibiosis, can realize large-scale production, and is suitable for scenes such as seawater desalination, sewage purification and emergency water supply.

The invention discloses a method for degrading antibiotics in wastewater based on chitosan aerogel. The method comprises the following steps: adding chitosan aerogel Co-PBA / CS and potassium hydrogen peroxymonosulfate into the antibiotic-containing wastewater, and degrading under stirring. The method provided by the invention has a ciprofloxacin degradation capability of 94.7%. In addition, the material also has excellent self-cleaning and photo-thermal conversion performance, and can realize surface cleaning. The multifunctional aerogel provides a new strategy for removing pollutants such as ciprofloxacin in a complex and severe water environment.

The invention belongs to the technical field of sewage treatment, and particularly discloses a treatment method and device for degrading tetracycline antibiotics in wastewater based on solar energy. The photo-thermal continuous flow reactor comprises a copper heat exchanger, the surface of the copper heat exchanger is sequentially coated with a heat conduction material and a photo-thermal conversion material from inside to outside, and the copper heat exchanger is provided with a water inlet and a water outlet. The treatment method for degrading the tetracycline antibiotics in the wastewater utilizes a photo-thermal continuous flow reactor for treatment, and comprises the following steps: adding an oxidizing agent into the wastewater containing the tetracycline antibiotics, and then introducing the wastewater into a copper heat exchanger from a water inlet; the copper heat exchanger is illuminated for degradation treatment; finally, the degraded wastewater is discharged through a water outlet. According to the method, the tetracycline antibiotics are converted into copper complexes of the tetracycline antibiotics, so that not only is the dependence on temperature reduced, but also the degradation efficiency is improved, and the tetracycline antibiotics in the wastewater are degraded by continuous flow based on solar energy.

The invention discloses a targeted nano delivery system based on curcumin (Cur) and near-infrared aggregation-induced emission (AIE) molecule BDTA and application of the targeted nano delivery system in treatment of glioblastoma (GBM), and belongs to the field of biomedicine. The nano platform is composed of nanoparticles (MPMs (at) Cur-BDTA NPs) modified by a macrophage membrane, curcumin and BDTA are combined by adopting a coprecipitation method, and the targeting property of the nano platform to tumors is enhanced through modification of the macrophage membrane. The nanometer platform combines the functions of photo-thermal therapy (PTT), photodynamic therapy (PDT) and chemotherapy, and can achieve multiple treatment effects. The curcumin improves PTT sensitivity by down-regulating expression of heat shock protein HSP-70 in the platform, and effectively improves photothermal conversion efficiency (87.6%) and singlet oxygen generation amount (1.7 times higher than that of a control group) through a Foster resonance energy transfer (FRET) mechanism. In a glioblastoma in-vitro experiment, the nano platform shows a synergistic treatment effect of photo-thermal, photodynamic and chemotherapy. The invention provides an intelligent treatment platform integrating photo-thermal treatment, photodynamic treatment and chemotherapy, and provides an efficient and safe innovative treatment strategy for precise treatment of glioblastoma.

The invention discloses an aggregation-induced emission fluorescent compound with near infrared (NIR) luminescence. The fluorescent compound is wrapped by a polymer matrix to form a nano aggregate, which proves that the fluorescent compound shows excellent photothermal conversion efficiency while maintaining high fluorescence quantum yield. Therefore, compared with the mode of relying on high permeability and retention (EPR) effect, the nanometer aggregate accumulation guided by the photo-induced thermoacoustic effect (PTA) can further improve the photo-thermal treatment effect. In-vitro and in-vivo verification further confirms that the nano-aggregate shows excellent fluorescence-guided optical diagnosis and treatment capability in the aspect of tumor elimination.

The invention discloses a preparation method of a salt-resistant double-layer photo-thermal aerogel evaporator. The preparation method comprises the following steps: S1, cutting and cleaning foamed nickel, and then carrying out vacuum drying; s2, preparing Cu2O / NF (nickel nitrate); s3, preparing ppy-Cu2O / NF (nickel fluoride); s4, preparing hydrogel; and S5, flatly placing a sample ppy-Cu2O / NF on the top surface of the hydrogel, continuing to stand for gelling, enabling the photo-thermal layer and the bottom layer hydrogel to be fully combined, pre-freezing, transferring into a freeze dryer, and freeze-drying to finally obtain the salt-tolerant double-layer photo-thermal aerogel evaporator, namely the lightweight porous aerogel material ppy-Cu2O / NF / FCP with the double-layer structure. The device has the advantages that the high-level evaporation rate and efficient energy conversion are achieved, and efficient photo-thermal conversion and heat management are achieved through the double-layer structure design.

The invention discloses a method for improving photo-thermal conversion efficiency of a photo-thermal material under large-range light intensity, the photo-thermal material and a solar heat collector, and belongs to the field of solar evaporation water treatment. According to the technical scheme, the method comprises the steps that polyaniline particle-loaded carbon aerogel is prepared, the light intensity range is greatly widened to 10 sunlight intensities or above through a Fresnel lens, the corresponding relation between the material surface water evaporation rate and the temperature change is established, and the energy loss is reduced to the maximum extent by adding a foam side heat insulation layer; and the water evaporation rate of the photo-thermal material is improved. The method is applied to the aspect of solar water evaporation, and the problem that the water evaporation rate is low in an existing solar evaporation method is solved.

The invention belongs to the technical field of medicines, and discloses a near-infrared cyanine probe for detecting penicillin G acylase as well as a preparation method and application of the near-infrared cyanine probe. According to the research, a near-infrared fluorescent probe Cy-NEO-PA responding to penicillin G acylase (PGA) is developed, so that the influence of environmental factors on the formation of an acinetobacter baumannii biological membrane is observed. Research results show that glucose inhibits the generation of PGA to enhance the formation of a biological membrane, while phenylacetic acid (PAA) stimulates the generation of PGA and inhibits the formation of the biological membrane. The observation results highlight the excellent capability of Cy-NEO-PA in accurately measuring PGA kinetics, and reveal the key effect of PGA in biological membrane development. In addition, the Cy-NEO-PA has good biocompatibility, strong active oxygen generation, efficient photo-thermal conversion and bacterial targeting ability, so that the Cy-NEO-PA becomes a promising drug for resisting bacterial infection and promoting wound healing through photo-thermal / photodynamic therapy.

The invention discloses a preparation method of a protein halo-coated silicon-coated gold nanorod and a PCR amplification method and kit based on the protein halo-coated silicon-coated gold nanorod, and belongs to the technical field of PCR detection. The photo-thermal nano material is composed of an AuNR coated SiO2 core-shell structure and an external protein halo layer, the protein halo layer avoids inhibition of AuNR on a PCR reaction system, meanwhile, adsorption of AuNR on biological small molecules is effectively reduced, non-specific amplification is reduced, and normal amplification of PCR reaction is guaranteed; and the protein halo layer is used as a thermal insulation layer to optimize heat exchange and maintain the temperature uniformity of the reaction liquid. When the kit is applied to a photo-thermal PCR detection reagent, DNA of a pathogen to be detected can be efficiently and stably amplified and detected within 10 minutes, the kit has huge application potential in the fields of early screening of infectious diseases, food safety detection and the like, collaborative optimization of photo-thermal conversion efficiency, biocompatibility, detection sensitivity and operation convenience is achieved, and the kit has a wide application prospect. And an efficient solution is provided for prevention and control of infectious diseases, food safety monitoring and biomedical research.

The invention provides an optical transparency-optical confinement composite nanofiber membrane as well as a preparation method and application thereof. The optical transparency-optical confinement composite nanofiber membrane comprises a PDMS (Polydimethylsiloxane) / PS (Polystyrene) / TPU (Thermoplastic Polyurethane) nanofiber membrane and a photothermal conversion material layer loaded on the PDMS / PS / TPU nanofiber membrane, the PDMS / PS / TPU nanofiber membrane is prepared by taking PDMS, PS and TPU as raw materials and adopting an electrostatic spinning technology; the photothermal conversion material layer comprises honeycomb porous carbon nanofibers and PDA (Personal Digital Assistant). The optical transparency-optical confinement composite nanofiber membrane and the PDMS / PS / TPU nanofiber membrane have excellent light transmittance and hydrophobicity, the photo-thermal conversion material layer has excellent light absorptivity and high photo-thermal conversion capacity, and the optical transparency-optical confinement composite nanofiber membrane has high membrane flux when being used for photo-thermal membrane distillation desalination. And the photo-thermal film is excellent in distillation performance stability.

The invention discloses a multi-shell photo-thermal phase change microcapsule and a preparation method thereof, the multi-shell photo-thermal phase change microcapsule comprises a capsule wall and a capsule core, the capsule core is an organic phase change material, the capsule wall comprises a titanium dioxide layer, a graphene layer and a polydopamine layer, the graphene layer is located outside the titanium dioxide layer, and the polydopamine layer is located outside the graphene layer. The multi-shell photo-thermal phase change microcapsule disclosed by the invention can realize full-wave band capture, and is high in photo-thermal conversion efficiency and good in shell stability.

The invention relates to the technical field of hydrogel preparation, in particular to a preparation method of novel biomass hydrogel. The biomass hydrogel prepared by the invention overcomes the problems of poor hygroscopicity and poor recyclability of traditional hydrogel in a low-humidity environment. The cassava starch is oxidized by sodium periodate to prepare dialdehyde starch, so that the hydrophilicity is enhanced; sodium alginate is coated and combined with an epoxy group to covalently bond and fix lithium chloride, so that salt slow release and low-humidity deliquescence are realized; the ink containing the nano carbon material is introduced, so that efficient photo-thermal conversion is realized; meanwhile, after the substances are subjected to three-dimensional crosslinking, a polymer network-shaped gel structure is formed, and gradient drying and rehydration control are combined, so that the porous structure and the mechanical strength are guaranteed. The prepared hydrogel can quickly absorb moisture and efficiently perform photo-thermal evaporation in a low-humidity environment, and is good in recyclability.

The invention provides a solar seawater desalination photothermal conversion efficiency optimization method and system based on machine learning, and the method comprises the steps: firstly collecting the solar spectrum distribution data, seawater turbidity spectrum data, real-time heat flow data and semiconductor nanomaterial data of a target sea area; and constructing a material spectrum mapping library based on the light absorption characteristics of the nano material. Through coupling analysis of a solar spectrum and a seawater turbidity spectrum, an environmental constraint condition is formed, a Bayesian optimization model is combined with a material spectrum mapping library and real-time heat flow data, and an optimal nano material mixing ratio is generated under environmental constraint. Then, the interface evaporation rate is predicted through the deep residual network, an optimal material morphology configuration scheme is obtained, and finally the morphology configuration is applied to semiconductor nanomaterial preparation. The photo-thermal conversion efficiency of the solar desalination system in the high-turbidity seawater environment is improved.

The invention belongs to the technical field of mid-infrared photoelectric detectors, and particularly relates to a mid-infrared photoelectric detector based on an ultra-thin metasurface and a preparation method thereof.The method comprises the steps that firstly, a substrate and an element atomic material are provided, an ellipsometry test is conducted to obtain dielectric functions of the substrate and the element atomic material, the dielectric functions serve as input to be substituted into finite element software, and the finite element software serves as the input to obtain the ultra-thin metasurface-based mid-infrared photoelectric detector; theoretical modeling design is carried out on the metasurface, the metasurface is manufactured after the appropriate metasurface size is obtained, then reflectivity and transmissivity tests under different polarizations are carried out on the metasurface through an ellipsometry test, a metal layer is deposited on the metasurface through a standard electron beam evaporation technology to serve as an electrode, and the metasurface is manufactured. And finally, a CO2 laser is selected to irradiate the metasurface in a photoelectric detection experiment. By optimizing the structure parameters and the material performance of the metasurface, middle and far infrared broadband absorption, efficient photo-thermal conversion and photoelectric response are achieved, and therefore the problems that in the prior art, the corresponding wavelength is short, devices are heavy, and the detection efficiency is insufficient are solved.

The invention provides a composite photo-thermal hydrogel for seawater desalination and a preparation method and application thereof, the hydrogel has a structural unit of a structure as shown in a formula I. COF with photo-thermal performance is compounded with the hydrogel, and the hydrogel has a three-dimensional long-range ordered pore structure to promote transmission of water molecules; and the COF dispersed in the material contains porphyrin and a C = N double-bond connection structure, so that the material has excellent photothermal conversion efficiency. Therefore, under the irradiation of sunlight, the composite photo-thermal hydrogel disclosed by the invention can realize photo-thermal conversion to realize seawater evaporation, the seawater evaporation rate reaches 3.6 kgm <-1 > h <-1 >, and the performance is improved by about 3 times compared with that of a traditional carbon-based material. According to the preparation method of the composite photo-thermal hydrogel, large and complex equipment is not involved in the preparation method, the preparation technological process is simple, and industrial large-scale production is facilitated; and the reaction temperature in the preparation process is low, the energy consumption is also reduced, and the cost advantage is remarkable.

The invention discloses a carbon aerogel / reduced graphene oxide double-framework composite phase change material based on shaddock peel as well as a preparation method and application of the carbon aerogel / reduced graphene oxide double-framework composite phase change material. According to the method, the carbon aerogel / reduced graphene oxide double-framework material (CPA-rGO) with a hierarchical pore structure is constructed by taking waste shaddock peel as a raw material through freeze drying, a layer-by-layer self-assembly (LbL) technology and a gas-phase reduction and high-temperature carbonization process. And then, loading n-octacosane in the porous skeleton by a vacuum-assisted impregnation method to form the composite phase change material (OCPA-rGO) with a stable shape. The material has excellent leakproof performance (the leakage rate at 70 DEG C is only 4%), high thermal conductivity (0.366 W / (m.K)), remarkable photothermal conversion efficiency (91.6%) and electrothermal response characteristic, has a temperature sensitive resistance function, and can be applied to building energy-saving temperature control and intelligent household high-temperature early warning systems. According to the invention, high-value utilization of agricultural wastes is realized, and a new thought is provided for design of efficient and multifunctional phase change energy storage materials.

The invention discloses a metal polyphenol nano material based on chlorogenic acid and a preparation method and application thereof.The preparation method comprises the steps that chlorogenic acid and distearoyl phosphatidyl ethanolamine-polyethylene glycol 2000 are mixed and dissolved in an anhydrous tetrahydrofuran solvent, and a first mixed solution is prepared; adding a FeCl3 solution into the first mixed solution until a clear and transparent system is formed, so as to obtain a second mixed solution; and removing the anhydrous tetrahydrofuran solvent of the second mixed solution to obtain the metal polyphenol nano material (CA-Fe NPs) based on chlorogenic acid. The metal polyphenol nano material has excellent photothermal conversion performance, and can be applied to in-vitro antibiosis, antioxidation, anti-inflammation and wound healing promotion.

The invention discloses photo-thermal conversion wood-based hydrogel and a preparation method thereof in the technical field of nano materials and biological materials, and the preparation method comprises the following steps: synthesizing a conjugated polymer CP, dissolving the CP in THF, and adding DSPE-PEG2000 and hemin to obtain CP-Hemin nano powder; and compounding the CP-coated Hemin nano powder, flexible wood and PVA (Polyvinyl Alcohol) to obtain the wood-based hydrogel. The wood-based hydrogel provided by the invention has high photothermal conversion efficiency, can be rapidly heated under laser induction of a near-infrared second region, releases reactive oxygen free radicals at the same time, can be applied to photothermal therapy and photodynamic therapy, and has a prospect of being applied to the fields of catalysis, medical treatment and the like.