The invention discloses a
lithium-rich
manganese-based
lithium ion battery and a preparation method thereof, the
lithium ion battery comprises a positive
electrode, a negative
electrode and an
electrolyte, the positive
electrode comprises a collector electrode and a positive
electrode material uniformly deposited on the surface of the collector electrode, and the positive
electrode material comprises a positive electrode active material, a conductive agent and a binder which are uniformly mixed; the positive electrode active material comprises a layered lithium-
manganese-rich positive
electrode material and a lithium heteropolyacid
coating layer
coating the surface of the layered lithium-
manganese-rich positive electrode material in situ; according to the
lithium ion battery disclosed by the invention, layered lithium-rich manganese modified by
heteropoly acid and salt thereof is taken as a positive electrode active material, so that the
lithium ion battery has excellent
cycling stability, and has an extremely high capacity
retention ratio which can reach 100% at most after being circulated for 400 times under the
high current density of 200
milliampere / g; and meanwhile, better
voltage holding ratio and rate capability are realized. The preparation process still uses the traditional
coating process, and no additional modification step is needed.