The invention relates to a preparation method and application of a
lithium battery negative
electrode binder, belongs to the technical field of
lithium batteries, and solves the technical problems that an existing
lithium battery negative
electrode binder is poor in
mechanical strength, poor in cycle performance when applied to a
lithium battery, unstable in
processing and the like. According to the solution, the
lithium battery negative
electrode binder is prepared from the following components in percentage by
mass: 0.5 to 1 percent of
sulfonic acid functionalized COFs and 99 to 99.5 percent of
polyacrylic acid aqueous solution or 0.5 to 1 percent of
carboxylic acid functionalized COFs and 99 to 99.5 percent of
polyacrylic acid aqueous solution; the
sulfonic acid functionalized COFs or
carboxylic acid functionalized COFs are prepared from a first
monomer and a second
monomer through a
Schiff base reaction; the preparation method of the
lithium battery negative electrode binder comprises the following steps: 1) preparing
sulfonic acid functionalized COFs or
carboxylic acid functionalized COFs; 2) weighing
polyacrylic acid and water, and uniformly mixing to prepare a polyacrylic acid
aqueous solution; and 3) weighing 0.5%-1% of sulfonic acid functionalized COFs or carboxylic acid functionalized COFs prepared in the step 1), adding the weighed sulfonic acid functionalized COFs or carboxylic acid functionalized COFs into 99%-99.5% of a polyacrylic acid aqueous solution, and uniformly dispersing the sulfonic acid functionalized COFs or carboxylic acid functionalized COFs in the polyacrylic acid aqueous solution in an ultrasonic manner. Compared with the prior art, the lithium battery negative electrode binder has the advantages that the lithium battery negative electrode binder is high in
mechanical strength, a prepared electrode plate is small in impedance and not prone to breakage during
processing, and a prepared lithium battery is high in
cycling stability and
cycling efficiency, large in capacity and the like.