21results about How to "Improve crystal structure" patented technology

The invention discloses a catalyst used for preparing acrylic acid and butyl ester by the dehydration of butyl lactate and a preparation method thereof. The catalyst is a composite catalyst, comprising a main catalyst A and auxiliary catalysts B, C, D and E, wherein, A is calcium sulphate, B is sulphuric acid, C is phosphate, D is alkaline matter and E is promoter. The preparation method comprises the steps as follows: five compositions A, B, C, D and E are sufficiently mixed, baked for 2-10 hours at the temperature of 200-800DEG C and formed for standby. The catalyst has high catalytic activation; under the catalysis of the catalyst, the molar yield reaches 75.1 percent and the molar selectivity of the acrylic acid and butyl ester reaches 71.5 percent. The preparation method has the advantages that the crystal structure of the main catalyst can be improved so as to be beneficial for carrying out the reaction; and the introduction of different auxiliary catalysts and quantities is helpful to improve the conversion ratio of the raw material and the product selectivity and is beneficial for improving the strength of the catalyst.

The invention relates to the technical field of lithium battery positive electrode material preparation, in particular to coated doped type lithium manganese iron phosphate gradient temperature control preparation equipment and method.The equipment comprises five temperature control bins arranged side by side, a sintering bin, a vertical flow guide plate, a unique temperature control gas inlet assembly and the like work cooperatively, the temperature control gas inlet assembly can flexibly adjust the gas state, and the temperature control gas inlet assembly can control the temperature of the lithium manganese iron phosphate; the preparation method comprises the following steps: firstly, mixing a lithium source, a manganese source and the like with a specific composite carbon source, and performing spray drying to obtain precursor particles; according to the preparation method, the defects of a traditional preparation technology in the aspects of temperature control and coating forming are overcome, accurate gradient temperature control can be achieved, the temperature uniformity can be improved, the coating effect can be optimized, and the preparation method is suitable for industrial production. And the performance of the lithium manganese iron phosphate positive electrode material is remarkably improved.

This invention discloses an epitaxial wafer for a deep ultraviolet (UV) light-emitting diode (LED) and its fabrication method, relating to the field of semiconductor optoelectronic devices. The UV LED epitaxial wafer includes a substrate and a buffer layer, an N-type AlGaN layer, an active layer, an electron blocking layer, and a P-type AlGaN layer sequentially grown on the substrate. The active layer has a periodic structure, with each period comprising a sequentially stacked quantum well layer and a quantum barrier layer, and the number of periods in the active layer is ≥2. The quantum barrier layer comprises a sequentially stacked AlInGaN layer and a P-AlInGaN layer. Implementing this invention can effectively improve the luminous efficiency of deep ultraviolet LEDs.

The invention provides a production process of a high-wear-resistance and impact-resistance aramid fiber material, and relates to the technical field of material preparation, and the production process comprises the following steps: S1, raw material preparation: selecting a para-aramid fiber prepolymer, a hydroxylated boron nitride nanosheet, N-methyl pyrrolidone, a wear-resistance enhancer and an impact-resistance modifier according to a preset proportion, S2, mixing, S3, polymerization reaction, S5, extrusion molding, S6, extrusion molding, and S7, molding. Transferring the mixed system into a reaction kettle, introducing nitrogen for 35-55 minutes, and replacing air in the reaction kettle to form an aramid polymer; s4, molding processing: cooling the nylon polymer to room temperature, then putting the nylon polymer into spinning solution storage equipment, and winding the stretched fibers; s5, auxiliary treatment, wherein the wound fibers are washed with water and dried; according to the invention, the aramid polymer has a good crystal structure and high molecular weight, the wear resistance of the material is improved, the interface bonding force between the fiber and the matrix can be improved, and the impact resistance of the material is further improved.

A catalyst for coupling pyridine to prepare 2,2-bipyridine and a preparation method thereof, relates to the technical field of catalyst preparation. The catalyst takes nickel oxide as an active component, enhances the basicity of the catalyst surface by introducing an auxiliary element, loads the active component on alumina by a deposition precipitation method, and is prepared by kneading and extruding into a strip. The method is simple in preparation and low in cost. The obtained catalyst can make the conversion rate of pyridine reach 14.98% and above under low temperature reaction conditions of 110 DEG C, the selectivity of 2,2-bipyridine is as high as 80% and above, and the catalyst has good catalytic activity and application prospect.

A highly efficient method for recycling waste crystalline silicon solar cells includes the following steps: S1, placing the waste crystalline silicon solar cells in a mixed solution of phosphate and ammonium fluoride to react, dissolving the aluminum back surface and initially etching the silicon nitride layer, causing the silver grid lines to detach, resulting in solid-liquid separation of the silver grid lines and a filter cake; S2, continuing to immerse the filter cake in the mixed solution from step S1 to completely etch the silicon nitride layer, obtaining a silicon wafer; S3, immersing the silicon wafer in a sodium hydroxide solution to remove the surface oxide layer, cleaning, and drying to obtain a high-purity silicon wafer. This invention achieves highly efficient separation of silver and aluminum grid lines from the silicon wafer and precise removal of silicon nitride and oxide layers through a stepwise chemical etching strategy, achieving a total silicon wafer recovery rate of over 96%. The process is short, simple to operate, and has low reagent costs, effectively solving the pollution problem of waste crystalline silicon solar cells, demonstrating significant environmental benefits and economic value, and is easy to scale up and apply.

This invention discloses a method for preparing rare earth metals by electrolytic oxides using a fluoride system, belonging to the field of rare earth metal preparation technology. This invention modifies graphite anodes used in rare earth molten salt electrolysis. It improves oxidation and corrosion resistance, reduces anode wear, lowers replacement frequency, and increases production efficiency, yielding high-purity, low-carbon rare earth metal lanthanum. A three-dimensional network framework material is constructed using Prussian blue self-assembly and SiC is deposited to obtain a composite framework material. During pre-calcination with graphite and other materials, the derivatives optimize the crystal structure and interfacial bonding, enhancing the strength of the pre-shaped anode material and ensuring the integrity and performance stability of the electrode structure. Thirdly, the pre-shaped anode material is impregnated with a specific impregnation solution, altering the gas diffusion path and resistance, inhibiting oxidation reactions, and high-temperature sintering generates substances that fill the pores, forming a dense microstructure. Simultaneously, the compounds formed by phosphoric acid enhance cohesion and adhesion, improving oxidation and molten salt corrosion resistance, and extending the service life of the graphite anode.

The present disclosure relates to a kind of metal organic framework adsorption material and its preparation method and use, the method comprises: S1, the suspension of containing metal organic framework raw material is carried out ultraviolet irradiation treatment, obtain the light product;S2, the light product is carried out solid-liquid separation, obtain the solid product;Wherein, the wavelength of ultraviolet irradiation treatment is 200-400nm.The method provided in the present disclosure can efficiently and accurately regulate defect concentration, the crystal structure and morphology of the material prepared are intact, and have more active sites.The metal organic framework adsorption material provided in the present disclosure has excellent adsorption performance when used for adsorbing antibiotics.

This invention belongs to the field of ceramic equipment manufacturing technology, and discloses a metallized ceramic shell for a vacuum interrupter and its processing technology. The process uses low-sodium α-alumina with 0.5~1μm grain size as raw material, and acid washing improves its chemical purity and grain boundary stability. During granulation, the moisture content is controlled to ≤0.1%, and homogenization is used to remove iron and eliminate conductive impurities. A drying process is added between pressing and turning to improve processing precision. Through programmed temperature sintering combined with atmosphere control, the crystal structure is optimized and organic matter and gases are expelled, avoiding closed pore defects. After firing, polishing reduces surface roughness and prevents dust adsorption and conductivity. The glazing process uses bentonite and silica to adjust the glaze viscosity, ensuring uniform glaze coverage and matching the thermal expansion of the ceramic body, improving the outer surface insulation performance. The synergistic effect of each step comprehensively improves the purity, density, and surface quality of the ceramic shell, effectively meeting the stringent insulation strength requirements of high-voltage vacuum interrupters.

The invention belongs to the technical field of organic photoelectric materials, and particularly relates to a nitrogen-containing heterocyclic compound and an organic electroluminescent device thereof. According to the nitrogen-containing heterocyclic compound provided by the invention, through accurate design and coordinated regulation of a molecular structure, an energy barrier of electron transmission is effectively reduced, and efficient electron injection and transmission are realized, so that a device can achieve high brightness and high current efficiency under low driving voltage, and the power consumption of the device is reduced. The nitrogen-containing heterocyclic compound provided by the invention has a very good crystal structure and film form, and can prolong the service life and work stability of a device. Meanwhile, the nitrogen-containing heterocyclic compound provided by the invention also has proper HOMO energy level and LUMO energy level, can be well matched with an adjacent organic functional layer in energy level, can effectively reduce interface defects and charge recombination, and improves the overall photoelectric conversion efficiency and stability of a device.

The invention relates to a precious metal three-way catalyst as well as a preparation method and application thereof. The precious metal three-way catalyst comprises an alumina carrier, a cerium-zirconium solid solution and an active component M1, metal M2 is also loaded on the alumina carrier; the cerium-zirconium solid solution covers the surface of the alumina carrier, and the active component M1 is dispersed on the surface of the cerium-zirconium solid solution; the active component M1 comprises any one or a combination of at least two of Rh, Ir or Ru; the metal M2 comprises a combination of at least two of Pd, Pt, Rh or Au; the active component M1 and the metal M2 comprise at least three different elements. The noble metal three-way catalyst provided by the invention is used for degrading CO, NOx and CH3OH in an equivalent combustion mode, and is good in low-temperature activity, good in hydrothermal stability, relatively small in performance difference after hydrothermal aging, and wide in application prospect.

The invention relates to the technical field of batteries, and discloses a sodium battery positive electrode material with a heterostructure and a preparation method and application thereof.The preparation method comprises the steps that 1, a nickel source, a manganese source and a first solvent are subjected to first mixing, and a solution A is obtained; carrying out second mixing on a niobium source and a second solvent to obtain a solution B; (2) under a protective atmosphere, carrying out a co-precipitation reaction on the solution A, the solution B, a precipitator solution and a complexing agent solution to obtain a first precursor material; (3) performing third mixing on the first precursor material, a lithium source and a sodium source, and performing first heat treatment to obtain a second precursor material; and (4) carrying out second heat treatment on the second precursor material to obtain the sodium battery positive electrode material with the heterostructure. According to the preparation method provided by the invention, a coprecipitation reaction is combined with a two-time heat treatment process, and the cathode material with a heterostructure, which is uniform in distribution and stable in structure, is prepared, so that the electrochemical performance of a battery is improved.

The invention discloses ultra-white quartz sand, raw materials for manufacturing the ultra-white quartz sand comprise quartz ore and a composite fluxing agent, raw materials for manufacturing the composite fluxing agent comprise sodium chloride powder and potassium chloride, the mass fraction of the quartz ore is 100 parts, and the mass fraction of the composite fluxing agent is 0.9-1.1 parts. The high-purity quartz ore and high-precision color sorting equipment are adopted, visible impurities and part of harmful impurities are preliminarily removed, a good foundation is laid for the subsequent process, the arranged composite pickling solution contains hydrochloric acid, concentrated sulfuric acid and oxalic acid, compared with a single pickling solution, different types of impurities can be removed in a targeted mode, and the production efficiency is improved. The removal rate of impurities such as iron and aluminum is obviously improved; and secondly, sodium chloride powder and potassium chloride are added as fluxing agents in the drying and calcining process, and two-stage calcining and inert gas protection are adopted, so that trace impurities can be further removed, the crystal structure of the quartz ore can be optimized, and the whiteness and purity of the product can be improved.

The invention discloses a Mo-assisted co-doped disordered rock salt Li1. 3Mn0. 4Nb0. 3O2 lithium-rich positive electrode material as well as a preparation method and application thereof. The preparation method comprises the following steps: taking metal oxides such as Li2CO3, Mn2O3, Nb2O5, MoO2, SnO2 and Fe2O3 as precursors, weighing according to a specific stoichiometric ratio, and additionally adding about 10% of Li2CO3 to compensate for Li loss; the preparation method comprises the following steps: fully mixing, carrying out high-energy ball milling in an argon atmosphere, tabletting, heating to 1000 DEG C at a speed of 5 DEG C / min in the argon atmosphere in a tubular furnace, calcining for a certain time at a constant temperature, naturally cooling, and rapidly transferring to a glove box. The positive electrode material is used for the lithium ion battery, the charge-discharge specific capacity and the energy density of the lithium ion battery can be improved, the preparation process is simple, the cost is low, and large-scale production is easy.

The application belongs to the technical field of ion sieve adsorption, and particularly relates to a manganese-based ion sieve composite hydrogel and a preparation method thereof. 1.6 Mn 1.6 O4 precursor, and further processing obtains H 1.6 Mn 1.6 O4 ion sieve. The H 1.6 Mn 1.6 O4 ion sieve is mixed with a photo-thermal agent and a surfactant to obtain an HMO suspension; the HMO suspension is mixed with a gelatin aqueous solution, acrylamide and a pore-forming agent to obtain a hydrogel premix; the hydrogel premix is subjected to low-temperature initiation and high-temperature curing, and then is soaked in deionized water to obtain the manganese-based ion sieve composite hydrogel. The composite hydrogel prepared by the application has strong lithium ion adsorption force and can effectively complete the function of lithium extraction from salt lake brine.

The utility model relates to a kind of phosphogypsum heat treatment modification devices, belong to phosphogypsum processing technical field.It includes feeding system, and feeding system includes feed hopper, and feed hopper bottom is equipped with discharge pipe, and discharge pipe is equipped with discharge monitoring mechanism on, and feed hopper is also equipped with anti-blocking mechanism in, and discharge pipe one end is equipped with conveying mechanism, and conveying mechanism one end is rotatably installed with rotary kiln, and rotary kiln is equipped with atmosphere control system on, and the burner of rotary kiln other end is equipped with, and rotary kiln other end is also equipped with cooling system, and the cooling system one end is equipped with receiving hopper.The utility model is equipped with discharge monitoring mechanism on discharge pipe, whether discharge pipe is blocked during discharging process can be monitored, if there is blockage, can be found in time and handle through anti-blocking mechanism, ensure normal discharging.Prevent phosphogypsum from adhering and accumulating in feed hopper, avoid forming "bridge" phenomenon.

This invention relates to the field of advanced petrochemical new materials technology, and discloses a luminescent composite material, its preparation method, and its application. The composite material comprises the following components: homopolymer polypropylene, polybutylene succinate, a compatibility modification system, double-modified rare-earth strontium aluminate luminescent powder, dispersant, antioxidant, weathering agent, toughening agent, nucleating agent, and silane coupling agent. This invention employs a compatibility modification system composed of maleic anhydride-grafted PP-g-PBS copolymer and double-modified nano-montmorillonite. The maleic anhydride-grafted PP-g-PBS copolymer constructs a chemical link between the polypropylene and polybutylene succinate molecular chains through a grafting reaction, reducing the interfacial tension between the two resins. The double-modified nano-montmorillonite, after ionic liquid intercalation and silane grafting treatment, exhibits increased interlayer spacing and improved surface activity, uniformly dispersed in the matrix, and acts as a physical crosslinking point, improving the compatibility of the matrix resin and preventing phase separation.

This invention relates to the field of food processing technology, specifically to a method for improving the starch structure and digestibility of sprouted corn flour, the prepared sprouted corn flour, and its applications. A method for improving the starch structure and digestibility of sprouted corn flour includes the following steps: S1, preparation of sprouted corn: soaking and germinating corn kernels to obtain sprouted corn; S2, microwave treatment: subjecting the sprouted corn to microwave treatment; S3, forced-air drying: subjecting the microwave-treated sprouted corn to forced-air drying until constant weight, obtaining dried sprouted corn; S4, pulverization: pulverizing and sieving the dried sprouted corn to obtain sprouted corn flour. This method not only significantly improves the drying efficiency of sprouted corn but also improves the starch structure characteristics of the sprouted corn flour, particularly increasing the content of resistant starch and reducing in vitro digestibility, thereby providing a high-quality raw material for developing corn-based foods with low digestibility or low glycemic index.

This application provides a phosphogypsum and its modification method, as well as a high-strength, water-resistant paper-faced gypsum board and its preparation method. The phosphogypsum modification method includes: drying the phosphogypsum to be modified to constant weight; mixing aluminum sulfate with the dried phosphogypsum, followed by microwave calcination, grinding, and aging to obtain modified anhydrous phosphogypsum. This phosphogypsum modification method can effectively reduce the content of soluble impurities in phosphogypsum, and the process is simple.

The invention relates to the technical field of biological coating preparation, in particular to a calcium-phosphorus coating preparation method and system.The method comprises the steps that a to-be-treated base body in a coating preparation environment is pretreated, a pretreated base body is obtained, a coating base material set is used for obtaining calcium-phosphorus precursor slurry, and the calcium-phosphorus precursor slurry is prepared; the method comprises the following steps: carrying out laser melting on a pretreated matrix and calcium-phosphorus precursor slurry to obtain a molten calcium-phosphorus layer, carrying out cooling crystallization on the molten calcium-phosphorus layer to obtain a target coating, carrying out quality detection on the target coating to obtain a detection result, if the detection result is unqualified, obtaining an abnormal type, and carrying out adjustment preparation on the target coating based on the abnormal type. And if the detection result is qualified, taking the target coating as the qualified coating. According to the invention, the high efficiency and stability of preparation of the calcium-phosphorus coating can be improved.

The present application provides a ternary cathode material, a method for preparing the same, a cathode plate, a secondary battery, and an electronic device. The ternary cathode material includes a ternary cathode material matrix including a doped region. The doped region includes an aluminum-rich doped region distributed within a bulk phase of the ternary cathode material matrix, and a titanium-rich doped region distributed in a surface layer of the ternary cathode material matrix.