706 results about "Functional composite" patented technology

The invention relates to a biodegradable high-strength medical soft tissue adhesive as well as a preparation method and application thereof. The medical soft tissue adhesive comprises a soft segment, a hard segment and a hard segment chain extender, the soft segment is a polyethylene glycol polymer; the hard segment is isocyanate; the hard segment chain extender comprises a hard segment electrically neutral chain extender and a hard segment ionized chain extender; the molar ratio of the polyethylene glycol polymer to the isocyanate to the hard segment electrically neutral chain extender to the hard segment ionized chain extender is (1-7): (50-95): (14-20): (2-6). The preparation method comprises the following steps: mixing the polyethylene glycol polymer, the hard segment chain extender and the isocyanate, heating and reacting to obtain a mixed reaction system; cooling after the reaction is completed, adding a rheology modifier, a foaming catalyst and a stabilizer into the mixed reaction system, and uniformly mixing to obtain the biodegradable high-strength medical soft tissue adhesive which is suitable for functional composite materials.

The invention discloses a polypyrrole / cobalt / nitrogen-doped carbon composite material with a coaxial hollow structure and a preparation method thereof, and belongs to the technical field of advanced functional composite materials. The method comprises the following steps: firstly, synthesizing a hollow polypyrrole nanotube by a soft template method; secondly, cobalt / nitrogen-doped carbon is synthesized by adopting a template guiding method; and finally, secondarily coating the outer surface of the cobalt / nitrogen-doped carbon with a polypyrrole layer by adopting an in-situ oxidative polymerization method to construct the polypyrrole / cobalt / nitrogen-doped carbon composite material with a coaxial hollow heterostructure, and the polypyrrole / cobalt / nitrogen-doped carbon composite material has a coaxial sandwich structure: the inner core is a nitrogen-doped carbon hollow tube, the middle layer is a nitrogen-doped porous carbon matrix embedded with cobalt nanoparticles, and the outer surface of the cobalt / nitrogen-doped carbon composite material is a porous carbon matrix embedded with cobalt nanoparticles. And the outer layer is a conductive polypyrrole coating layer. The preparation method provided by the invention can successfully realize in-situ confinement growth and stable combination of ZIF-67, and has the advantages of high repetition rate, high yield and simple method; by adjusting the proportion of polypyrrole in the composite material, good impedance matching and large dielectric loss can be realized, and excellent electromagnetic wave absorption performance can be obtained.

The invention relates to the technical field of antibacterial and antifouling fabrics, provides a preparation method of an antibacterial and antifouling fabric, and solves the problem of poor fabric durability caused by single functional component and lack of physical protection in the prior art. The preparation method comprises the following steps: S1, preparing MOFs loaded antibacterial fibers: blending a metal organic framework antibacterial composite nanomaterial and a polymer matrix material, and carrying out melt spinning to prepare the MOFs loaded antibacterial fibers; s2, constructing a self-cleaning functional coating: dispersing the fluorinated nanoparticles and a polymer adhesive in a solvent to prepare a self-cleaning coating solution; s2, performing surface activation treatment on the MOFs-loaded antibacterial fiber obtained in the step S1, soaking the MOFs-loaded antibacterial fiber in the self-cleaning coating liquid, and performing pulling and curing to form a bionic micro-nano structure coating on the surface of the MOFs-loaded antibacterial fiber so as to obtain a functional composite fiber; s3, spinning forming: taking the functional composite fibers obtained in the step S2 as warp yarns and / or weft yarns, and weaving to obtain the antibacterial and antifouling fabric.

The invention discloses a heat-dissipation flame-retardant composite material as well as a preparation method and application thereof, and belongs to the field of functional composite materials. The preparation method comprises the following steps: S1, mixing a ceramic filler with a phosphorus-containing modifier, and carrying out inorganic modification to obtain a first modified filler; s2, mixing the first modified filler with an organic modifier to obtain a second modified filler; s3, mixing the second modified filler with the polymer matrix to obtain the heat-dissipation flame-retardant composite material. The organic modifier is at least one of polysilazane, polysilazane and polysiloxane. The phosphorus-containing modifier and the organic modifier are adopted to modify the ceramic filler, so that the flame retardant property, the thermal stability and the high temperature resistance of the composite material are improved, the compatibility between the ceramic filler and the filler and between the filler and a polymer substrate is improved, the dispersity of the ceramic filler in the polymer substrate is improved, and the thermal resistance of the composite material is reduced; and the heat dissipation capability of the composite material is improved.

The invention relates to the field of electromagnetic functional composite materials, and particularly discloses a multi-layer composite structure flexible frequency selective surface material and a preparation method thereof. The ultra-high molecular weight polymer fiber-reinforced polymer-based composite material thin-film mechanical enhanced band-pass frequency selection array sequentially comprises an acrylic acid polyvinylidene fluoride organic polymer coating environment-resistant layer, a metal oxide organic film isolation layer, an ultra-high molecular weight polymer fiber-reinforced polymer-based composite material thin-film mechanical enhanced layer, a band-pass frequency selection layer and a packaging protection layer from top to bottom, and the band-pass frequency selection layer is a hexagonal / circular ring nested band-pass frequency selection pattern array. The packaging protection layer is formed by printing a conductive coating composed of conductive filler / polymer resin matrix, and the packaging protection layer is an ink coating. The flexible frequency selective surface material has the characteristics of light weight, high strength, salt fog / rain / ultraviolet and other severe environments, frequency selective wave transmission and multiple functions, has good gas barrier property, is beneficial to maintaining the shape of an inflatable hangar made of a skin and ensuring normal operation of radar equipment, and has good practical engineering application value.

The invention relates to a multi-modal multifunctional composite metasurface design method and device and a medium, and the method comprises the steps: carrying out the parameterized sampling of the key size of a unit structure through Latin hypercube sampling, and generating a training sample set; electromagnetic simulation is carried out on the sampled structure to obtain two-state electromagnetic response data, and a mixed variable database is obtained; according to the target response, generating a plurality of groups of candidate structures through a generator in the improved conditional variation auto-encoder generative adversarial network, screening the candidate structures through a predictor, calculating a prediction comprehensive error, and selecting a preset number of candidate structures with the minimum prediction comprehensive error to perform full-wave simulation verification; and obtaining a simulation double-state response, calculating a simulation comprehensive error, and judging the current candidate structure according to a preset comprehensive error threshold value. Compared with the prior art, the method has the advantages of multi-state collaboration, low calculation cost, high degree of freedom and the like.

The invention provides a preparation method of a full-hydrophilic composite material with a pore diameter gradient and a one-way moisture conduction function. A double-layer hydrophilic composite layer with a pore difference structure is prepared by adopting a means of combining an electrostatic spinning process and a spunlace non-woven process, so that the one-way moisture conduction function is realized. The preparation method comprises the following steps: firstly preparing a hemp / viscose spunlace non-woven layer, then preparing a polylactic acid / chitosan nanofiber membrane through an electrostatic spinning process, and finally compounding the hemp / viscose spunlace non-woven layer and the polylactic acid / chitosan nanofiber membrane to prepare the composite material with the one-way moisture conduction function. The two hydrophilic layers with fiber diameter difference and pore size difference are compounded through a double-layer assembly strategy, the composite material with a brand-new structure and a one-way moisture guiding function is constructed, the composite material has a good one-way liquid conveying function, the continuous one-way moisture guiding function is achieved, and the composite material is suitable for large-scale popularization and application. Wide application prospects are realized in the fields of textile clothing, medical and health materials and the like.

The invention belongs to the technical field of functional composite fibers, and discloses a wear-resistant nanofiber-reinforced protective graphene fiber and a preparation method and application thereof.The wear-resistant nanofiber-reinforced protective graphene fiber comprises a graphene fiber tow and nanofibers, the nanofibers coat the graphene fiber tow in a three-dimensional porous network mode, and the nanofibers coat the graphene fiber tow in a three-dimensional porous network mode. Forming a stress buffer layer; wear-resistant particles are uniformly loaded in the three-dimensional porous network; the preparation method comprises the following steps: fixing the graphene fibers subjected to surface pretreatment on an electrostatic spinning nano-yarn machine, forming a nano-fiber membrane by utilizing electrostatic spinning, uniformly wrapping the graphene fibers subjected to surface pretreatment with the nano-fiber membrane, then rolling into a shaft, and then carrying out hot-pressing roller treatment on the rolled fiber bundle, so as to obtain the graphene nano-yarn. The wear-resistant nanofiber reinforced protective graphene fiber is prepared; the graphene fiber is used for weaving to obtain the graphene fiber fabric. The fiber prepared by the invention and a fabric woven by using the fiber have excellent mechanical properties, wear resistance, electric conductivity and heat conductivity.

The invention relates to a soft electronic device based on a particle phagocytosis effect and a preparation method thereof, and the preparation method comprises the following steps: S1, attaching a hollow mask plate to a polymer substrate, and controlling the position where the polymer substrate can be printed; s2, uniformly dispersing micro-nano particles on the mask plate, wherein the micro-nano particles are in contact with the polymer substrate at the hollowed-out part of the hollowed-out mask plate; s3, after the micro-nano particles make contact with the polymer substrate, the micro-nano particles gradually enter the polymer substrate through the particle phagocytosis effect, and a functional composite material is formed; and S4, removing the hollow mask plate to form the soft electronic device. According to the method, the micro / nano material is directly printed in the soft polymer matrix without introducing a solvent, so that chemical incompatibility and complex fluid dynamic behaviors are avoided. The surface energy-driven particle phagocytosis phenomenon is utilized to realize deep embedding of the material, spontaneous generation is realized, and additional introduction of energy is not needed. Different materials can be seamlessly integrated into the high-performance elastic electronic equipment. Multi-material wireless electronic equipment is created through a multi-layer phagocytic printing technology, and layered printing can be achieved.

The invention provides a functional composite one-dimensional metal cavity slot array antenna, which belongs to the field of antennae, and comprises a feed cavity and a cover plate located at the top of the feed cavity, a plurality of groups of periodic intermediate-frequency anti-interference metal blocks and high-frequency anti-interference metal blocks are arranged in the feed cavity, and a radiation slot is formed in the cover plate. The polarization conversion structures are arranged on the two sides of the radiation slot in a stepped and open manner to form an undulating shape; an antenna array is also provided. An anti-interference periodic structure is embedded in the feed cavity, the antenna is endowed with anti-interference capacity in multiple different frequency bands, the polarization conversion structures are arranged on the two sides of the radiation slot in a stepped and open mode to form an undulating shape, an electromagnetic signal is input into the feed cavity, linearly polarized electromagnetic waves are radiated outwards through the radiation slot, and the antenna is formed. Linear polarization electromagnetic waves are decomposed into a group of orthogonal components with the same amplitude after passing through the polarization conversion structure, a 90-degree phase difference exists between the two components, circular polarization is formed to radiate towards the space, the polarization conversion structure is simple in structure and convenient to process, and the scattering characteristic of the antenna is improved.

The invention discloses a multi-action compound server liquid cooling method, which comprises the following steps of: forming an interlayer by adopting a partition plate, placing a server in the interlayer of the partition plate, immersing the server in a flowing liquid-phase cooling liquid for cooling, arranging a spray head above the partition plate to spray a phase-change cooling liquid, and driving the phase-change cooling liquid to be subjected to phase-change gasification by utilizing air flow to take away heat. And multiple composite cooling heat dissipation is realized. According to the invention, a multi-effect composite cooling mode is adopted, the cooling efficiency and the cooling effect are better, the problem of heat explosion in a local area of a server can be solved, and the overall working efficiency and the safety of a server chip are better improved.

The invention relates to the technical field of functional composite probe material preparation, in particular to a three-core spinning technology-based bio-compatible gel probe and a preparation method thereof, and the three-core spinning technology-based bio-compatible gel probe comprises a composite skin layer and three functional core layers; the composite skin layer is composed of a sodium alginate-polydopamine-chitosan grafted copolymer in a mass ratio of 2: 1: 0.5, and contains # imgabs 0 # chondroitin sulfate and # imgabs 1 # polyoxyethylene; the three core layers are respectively a carbon nanotube-polyaniline # imgabs2 # hybrid material, a graphene-polypyrrole-boron nitride hybrid material and a # imgabs3 # polythiophene-hydroxyapatite hybrid material, and the mass ratio of the carbon material to the conductive polymer to the newly added nano material in each core layer is 1: 2: 0.3; and the diameter ratio of the skin layer to the three core layers is 1: 0.28: 0.22: 0.17. According to the invention, multichannel signal transmission is realized, the impedance is reduced by the hybrid material, and the conductivity is improved; the composite skin layer is matched with soft tissue mechanical properties, and interface bonding is stable; and the biocompatible component reduces inflammation, is suitable for acquiring nerve electrophysiological signals, and is easy for large-scale production.

The invention provides a wave-absorbing material, and belongs to the technical field of electromagnetic wave absorption. The wave-absorbing material comprises a metal reflection bottom layer, a wave-absorbing middle layer and a scattering upper layer, the wave-absorbing middle layer is made of a ferroferric oxide loaded reduced graphene oxide and epoxy resin (Fe3O4 (at) RGO / EP) composite material and used for absorbing electromagnetic wave energy, and the scattering upper layer is of a patterned metasurface structure made of chopped carbon fiber reinforced epoxy resin (SCF / EP). And a phase-regulated two-dimensional periodic array is formed. By arranging a three-layer structure of the metal reflecting layer, the Fe3O4 (at) RGO / epoxy composite wave-absorbing layer and the chopped carbon fiber scattering layer, broadband absorption and directional scattering control of electromagnetic waves within the range of 2-18 GHz are achieved, a stealth function composite material system with dissipation and deflection dual-mechanism cooperative work is formed, the structure utilizes the patterning design of the scattering layer, and the structure has the advantages that the structure is simple, the structure is compact, and the application range is wide. On the basis of the generalized Snell's law, engineering regulation and control of the radar wave reflection direction are achieved by regulating and controlling the reflection phase difference between pattern units, reflection energy is effectively deviated from the main lobe direction of a radar receiver, and therefore the reflection signal intensity of a target in a radar detection system is reduced.

The invention relates to a high-temperature electromagnetic functional composite coating and a preparation method thereof, belongs to the technical field of high-temperature electromagnetic functional materials, and solves the problems of narrow absorption frequency band, low absorption loss, poor temperature resistance, poor corrosion resistance, poor environmental medium resistance and poor mechanical property of the existing high-temperature electromagnetic functional coating. From the surface of the substrate from inside to outside, the high-temperature electromagnetic functional composite coating comprises a bonding layer, a protective layer, a functional layer and a surface layer, and the functional layer is made of a thermal spraying composite ceramic material; the multi-layer structure of each layer of the composite coating is mutually coordinated and matched, so that the temperature resistance, the corrosion resistance and the environmental medium resistance of the coating are improved, the electromagnetic wave absorption efficiency is improved, and the service life is prolonged; in addition, the composite ceramic material forming the functional layer has multiple loss mechanisms, the electromagnetic wave absorption frequency band is further widened, and the absorption loss is improved.

The invention provides a monolithic integrated multifunctional composite sensor and a preparation method thereof, a single silicon wafer single-sided bulk silicon micro-manufacturing technology is adopted, a first microgroove of a gas flow sensing unit is pre-defined and covered, a pressure reference cavity and a pressure sensitive diaphragm are firstly formed, and then through protection of the first microgroove and a side wall, the gas flow sensing unit and the pressure reference cavity are combined. A monocrystalline silicon thermocouple arm and a heating resistor pattern are pre-defined, then a pressure sensing unit is protected through a heat insulation medium layer, then a heat insulation cavity and a temperature sensing unit are formed, and finally the gas flow sensing unit, the pressure sensing unit and the temperature sensing unit are integrated on the same single chip. The structure that the heat insulation cavity and the pressure reference cavity are located in the same monocrystalline silicon substrate is achieved. According to the method, the traditional double-sided processing technology is replaced, the problem that the small size of the traditional composite chip is difficult to realize is solved, the complex process caused by the traditional silicon-silicon or silicon-glass bonding structure is avoided, the process difficulty and cost are greatly reduced, the yield of the composite chip is improved, and the reliability of the sensor is improved.

The present invention belongs to the technical field of functional composite fibers, and discloses a wear-resistant nanofiber-reinforced and protected graphene fiber, a preparation method thereof and an application. The wear-resistant nanofiber-reinforced and protected graphene fiber comprises a graphene fiber bundle and nanofibers. The nanofibers coat the graphene fiber bundle in the form of a three-dimensional porous network to form a stress buffer layer; wear-resistant particles are uniformly loaded inside the three-dimensional porous network. The preparation method is as follows: fixing the surface-pretreated graphene fiber on an electrospinning nanofiber yarn machine, forming a nanofiber membrane by electrospinning and uniformly wrapping it on the surface-pretreated graphene fiber, then winding it into a roll, and then performing a hot roll treatment on the wound fiber bundle to obtain the wear-resistant nanofiber-reinforced and protected graphene fiber. The application is: used for weaving to obtain a graphene fiber fabric. The fiber prepared by the present invention and the fabric woven therefrom have excellent mechanical properties, wear resistance, electrical conductivity and thermal conductivity at the same time.

The invention belongs to the field of functional composite materials, and particularly relates to low-viscosity and high-dispersity aluminum oxide slurry and a preparation method thereof.The low-viscosity and high-dispersity aluminum oxide slurry is prepared from a newly-designed phosphono-carboxyl block copolymer and biquaternary ammonium salt polyether silane as composite modifiers; and efficient anchoring and stable dispersion of the surfaces of alumina particles are realized through the synergistic effect of molecular structures. The phosphono-carboxyl block copolymer is prepared through controllable polymerization and deprotection reaction, and strong chemical bonding is formed between a phosphono group and the surface of aluminum oxide; the biquaternary ammonium salt polyether silane is subjected to click chemical synthesis, and electrostatic adsorption of quaternary ammonium salt and the steric hindrance effect of a polyether chain are combined. When the slurry is prepared, the two modifiers are sequentially added into water, the aluminum oxide powder is added after the pH value is adjusted, finally, the isobutylene maleic anhydride copolymer and the defoaming agent are introduced, and the slurry is obtained through vacuum defoaming and filtering. The slurry prepared by the method has the characteristics of high solid content, low viscosity and good dispersion stability.

The invention relates to the technical field of special functional coating materials for lost foam casting, and particularly discloses a special coating for a large machine tool casting lost foam as well as application and a use method of the special coating. According to the invention, the full-temperature-range functional composite material and the composite aggregate are used for synergistic reinforcement, and mullite is used for high-temperature reinforcement; the temperature-sensitive polymer modified graphite can realize intelligent temperature response of graphite performance; spodumene is used as a thermal expansion adaptive fluxing agent, so that medium-temperature healing and thermal expansion adjustment of a coating system are facilitated; the composite reinforced fibers are reinforced and toughened aiming at large thermal stress of thick and large parts; as an ultralow-temperature glazing agent, the boron-containing glazing agent can form an initial liquid phase at about 450 DEG C to seal the surface of the coating and purify a ventilation channel; the rare earth oxide serving as a high-temperature phase stabilizer can be dissolved in mullite crystal lattices, so that the high-temperature phase stability is improved, and ceramic nodes are refined. Through raw material design, on the premise of ensuring moderate air permeability, the ultrahigh strength and crack resistance of a coating system at extremely high temperature are improved.

The invention provides a multifunctional carbon fiber lithium battery based on a sulfide composite electrolyte membrane and a preparation method and application of the multifunctional carbon fiber lithium battery, and belongs to the technical field of lithium batteries and functional composite materials. According to the invention, a nitrogen phosphide interface layer is constructed on the surface of a sulfide electrolyte membrane or a nitrogen phosphide derivative is dispersed in a bulk phase, so that the stability of an electrolyte and a metal lithium interface is effectively improved, and lithium dendrites are inhibited; and by combining the multifunctional characteristics of the carbon fiber and glass fiber woven cloth, high specific energy and light weight can be realized, the overall safety and mechanical strength are enhanced, and the composite material is suitable for various high-performance energy storage occasions.

The invention belongs to the technical field of phase-change composite materials, and in order to solve the problem that thermal management and electromagnetic shielding functions of the phase-change composite materials cannot be compatible, polyethyleneimine (PEI) and carboxymethyl cellulose (CMC) are added into a titanium carbide (Ti3C2Tx) nanosheet (MXene) aqueous dispersion to be uniformly dispersed to obtain a mixed solution, directional freezing is performed in liquid nitrogen, vacuum freeze drying is performed to obtain an MXene-based aerogel skeleton MCP, and the MXene-based aerogel skeleton MCP is prepared into the phase-change composite material. The phase-change composite material with a stable shape is obtained by vacuum impregnation and adsorption of a phase-change material in a molten state, not only has excellent thermal conductivity and electrical conductivity, but also has stable electrothermal conversion energy storage capacity and good electromagnetic shielding performance, and provides opportunities for meeting multi-scene response and practical application of multifunctional composite materials.

The invention discloses a wave-absorbing material based on a bionic cobweb structure and a preparation method and application thereof, and belongs to the technical field of functional composite materials. The material comprises a bionic cobweb flat plate, the bionic cobweb flat plate has a cobweb-like structure; the cobweb-like structure is composed of n fan-like areas; meanwhile, the cobweb-like structure is formed by overlapping a framework and second fibers, the framework is formed by arranging n first fibers around the axis in the same plane in the radial direction, no cross-linking point exists between any two first fibers, a plurality of second fibers are arranged on every two adjacent first fibers, and the lengths of the second fibers are sequentially increased in the radial direction; and the second fibers in the bionic cobweb flat plate are non-continuously arranged along the circumferential direction. According to the wave-absorbing material, the periodicity, the structural anisotropy and the node enhancement of a special network structure are combined with the discontinuous conductive network design, and the excellent impedance matching and electromagnetic wave attenuation capacity is achieved at the same time.

The invention discloses a three-dimensional porous graphene / ferric oxide electromagnetic shielding composite film and a preparation method thereof, and belongs to the technical field of functional composite materials. In order to reduce or eliminate electromagnetic radiation, the three-dimensional porous rGO / Fe3O4 composite material is prepared by taking nano Fe3O4 and GO as raw materials and adopting a graphene oxide reduction self-assembly nanoparticle capturing method. The porous 3D rGO / Fe3O4 composite electromagnetic shielding material is obtained by mixing a dispersing agent and Fe3O4, adding the mixture into a graphene oxide dispersion liquid and capturing nano Fe3O4 through a graphene oxide reduction self-assembly process. Drying the 3D rGO / Fe3O4, and then mixing the 3D rGO / Fe3O4 with waterborne polyurethane to prepare an rGO / Fe3O4 / waterborne polyurethane composite coating; and coating the slurry on a base material to prepare the rGO / Fe3O4 electromagnetic shielding film. The preparation process is simple and easy to control, and raw materials are low in cost, easy to obtain and environmentally friendly; the graphene-based composite electromagnetic shielding material which is light in weight, high in strength, good in stability, good in flexibility and high in electromagnetic shielding efficiency can be prepared at present.

The invention relates to a damp-proof multifunctional air bubble film packaging bag which comprises a first air bubble film and a second air bubble film which are oppositely arranged, the first air bubble film and the second air bubble film comprise the first air bubble film and the second air bubble film which are oppositely arranged, and the three edges of the first air bubble film and the three edges of the second air bubble film are connected with edge sealing layers in a sealed mode. A top sealing structure is arranged on the outer surfaces of the upper ends of the first air bubble film and the second air bubble film, a fixing strip is fixedly connected to the inner surface of the front end of the top sealing structure, and the top sealing structure comprises a second sealing strip and a first sealing strip. The packaging bag has the beneficial effects that many defects of a traditional packaging bag in the aspects of moisture resistance and sealing performance are effectively overcome, the packaging bag has excellent physical protection performance and functional characteristics through the design of the six-layer functional composite film structure, the durability of the packaging bag is greatly improved through the arrangement of the anti-abrasion layer, and the effect that damage caused by friction in the transportation process is avoided.

The invention relates to a degradable high-strength medical adhesive and a preparation method and application thereof.The medical adhesive is prepared from raw materials through reaction, the raw materials comprise a component A, a component B and a component C. The component A is trihydric alcohol and derivatives thereof and / or trihydric alcohol modified by polyethylene glycol carboxylic acid derivatives and derivatives thereof, and the component C is trihydric alcohol modified by polyethylene glycol carboxylic acid derivatives and derivatives thereof. The component B is isocyanate, amino acid or an amino acid derivative, and the component C is N-methyldiethanolamine and / or bis (2-ethoxyl)-N-methyl-N-trifluoromethyl ammonium iodide and a derivative of the bis (2-ethoxyl)-N-methyl-N-trifluoromethyl ammonium iodide; the molar ratio of-NCO groups in the component B to total-OH groups in the component A and the component C is 2: 1, and the molar ratio of the component A to the component C is (1-9): 2. The component A and the component C are mixed, heated and dissolved, then a catalyst and the component B are added, and a mixed reaction system is obtained; and cooling after the reaction is completed, adding a rheology modifier, a foaming catalyst and a stabilizer, and uniformly mixing to obtain the degradable high-strength medical adhesive which can be applied to a functional composite material.

A multi-layer and multi-functional composite structure includes a structural reinforcing portion configured to provide structural support. The structural reinforcing portion includes reinforcing fibers consolidated in a thermoplastic resin. A protecting portion is arranged on one side of the structural reinforcing portion and configured to provide at least one of thermal blocking and fire resistance. A shielding portion is arranged on an opposite side of the structural reinforcing portion and configured to shield electromagnetic interference (EMI).

The invention provides a multifunctional structure energy storage composite material and a preparation method thereof, and belongs to the technical field of multifunctional composite materials. The carbon fiber reinforced matrix and the optimized special-shaped structure design are combined, excellent mechanical strength and rigidity are provided, so that high mechanical performance is achieved, meanwhile, due to application of the multi-stage conductive network and the electrolyte layer, the conductivity of the electrode and the utilization rate of active substances are remarkably improved, and excellent electrochemical performance is achieved. By introducing the multi-stage conductive network, the resin-based electrolyte and the optimized special-shaped structure design, the technical breakthrough is realized, the structural energy storage composite material with high performance (mechanical and electrochemical performance) is obtained, and the actual application requirements are met.

The invention belongs to the technical field of bio-based polyurethane functional composite materials, and relates to a preparation method and application of a cellulose / polyurethane functional composite material based on a Diels-Alder reaction, the preparation method comprises the following steps: mixing furan functionalized cellulose nanofibers with maleimide-terminated waterborne polyurethane, and carrying out copolymerization through the Diels-Alder reaction to obtain the cellulose / polyurethane functional composite material based on the Diels-Alder reaction. The cellulose / polyurethane functional composite material is prepared. Compared with the prior art, the method has the advantages that a reversible dynamic covalent network is generated through Diels-Alder reaction to endow the material with self-healing and recoverability, so that the material realizes self-healing under temperature fluctuation, the service life is prolonged, the sustainability is improved, and the problem of poor compatibility of biomass components and a polyurethane matrix in a traditional mixing method is solved; the cellulose nanofiber / polyurethane composite material is endowed with good mechanical properties, high-temperature strength and low-temperature toughness.

The invention belongs to the field of functional composite fabrics, and provides a mosquito-repellent thermoplastic polyurethane composite fabric and a preparation method thereof.According to the mosquito-repellent thermoplastic polyurethane composite fabric and the preparation method thereof, the design that mosquito-repellent microcapsules of a core-shell structure are dispersed in a thermoplastic polyurethane hot melt adhesive layer is adopted, a microcapsule core layer comprises mosquito-repellent active ingredients such as icaridin, deet or dimethyl phthalate, and the mosquito-repellent active ingredients are dispersed in a thermoplastic polyurethane hot melt adhesive layer; the shell layer is made of a polyurea material and is prepared through an interfacial polymerization method, high-load stable dispersion and controllable dot matrix film forming of the microcapsule in a hot melt adhesive system are achieved, the content of the microcapsule can reach 0.5-15 wt%, the particle size is controlled to be 0.1-2.0 m, the drug loading capacity reaches 10-60 wt%, the problem that the mosquito-repelling microcapsule is prone to damage and failure in the high-temperature melting mixing and hot-pressing compounding process is solved, and the mosquito-repelling microcapsule has good application prospects. The prepared composite fabric is high in mosquito repelling rate, still keeps an effective mosquito repelling function after being washed for multiple times, and has a wide application value.

The invention discloses a high-strength, light-weight and multifunctional composite shell for a warhead, and relates to the field of ship protection, the composite shell comprises a front protection layer, a rear protection layer and a composite sandwich panel arranged between the front protection layer and the rear protection layer, the composite sandwich panel is of a honeycomb structure, and the composite sandwich panel is of a honeycomb structure. The honeycomb structure is filled with energy-absorbing substances. The energy absorption substance is shear thickening glue doped with silicon dioxide particles. By manufacturing the light multifunctional composite shell and integrating the energy absorption layer, the impact resistance and fragment penetration resistance of the shell are improved. Material distribution is optimized, light weight and structural strength are balanced, a shear thickening material (STG) is added, and multi-dimensional energy dissipation is achieved.

The invention discloses a functional composite fabric multi-layer collaborative printing and dyeing process and device, and belongs to the technical field of composite fabric printing and dyeing. The device comprises a plurality of sets of base material processing units arranged in parallel, an online alignment device, a composite unit, a quality detection unit and a digital twinning control unit, wherein each set of base material processing unit comprises an unwinding device, a plasma pretreatment device and a dynamic energy template printing and color fixing device which are sequentially arranged; the dynamic energy template printing and color fixing device is integrated with a multi-channel feeding system, the dynamic template of the pattern and the energy field applying module can be controlled by an electric signal, and synchronous printing and dyeing and targeted color fixing of base materials made of different materials are achieved. Parameters are optimized through digital twinning modeling, plasma pretreatment, pattern printing and energy color fixation are synchronously carried out on all layers of base materials, then accurate alignment and hot-pressing compounding are carried out, and a digital twinning control unit carries out whole-process cooperative control and closed-loop feedback.