The invention respectively discloses bullet-resistant glass and fireproof glass for insulating heat and resisting radiation, as well as and compound glass thereof, which respectively comprise laminated safety glass, bullet-resistent glue and/or fire-retardant glue and an outer-layer glass substrate, wherein the outer-layer glass substrate is bonded on the surface of the laminated safety glass by the bullet-resisting glue and/or the fire-retardant glue; and the laminated safety glass comprises two inner-layer glass substrates and an organic laminated adhesive material which is arranged between the two inner-layer glass substrates. The bullet-resistant glass and the fireproof glass not only can resist bullets and fire, but also can absorb ultraviolet rays, near infrared rays and strong dazzling light to insulate heat, prevent freeze, resist bright light, strong heat, the penetration of harmful radiant rays for human bodies, and the like, can prevent rain pulverization, snow adhesion and self-pulverization of glass under strong shock waves, realize self protection, and the like.