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Efficient flocculent precipitate purification method for polymetallic ore benefication wastewater

The invention discloses an efficient flocculent precipitate purification method for polymetallic ore benefication wastewater. Specifically, the purification method comprises the steps of: neutralizing and regulating the pH value of benefication wastewater by adopting a little amount of alkaline materials; then sequentially feeding a proper amount of proper suitable flocculant for efficient flocculation and a little amount of efficient coagulant aids for fast precipitation; separating sludge from water through action of a partition wall, wherein the treated wastewater achieves primary standardof national Integrated wastewater discharge standard (GB8978-1996); through SV30 evaluation; settling for 5minutes to achieve 45-55mL of supernatant by volume; and settling for 15 minutes to achieve 70-80mL of supernatant by volume. The purification method can fully utilize the traditional benefication wastewater lime and sedimentation process, is simple in procedure, and can simultaneously remove suspended particulate matters, organic matters and heavy metal ions in wastewater, is high in flocculation efficiency and fast in sedimentation speed, and can better solve the purification problem of the low-concentration and high-tubidity polymetallic ore benefication wastewater of multiple heavy metals.
Owner:CENT SOUTH UNIV

Polyaluminum calcium hydroxychlorides and methods of making the same

A process is provided for the preparation of a novel polyaluminum calcium hydroxychloride composition of enhanced efficiency for water treatment, paper sizing, and antiperspirant applications. The polyaluminum calcium hydroxychloride compositions are prepared via the acidification of higher basicity reaction products to form mid-to-high basicity final products. Two methods are provided for the preparation of higher basicity products, contemplated in the first, and an aqueous acid solution, such as hydrochloric acid, aluminum chloride, or a mixture thereof, is mixed with a strong alkaline calcium salt such as calcium oxide or calcium carbonate and aluminum powder at temperatures greater than 60° C. In a second method, bauxite, aluminum hydrate, or aluminum metal, and calcium aluminate are mixed with hydrochloric acid and are reacted at high temperatures and / or elevated pressures for a certain period of time whereby, when the reaction is complete, the mixtures are filtered to obtain clear solutions. The final PAC-Ca solutions may be dried to powder to have a wide range of basicities from about 40% to about 80%. At lower basicities, the polyaluminum calcium hydroxychloride sales are used preferably as antiperspirants, while at higher basicities, the solutions are used preferably as water treatment chemicals.
Owner:GENERAL CHEM LLC

Comprehensive electroplating wastewater treating agent

The invention relates to a comprehensive electroplating wastewater treating agent. The comprehensive electroplating wastewater treating agent is composed of the following components in percentage by mass: 10-35% of reducing agent, 20-50% of sulfide, 10-30% of aluminum salt, 10-30% of adsorbing material and 5-15% of alkaline substances. The raw materials of the treating agent provided by the invention are low in cost and easy to obtain, and the treating agent is easy to prepare; through compounding the raw materials, a synergistic effect is exerted, and the treating agent is favorable in broad spectrum, capable of effectively removing heavy metals such as nickel, chromium, copper, zinc and the like, high in removal rate up to more than 96% and relatively good in COD (Chemical Oxygen Demand) removal effect; the comprehensive electroplating wastewater treating agent also has the characteristics of strong electroplating wastewater treating capacity, high heavy metal ion sedimentation speed and efficiency, no secondary pollution after treatment and the like; in addition, the treating agent provided by the invention is convenient to use, simple and feasible in treating process, capable of realizing operation by only using a vessel or pool with an aerating agitation device, reducing the floor area and reducing the investment, and easy to realize operation management.
Owner:浙江一清环保工程有限公司

Polymetallic-ore-dressing wastewater coagulating sedimentation device and method

The invention discloses a polymetallic-ore-dressing wastewater coagulating sedimentation device and a polymetallic-ore-dressing wastewater coagulating sedimentation method. The process comprises the following main devices: a coagulation reaction tank, a flocculation, sedimentation and separation integrated device and a separation wall. The process flows are as follows: the polymetallic-ore-dressing wastewater fully reacts with a coagulant in the coagulation reaction tank to enable the wastewater to be destabilized quickly and flocculated efficiently; the coagulated wastewater enters the flocculation, sedimentation and separation integrated device to fully react with coagulant aid to further perform flocculation coarsening and fast sedimentation, so that high-efficiency mud-water separation is realized; and the processed wastewater is discharged directly or deeply purified by the separation wall to be recycled. The device and the method can effectively solve the problems that in the polymetallic-ore-dressing wastewater treatment, the flocculent precipitation is instable, the flocculation time and sedimentation time are long and the like, and can quickly perform destabilization and realize high-efficiency flocculation, high-efficiency sedimentation and high-efficiency separation. The device and the process flow are simple and practical, the wastewater purifying efficiency can be remarkably improved and the effluent water quality is stable and reaches the standard.
Owner:CENT SOUTH UNIV

Technique for purifying and producing industrial phosphoric acid by wet-process phosphoric acid

The invention relates to the technique for purifying and producing industrial phosphoric acid by wet-process phosphoric acid, which comprises the following steps of: (1) desulfurization and defluorination sedimentation-filtration process; (2) the extraction of wet-process phosphoric acid after desulfurization and defluorination process; (3) the washing of organic phase after extraction; (4) the back extraction of the organic phase after washing; (5) the refining of aqueous phase after the back extraction; (6) concentrating till containing 85wt% H3PO4 and recycling organic solvent. The technique has the beneficial effects that (1) the wet-process phosphoric acid produced by adopting the existing sulfuric acid process does need to be preconcentrated; (2) compound extracting agent of the technique has good suitability for the extraction of the wet-process phosphoric acid; (3) the compound extracting agent has better separating effect on iron ions and other heavy metal ions; (4) emulsion generated by the organic phase in the washing process can be eliminated by a warming/stewing mode; (5) the technique adopts amidine fiber adsorption column to refine wet-process phosphoric acid and can effectively absorb trace metal ions, and the clearance of the metal ions can reach 99 wt%.
Owner:WUHAN INSTITUTE OF TECHNOLOGY +1

Treatment method of heavy metal wastewater

The invention provides a treatment method of heavy metal wastewater, and particularly relates to a method for treating heavy metal wastewater by virtue of a precipitation method. The method comprises the following steps: adding sodium sulfide in a heavy metal wastewater treatment process, reacting sulfur ions with heavy metal ions in the wastewater to generate particulate matters, further adding sulfide precipitates of heavy metal, stirring, standing, and accelerating the sedimentation of micro particulate matters and other substances by using generated particulate matter precipitates; further preferably adding quartz sand, and accelerating the rapid sedimentation of the particulate matters and other substances under the wrapping action of quartz sand; further performing subsequent process treatment including sand filtration and ion exchange on a supernatant liquor obtained after sedimentation to reach the emission standard; and periodically discharging and collecting part of the precipitates, and recycling heavy metals in the precipitates. Because the method provided by the invention is simple in working procedure, low in cost and high in efficiency, the method can be widely applied to the treatment of industrial wastewater particularly the heavy metal wastewater.
Owner:HARBIN INST OF TECH SHENZHEN GRADUATE SCHOOL

Purifying treatment agent for coal-washing wastewater and preparation method thereof

The invention discloses a purifying treatment agent for coal-washing wastewater and a preparation method thereof. The purifying treatment agent is prepared from the following materials in parts by weight: 30-40 parts of sepiolite, 15-20 parts of montmorillonite, 10-15 parts of medical stone, 15-20 parts of polyacrylamide, 5-10 parts of sodium polyacrylate, 3-6 parts of aluminium polychlorid, 2-4 parts of sodium lignin sulfonate, 3-5 parts of alum powder, 6-9 parts of ferrous sulfate, 8-12 parts of guar gum powder, 5-10 parts of nano carbon, 4-8 parts of porous calcium phosphate, 10-15 parts of carboxymethyl chitosan, 5-10 parts of sodium alginate, 2-3 parts of span-80, 1-2 parts of sodium lauryl sulfate, 1-2 parts of stearic acid and 0.5-1 parts of gamma-aminopropyltriethoxysilane. The purifying treatment agent disclosed by the invention has the advantages that the flocculation effect is good, impurity particles in coal-washing water can be rapidly agglutinate and settled, simultaneously heavy-metal elements in the coal-washing water can be absorbed, the purifying effect is very obvious, the water purifying effect is 4-6 times of that of the common flocculating agent; and the used amount is less, the efficiency is high, the cost is low, the benefit is high, the complete environmental-friendly effect is achieved and the application prospect is wide.
Owner:青岛中科菲力工程技术研发有限公司
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