The invention relates to a recycling method of chemical
polishing waste liquid, which comprises the following steps: (1) carrying out first
pH regulation treatment on the chemical
polishing waste liquid containing
phosphate radicals,
sulfate radicals, aluminum ions and + 3 valent iron ions to obtain aluminum mud and aluminum-removed liquid; (2) sequentially carrying out second
pH regulation treatment, third
pH regulation treatment and dealumination treatment on the aluminum mud to obtain a hydrated
calcium aluminate product; (3) the aluminum-removed liquid is subjected to
phosphorus removal treatment, and first
phosphorus mud and
phosphorus-removed liquid are obtained; sequentially carrying out fourth pH regulation treatment and first evaporative
crystallization treatment on the first phosphorus
sludge to obtain a
sodium phosphate product; and sequentially carrying out fifth pH regulation treatment and second evaporative
crystallization treatment on the dephosphorized liquid to obtain a
sodium sulfate product. According to the method disclosed by the invention, phosphorus,
sulfur and aluminum in the chemical
polishing waste liquid are completely separated by utilizing different
solubility of different substances in the solution when the pH value is the same, and a
sodium phosphate product, a
sodium sulfate product and a hydrated
calcium aluminate product are respectively obtained, so that complete recycling of elements in the chemical polishing waste liquid is realized, and no byproduct waste is produced.