The invention discloses an aqueous high-performance monocomponent primer-topcoat anti-corrosion coating, comprising aqueous modified acrylic acid emulsion, coloring pigment, antirust pigment, filling material, film forming auxiliary agent, thickening anti-settling agent, softened water, anti-flash rust agent, and auxiliary additive. The coating disclosed herein has excellent salt mist resistance, can resist salt mist for more than 1000h and resist weather for more than 200h, and has the characteristics of rapid drying, low content of VOC, no environmental pollution, and no harm to constructers' health. The coating disclosed therein is convenient for using, can be applied in high pressure airless spraying and ordinary air spraying, the thickness of single coating wet film can reach 200 mum without sagging or cracking, and the coating disclosed herein is widely suitable for anti-corrosion protection of locomotive, container, automobile, ship, bridge, iron tower, storage tank, pipeline and other steel structures.